Future Trends and Aging Analysis of Battery Energy Storage Systems for Electric Vehicles

The increase of electric vehicles (EVs), environmental concerns, energy preservation, battery selection, and characteristics have demonstrated the headway of EV development. It is known that the battery units require special considerations because of their nature of temperature sensitivity, aging effects, degradation, cost, and sustainability. Hence, EV advancement is currently concerned where batteries are the energy accumulating infers for EVs. This paper discusses recent trends and developments in battery deployment for EVs. Systematic reviews on explicit energy, state-ofcharge, thermal efficiency, energy productivity, life cycle, battery size, market revenue, security, and commerciality are provided. The review includes battery-based energy storage advances and their development, characterizations, qualities of power transformation, and evaluation measures with advantages and burdens for EV applications. This study offers a guide for better battery selection based on exceptional performance proposed for traction applications (e.g., BEVs and HEVs), considering EV’s advancement subjected to sustainability issues, such as resource depletion and the release in the environment of ozone and carbon-damaging substances. This study also provides a case study on an aging assessment for the different types of batteries investigated. The case study targeted lithium-ion battery cells and how aging analysis can be influenced by factors such as ambient temperature, cell temperature, and charging and discharging currents. These parameters showed considerable impacts on life cycle numbers, as a capacity fading of 18.42%, between 25–65 ◦C was observed. Finally, future trends and demand of the lithium-ion batteries market could increase by 11% and 65%, between 2020–2025, for light-duty and heavy-duty EVs.


Introduction
Electrification in transportation plays an essential role in decarbonization for reducing carbon discharge from the transportation sector by 2030 target. This process will be unreachable unless many researchers pay particular attention to CO2 emission reduction and different greenhouse gases (GHG), see [1]. Today, internal combustion engine (ICE) replacement with electrical machines [2] provides a significantly higher efficiency and is targeted worldwide, as the electrical machines can offer above 90% efficiency, while the ICE's median efficiency rate is 30% [3]. Despite numerous benefits, the utilization of EVs remains limited compared to ICE-based vehicles, the primary issue being the energy stockpile. Currently, no technologies are comparable with the specific energy and range affordability of fossil fuels, and future goals are set to satisfy the requirement of above 200 Wh/kg energy density. The flywheels [4,5] and ultracapacitors [6,7] are a few alternatives to batteries. These come with the same power restriction, a complicated process from storing and planning hydrogen fuel cells [8,9]. However, the low range of specific power Sustainability 2021, 13, 13779 2 of 28 restricts EVs' usage because almost all reasonable choices come with increasing costs and short life cycle, which eventually limits the production of EVs [10].
Commercial electrochemical batteries are currently the essential energy stockpile candidates used in EVs. For example, LCO cathodes are still the most used among Liion batteries. However, they should be replaced due to environmental, safety, and cost considerations. A greener and safer type are LMO. LFP also offers the safest and most sustainable cathodes used in hybrid BMW i5 cars. NCA and NMC are the most promising cathodes for EVs due to their capacity. Table 1 demonstrates the specific capacity and discharge midpoint of different lithium-ion batteries. The discharge is set to the midpoint as calculated based on one voltage toward Li/Li at C/20 for all cases, except LNMO, which is C/10. EVs are made with advanced electric-related components for ensuring their longlasting and efficacy runs. Factors such as selection and planning of power resources, energy stockpiles, and stockpile planning methods are important for the future of EV technology. Ensuring smooth services in EV demands planning power resources, selecting battery energy storage systems (BESS), maintaining the capacity of the stockpile cell, and causing regularity. This study [11] has reviewed the current scene of energy storage systems (ESS)s, advanced qualities of BESSs, analysis, problems, and the difficulties of current methods.

