Durability Performance Evaluation of Rubberized Geopolymer Concrete

: Unfortunately, the production of cement impacts pessimistically on environments since it emits CO 2 —a principal Green House Gas (GHG)—encouraging the earth-heating dilemma. More-over, it necessitates not only high temperature produced by the devouring of narrow natural mineral coal resources to obtain very high amounts of energy, but it also gulps down natural limestone deposits as a raw material that is found conﬁned in nature to obtain intense energy. Quite recently, geopolymerisation—an exothermic process, through which geopolymeric binders can be produced by synthesis of a pozzolanic precursor rich in Alumina and Silica, for an instant, Fly Ash, with alkali solution for activation in an alkali medium at a low temperature and low operational energy—is recognized as a brilliantly promising alternative to conventional cement. That means, no elevated temperature and higher energy consuming reactions are essential any more as found associated with contemporary cement production. This research paper moves towards fulﬁlling the performance evaluation of durability studies viz., water permeability, sorptivity, sulphate resistance, acid resistance, salt resistance, chloride diffusion, drying shrinkage, and corrosion of ﬂy ash based user and eco-friendly rubberized (containing rubber tyre ﬁbres) geopolymer concrete. Comparisons of the outcomes have been made with its counterpart, which has unearthed that Rubberized Geopolymer Concrete proved to better concerning all the above-mentioned parameters than Rubberized OPC-Concrete.


Introduction
Even though Portland cement is an excellent and vital binder for construction composites but unfortunately, its present production process is highly energy consuming [1] and on the top of that, it emits approximately one tonne of CO 2 for the production of each ton of Portland cement [2,3]. Not only that, the process also gulps down confined natural rock resources of limestones as raw material and mineral coals as fuel to obtain the elevated temperatures essential for calcination [3]. All these challenges have compelled world researchers to develop new, user and eco-friendly alternative construction materials with reduced energy and low levels of carbon footprints, which can desirably integrate with profound diverse wastes while keeping the performance of the resulting building materials as high as or even higher than the ordinary Portland cement system [4]. Nowadays, the innovative green Geopolymer technology is eye-catching due to its outstanding performances of Geopolymer construction composites like nine times lesser CO 2 emissions, and six-fold lower operational energy consumption [2], preventing the degradation of

Raw Materials
For the production of RGPC, rubber tyre fibres procured from tyre waste grinding unit as well as Class F type fly ash were used to confirm the Indian standard IS 3812 [21]. Table 1 [18,22] displays the chemical composition of fly ash. To partly substitute river sand, rubber fibres (10,20, and 30% substitution) with a specific gravity of 1.09 and 8-10 aspect ratio, the rubber fibres were almost 2-4 mm thick and up to 22 mm in length were used. The particle distribution curve for the rubber fibres is lying Zone II, as shown in Figure 1 according to IS: 383-1970 [23]. The fineness modulus −2.56, specific gravity −2.61 as well as water absorption-0.5% pragmatized. The sand of the river meets zone II according to IS: 383-1970 [23]. The superplasticizer based on naphthalene sulphonate was employed to accomplish the anticipated workability. The fly ash XRD is displayed in Figure 2.

Raw Materials
For the production of RGPC, rubber tyre fibres procured from tyre waste grinding unit as well as Class F type fly ash were used to confirm the Indian standard IS 3812 [21]. Table 1 [18,22] displays the chemical composition of fly ash. To partly substitute river sand, rubber fibres (10,20, and 30% substitution) with a specific gravity of 1.09 and 8-10 aspect ratio, the rubber fibres were almost 2-4 mm thick and up to 22 mm in length were used. The particle distribution curve for the rubber fibres is lying Zone II, as shown in Figure 1 according to IS: 383-1970 [23]. The fineness modulus −2.56, specific gravity −2.61 as well as water absorption-0.5% pragmatized. The sand of the river meets zone II according to IS: 383-1970 [23]. The superplasticizer based on naphthalene sulphonate was employed to accomplish the anticipated workability. The fly ash XRD is displayed in Figure 2.  1. Particle size distribution curve [18,22]. Figure 1. Particle size distribution curve [18,22].  Table 2 demonstrate the parameters used for this study. Based on this mixing design method, the final mass of the parts was calculated as outlined in Table 3. The OPC concrete mix was calculated as per IS 10262-2009 [24]. Table 3 lists the OPC concrete mix. The fine aggregate in concrete was partially substituted with waste rubber tyre fibres. Table 2. The following parameters were used for this research study [19].
Alkaline liquid to fly ash ratio 0.4 5.
Curing temperature 90℃    Table 3 lists the OPC concrete mix. The fine aggregate in concrete was partially substituted with waste rubber tyre fibres. Table 2. The following parameters were used for this research study [19].

Sr.No
Parameters Value
Alkaline liquid to fly ash ratio 0.4 5.

Details of the Experiment
Durability testing in compliance with norms has been carried out (see Table 4). The information is shown in Table 4.

Durability Experiments Methods
Concrete durability is described as its capability to withstand weathering, abrasion, chemical attachments, or other deterioration processes.

Water Permeability
The capacity of a fluid to pass through concrete is described by permissibility. It is the key durability parameter. Tests were performed as per DIN 1048DIN -1991. Concrete cubes of 150 × 150 × 150 mm size were dried in a drying chamber for 14 days. The depth of water permeation inside the concrete under sustained pressure was inspected from this test. A sustained pressure of 5 bars (0.5 N/mm 2 ) was applied in the vertical plane along the mould filled direction for three days. The penetration depth was evaluated after three days by half dividing the cube. The average penetration depth of three cubes was regarded.

