An Experimental and Environmental Evaluation of Mortars with Recycled Demolition Waste from a Hospital Implosion in Rio de Janeiro

: Construction and demolition waste generation have increased signiﬁcantly over the century, many times, as a result of obsolete buildings that lead the e ﬀ ort toward demolition. This paper investigates the environmental performance of mortars developed with recycled concrete from the partial building demolition of the Clementino Fraga Filho University Hospital in Rio de Janeiro, Brazil. Life Cycle Assessment is associated with experimental data to validate the application of the residue as an alternative to cement-based mortars. Natural river sand and recycled concrete aggregates, both at a micrometer scale, are employed in the production of four di ﬀ erent mortars of compressive strength ranging 50 MPa. The aggregates’ replacement rates deﬁned are 15, 25, and 50% in volume. The recycled microparticles’ mineralogical composition was determined by SEM images and XRD analysis. In addition, the attached cement paste surrounding the original aggregate particle was quantiﬁed by chemical attack. Rheological and mechanical properties of the resulting mortars were assessed by the Vane spindle rheometer and uniaxial compressive strength experiments, respectively. The approach to mortars’ environmental performance considered a cradle-to-gate scope using di ﬀ erent sensitivity analysis parameters. We demonstrated the feasibility of developing an eco-e ﬃ cient mortar taking advantage of rarely applied recycled particles. Compressive strength and environmental performance (particularly, the ozone layer depletion potential and abiotic resource depletion potential categories) increased with the aggregate replacement rate. In addition, the rheological results provided relevant data, still insu ﬃ cient to recycled aggregate mortars, presenting an exponential increase of yield stress with e ﬀ ective water to cement ratio.


Introduction
Recycling construction and demolition waste (CDW) as aggregates for cement-based materials minimize the environmental impacts of landfill disposal and overcomes the lack of natural resources [1]. Crushing procedures of CDW, e.g., in the recycled coarse aggregates production, generate large amounts of fine particle fractions, smaller than 4 mm [2,3]. In this context, several researchers have studied the possibility of replacing natural by recycled fine aggregates from CDW. Most of these studies limited the subject to the comprehension of physical and mechanical aspects of the recycled aggregate mortars [4][5][6]. Overall, they have shown satisfactory results. On the other hand, recycled aggregates the full characterization of the material behavior and its application are also essential to validate its purpose.
The research developed herein deals with a real demolition case study that focuses on generally rejected aggregate-size fractions. It is of great relevance since the number of obsolescent buildings is on the rise in many countries and the demolitions tend to consequently increase. Therefore, it is essential to evaluate the feasibility of recycling the generated waste technically and environmentally. Additionally, the study aligns with principles of the Circular Economy that should guide development plans in many countries, especially in emerging economies [27].
This paper aims to evaluate the effects of the recycled concrete aggregates-at a micrometer scale-originating from building demolition, on the environmental, rheological, and mechanical performances of mortars. Instead of limiting the study to experimental characterization data, the proposed approach also deals with the environmental performance to demonstrate the potential of its implementation. Therefore, contributing to overcome important state-of-the-art gaps, we first evaluate a demolition waste and demonstrate the feasibility of recycled aggregate particles rarely applied. Then, a more systematic analysis, using the LCA, considering different aspects in the sensitivity analysis, was carried out. The proposed approach can be applied in similar cases and stimulates the investigation of CDW from actual situations.

Materials
Brazilian high early strength Portland cement type according to ABNT NBR 16,697 [28] of 40 MPa strength class and 3.16 g/cm3 density, siliceous river sand, and deionized water were employed in the preparation of mortars.
The recycled concrete aggregate originates from the debris of the Clementino Fraga Filho University Hospital's partial implosion. Consistent details regarding the implosion procedure are described by Barreiro et al. [25], and the processing of the rubble, as well as its crushing and homogenization strategies to produce the recycled aggregates, were previously reported [6,26]. The mixtures studied herein are produced with aggregate microparticles of diameter ranging from 125 to 450 µm. Table 1 summarizes the materials' chemical composition, bulk-specific gravity, according to ABNT NBR NM 52 [29], and water absorption, according to ABNT NBR NM 30 [30], as well as the morphological aspects of both aggregate types. Of particular interest is the high content of calcium (11%) and aluminum oxide (7.8%) in the silica (66%) rich recycled sand, which evidences the presence of a cementitious layer covering the original aggregate particle. Furthermore, the low density and high-water absorption capacity of the recycled aggregate-about 5 times higher than the natural sand-are directly associated with this adhered cement paste.  Figure 1 shows the particle size distribution of the aggregates, emphasizing the size fraction between 0.15 and 0.425 mm that was extracted from the complete array of fine aggregate particles after mining (natural river sand), crushing (recycled debris), and sieving. Figure 1. Particle size distribution of the aggregates. In the main panel, only the particle size fractions between 0.15 and 0.45 mm selected for this study. The upper left inset displays the particle distribution within the complete array of fine aggregates.