Related Works
Several review papers were published on BESS-related technologies and development [12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29]. In summary, researchers [12] have studied the state-of-the-art wired and wireless technologies in battery EVs. They introduced AC and DC charging methods, as well as conventional charging technologies. M. Naguib et al. [13] demonstrated a review on lithium-ion battery performance such as robust state of charge (SoC) prediction, and investigated on prediction algorithms used for SoC estimations. The latest status and gap in the lithium-ion battery supply chain is reported in [15], where the authors highlighted a consistent increase in demand and, subsequently, possible resource shortages. In another review paper [17], the researchers presented machine learning algorithms, such as support vector machines, neural networks, and radial basis functions for battery SoC and state of health (SoH) prediction purposes. T.A. Lehtola and A. Zahedi [18] discussed battery cell cycle aging for the vehicle-to-grid operations. This review paper studied different batteries, considering the vehicle's range, capacity, and SoC. H. Karlsen et al. [21] reviewed the challenges, criteria, and solutions in temperature dependence in battery management systems used in EVs. The authors investigated the challenges in another work and provided recommendations about the energy management systems for lithium-ion batteries utilized in EVs [22]. E. Chemali et al. [23] reviewed electromechanical and electrostatic energy storage systems and EV management. They discussed batteries, ultracapacitors, and future battery chemistries. E. Hossain et al. [24] reviewed second-life battery technologies and challenges. They studied the increasing demand for batteries in EVs, where environmental effects and effective disposal of battery production were considered. The paper guided second-life battery technologies, which can ultimately reduce battery manufacturing and provide a better disposal process on a large scale. C. Vidal et al. [29] reviewed the recent publications about the impacts of low temperatures on lithium-ion batteries for EVs. This study considered a capacity loss, power loss, life degradation, safety hazard, unbalanced Sustainability 2021, 13, 13779 3 of 28 capacity, charging difficulty, thermal management system complexity, battery model and state estimation method complexity, and incremental cost. Finally, the study offered correlations and possible solutions for future investigations. The further grouping of ESSs is investigated in this paper [30], including the advantages and disadvantages of all types of ESS and their building, electric-based qualities, and usage.
Electrochemical batteries are time-dependent, defective components due to the nature of their chemical elements, which influence their performance and lifetime [31][32][33][34][35][36][37][38][39][40][41][42][43]. The main parameter for evaluating aging effects [31][32][33][34][35][36] is battery capacity. Battery capacity fading evaluation can be possible in real-world practices if battery indications can be properly monitored [37]. Therefore, battery calendar aging estimation is of extreme importance for developing persistent ESSs for EVs. The use of machine learning techniques [38][39][40][41], such as neural networks for prediction purposes has recently increased. Also, the development of management strategies for ESS has been reported in many papers [42][43][44][45]. To highlight some of the most recent developments: A. E. Mejdoubi et al. [31] studied the lithium-ion battery health assessment, considered SoH, and estimated remaining useful life (RUL). They studied the aging of the battery by proposing the Rao-Blackwellization particle filter for EVs. In these studies [32,33], the researchers evaluated battery aging for EVs, considering different driving behaviors. The study showed that aggressive driving, recharging behavior, and temperature changes significantly impact battery life suppression. Concerning EV driving characteristics, B. Gao et al. [34] proposed an acceleration speed optimization considering battery aging. Their research could improve battery capacity loss by 9.6%. For improving aging monitoring methods, S. H. Kim et al. [37] developed a new technique tested for lithium-ion batteries using harmonic-based analysis. Foraging prediction purposes, researchers recently applied machine learning techniques. K. Liu et al. [38] investigated gaussian process regression. The proposed method enhanced prediction performance with higher accuracy and better generalization ability. In [39,40], the researchers successfully used the neural networks approach for battery aging predations. S. B. Vilsen et al. [41] studied a log-linear model which estimates battery aging. In this technique, they utilized dynamic aging profiles every week. To perform accurate predictions, R. Xiong et al. [42] developed a battery management system to study SoH in a lithium-ion battery. They employed online monitoring of SoH to estimate battery capacity and RUL. In another study [43], the researchers developed an active adaptive battery aging management system for EVs, controlling the battery capacity degradation. The strategy considered vehicle performance, including driving range, recharge time, and drivability. F. Chang et al. [44] studied the impact of current ripples on the aging of lithium batteries. They experimented with a long-term aging assessment on battery cells to investigate the effect of the current ripples in cascaded multilevel topologies. It is reported that the impact of most cascaded multilevel topologies is insignificant for lithium-ion batteries. The fast charging of lithium-ion batteries has also become popular in recent years. In reference [45], the authors performed a populationbased optimization algorithm for finding the optimum charging current patterns within a charging control strategy considering aging effects. The study is based on an electricthermal model considering battery temperature under different charging conditions. At this stage, it is also important to stress the implications that the battery aging process may have on the environmental sustainability of EVs and the future availability of resources. In fact, due to aging effects, the demand for electrochemical batteries may increase due to the need for battery replacement during the vehicle's service life [46][47][48][49][50][51][52] or to a shorter vehicle life cycle, which Y. Ma et al. [53] envisaged being reduced to 8-10 years. This will inevitably pose a series of challenges for the environment at a different level of the supply chain. As noted by T. R. Hawkins et al. [48], the EVs' environmental performance across all impact categories are sensitive to the battery replacement schedules. This is mainly due to the intensity of the activities related to battery manufacturing and raw materials extraction, which contribute to a significant share of the environmental impacts of EVs [51][52][53][54], including the depletion of resources [55,56]. In battery replacement, the impact of manufacturing needs to be doubled in the calculation for all impact categories. If the vehicle has a shorter life cycle, the shorter timeframe should be considered in the analyses. T. R. Hawkins et al. [48] and P. Marques et al. [49,50] stressed the importance of accounting for battery replacement schedules when assessing the impact of lithium-ion batteries for automotive applications or EVs. Existing studies considered capacity fade models to estimate the number of batteries required during the vehicle life [57][58][59]. P. Marques et al. [49] published a study that integrates capacity fade in the LCA assessment. It was found that when aging effects are considered, battery replacement could increase up to 31% for EVs based on the type of chemistry and driving conditions. These results reflect state of the art and do not consider recycling pathways for recycling key materials used in lithium-ion batteries, potentially reducing up to 50% of material production intensity and decelerating the material depletion process [60]. However, the development of recycling facilities is critical to support the transition to electric mobility and decoupling society from the intensive consumption of finite resources [61,62].
Because of raising environmental concerns and technological limitations for the effective disposal of electrochemical batteries, battery selection, and usage criteria are required. This paper's contribution provides a systematic review of recent performance achievements, developments, and future trends of batteries for EVs. Due to concerns arising from an increase in the demand for batteries, i.e., material consumption and the harmful implications of manufacturing-related activities on the environment; the study also offers a comparative aging analysis to demonstrate the life cycle of different types of popular batteries. A sensitivity analysis is also provided to better understand the effects of other effective parameters on aging performance. Based on the historical data gathered for battery demands in EVs, the study also presented future directions using time series analysis techniques.
The paper's main highlights and findings are listed as: • The paper provides an overview of the latest technologies and developments of electrochemical batteries used in EVs.

•
The best performance was reported by LiNi 1−x−y MnxCoyO 2 , whereas LiFePO 4 is the greenest and safest battery. • Capacity fading of 18.42%, between 25-65 • C, is studied as a function of the cycle number and cell temperature.

•
The lithium-ion market will be increasing by 11% and 65%, between 2020-2025, for light-duty and heavy-duty EVs.

•
The lithium-ion cell production mass will rise by 81% and 74% for both light-and heavy-duty EVs in the market between 2020-2025.
This paper is organized as follows: a systematic review of the recent developments and findings for electrochemical batteries is given in Section 2. In Section 3, battery aging is mathematically defined, and the modeling is presented. The simulation results are also discussed in this section. Based on extensive historical data on batteries' EV demand and their environmental impacts, the future trends are predicted and discussed in Section 4; and conclusions are in Section 5.