Carbonation
The calculation is the gradual neutralisation of the alkali from external sources (primarily atmospheric carbon dioxide) in the concrete cover with acidic gasses. This test method involves determining, by way of an indicator, the depth of the carbonated layer on the surface of hardened concrete. The 100 mm 3 cubes were divided into four prisms sized 50 × 50 × 100 mm to perform the accelerated carbonation test. Each prism specimen was allowed to dry in a drying chamber for 2 weeks until a persistent weight was accomplished. After drying, two coats of epoxy paint were applied on the longitudinal side of the specimens to resist the penetration of carbon dioxide, leaving the top and bottom sides of each specimen to be penetrated by carbon dioxide. The samples were held in a carbonation chamber. A 5% -carbon dioxide, relative humidity-50 ± 5%, and temperature-25 ± 1 • C are maintained by the carbonating chamber. After 14,21,28,35,42,56, and 90 days of CO 2 exposure, carbon concentration depth was measured. The depth of carbonation was measured by splitting the specimens in half and instantly spraying a phenolphthalein indicator over the broken surface. By blending 1% phenolphthalein in 70% ethyl alcohol, the indicator was made. The carbonation depth from the top and bottom of the sample was evaluated after praying the indicator. The average of three specimen readings was considered to be the depth of carbonation of that mix.

Drying Shrinkage
This test examined the effect of rubber tyre fibre replacement on the shrinkage of geopolymer concrete as well as cement concrete. Each mix was moulded with three prisms of 75 × 75 × 285 mm in size. After curing, Demec studs were pasted 212 ± 1 mm apart on the uppermost surface of each sample. Shrinkage strain was measured using a mechanical strain gauge three days after casting. The next shrinkage strain measurement was taken 4 days after casting, and this was considered to be the first-day shrinkage measurement of the specimen. In the first week, measures were taken every day, from 1 to 4 weeks, once every 2 weeks up to 12 weeks, and then once in 4 weeks. The gauge has a minimum resolution of 0.002 mm. Specimens were maintained at a laboratory room temperature at 25 • C with a relative humidity of 50-60%.

Sulfate Resistance
The resistance against sulphate of the control geopolymer concrete and cement concrete was inspected through the change in mass as well as residual compressive strength. Cubes of 100 × 100 × 100 mm have been cast to assess weight and residual compressive strength. After curing, each specimen was weighed to give an initial weight. Seven days after curing, the samples were submerged in a 5% concentration of sodium sulphate solution. The volume of sodium sulphate was calculated based on the volume of sulphate solution: the volume of the specimen (4:1 ratio).
The solution was swapped every month to maintain its concentration. The mass change, length change, and residual compressive resistance changes were evaluated after exposure to 7, 28, 84, 162, and 365 days. The remaining compressive strength was assessed after exposure by checking the samples in saturated dry surface conditions (SSD). To measure the change in mass, samples were detached from the solution, wiped properly, and their mass was measured. The specimens were then returned to soak in the sulphate solution. A mechanical strain gauge was used to measure the shift in length.

Acid Resistance
Resistance against acid was evaluated using geopolymer and cement concrete samples-100 × 100 × 100 mm in size. Solutions of 3%, 5%, and 10% concentrated sulfuric acid were produced to examine the upshot of acid on the specimens. The original weight or dry weight was assessed for 7, 28, 84, 162, and 365 days after casting, and then the specific samples were taken in the solution. At every selected exposure period, the mass change and residual compressive strength were measured. The solution was removed weekly and substituted each month to preserve the pH level. The volume of solution was determined based on the solution volume to the specimen volume (4:1ratio). The samples were separated from the solution and wiped off to remove the solution from the surface after the chosen phases of exposure. The weight of the specimens was measured in SSD condition and the residual compressive strength was tested.

Salt Attack Resistance
Salt attack resistance was measured using 100 × 100 × 100 mm cubes for 7, 28-, 84-, 162-, and 365-days exposure periods. A solution was prepared with a 5% concentration of sodium chloride. After curing, the specimens were weighed to determine their initial weight. The specimens were then engrossed in solution for a selected exposure period. The mass change and residual compressive strength were investigated from this test. Specimens have been removed, wiped, and weighed to alter the mass. The samples were evaluated in SSD conditions for the change in compressive strength.

Water Sorptivity
Water sorptivity experiments were performed to assess the absorbance level (sorptivity) of water by capillary concrete suction. The experiments were done following the requirements of ASTM C1585-04 [26]. This experiment was carried out using specimens with a diameter of 100 ± 6 mm and a height of 50 ± 3 mm. This test included samples placed at 50 ± 2 • C in a desiccator. To control the relative humidity, potassium bromide solution was placed in the bottom of the desiccator in such a way that the test specimens could not contact the solution. Each specimen was placed in the desiccator for up to three days. Afterwards, the sample was positioned inside a sealable ampoule to prevent contact with free air. At least 15 days before the sorptive procedure, the container is stored at 23 ± 2 • C. Specimens have been removed from storage, and before sealing, their mass was registered. The bottom and side surfaces of each sample were wrapped with a sealing material. The measurement of the mass in each given sample was done as the original mass for calculations of water sportiveness. The bars were positioned on the bottom of a pot for assistance. The plate was filled to 1-3 mm above the top of the support bars with distilled water. The original contact time and date with water have been registered. The masses were registered at the 60 s, 5 min, 10 min, 20 min, 30 min, 60 min, and then up to 6 h, once a day for a week. One final reading was taken on day 9. To weigh the specimens, they were taken from the tray, excess water removed, and their dry surface placed on an electronic pan balance. The engrossing surface was not touched, and the specimen was returned to the tray within 15 s.