Mineralogical Composition of the Recycled Concrete Aggregates by SEM Images
A series of scanning electron microscopy (SEM) analyses are performed to qualitatively evaluate the mineralogical composition of the recycled concrete aggregates, since, in a general way, the recycled aggregate particles seem highly heterogeneous, mainly because two different mineral materials compose them: natural aggregates and alkaline cement paste (see, e.g., Figure 2). . The black background is the space between particles that are filled by epoxy resin, solid gray represents the natural aggregate (NA) particles, and the more heterogeneous gray zones are the attached cement paste (AP). The samples were segregated by a sieve series, and the fraction between 150 and 600 µm was employed. The obtained samples were cold mounted with epoxy resin and subsequently ground and polished in a conventional metallographic approach. Then, the cross-sections were covered by evaporated carbon to make them conductive and suitable for SEM analysis [31].
For each sample, 10 fields, regularly spaced on the cross-sections, were imaged (1024 × 1024 pixels with 8-bit digitization) through a specimen, scanning with a motorized stage, resulting in at least 500 particles per sample. The pixel size corresponds to 2.65 µm with the applied magnification. An SEM LEO S440 was employed with a back-scattered electrons (BSE) detector, which produces images with atomic number contrast.
The image analysis procedure was performed by an automatic routine implemented in the Carl Zeiss Axiovision software. This routine separates the particles and measures some shape and texture parameters in each particle.
The particles were segmented, thresholding the grey level histogram using a fixed criterion. The careful image acquisition guaranteed that the brightness and contrast were reproducible and that the corresponding digital pixel values were stable. Thus, it was possible to use a fixed grey-level threshold, effectively automating this step.
Considering the shape characterization, no universal definition for the form of an object exists. Intuitively, the shape of an object can be described by comparing it with another one. Thus, in image analysis, the shape is commonly characterized by quantifying the differences between a given object and a reference shape.
In this analysis, only a qualitative comparison of the images was carried out, proving that the recycled aggregates present attached Portland cement paste on the original aggregate particle from crushed CDW (Figure 2), thus evidencing physical differences between natural and recycled particles, as previously discussed. In other words, this 2D view displays natural aggregate (NA) particles without surrounding attached cement paste (AP), while some others are partially or entirely covered by AP.

Mineralogical Composition of the Recycled Concrete Aggregates by X-ray Diffraction
X-ray diffraction analysis was performed on a Bruker-AXS D4 Endeavor diffractometer, with Co kα radiation (35 kV/40 mA). Diffraction patterns were acquired from 5 to 80 • (2θ) at 0.02 • steps, with a counting time of 1s per step. The identification of all the minerals was done with Bruker-AXS's DIFFRAC.EVA suite and PDF4 + 2012 relational database [32]. The aliquots for quantitative X-ray diffraction analysis were ground in a MacCrone oscillating grinder with agate grinding, mounted on the backload type support (for preferential orientation reduction), and analyzed on the X-ray diffractometer. An internal standard of 20% fluorite was used for the quantification of amorphous material.
Quantitative analyses using X-ray data were calculated using the total multiphase spectrum refinement method (Rietveld method) with Bruker-AXS Topas 4.2 software. The crystalline structure information of the refined phases was supplied by the Bruker-AXS Crystal Structures Database or obtained from the Crystallography Open Database (COD) or International Crystal Structure Database (ICSD) [33].
X-ray diffraction patterns of the aggregates are presented in Figure 3. The natural aggregate evaluation displays characteristic peaks of crystalline phases of quartz, microcline, muscovite, and fluorite minerals (see Figure 3a), while in the recycled aggregates, nearly the same minerals are found, in addition to calcite (see Figure 3b). The presence of calcite, i.e., calcium carbonate (CaCO3), evidences the occurrence of cement paste adhered to the recycled aggregate. It is possible to endorse that the recycled aggregate prevails from concrete structures due to the presence of about 12% of calcite; additionally, a very small content of kaolinite or hydrated aluminum silicate, i.e., a clay mineral, reveals some ceramic contamination. In general, the difference between both aggregates is emphasized by the presence of calcium carbonate.