Systematic Review of Recent Development in BESSs
All regular chargeable batteries are considered electrochemical energy storage systems. These include flow batteries and other chargeable batteries [63]. In the electrochemical energy storage systems, energy is transformed into chemical power from electrical energy and again changed via a reversible function using power efficiency and physical changes. To evaluate the performance of all electrochemical rechargeable batteries, the role of several technical parameters, like SoC, SoH, DoD, operating cell temperature, aging, RUL, etc. , is inevitable in EVs. Because of the traction application's fast charging and discharging nature, accelerations and decelerations have considerable effects on the battery cycle number and battery life. The BESS market is still experiencing the impact of range anxiety of EVs, which is critically influenced by battery capacity fading and aging [166]. Secondary batteries (SB)s dictate the market of portable power storehouse devices used in EVs and different electric usage (Spinel NixCo 2−x O 4 ) as a bifunctional air electrode for zinc-air batteries [137]. Such batteries stock electricity in chemical power, and they create electricity via an electrochemical reaction method. Normally, SB involves electrodes, anode, and another cathode, electrolytes, dividers, and cases. SB has remarkable qualities like high energy [167,168], power density, leveled discharge, less resistance, small memory result, and a good range of performance in temperature. However, almost all batteries include toxic elements. Therefore, ecological consequences at the time of discharge must be considered [169]. The SBs provide high power density and a specific energy of electricity storehouse systems in most EV implementations because of cell technologies' high technologies and competitive costs [170,171]. For different EVs, the SB can be made of a zinc-halogen category (Zn-Cl 2 , Zn-Br 2 ), metal-air category (Fe-Air [65,66], Al-Air [64,65], Zn-Air [136][137][138][139][140][141][142][143]), sodium-beta (Na-S, Na-NiCl 2 ), lithium high temperature (Li-AlFeS, Li-AlFeS 2 ), medium temperature lithium, such as lithium-polymer (Li-polymer) and lithium-ion (Li-ion), and batteries family, such as Li-NiCoAlO 2 , LiNixMnyCozO 2 , LiFePO 4 , and LiCoO 2 cathodes. Compared to other Li-ion batteries, Li-S offer higher specific energy, better safety, and a slightly wider operating temperature. They are currently under extensive development research. These high-energy lithium-ion batteries are the most utilized type within modern and emerging EVs today. Lead-acid (LA) with Pb-O 2 formula [67,68] batteries are generally regarded as the worst choice, mainly because of their poor energy density compared to other presented batteries, as shown in Table 2. They were used, however, to replace ICE vehicles and applied for other areas such as the grid ESSs, renewable ESSs, and emergency power supply due to their low cost, temperature tolerance, safe operation, and ruggedness. The comparative performance of these batteries, presented in Table 2, is lower than nickel-based batteries (Ni-Fe, Ni-Zn, Ni-Cd, Ni-MH, Ni-H 2 ) [170][171][172][173][174][175][176]. The most recent battery candidates developed are Li-Ion [76][77][78][79][80][81][82][83], Lipolymer [84][85][86][87][88][89][90][91], and NiMH [122][123][124][125][126][127][128] batteries, due to significant energy density, life cycle, and operating temperature range, where the battery can provide its highest promising efficiency. The other listed batteries are undesirable for EVs; the worst kinds are NaNiCl 2 [92][93][94][95][96][97][98][99][100][101][102][103], NaS, NiZn [129][130][131][132][133][134][135], and ZnCl 2 . Although NaNiCl 2 and NaS have shown a notable life cycle, their operating temperature is the main reason for not deploying them. Vice versa, NiZn and ZnCl 2 lack a reasonable life cycle, which eventually results in lower total range capability. As shown in Table 2, energy density, cut-off voltage (about 4.2 V), and cell voltage are relatively higher than other types of electrochemical batteries for the lithium-ion cobalt (Li-Ion-Co) battery. Therefore, they are selected as one of the best cost-effective candidates for EV applications. Among newly developed batteries, lithium-titanate or titanium oxide batteries (e.g., Li 4 Ti 5 O 12 LTO) can offer considerably long life cycles (up to 15,000) and high charging efficiencies (85-90%). However, their disadvantages are low energy density and high cost. After discovering modern batteries such as lithium batteries and Li-polymer batteries, LA batteries continue to have a presence in the industry, particularly within devices whose temperatures are not regulated and durability is needed. One downside of lead-acid cells is their limited life cycle, which ranges from 400 to 2000 cycles [176,177]. Smaller versions of the LA batteries have become increasingly popular for automotive electric equipment and rescue services. While larger ones are typically used for stationary and starting, lighting, and ignition (SLI), applications have only lately been produced [178]. For example, SLI and uninterruptible power supply (UPS) batteries are usually LA batteries that have small voltages and ratings of 12, 8, and 6 V. A valve-regulated lead-acid (VRLA) has also been used to power the EVs due to no maintenance being needed, the capability of rapid charging, low cost, and high power. Recent studies have also investigated the weight and size minimization of advanced batteries and maintaining energy density [179][180][181], such as VRLA batteries including gel and absorbent glass mat (AGM) batteries [182][183][184], which are made of fiberglass electrolytes; a solid material which contains and absorbs acid without any leakage. They require less space and have a compact volume, and their vibration resistance is higher than many other standard batteries [185,186]. This battery has a specific function that can recombine oxygen and hydrogen into the water during charging inside a unit and limit water loss. On the other hand, a gel battery is composed of the electrolyte of gel-state which is gelatinous and not solid enough to contain acid without any leakage. These batteries require controlled and slower charging as compared to many others. These batteries' corresponding challenges, strategies, and perspectives are discussed in [187][188][189][190]. For example, the risk of using gel batteries can be the bubbles of gas produced in the electrolyte. They may damage a battery permanently.  Table 3 demonstrates several popular electrochemical batteries for EVs, where the anode is graphite for all presented batteries. LiMn 2 O 4 has the highest nominal tension capability; NaNiCl 2 has shown the greatest thermal runaway feature, while the specific energy is reported as the weakest. Also, ZnOH 42− offers the highest specific energy among others. In commercialized batteries, LiCoO 2 is still the most used cathode material. It was an unbeatable cathode for decades due to its large energy density, long life, and ease of preparation. Nonetheless, the phase transition from hexagonal to monoclinic at high voltages, and the cost of cobalt and its toxicity, motivated the scientists to search for a better solution [191,192]. H 2 SO 4 and hydrochloric acid (HCl) were used as the main agent to compare the effects on cobalt and lithium extraction. In the recovery of cobalt and lithium from Li-Ion battery active mass, HCl performs better than H 2 SO 4 . The actual state for cobalt and lithium recovery is 2M HCl, 90 min of leaching time, and 60-80 • C of leaching temperature. In this condition, the extraction ratio for Co and Li is nearly 100%. The methods used for synthesizing LiCoO 2 as a cathode and recycling the cobalt and lithium from spent Li-Ion batteries are mechanical, thermal, hydrometallurgical, and the sol-gel phases. The active cathode material has a good chargedischarge capability and cycling performance because of LiCoO 2 powder [193][194][195]. Less life span, low thermal stability, and reduced specific power capability are the disadvantages Sustainability 2021, 13, 13779 7 of 28 of LiCo-based batteries. Some batteries, such as Li-Ion and Cobalt-blended Li-Ion, reduce the life span due to mainly anode thickening, solid electrolyte interface, and lithium plating during rapid charging and reduced charging [196].
A lithium-ion manganese oxide battery is a lithium-ion cell with a cathode made of manganese dioxide (MnO 2 ). Their issues and challenges are discussed in [197,198]. They vary widely for EVs, such as LiNi 0 . 5 CO 0 . 2 2Mn 0 . 3 O 2 (NCM523). Solvent-based slurry casting techniques are widely used to create these cathodes, which are harmful to the environment, energy-intensive, and time-consuming.
Longer transit distances at a lower cost have been a focus, ensuring optimum performance and reducing utilizing second-life batteries for EVs. In an approach to reduce battery production, their performance, application, feasibility, environmental impacts, economic benefits, and challenges are reported in [199][200][201][202]. They work under the same intercalation/de-intercalation principle as commercialized secondary rechargeable batteries such as LiCoO 2 . Earth-abundant, cheap, non-toxic, and thermally stable, cathodes dependent on manganese-oxide compounds are used. Another advanced type of battery is the lithium manganese oxide, LiMnO 2 ; the battery uses manganese for the cathode and lithium as the anode. For the boost ion transfer, the battery is shaped like a spinel. It contains lithium chloride, which acts as an organic solvent to help electrons flow between the anode and the cathode. The lithium manganese oxide battery has several benefits that make it appealing to users. It has a large life cycle of about ten years, which ensures long-term dependability. For example, Nissan Leaf EV, in 2013, adopted LiMnO 2 , which offers up to 225 miles in driving range. Additionally, the reports and innovative studies on how to deal with their temperature rise and thermal management solutions can be found in .
While there is widespread consensus that the demand for EVs is growing, a substantial portion of the population remains skeptical. The key concerns are range limits, battery durability, and safety. As the market grows, Table 4 presents considerations to overcome these challenges. The recent and new manufactured EVs in the market are reported in Table 4. Their key parameters are reported, such as driving range, battery capacity, charging duration, power, and energy consumption. It is also reported that the battery size in terms of power significantly increased up to 67 kWh in 2020, which is predicted to rise to 80 kWh in 2030 (see [246,247] for more details). From the table, the best overall performance can be selected for Jaguar I-Pace EV400 using a lithium-ion battery, where the highest top speed, driving range, and battery capacity are provided. Critical safety problems in BESSs comprise temperature rises and management. Improving efficiency, range, charging, durability, and protection can be achieved by effectively handling the heat in the utilized BESS. In Table 5, several thermal cooling methods consider their efficiency and operating temperature such as air, liquid, direct refrigerant, phase change material, thermoelectric, and heat pipe. The highest efficiency could be seen for direct refrigerant and thermoelectric cooling methods. Battery thermal management advances can be found in the following review and technical papers [247][248][249][250][251][252][253][254].