Chloride Ion Migration
This test examined the resistance of the concrete samples against chloride ion penetration. This experiment consisted of concrete codes with a diameter of 60 mm and a height of 150 mm. With the assistance of a cutting saw machine, each core was sliced to a thickness of 40 mm. The side and ends of the specimen were covered with silicon sealant and masking tape, respectively. The specimen was then mounted on top and bottom with a rubber gasket and masking tape before being immersed in distilled water. The chloride cell consisted of two parts: an upstream part acting as the anode was occupied with 3% sodium chloride solution concentration; a distilled water portion was loaded downstream to function as a cathode. A possible distinction of 30 V DC was implemented between the migrating cells. The chloride ion concentration was examined in the upstream cell using a titration method. Similarly, in the downward part, the chloride ion concentration was calculated every 4 h until the steady-state condition was reached. The titration process was performed by taking 20 mL solution samples from the downstream cell and adding an indicator of potassium chromate. Silver nitrate solution (0.0141 N) was then slowly added to the ask until the solution had a reddish tinge, and the volume of silver nitrate was recorded. The concentration of chloride ion in the downstream cell was calculated as the steady-state chloride diffusion coefficient Dssm was assessed,

Corrosion
To study the resistance of concrete to steel corrosion, a chloride-induced corrosion technique was employed. To examine the corrosion induced by embedded steel in concrete, we used a macro-cell corrosion method and a half-cell potential method. In these methods, 12 mm diameter Thermo mechanically treated reinforcements of a length of 350 mm were first cleaned using a wire brush. Then, 70 mm at the apiece end of the bar was coated with epoxy paint to prevent corrosion of that portion of the bar outside the specimen. Specimens of 250 × 205 × 135 mm with a ponding well of 15 mm at the top were cast. The bars were arranged such that 350 mm of their length was within the sample, with one bar centrally placed at the top as well as two bars placed with 30 mm cover at the bottom, such that the middle portion of the bars (210 mm length) was exposed to corrosion and 70 mm protruded from each side of the concrete specimen. The upper bars were the anode, and the lower bars were the cathode. The reinforcement bars were weighed adequately before casting the corrosion samples. The bottom and lateral faces of the samples were covered with epoxy after curing. In a temperature and humidity-controlled space, specimens were maintained. The electrical connection between the anode and cathode was ensured utilizing a soldered wire. Between the top and bottom bars, a 100 mm resistor was linked. A 3% concentration of sodium chloride solution filled the 15 mm depression at the top of each specimen, and alternating cycles of wetting and drying were conducted for up to 2 weeks.
To assess the potential difference between the anode and cathode bar in the resistor with a voltmeter, the macro cell corrosion experiment was used. The test was conducted as per ASTM G 109 [27]. An initial reading was taken 7 days after ponding the sodium chloride over the specimen. The terminal of the voltmeter was connected with the bottom bars for reading. A negative voltage link to the positive Galvanic current, i.e., the anode at the top of the bar. Every month, over 12 months, readings were taken. The macro-cell current was calculated as I j = V i 100 where as, I j = Macro-cell current V j = Voltage measured over 100 Ω resistor Half-cell potential measurements were done at the top steel bar according to the reference copper-copper sulphate electrode (CSE) by immersing it in a 3% concentrated NaCl solution. The top and bottom bars were separated before the reading and the current could be stabilized. A voltmeter was used to read the potential once a month. The possibility of corrosion based on the value of potential difference concerning CSE was measured as per ASTM C 876 [28]. If the potential over an area is higher than −200 mV, there is a chance of there being no reinforcing corrosion in that area of more than 90% when the measurement is made. If the potential of the reinforcing steel in that region is between −200 to −350 mV, corrosion in that region is uncertain. When the potential for a region is less than −350 mV, it is more than 90% likely that steel corrosion will be reinforced when the measurement is carried out in that region.

Water Permeability
Permeability was evaluated in terms of the depth of water penetration. The depth of penetration of the water in terms of rubber fibre content demonstrates variety in Figure 3. The water penetration depth increases as the content of rubber fibre are increased. In geopolymer concrete, the water penetration is smaller than in OPC concrete. In a prior study, a similar outcome was noted [29]. The continuous chemical reaction amid fly ash as well as alkaline solution results in a change in porosity and creates denser pores in geopolymer concrete [29,30]. However, a detailed examination found that the variations were very small in the case of geopolymer concrete. Minimum and maximum water penetration values of 31.2 mm and 35.7 mm occur in the geopolymer concrete.
The rise in penetration depth may be ascribed to the rise of concrete porosity, which can be seen at greater rubber fibre replacement rates. In OPC concrete, the minimum and maximum water penetration are 38.03 mm and 42.8 mm, respectively. The development of pores is dependent on the alkaline solution, aggregate, and source materials. Unlike the OPC concrete, which undergoes a hydration process, the pores in the geopolymer are filled by alumino-silicates. This lower permeability of geopolymer concrete has led to it being referred to as "excellent" concrete [29,31].