Quantification of the Attached Cement Paste
In this study, the attached cement material was quantified by a chemical attack with hydrochloric acid (HCl) [34,35], which lies on the dissolution of the cement paste when immersing the recycled aggregate in an HCl solution.
The chemical attack was performed according to Braymand et al. [34] using a 30% concentrated HCl solution. First, three aggregate samples of approximately 100 g were oven-dried at 60 ± 5 • C until reaching stable mass, i.e., the initial mass (m i ) recorded. Then, they are immersed in the acidic solution for 24 h, which is sufficient to dissolute the cement matrix. In sequence, the samples are neutralized by water rinse in a 150-µm sieve, followed again by the oven drying process. Then, the final mass after attack (m f ) is recorded. Finally, the attached paste (A P ) is the difference between the sample weight after and before the attack as follows.
The amount of attached Portland cement paste determined by the chemical attack is about 43%. It is commonsensical with the previous XRD and SEM analyses that qualitatively display the presence of the attached paste. In principle, it seems more consistent with the 2D image analysis of the SEM pictures than with the Rietvel refinement of the XRD data. Note, however, that the Rietveld method quantifies only the crystalline phases (i.e., underestimating the total quantity), which lies in this considerable difference in quantification between the calcite and the attached paste by chemical attack. Overall, this high percentage of the attached paste covering the (original) aggregate particle explains the raised absorption ratio and low-density properties of the recycled material.

Mixture Proportions, Production, and Characterization of the Mortars
One reference mixture containing 100% natural aggregates is designed for 28 days compressive strength of around 45 MPa. Then, limiting the cement consumption to 750 kg/m 3 and keeping the water-to-cement (w/c) ratio to 0.45, three different aggregates substitution rates (in volume) are defined to 15, 25, and 50%. Thereby, only the proportion of aggregates (natural and recycled) changed between the four mortars: REF, M15, M25, and M50, respectively.
It is worth noting the difference between the water absorption capacities of each aggregate type used herein. The recycled one absorbs about 4.5 times more water than the natural aggregate. This fact would directly affect the mixture proportion of the three mortars incorporating it. Because any additional water related to its absorption capacity is added in the mortar's composition, the effective w/c-obtained by deducting the water amount corresponding to the absorption capacity of the aggregates (see Table 1)-consequently decreases. Table 2 shows the mortar mixture compositions. This experimental step provides classical fresh mortars' characterization from flow table tests, according to ASTM C230 [36] and vane rheometer yield stress data [7,37]. The mortars' preparation was initiated with manual mixing for 30 s to homogenize the materials, followed by a planetary mixer stirring at 300 rpm for 120 s. Then, the flow table and rheological tests were performed.
The sought rheological parameter of the fluid, namely yield stress, was determined by a Vane spindle rheometer (Brookfield DV-III Ultra Programmable Rheometer) in 600 mL of a fresh sample within a beaker vessel. The vane dimensions are 8 mm diameter and 16 mm length; about twenty times larger than the maximum aggregate diameter-restricted to 0.425 mm-which is necessary to limit disorders in the sample during probe insertion and to define the sheared surface [7]. The loading procedure is adapted from [7,38] and consists of manually placing the fresh sample spading three equal layers (≈200 mL) of it to fill the measurement vessel before starting the shearing history. Then, the vane device is inserted to perform shearing, at a given resting time, and an imposed slow angular velocity of 0.1 rpm, i.e., rotational speed, as suggested in rheology studies on cementitious materials [7,[37][38][39]. The experiments are performed in laboratory conditions at 21 ± 2 • C room temperature, and the data are recorded every 5 s. The static yield stress measures correspond to the maximum shear stress achieved, i.e., at maximum torque. Results are expressed as an average of three samples for each mortar's composition.
Compressive strength experiments are performed in cylindrical specimens of 50 mm diameter and 100 mm height at 7 and 28 days. The specimens are cast remaining in a closed container during the first 24 h to prevent water loss. Then, the specimens remain inside a moist chamber until they reach the age established for the experiment. The experiments are carried out in a servo-hydraulic machine (Shimadzu model UH-F1000kNI) with displacement control at a loading rate of 0.1 mm/min. Results are expressed as an average of three specimens to determine the mortars' compressive strength (fc) and Young's modulus (E). The latter is recorded considering the axial stress-to-strain ratio obtained within the linear regime. Statistical analyses of the experimental results are performed using analysis of variance to assess significant differences between mortars, which is considered with the probability p ≤ 0.05.

Definition of Goal, Scope, and Functional Unit
This LCA study aims to evaluate the environmental performance of the studied mortars presented in Table 2. It determines if the replacement of natural by recycled aggregate is a reliable choice in terms of minimizing negative impacts on the environment, considering which aspects are significantly constrained by the recycled aggregates.
The scope of this study is classified as cradle-to-gate since we evaluated the following life cycle stages: (A1) raw materials extraction, (A2) transportation, and (A3) mortars production, according to the recommendations of [40]. The avoided impacts (D) due to the use of recycled aggregates are also accounted for. The LCA has been performed with the software SimaPro 8.3. The functional unit (FU) chosen is one m 3 of mortar developed and tested in the laboratory. Figure 4 displays the scope and system boundaries for the processing of recycled aggregates from CDW.