Mathematical Equations
The HEV's powertrain is modeled to deliver power demands from the BESS to the wheels. Depending on the driving conditions, the power demand P demand varies, which combines both ICE and electric machine (EM) with motoring and generating capabilities. Hence, the P demand can be introduced into two categories, (1) braking and coasting; and (2) accelerating and cursing modes: where P rpb is the regenerative power braking produced from the negative acceleration, under braking condition P EM is the net output power from the EM, and P ICE is the net output power from the ICE. η t is the total transmission efficiency, which is a function of gear ratio GR. Battery aging analysis considering the electro-thermal effects demonstrates how the performance of the BESS can be degraded. The electro-thermal modeling of the BESS using a Thevenin circuit is considered for this study, based on [254][255][256][257]. Considering the Thevenin circuit, presented in Figure 1, the terminal voltage U c can be given as: where V oc is the open-circuit voltage, T is the operating cell temperature of the battery, I L is the load (or battery) current, V Rs is the instantaneous voltage drop over the ohmic internal resistance (R 0 ), which is computed using R 0 × ∆I, where ∆I indicates the step change of battery charging or discharging current. V RC is the transient voltage drop over the ith RC shown in Figure 1.
where is the open-circuit voltage, is the operating cell temperature of the battery, is the load (or battery) current, is the instantaneous voltage drop over the ohmic internal resistance ( 0 ), which is computed using 0 × ∆ , where ∆ indicates the step change of battery charging or discharging current.
is the transient voltage drop over the ith RC shown in Figure 1. In this study, the aging analysis of multiple connected lithium-ion battery cells is modeled. The effects of battery temperature on the capacity degradation and life cycle are investigated, where the battery temperature is: where is the average battery temperature, resulting from all considered battery cells = 1 + 2 + 3 + ⋯ + ; ℎ is the heat transfer coefficient, and is the total superficial area of battery; is the open circuit voltage; is the ambient temperature of the battery cells. These are varied for better understanding its impact on the battery's aging, using a global sensitivity method based on Sobol random sampling and Monte Carlo analysis.
is the heat capacity of the battery cells, and is the battery total mass. The discharging/charging functions 1 and 2 of the lithium-ion battery cell is: In this study, the aging analysis of multiple connected lithium-ion battery cells is modeled. The effects of battery temperature on the capacity degradation and life cycle are investigated, where the battery temperature is: where T c is the average battery temperature, resulting from all considered battery cells T c = T c1 + T c2 + T c3 + · · · + T cn ; h is the heat transfer coefficient, and S is the total superficial area of battery; U ocv is the open circuit voltage; T a is the ambient temperature of the battery cells. These are varied for better understanding its impact on the battery's aging, using a global sensitivity method based on Sobol random sampling and Monte Carlo analysis. C is the heat capacity of the battery cells, and m is the battery total mass. The discharging/charging functions f 1 and f 2 of the lithium-ion battery cell is: where E 0 is the constant voltage; . Q is the extracted capacity; Q is the maximum battery capacity; K is polarization resistance; i * is the low-frequency current dynamics; i is the battery current; A and B are exponential voltage and capacity constant, and C is the nominal discharge curve slope. To calculate the polarization resistance or constant: where T re f is the reference cell temperature, and K T_re f is the constant related to T re f . Considering the aging effects of a lithium-ion battery cell, the capacity degradation can be defined as: where Q BOL is the capacity of battery under the beginning of the life (BoL) condition, Q EOL is the capacity of the battery under the end of life (EoL) condition. Both are measured at the nominal (or reference) ambient temperature. ε is the battery cell aging parameter, and n is the sequence number.