Sorptivity
Sorptivity measures the transport properties of concrete by which water passes through capillary pores into the concrete. Figures 4 and 5 illustrate the sorptivity index of geopolymer as well as OPC concrete. From Figure 4, it is possible to conclude that the geopolymer concrete has lower sorptivity (0.09-0.164 mm/min 0.5 ) than OPC concrete (0.113-0.203 mm/min 0.5 ) after 28 days. A similar observation was recorded in previous research [32]. The limit of the sorptivity index is below 0.200 mm/min 0.5 , which is the recommended value for concrete according to previous research [32]. The control geopolymer concrete has a sorptivity index of 0.09 mm/min 0.5 after 28 days ( Figure 5).
This fact indicates that few capillary pores exist following the effective reaction amid the alkaline solution as well as source material, whereas capillary pores persist in the OPC concrete to enable the hydration of the cement. Additionally, as the rubber fibre content is increased, the sorptivity index is increased for both the concrete (geopolymer and OPC). Hence, geopolymer concrete has fewer capillary pores than OPC concrete. This results in a slower rate of sorptivity into the geopolymer concrete compared with OPC concrete. The rise in penetration depth may be ascribed to the rise of concrete porosity, which can be seen at greater rubber fibre replacement rates. In OPC concrete, the minimum and maximum water penetration are 38.03 mm and 42.8 mm, respectively. The development of pores is dependent on the alkaline solution, aggregate, and source materials. Unlike the OPC concrete, which undergoes a hydration process, the pores in the geopolymer are filled by alumino-silicates. This lower permeability of geopolymer concrete has led to it being referred to as "excellent" concrete [29,31].

Sorptivity
Sorptivity measures the transport properties of concrete by which water passes through capillary pores into the concrete. Figures 4 and 5 illustrate the sorptivity index of geopolymer as well as OPC concrete. From Figure 4, it is possible to conclude that the geopolymer concrete has lower sorptivity (0.09-0.164 mm/min 0.5 ) than OPC concrete (0.113-0.203 mm/min 0.5 ) after 28 days. A similar observation was recorded in previous research [32]. The limit of the sorptivity index is below 0.200 mm/min 0.5 , which is the recommended value for concrete according to previous research [32]. The control geopolymer concrete has a sorptivity index of 0.09 mm/min 0.5 after 28 days ( Figure 5).
This fact indicates that few capillary pores exist following the effective reaction amid the alkaline solution as well as source material, whereas capillary pores persist in the OPC concrete to enable the hydration of the cement. Additionally, as the rubber fibre content is increased, the sorptivity index is increased for both the concrete (geopolymer and OPC). Hence, geopolymer concrete has fewer capillary pores than OPC concrete. This results in a slower rate of sorptivity into the geopolymer concrete compared with OPC concrete. Sustainability 2021, 13, × FOR PEER REVIEW 10 of 27

Sulfate Resistance
On geopolymer concrete and OPC cement, the sulphate resistance test has been performed. The experiment was carried out with samples soaked in 5% Na2SO4 (sodium sulphate) solution. After exposure periods of 7, 28,84, 162, and 365 days, the sulphate resistance was assessed based on changes in physical appearance, mass, length, and compressive strength. Samples were also soaked in distilled water for comparison. Following one year of exposure, the physical appearance of the geopolymers is shown in Figure 6.

Sulfate Resistance
On geopolymer concrete and OPC cement, the sulphate resistance test has been performed. The experiment was carried out with samples soaked in 5% Na2SO4 (sodium sulphate) solution. After exposure periods of 7, 28,84, 162, and 365 days, the sulphate resistance was assessed based on changes in physical appearance, mass, length, and compressive strength. Samples were also soaked in distilled water for comparison. Following one year of exposure, the physical appearance of the geopolymers is shown in Figure 6.

Sulfate Resistance
On geopolymer concrete and OPC cement, the sulphate resistance test has been performed. The experiment was carried out with samples soaked in 5% Na 2 SO 4 (sodium sulphate) solution. After exposure periods of 7, 28,84, 162, and 365 days, the sulphate resistance was assessed based on changes in physical appearance, mass, length, and compressive strength. Samples were also soaked in distilled water for comparison. Following one year of exposure, the physical appearance of the geopolymers is shown in Figure 6. No modifications were noted in the geopolymer samples after exposure to sodium sulphates for up to one year. The OPC concrete specimen was, by comparison, widened and often randomly cracked. Similar observations in prior studies have been recorded [33]. No modifications were noted in the geopolymer samples after exposure to sodium sulphates for up to one year. The OPC concrete specimen was, by comparison, widened and often randomly cracked. Similar observations in prior studies have been recorded [33].     Figure 7 illustrates the mass change of geopolymer concrete specimens subsequently sodium sulphate exposure up to one year. It can be seen that there has been no significant change in mass in the geopolymer specimen, whereas the mass of the OPC concrete specimen (Figure 8) has increase initially due to fascination of sodium sulphate solution and degradation of mass observed due to the effect of sodium sulphate solution shown in Figure 8. A significant increase in mass was observed in the geopolymer specimen as a result of the absorption of liquid through geopolymer specimens. The absorption of liquid by the geopolymer specimens increased their mass by 1.3%, compared with an increase in mass of 3.0-3.5% in the OPC specimens. No modifications were noted in the geopolymer samples after exposure to sodium sulphates for up to one year. The OPC concrete specimen was, by comparison, widened and often randomly cracked. Similar observations in prior studies have been recorded [33].    and extended gypsum, the lower compressive strength in OPC concrete results in cracking, extension, and degradation. In previous studies, similar findings were noted [33][34][35][36][37][38][39][40]. In geopolymer concrete, the hydration method is replaced by the geopolymerisation method, meaning that gypsum and ettringite are usually not formed. The high alkali content improves the resistance of geopolymers against sulphate exposure, as confirmed by previous research [33]. The findings indicate obviously that the geopolymer concrete is superior in resistance to sulphates to OPC concrete.    Figures 9 and 10 show changes in the compressive strength of the geopolymer and OPC concrete samples following exposure to sodium sulphate. After exposure, each specimen had compressive strength measured in SSD conditions. In geopolymer samples with exposure, there has been an important shift in compressive strength while in OPC concrete samples, compressive strength has been lowered. Due to the creation of ettringite and extended gypsum, the lower compressive strength in OPC concrete results in cracking, extension, and degradation. In previous studies, similar findings were noted [33][34][35][36][37][38][39][40]. In geopolymer concrete, the hydration method is replaced by the geopolymerisation method, meaning that gypsum and ettringite are usually not formed. The high alkali content improves the resistance of geopolymers against sulphate exposure, as confirmed by previous research [33]. The findings indicate obviously that the geopolymer concrete is superior in resistance to sulphates to OPC concrete.  10 show changes in the compressive strength of the geopolymer and OPC concrete samples following exposure to sodium sulphate. After exposure, each specimen had compressive strength measured in SSD conditions. In geopolymer samples with exposure, there has been an important shift in compressive strength while in OPC concrete samples, compressive strength has been lowered. Due to the creation of ettringite and extended gypsum, the lower compressive strength in OPC concrete results in cracking, extension, and degradation. In previous studies, similar findings were noted [33][34][35][36][37][38][39][40]. In geopolymer concrete, the hydration method is replaced by the geopolymerisation method, meaning that gypsum and ettringite are usually not formed. The high alkali content improves the resistance of geopolymers against sulphate exposure, as confirmed by previous research [33]. The findings indicate obviously that the geopolymer concrete is superior in resistance to sulphates to OPC concrete.