Battery Cell Modeling and Settings
In this electro-thermal modeling, the BESS is designed using a MATLAB Simulink environment ans simscape library, as shown in Figure 2. The designed HEV powertrain is developed for a passenger vehicle with a curb weight of 1600 kg which can travel up to 980 km (total range). Under positive acceleration a permanent magnet synchronous machine (PMSM) is employed to deliver a continuous torque between 0-450 Nm and a maximum shaft speed of 10,000 rpm. A planetary gear with 2.8 gear ratio is selected to manage the power between the fuel engine with 120 kW maximum power and PMSM. In addition, a proportional and integral (PI) controller is used to control the speed at the proposition shaft in the drivetrain, and to study the aging of a lithium-ion (LiFePO 4 ) battery pack, the effects of different depth of discharge (DoD), state of health (SoH), capacity degradation, discharge current, SoC, and T a . As presented in Figure 2, the changes of positive (motoring) and negative (generating) accelerations from a standard Worldwide Harmonized Light Vehicle Test Procedure (WLTP) drive cycle [258] play an important role in battery charging and discharging bus currents.   Figure  1. The model uses a simscape library from MATLAB Simulink, where multi-domain components (blue and orange lines indicate the electric and thermal connections physical system) are modeled. The selected solver is a variable-step type with an absolute tolerance of 1 × 10 −6 , in which an adaptive zero-crossing algorithm is selected. Along with the battery cell's electrical components, such as resistors 0 , 1 , 2 , , , and 1 , other thermaloriented components like heat flow source, battery cell thermal mass, and sensors are utilized in this model. In the employed battery model, each cell contains an internal resistance of 0 = 0.0043 Ω, the main resistances of 1 = 1 Ω, 2 = 0.1 Ω, and in the parasitic branch resistance of = 2 −11 Ω −1 , the main branch capacitance is 1 = 0.001 . The thermal model of each cell consists of a cell thermal mass of 400 J/kg/K which is inversely proportional to the heat flow rate in the cell. The output of the battery is connected to a DC/DC converter which also includes a thermal model to calculate the heat flow, and its associated power loss, via a convective heat transfer block. In this simulation, the average DC/DC converter temperature is 38 °C. The maximum DC bus voltage of 550 V and maximum battery voltage of 260 V is reported. Additionally, the ratio of ampere-hour capacity, ( ), is a lookup table gathered at a standard time rate for a range of operating cell temperatures. The battery cell's specification is given in Table 6.   Figure 1. The model uses a simscape library from MATLAB Simulink, where multi-domain components (blue and orange lines indicate the electric and thermal connections physical system) are modeled. The selected solver is a variable-step type with an absolute tolerance of 1 × 10 −6 , in which an adaptive zero-crossing algorithm is selected. Along with the battery cell's electrical components, such as resistors R 0 , R 1 , R 2 , R p , E p , and C 1 , other thermaloriented components like heat flow source, battery cell thermal mass, and sensors are utilized in this model. In the employed battery model, each cell contains an internal resistance of R 0 = 0.0043 Ω, the main resistances of R 1 = 1 mΩ, R 2 = 0.1 Ω, and in the parasitic branch resistance of R p = 2e −11 Ω −1 , the main branch capacitance is C 1 = 0.001 mF. The thermal model of each cell consists of a cell thermal mass of 400 J/kg/K which is inversely proportional to the heat flow rate in the cell. The output of the battery is connected to a DC/DC converter which also includes a thermal model to calculate the heat flow, and its associated power loss, via a convective heat transfer block. In this simulation, the average DC/DC converter temperature is 38 • C. The maximum DC bus voltage of 550 V and maximum battery voltage of 260 V is reported. Additionally, the ratio of ampere-hour capacity, K t (T), is a lookup table gathered at a standard time rate for a range of operating cell temperatures. The battery cell's specification is given in Table 6.
versely proportional to the heat flow rate in the cell. The output of the battery is connected to a DC/DC converter which also includes a thermal model to calculate the heat flow, and its associated power loss, via a convective heat transfer block. In this simulation, the average DC/DC converter temperature is 38 °C. The maximum DC bus voltage of 550 V and maximum battery voltage of 260 V is reported. Additionally, the ratio of ampere-hour capacity, ( ), is a lookup table gathered at a standard time rate for a range of operating cell temperatures. The battery cell's specification is given in Table 6.   A quasi-Monte Carlo (QMC) simulation with Sobol sampling [259] is used for sensitivity analysis of several battery cell parameters to provide a simulation-based investigation on aging effects. The sensitivity analysis is done for 5000 h of driving using the WLTP drive cycle. Simulating QMC requires sampling generation through computed Sobol sensitivity indices. In this study, the sample number is 100 for every cell temperature from 25-55°C. The sensitivity function f (x) is defined as an n-dimensional unit hypercube, assuming x u , as the |u|-dimensional vector, which contains variables x j . Using analysis of variance (ANOVA) decomposition of f (x), more details can be found in [260], each iteration computing as: where the partial and total variance of f (x) is given as: Based on Sobal's global sensitivity analysis, the indices to be calculated are: Sustainability 2021, 13, 13779 12 of 28 The aging simulations are successfully done using an Intel i7-9700 CPU at 3.00 GHz, with RAM of 32 GB and a 64-bit operating system. By using the parallel computing feature of MATLAB Simulink, each simulation took 450 min.

Results and Discussion
A standard driving cycling profile is chosen to evaluate the life cycle of a LiFePO 4 cell for EVs. The European Union (EU) has developed a new profile known as WLTP. This drive cycle has different average speeds such as low, medium, high, and extra high. The EU automobile industry welcomes the shift to WLTP and has actively contributed to developing this new test cycle. As a result of WLTP power demand, the simulations consist of a sequence of full charge and discharge cycles between the voltage limits of the battery cell.
The battery cell aging simulation allows characterizing cell temperature and degradation in-depth, providing the aging knee and thus offering useful information about the cell performance tested under the requested vehicle's power demand. The main parameters such as capacity, battery cell, and life cycles are presented for the total driving time of five hours.
Capacity degradation for five-hour performance is of considerable interest because of the impact of aging in batteries. Figure 4 demonstrates the variations of the equivalent cycle number and capacity, where the level of impact varies with the ambient temperature. The results show that the higher the ambient temperature, the higher the difference between BoL and EoL performance. For example, the life cycle varies between 1100-2500 for the range ambient temperature (25-65 • C) tested in this contribution. The capacity degradation between 43-31 can also be reported for corresponding ambient temperatures of 25-65 • C. For this graph, high-dimensional datasets with 3,000,000 operating points were generated. Capacity degradation for five-hour performance is of considerable interest because of the impact of aging in batteries. Figure 4 demonstrates the variations of the equivalent cycle number and capacity, where the level of impact varies with the ambient temperature. The results show that the higher the ambient temperature, the higher the difference between BoL and EoL performance. For example, the life cycle varies between 1100-2500 for the range ambient temperature (25-65 °C ) tested in this contribution. The capacity degradation between 43-31 can also be reported for corresponding ambient temperatures of 25-65 °C. For this graph, high-dimensional datasets with 3,000,000 operating points were generated. In this case study, the electro-thermal system is primarily based on irreversible heat generation due to losses at the current collector and active cell materials. Also, the reversible heat production originates from an entropy change resulting from the intercalation and deintercalation of LiFePO4 cells. Figure 5 illustrates how the battery cell temperature varies depending on the charge and discharge current changes, which arise due to the power demand requested by the vehicle. The graph indicates that rationally higher cell temperatures occur when the discharge current is higher. Under the WLTP cycle, the cell temperature is mostly recorded below 65 °C. However, the highest is reported when both charging and discharging currents are very high, which happens during the major accelerations and decelerations, also known as harsh driving environments. Note that a natural air-cooling system is considered for generating this figure. In this case study, the electro-thermal system is primarily based on irreversible heat generation due to losses at the current collector and active cell materials. Also, the reversible heat production originates from an entropy change resulting from the intercalation and deintercalation of LiFePO 4 cells. Figure 5 illustrates how the battery cell temperature varies depending on the charge and discharge current changes, which arise due to the power demand requested by the vehicle. The graph indicates that rationally higher cell temperatures occur when the discharge current is higher. Under the WLTP cycle, the cell temperature is mostly recorded below 65 • C. However, the highest is reported when both charging and discharging currents are very high, which happens during the major accelerations and decelerations, also known as harsh driving environments. Note that a natural air-cooling system is considered for generating this figure. To better determine the impacts of charging and discharging requested currents, a global, randomized QMC sensitivity analysis was conducted ( Figure 6). The different ambient temperatures eventually play a significant role in the battery cell operating temperature. For this simulation, 500 randomized samples were generated, where every 100 samples belong to one temperature category, e.g., 100 samples when the temperature remains 25 °C. The results explain how the maximum cycle number can substantially increase when the ambient temperature is higher. The dashed line area indicates the samples that critically suppress the battery cell capacity while the battery cell capacity falls between 1-10 Ah. Among them, most of the samples belong to 55-65 °C cell temperature. The changes in both charging and discharging currents also affect the cycle number linearly until the aging knee. The aging knee light blue dashed line separates the samples into two regions. In the first region below the aging knee line, the battery cell's fading power capability is still linear; however, significant rises can be seen above the dashed line; primarily at the high charging and discharging bus currents. This cycle number increase mechanism is quantified based on the internal resistance increase (which is highly dependent on the cell operating temperature) and capacity loss. To better determine the impacts of charging and discharging requested currents, a global, randomized QMC sensitivity analysis was conducted ( Figure 6). The different ambient temperatures eventually play a significant role in the battery cell operating temperature. For this simulation, 500 randomized samples were generated, where every 100 samples belong to one temperature category, e.g., 100 samples when the temperature remains 25 • C. The results explain how the maximum cycle number can substantially increase when the ambient temperature is higher. The dashed line area indicates the samples that critically suppress the battery cell capacity while the battery cell capacity falls between 1-10 Ah. Among them, most of the samples belong to 55-65 • C cell temperature. The changes in both charging and discharging currents also affect the cycle number linearly until the aging knee. The aging knee light blue dashed line separates the samples into two regions. In the first region below the aging knee line, the battery cell's fading power capability is still linear; however, significant rises can be seen above the dashed line; primarily at the high charging and discharging bus currents. This cycle number increase mechanism is quantified based on the internal resistance increase (which is highly dependent on the cell operating temperature) and capacity loss. Sustainability 2021, 13, x FOR PEER REVIEW 15 of 30 Figure 6. Lithium-ion battery cell life cycle as a functioning charging/discharging bus current, under WLTP drive cycle, using randomized samples in a QMC simulation.