Acid Resistance
The acid resistance assessment was observed on the geopolymer concrete as well as OPC concrete specimens by soaking them in 3%, 5%, and 10% concentrations of sulfuric acid for 7, 28, 84, 162, and 365 days. This experiment shows the behaviour, physical appearance, changes in weight, and compression strength changes, after exposure to sulfuric acid, of the geopolymer concrete and OPC concrete. Figure 11 demonstrates the physical appearance after one year of exposure to geopolymer samples. The specimens of all mixtures undergo erosion after exposure to acid. The damage to the concrete surface increases as the sulfuric acid becomes stronger. OPC concrete samples are more erosive than geopolymer concrete. Figure 11. Physical appearances of specimens after sulphuric acid exposure. Figures 12 and 13 show the change in mass of both types of concrete after 5% acid exposure for up to 365 days. It could be observed that the geopolymer concrete specimens

Acid Resistance
The acid resistance assessment was observed on the geopolymer concrete as well as OPC concrete specimens by soaking them in 3%, 5%, and 10% concentrations of sulfuric acid for 7, 28, 84, 162, and 365 days. This experiment shows the behaviour, physical appearance, changes in weight, and compression strength changes, after exposure to sulfuric acid, of the geopolymer concrete and OPC concrete. Figure 11 demonstrates the physical appearance after one year of exposure to geopolymer samples. The specimens of all mixtures undergo erosion after exposure to acid. The damage to the concrete surface increases as the sulfuric acid becomes stronger. OPC concrete samples are more erosive than geopolymer concrete.

Acid Resistance
The acid resistance assessment was observed on the geopolymer concrete as well as OPC concrete specimens by soaking them in 3%, 5%, and 10% concentrations of sulfuric acid for 7, 28, 84, 162, and 365 days. This experiment shows the behaviour, physical appearance, changes in weight, and compression strength changes, after exposure to sulfuric acid, of the geopolymer concrete and OPC concrete. Figure 11 demonstrates the physical appearance after one year of exposure to geopolymer samples. The specimens of all mixtures undergo erosion after exposure to acid. The damage to the concrete surface increases as the sulfuric acid becomes stronger. OPC concrete samples are more erosive than geopolymer concrete. Figure 11. Physical appearances of specimens after sulphuric acid exposure. Figures 12 and 13 show the change in mass of both types of concrete after 5% acid exposure for up to 365 days. It could be observed that the geopolymer concrete specimens gain some weight during the first week of exposure because they absorb the liquid over this period. From this point on, the mass of all specimens decreases as a result of acid exposure. It is apparent that with the exposure time, the proportion of mass loss rises. In geopolymer concrete, the results for the first week show that the mass of the specimens increased by 0.98-1.15% for all concentrations, then decreased over the remaining exposure period. In the OPC concrete, the mass of the specimen increased by 1.8-2.5% in the first week and then decreased. The OPC concrete specimens lost more mass than the geopolymer concrete specimens. This result agrees with previous research [33,[41][42][43][44][45]. gain some weight during the first week of exposure because they absorb the liquid over this period. From this point on, the mass of all specimens decreases as a result of acid exposure. It is apparent that with the exposure time, the proportion of mass loss rises. In geopolymer concrete, the results for the first week show that the mass of the specimens increased by 0.98-1.15% for all concentrations, then decreased over the remaining exposure period. In the OPC concrete, the mass of the specimen increased by 1.8-2.5% in the first week and then decreased. The OPC concrete specimens lost more mass than the geopolymer concrete specimens. This result agrees with previous research [33,[41][42][43][44][45].   gain some weight during the first week of exposure because they absorb the liquid over this period. From this point on, the mass of all specimens decreases as a result of acid exposure. It is apparent that with the exposure time, the proportion of mass loss rises. In geopolymer concrete, the results for the first week show that the mass of the specimens increased by 0.98-1.15% for all concentrations, then decreased over the remaining exposure period. In the OPC concrete, the mass of the specimen increased by 1.8-2.5% in the first week and then decreased. The OPC concrete specimens lost more mass than the geopolymer concrete specimens. This result agrees with previous research [33,[41][42][43][44][45].    sive strengths of 32.14,30.78, and 17.65 MPa, respectively, after 365 days, whereas for the control OPC concrete, the respective strengths are 29.23, 26.00, and 13.89 MPa. This demonstrates that the geopolymer concrete is stronger than OPC concrete against sulfuric acid. In geopolymer concrete, the source material contains relatively little calcium, which is the major factor in increasing resistance against acid [33,43,44]. In all mixes, it was found that higher concentrations of sulfuric acid result in greater deterioration, resulting in greater strength loss. In the geopolymer specimens, this deterioration is due to the formation of zeolite and the depolymerization of alumino-silicate. Similar results have been confirmed by previous research [33,44]. These results also prove that geopolymer and OPC concrete containing rubber fibres enhance the concrete porosity, which causes a greater reduction in compressive strength.   Figure 15. Modification of the geopolymer compressive strength following exposure to 5% sulfuric acid. Figure 15. Modification of the geopolymer compressive strength following exposure to 5% sulfuric acid. Figures 14-19 show that exposure to sulphuric acid decreases its compressive strength. Compressive strength change relies on the sulfuric acid concentration and exposure duration. Increases in the period of exposure and concentration of sulfuric acid enhance the degradation in compressive strength of all mixes. The rate of reduction of compressive strength is highest following the one-year exposure period. In the control geopolymer concrete, the 3%,5%, and 10% concentrations of sulfuric acid result in compressive strengths of 32.14,30.78, and 17.65 MPa, respectively, after 365 days, whereas for the control OPC concrete, the respective strengths are 29.23, 26.00, and 13.89 MPa. This demonstrates that the geopolymer concrete is stronger than OPC concrete against sulfuric acid. In geopolymer concrete, the source material contains relatively little calcium, which is the major factor in increasing resistance against acid [33,43,44]. In all mixes, it was found that higher concentrations of sulfuric acid result in greater deterioration, resulting in greater strength loss. In the geopolymer specimens, this deterioration is due to the formation of zeolite and the depolymerization of alumino-silicate. Similar results have been confirmed by previous research [33,44]. These results also prove that geopolymer and OPC concrete containing rubber fibres enhance the concrete porosity, which causes a greater reduction in compressive strength.