Potential and Future Prospects: A Prediction-Based Study on BESS for EVs
The future trends of lithium-ion batteries for powering EVs are studied in this section. Based on the historic databases reported by [261], short-term, medium-range forecasts are presented using additive Winter's method. The fitting accuracy measurers are given: where MAPE is the mean absolute percentage error, MAD is the mean absolute deviation, and MSD is the mean squared displacement. is the actual value, is the forecast value, is the number of times the summation iteration occurred, and is the dataset vector where the subscript shows the data point number. ( ) is the average value of the dataset. The ( ) vector is the ith data point at a time, and (0) is the ith datapoint at the reference position. All the smoothing constants such as level, trend, and seasonal are selected to reduce the MAPE, MAD, and MSD outputs. Figure 7 indicates the past, current, and future trends of worldwide growing lithiumion battery demand for light-duty and heavy-duty EVs. The historic data from 2009-2019 is provided by [261]. An additive winter method is used for future forecasting in this work. As presented in Figure 7a,c, the lithium-ion (capacity) market will increase by 11% and 65% between 2020-2025 for light-duty and heavy-duty EVs, respectively. The future short-term predictions show, in Figure 7b,d, that the lithium-ion equivalent in tons of cell mass will rise by 81% and 74% for both light-duty and heavy-duty EVs in the market between 2020-2025. As presented, the demand will significantly increase for lithium-ionpowered EVs globally. The results suggest that soon, the lithium-ion energy storage ca-

Potential and Future Prospects: A Prediction-Based Study on BESS for EVs
The future trends of lithium-ion batteries for powering EVs are studied in this section. Based on the historic databases reported by [261], short-term, medium-range forecasts are presented using additive Winter's method. The fitting accuracy measurers are given: where MAPE is the mean absolute percentage error, MAD is the mean absolute deviation, and MSD is the mean squared displacement. A t is the actual value, F t is the forecast value, n is the number of times the summation iteration occurred, and x i is the dataset vector where the i subscript shows the data point number. m(X) is the average value of the dataset. The x i (t) vector is the ith data point at a time, and x i (0) is the ith datapoint at the reference position. All the smoothing constants such as level, trend, and seasonal are selected to reduce the MAPE, MAD, and MSD outputs. Figure 7 indicates the past, current, and future trends of worldwide growing lithiumion battery demand for light-duty and heavy-duty EVs. The historic data from 2009-2019 is provided by [261]. An additive winter method is used for future forecasting in this work. As presented in Figure 7a,c, the lithium-ion (capacity) market will increase by 11% and 65% between 2020-2025 for light-duty and heavy-duty EVs, respectively. The future short-term predictions show, in Figure 7b,d, that the lithium-ion equivalent in tons of cell mass will rise by 81% and 74% for both light-duty and heavy-duty EVs in the market between 2020-2025. As presented, the demand will significantly increase for lithium-ion-powered EVs globally. The results suggest that soon, the lithium-ion energy storage capacity for both lights-and heavy-duty electric vehicles is expected to double. This confirms the pattern identified by [262]. Therefore, in the current scenario, because of the higher demand for EVs, several lithium-ion batteries which need to be produced to sustain the development of the market are envisaged to grow quite significantly in the forthcoming years. Therefore, as suggested by [247], the system's capability to achieve large-scale deployment of ESSs will determine whether the automotive industry could satisfy the demand for electric vehicles. A significant increase in the manufacturing capacity will be required at different levels of the supply chain. This potential increase in the demand for storage capacity may reduce the cost of batteries due to the advantages arising from learning curves and economies of scale; as such, the increase can further boost the demand since battery packs are the most expensive component in an electrified drivetrain. Reducing their cost may thus allow EVs to become more affordable for more individuals. Therefore, the growth in EVs' demand could further contribute to this positive trend, accelerate the transition to e-mobility, and promote the adoption of electrified means of transport. However, the sharp increase in demand is not expected to last for a long period of time. The curve will reach the settling point as soon as most of the vehicles in circulation are dismissed and substituted by electric ones.
pacity for both lights-and heavy-duty electric vehicles is expected to double. This confirms the pattern identified by [262]. Therefore, in the current scenario, because of the higher demand for EVs, several lithium-ion batteries which need to be produced to sustain the development of the market are envisaged to grow quite significantly in the forthcoming years. Therefore, as suggested by [247], the system's capability to achieve largescale deployment of ESSs will determine whether the automotive industry could satisfy the demand for electric vehicles. A significant increase in the manufacturing capacity will be required at different levels of the supply chain. This potential increase in the demand for storage capacity may reduce the cost of batteries due to the advantages arising from learning curves and economies of scale; as such, the increase can further boost the demand since battery packs are the most expensive component in an electrified drivetrain. Reducing their cost may thus allow EVs to become more affordable for more individuals. Therefore, the growth in EVs' demand could further contribute to this positive trend, accelerate the transition to e-mobility, and promote the adoption of electrified means of transport. However, the sharp increase in demand is not expected to last for a long period of time. The curve will reach the settling point as soon as most of the vehicles in circulation are dismissed and substituted by electric ones.   [247]. From the results obtained, the electric vehicle market will be characterized by a positive trend in different markets. Based on the predictions, the worldwide market will grow by about 140% up to 2025. Europe is likely to experience an increase of approximately 103% and 110% in the sales for BEV and PHEV in the next five years. Once again, that implies   [247]. From the results obtained, the electric vehicle market will be characterized by a positive trend in different markets. Based on the predictions, the worldwide market will grow by about 140% up to 2025. Europe is likely to experience an increase of approximately 103% and 110% in the sales for BEV and PHEV in the next five years. Once again, that implies that the number of vehicles sold in 2019 will more than double in five years. Similarly, the US demand will grow by approximately 135% for BEV and 114% for PHEV, almost tripling the 2019 recorded data. BEVs with a 110% increase and PHEVs with a 132% will observe a higher growth (increased percentage), but a lower total number of EVs in China, and other countries/regions, especially if the results are compared to the country's population. However, despite the difference in the adoption rate between different countries, the market size and the availability of financial support to purchase the vehicles, the number of vehicles sold will increase significantly considering the state of the art. There are reasons to believe that this trend is reinforced because of continuous government support to the transition to e-mobility. In fact, according to [247], environmental and sustainability objectives currently drive the policy framework, and more governments have announced strict measures to phase out traditional vehicles by 2050 [247,263]. However, the predicted growth of EVs may be hampered by potential bottlenecks caused by the finite availability of specialized materials required in battery manufacturing [264,265]. The natural scarcity of the critical material, the demand from competing sectors, the geographical concentration of resources, and the political instability of countries where resources are located pose a series of challenges for automotive supply chains due to the increase in supply disruption risk [266]. Therefore, future studies may assess whether production rates for material extraction and manufacturing could sustain the expansion of the electric vehicle market in different scenarios. In this context, it is paramount to consider battery aging patterns to improve the accuracy of the estimate in the battery demand and the number of necessary materials required.
that the number of vehicles sold in 2019 will more than double in five years. Similarly, the US demand will grow by approximately 135% for BEV and 114% for PHEV, almost tripling the 2019 recorded data. BEVs with a 110% increase and PHEVs with a 132% will observe a higher growth (increased percentage), but a lower total number of EVs in China, and other countries/regions, especially if the results are compared to the country's population. However, despite the difference in the adoption rate between different countries, the market size and the availability of financial support to purchase the vehicles, the number of vehicles sold will increase significantly considering the state of the art. There are reasons to believe that this trend is reinforced because of continuous government support to the transition to e-mobility. In fact, according to [247], environmental and sustainability objectives currently drive the policy framework, and more governments have announced strict measures to phase out traditional vehicles by 2050 [247,263]. However, the predicted growth of EVs may be hampered by potential bottlenecks caused by the finite availability of specialized materials required in battery manufacturing [264,265]. The natural scarcity of the critical material, the demand from competing sectors, the geographical concentration of resources, and the political instability of countries where resources are located pose a series of challenges for automotive supply chains due to the increase in supply disruption risk [266]. Therefore, future studies may assess whether production rates for material extraction and manufacturing could sustain the expansion of the electric vehicle market in different scenarios. In this context, it is paramount to consider battery aging patterns to improve the accuracy of the estimate in the battery demand and the number of necessary materials required. Similarly, the availability, accessibility, and capability of public charging infrastructures may pose a threat to the large-scale adoption of BEVs, which could potentially revert this trend. Despite this, requirements for the charging facilities, including the optimal number of stations, locations, and charge schedules, are currently being investigated and countries are planning the development of infrastructure. Delays in developing solid private and public infrastructure could cause a severe setback and hinder the transition to the electrification of road transports. Further studies are required to explore barriers to the development of charging station infrastructures and their optimal integration in future transport, where the charging demand will be increasing significantly.

Conclusions
High-energy modern batteries are enabling EVs to drive farther on a single charge. The role of lithium-ion batteries is inevitable in the coming years, considering environmental issues such as the shortage and recycling of raw materials. These limitations stress the importance of the optimum selection and sizing of BESS. At the same time, battery size is estimated to increase by 80 kWh to improve the range anxiety up to 400 km by 2030. The supply of rare earth elements may become critical, such as lithium, cobalt, manganese, and nickel. Upon reviewing current research on battery-powered EVs, the main conclusions drawn are the following:

•
Within the EV application operating temperature, the lithium-ion family batteries are, i.e., LiMO 2 , LiMn 2 O 4 , and LiFePO 4 . They are currently the best candidates because of their performance features, such as higher energy density, specific power, battery efficiency, and life cycle. Despite the technical suitability, such batteries may result in being more expensive compared to their alternatives. Therefore, advancements in battery technology or manufacturing processes are required to reduce their cost. LiFePO 4 is the greenest and safest type; for instance, it does not produce oxygen, even when completely decomposed due to heating. The proposed batteries in terms of performance are LiNi 1-x-y Mn x CoyO 2 because they can combine LiCoO 2 and LiNiO 2 and use much less Cobalt, making them safer. • Among all modern rechargeable electromechanical batteries, the impact of temperature on capacity degradation and aging is unavoidable within the operation. For this reason, NaNiCl 2 batteries have shown a greater thermal runaway range compared to other batteries. There is a gap in the literature on the thermal runaway of emerging lithium-ion batteries such as LiNiCoAlO 2 , LiNi x Mn y Co z O 2 , and LiCoO 2 cathodes. • While the life cycle plays an important role in BESS design requirements, e.g., the US-advanced battery consortium defines a life cycle of 1000 cycles as one of the design requirements. In this paper, the aging effects and capacity degradation of a lithium-ion battery pack were investigated. Considering the battery cell temperature, the simulation-based study considered the HEV to operate for five hours driving under the WLTP drive cycle. The recorded results reported capacity fading of 18.42% between 25-65 • C. The equivalent cycle number also rose by 19% for the same range of ambient temperature. Additionally, the impact of charging/discharging currents from the battery cell bus was presented using QMC simulations; the evaluations compared the increase of cycles required to finish the five-hour driving cycle. Higher temperatures resulted in a higher cycle number with consideration of the capacity fading. • Based on the predictions using additive Winter's method, the growing global market of EVs will increase by 140% in 2025. The lithium-ion market will increase by 11% and 65%, between 2020-2025, for light-duty and heavy-duty EVs. The future short-term predictions also indicate that the lithium-ion cell production mass will rise by 81% and 74% for both light-duty and heavy-duty EVs in the market between 2020-2025.

•
Based on the predictions in this study, the worldwide EV market will grow by approximately 140% up to 2025. Europe is likely to experience an increase of approximately 103% and 110% million in the sales for BEV and PHEV in the next five years. That implies that the number of vehicles sold in 2019 will more than double in five years. Similarly, the US demand will grow by approximately 135% for BEV and 114% for PHEV, almost tripling the 2019 recorded data. BEVs with a 110% increase and PHEVs with a 132% increase will significantly grow in China, regardless of population density.
The aging analysis and other post-processing considerations play a critical role in an optimum, sustainable, and cost-effective transport system. Improving the effective life of electrochemical batteries can significantly replace environment-related detriments, reducing emissions and production costs of new batteries with recovering market supply chains and economic viability. While engineers and scientists are advancing the BESS's technology, more investigations are needed to ensure that this will not become a crucial environmental liability. Although EVs' positive environmental impacts are indisputable, there are a few raised challenges, such as recycling, damaging local effects of uncontrolled mining and refining, raw materials shortages (e.g., Cobalt), second-life battery utilization, charging station infrastructure, and potential supply/demand mismatch. Sustainable transport development is only reachable if all of these questions are answered, and further research is thus required.