Chloride Diffusion
For geopolymer and OPC concrete samples, a continuous state chloride ion migration experiment was conducted, and the chloride diffusion coefficients are listed in Figure  20. The geopolymer concrete has reduced diffusion coefficients of chloride compared to OPC concrete from this figure. The chloride diffusion coefficients increase with the rubber fibre content in both types of concrete. The minimum chlorine diffusion coefficients for geopolymer concrete and OPC concrete are 1.0 × 10 −12 and 1.5 × 10 −12 , respectively, and the maximum chloride diffusion coefficients are 1.2 × 10 −12 and 1.7 × 10 −12 , respectively. These values are comparable to the values of earlier research [45].

Chloride Diffusion
For geopolymer and OPC concrete samples, a continuous state chloride ion migration experiment was conducted, and the chloride diffusion coefficients are listed in Figure 20. The geopolymer concrete has reduced diffusion coefficients of chloride compared to OPC concrete from this figure. The chloride diffusion coefficients increase with the rubber fibre content in both types of concrete. The minimum chlorine diffusion coefficients for geopolymer concrete and OPC concrete are 1.0 × 10 −12 and 1.5 × 10 −12 , respectively, and the maximum chloride diffusion coefficients are 1.2 × 10 −12 and 1.7 × 10 −12 , respectively. These values are comparable to the values of earlier research [45].

Macrocell Current Measurements
A 100-Ohm resistance was used to measure the macrocell current according to ASTM G109 [42]. The favourable macrocell current shows that the corrosion is ongoing. To guarantee adequate corrosion, a minimum of 10µA is regarded. Figure 21 demonstrates that macrocellular current was less than 10 µA in the case of both control and rubberized geopolymer concrete, up to 9 months, whereas, in the 10, 11, and 12th month all mixes received more than 10 µA macrocell currents. Figures 21 and 22 show the variability of macrocell current overtime for geopolymer concrete and OPC concrete. The macrocell current for rubberized concrete was more than that for the control concrete at all ages.
The current in OPC concrete exceeded 10 µA in all mixtures from the 8th month to the 12th month. For geopolymer concrete, the highest anode current for the control mixture was 11.2 µA, 13.4 µA, 17.1 µA, and 19.3 µA for the 12th month, while the peak current was measured at 15.3 µA, 18.9 µA, 15.8 µA, and 22.1 mA for OPC concrete. The above findings demonstrate that the incorporation of rubber waste fibres improve the likelihood of early corrosion initiation in both kinds of concrete.

Chloride Diffusion
For geopolymer and OPC concrete samples, a continuous state chloride ion migration experiment was conducted, and the chloride diffusion coefficients are listed in Figure  20. The geopolymer concrete has reduced diffusion coefficients of chloride compared to OPC concrete from this figure. The chloride diffusion coefficients increase with the rubber fibre content in both types of concrete. The minimum chlorine diffusion coefficients for geopolymer concrete and OPC concrete are 1.0 × 10 −12 and 1.5 × 10 −12 , respectively, and the maximum chloride diffusion coefficients are 1.2 × 10 −12 and 1.7 × 10 −12 , respectively. These values are comparable to the values of earlier research [45].

Macrocell Current Measurements
A 100-Ohm resistance was used to measure the macrocell current according to ASTM G109 [42]. The favourable macrocell current shows that the corrosion is ongoing. To guarantee adequate corrosion, a minimum of 10μA is regarded. Figure 21 demonstrates that macrocellular current was less than 10 μA in the case of both control and rubberized geopolymer concrete, up to 9 months, whereas, in the 10, 11, and 12th month all mixes received more than 10 μA macrocell currents. Figures 21 and 22 show the variability of macrocell current overtime for geopolymer concrete and OPC concrete. The macrocell current for rubberized concrete was more than that for the control concrete at all ages.
The current in OPC concrete exceeded 10 μA in all mixtures from the 8th month to the 12th month. For geopolymer concrete, the highest anode current for the control mixture was 11.2 μA, 13.4 μA, 17.1 μA, and 19.3 μA for the 12th month, while the peak current was measured at 15.3 μA, 18.9 μA, 15.8 μA, and 22.1 mA for OPC concrete. The above findings demonstrate that the incorporation of rubber waste fibres improve the likelihood of early corrosion initiation in both kinds of concrete.

Half-Cell Potential Measurements
The half cell potential was evaluated between the top bar and a reference electrode following ASTM C876 [28]. Figures 23 and 24 show the outcomes of half-cell potential measurements for geopolymer and OPC concrete. According to ASTM standards, the likelihood of corrosion in reinforcement steel bars is more than 90% where potentials are more negative than −350 mV. The potentials for geopolymer concrete were less negative than −350 mV up to 9 months, compared to −350 mV for the OPC concrete up to 8 months (See Figures 23 and 24).

Half-Cell Potential Measurements
The half cell potential was evaluated between the top bar and a reference electrode following ASTM C876 [28]. Figures 23 and 24 show the outcomes of half-cell potential measurements for geopolymer and OPC concrete. According to ASTM standards, the likelihood of corrosion in reinforcement steel bars is more than 90% where potentials are more negative than −350 mV. The potentials for geopolymer concrete were less negative than −350 mV up to 9 months, compared to −350 mV for the OPC concrete up to 8 months (See Figures 23 and 24).
The variance of geopolymer and OPC concrete half cell potential are shown in Figure 24. The half-cell potential of rubber fibre waste-concrete has been higher than that of the control mix at different ages. In the case of geopolymer concrete, a more negative than −350 mV was reported from the 10th month to 12th month, whilst in the 9th month to 12th month, OPC concrete potential became more negative than −350 mV. The maximum potential was measured as −360 mV, −400 mV, −420, and −460 mV for geopolymer concrete at 12 months while the supreme potential for OPC concrete at 12 months was obtained as −400 mV, −455 mV, −482 mV, and −500 mV. From the foregoing outcomes, the geopolymer concrete reduces the likelihood of corrosion initiation in comparison to OPC concrete.

Drying Shrinkage
The drying shrinkage with time is shown in Figures 25 and 26 for geopolymer concrete and OPC concrete. From the figure, it could be observed that geopolymer concrete undergoes a low drying shrinkage when compared with OPC concrete. The low drying shrink connected with its thin pores results in low diffusiveness and a significant reduction in the drying shrinkage rate. Water is expelled during the geopolymerisation phase and less water is found in geopolymer concrete micropores. This is caused by low drying shrinkage. Due to moisture motion from the atmosphere to the concrete, shrinking stress fluctuates over time and vice versa, which results in reversible shrinking and concrete swelling. The drying shrinkage can be observed as the content of the rubber fibre and time are increased. The boost in porosity owing to the inclusion of rubber particles in concrete.
The half cell potential was evaluated between the top bar and a reference electrode following ASTM C876 [28]. Figures 23 and 24 show the outcomes of half-cell potential measurements for geopolymer and OPC concrete. According to ASTM standards, the likelihood of corrosion in reinforcement steel bars is more than 90% where potentials are more negative than −350 mV. The potentials for geopolymer concrete were less negative than −350 mV up to 9 months, compared to −350 mV for the OPC concrete up to 8 months (See Figures 23 and 24).  The variance of geopolymer and OPC concrete half cell potential are shown in Figure  24. The half-cell potential of rubber fibre waste-concrete has been higher than that of the control mix at different ages. In the case of geopolymer concrete, a more negative than −350 mV was reported from the 10th month to 12th month, whilst in the 9th month to 12th month, OPC concrete potential became more negative than −350 mV. The maximum potential was measured as −360 mV, −400 mV, −420, and −460 mV for geopolymer concrete at 12 months while the supreme potential for OPC concrete at 12 months was obtained as −400 mV, −455 mV, −482 mV, and −500 mV. From the foregoing outcomes, the geopolymer concrete reduces the likelihood of corrosion initiation in comparison to OPC concrete.

Carbonation Resistance
The carbonation depth measured for geopolymer and OPC concrete is shown in Figures 27 and 28 for 14-, 21-, 28-, 35-, 42-, 56-, and 90-days duration (5% CO 2 exposure). The carbonation depth can be found to be increased by increasing the duration of CO 2 exposure and replacement of all mixes. The current study shows that carbonation depth was less than the minimum cover required for the concrete (15 mm) at the immense substitution level (30%) and elevated CO 2 levels (5% for 90 days). The carbonation depth reduced with increased rubber content for any replacement of the fine aggregate by rubber fibre. As previously noted in this study, an increase in carbon depth could be caused by a rise in water intake and water permeability. For geopolymer concrete with a 30% fine aggregate replacement level, the maximum carbonation depth of 8.0 mm had to be observed, whereas for OPC concrete, with an exposure of 90 days, at the same replacement level the carbonation depth was 9.0 mm.

Carbonation Resistance
The carbonation depth measured for geopolymer and OPC concrete is shown in Figures 27 and 28 for 14-, 21-, 28-, 35-, 42-, 56-, and 90-days duration (5% CO2exposure). The carbonation depth can be found to be increased by increasing the duration of CO2 exposure and replacement of all mixes. The current study shows that carbonation depth was less than the minimum cover required for the concrete (15 mm) at the immense substitution level (30%) and elevated CO2 levels (5% for 90 days). The carbonation depth reduced

Carbonation Resistance
The carbonation depth measured for geopolymer and OPC concrete is shown in Figures 27 and 28 for 14-, 21-, 28-, 35-, 42-, 56-, and 90-days duration (5% CO2exposure). The carbonation depth can be found to be increased by increasing the duration of CO2 exposure and replacement of all mixes. The current study shows that carbonation depth was less than the minimum cover required for the concrete (15 mm) at the immense substitu- in water intake and water permeability. For geopolymer concrete with a 30% fine aggregate replacement level, the maximum carbonation depth of 8.0 mm had to be observed, whereas for OPC concrete, with an exposure of 90 days, at the same replacement level the carbonation depth was 9.0 mm.

Salt Resistance
Geopolymer concrete and OPC concrete have been tested for salt resistance. The test was performed by soaking the specimen in 5% NaCl (Sodium chloride) solution. After exposure for 7, 28, 84, 162, and 365 days, salt resistance was assessed based on a shift in compression strength. Geopolymer concrete and OPC concrete compressive resistance are in water intake and water permeability. For geopolymer concrete with a 30% fine aggregate replacement level, the maximum carbonation depth of 8.0 mm had to be observed, whereas for OPC concrete, with an exposure of 90 days, at the same replacement level the carbonation depth was 9.0 mm.

Salt Resistance
Geopolymer concrete and OPC concrete have been tested for salt resistance. The test was performed by soaking the specimen in 5% NaCl (Sodium chloride) solution. After exposure for 7, 28, 84, 162, and 365 days, salt resistance was assessed based on a shift in compression strength. Geopolymer concrete and OPC concrete compressive resistance are

Salt Resistance
Geopolymer concrete and OPC concrete have been tested for salt resistance. The test was performed by soaking the specimen in 5% NaCl (Sodium chloride) solution. After exposure for 7, 28, 84, 162, and 365 days, salt resistance was assessed based on a shift in compression strength. Geopolymer concrete and OPC concrete compressive resistance are demonstrated in Figures 29 and 30, respectively, following sodium chloride exposures. The compressive strength of specimens was taken under saturated surface dry conditions after exposure and the results were compared with the specimens with no exposure. The compressive strength of geopolymer concrete on salty solution exposures was not significantly changed. However, the compressive strength of the rubberized geopolymer cement was somewhat reduced following the exposure of salt with 10% substitution. There was a significant reduction in the compressive strength on exposure to a salty solution for the control OPC concrete as well as the rubberized concrete. The results clearly show the excellent resistance of geopolymer concrete (both control as well as rubberized) against the OPC concrete (both rubberized as well as geopolymer).  Figures 29 and 30, respectively, following sodium chloride exposures. The compressive strength of specimens was taken under saturated surface dry conditions after exposure and the results were compared with the specimens with no exposure. The compressive strength of geopolymer concrete on salty solution exposures was not significantly changed. However, the compressive strength of the rubberized geopolymer cement was somewhat reduced following the exposure of salt with 10% substitution. There was a significant reduction in the compressive strength on exposure to a salty solution for the control OPC concrete as well as the rubberized concrete. The results clearly show the excellent resistance of geopolymer concrete (both control as well as rubberized) against the OPC concrete (both rubberized as well as geopolymer).

Conclusions
The following conclusions can be taken from the outcomes reported in this study: 1. The depth of water penetration rises with enhanced rubber fibre. In geopolymer con- Figure 30. Salt Resistance of OPC concrete specimen.

Conclusions
The following conclusions can be taken from the outcomes reported in this study: 1. The depth of water penetration rises with enhanced rubber fibre. In geopolymer concrete, the water penetration depth is smaller than in OPC concrete. The rise of the depth of penetration can be explained by the increased porosity of concrete, as is apparent at greater rubber fibre substitution concentrations.

2.
No physical modifications in the geopolymer samples were noted after exposure to sodium sulphate for up to a year. These specimens did not exhibit any change in shape, and no cracking or spalling. In contrast, the OPC concrete specimen had expanded and suffered from frequent random cracking. After exposure in the geopolymer samples, there were substantial changes in compressive strength, whereas OPC concrete samples showed lower compressive strength.

3.
The specimens of all mixtures undergo erosion after exposure to acid. The damage to the concrete surface increases as the sulfuric acid becomes stronger. It was found that higher concentrations of sulfuric acid result in greater deterioration, resulting in greater loss of strength.

4.
Geopolymer concrete has greater reduced diffusion coefficients of chloride than OPC concrete. The chloride diffusion coefficients increase with the rubber fibre content in both types of concrete. 5.
The macrocell current was greater than that for the control concrete at all ages for the rubberized concrete mixtures. The current for OPC concrete used is 10 µA for mixes at 8 months to 12 months. The incorporation of rubber waste fibre improves the likelihood of corrosion in both kinds of concrete at an early stage. 6.
The half-cell potential for the geopolymer and OPC concrete with waste fibres was greater than for the control geopolymer and OPC concrete. There recorded more negative than −350 mV in context to rubberized geopolymer concrete from the 10th month to the 12th month, while in the 9th month to the 12th month rubberized OPC concrete potential was higher than −350 mV. 7.
With the increase in the rubber fibre content and an increase in time for both cases, the drying shrinking has increased. Porosity increases due to the reduction of the shrinkage rate owing to rubber particles. 8. Carbonation depth decreased with an increase in rubber content for any substitution level of fine aggregates by a rubber fibre. For geopolymer concrete with 30% fine aggregate replacement levels, a peak carbonation depth of 8.0 mm has been noted, whereas for OPC concrete at 90 days of exposure, a carbonation depth of 9.0 mm was observed on the same replacement level.
The rubber tyre waste could be efficaciously substituting a portion of fine aggregate to form rubberized geopolymer concrete without effecting its properties.

Conflicts of Interest:
The authors declare no conflict of interest.