Life Cycle Inventory
For the Life Cycle Inventory (LCI), data from the laboratory (primary), Ecoinvent v. 3.3, and literature were used, adapted to the Brazilian context. Additional information given as Supplementary Material displays all the processes and data used.

Avoided Impacts
The avoided impacts related to the transporting and landfill disposal of CDW were accounted for (green stages of Figure 4) based on Hossain et al. [41]. Furthermore, the avoided impacts associated with the natural aggregates (natural sand) production were also accounted for. Both types of avoided impacts are described in module D, according to EN 15978:2011 [40].

Life Cycle Impact Assessment
The CML method and the categories recommended by EN 15978:2011 [40] were employed for the Life Cycle Impact Assessment (LCIA). The categories presented in Table 3 were evaluated. Table 3. Environmental categories evaluated in Life Cycle Impact Assessment (LCIA).

Categories Unit
Abiotic Resource Depletion Potential for nonfossil resources-ADP-n kg Sb-Eq Abiotic Resource Depletion Potential for fossil resources-ADP-f MJ-ultimate base Global Warming Potential for a 100-year time frame-GWP100 kg CO 2 -Eq Depletion Potential of the Ozone Layer-ODP kg CFC-11-Eq Formation Potential of Tropospheric Ozone-POCP kg C 2 H 4 -Eq Acidification Potential-AP kg SO 2 -Eq Eutrophication Potential-EP kg (PO 4 ) 3--Eq

Sensitivity Analysis
The sensitivity analyses performed herein verify how the main system boundaries and assumptions influence the LCA results, according to the parameters presented in Table 4, followed from previous studies [42][43][44]. Table 4. Parameters evaluated in sensitivity analysis.

Aspects Description
Portland cement types Two cement types, an alternative one frequently available in the Brazilian market, with mineral additions of filler and blast furnace slag, namely CPII-E40 (around 70% of clinker) and the CPV adopted during the experimental investigation. This choice is valid since cement is the material that most contributes to concrete and mortar's environmental impacts [42].
Recycling plant type Two different recycling plants, which are powered by electricity or diesel, as previously described by [43].

Transport distances
Transportation distances of the recycled aggregates; performed for the reference and M50 mortars (with the highest content of recycled aggregates). This evaluation provides information on how far the recycled aggregate can be transported without compromising its environmental performance when compared to the reference mortar [44].

Environmental Performance Indicator
An environmental-mechanical performance indicator (in environmental impact unit/m 3 . MPa), e.g., for GWP100 is presented in kg CO2-Eq/m 3 . MPa, was adopted to validate the differences between the compressive strength of the mortars relating it to the environmental categories. This approach was successfully applied in previous studies [42,45].

Effect of Recycled Particles on the Yield Stress Measurements
Figure 5a displays typical shear stress vs. time curves-based on Tm-t profiles extracted from the vane experiments-for the plain and recycled mortars studied herein. For all loaded mixtures, the shear stress increases nearly linear up to the complete failure of bonds independent of the yield stress value achieved. It occurs at approximately 50 s, except for the mortar containing 50% of recycled sand that reaches its maximum peak value at about 90 s. Then, the maintenance of the experiment originates stress results to fall towards a steady-state zone, where they oscillate ± 0.1 kPa up to around 160 s. Overall, the calculated yield stresses increase with the aggregate substitution rate. This behavior is presented in Figure 5b concerning the effective w/c ratio. In particular, substituting 25 and 50% of natural by recycled sand increases τ 0 about 22 and 45%, respectively.
The calculated yield stress and the slump flow results are confronted in Figure 6. We observe the spreading flow values decreasing as the yield stress increases. This is expected since the replacement of natural by recycled aggregates was performed without compensating water. This means less free water remaining in the final mixture. In addition, the water demand of the higher porosity and absorption ratio of the recycled aggregates grows as the substitution rate of natural by recycled aggregates increases. These results are in accordance with previous studies (see, e.g., Duan et al. [11] and Jiang et al. [13]).   Figure 7 displays typical stress-strain curves for the mortars tested at 28 days. The linear elastic behavior remains nearly the same-ranging from 40 to 45% of the peak stress-for the reference mixture and the mortars M15 and M25. In contrast, the results of M50 show a linear elastic branch moving upwards to 52% of the total stress, although the statistical analysis confirms the absence of significant differences between the Young's Modulus of all mortars. Interestingly, the inclusion of lightweight aggregates supposes to increase the linearity of the stress-strain curve since its Young's modulus is lower than that of the rock aggregate and analogous to that of the mortar [46]. Strictly speaking, the presence of the attached cement paste covering the regular rock aggregate promotes rough and porous surface features, which seems to lightweight aggregates superficial characteristics. Nevertheless, let us emphasize that both the recycled concrete aggregate and the resulting mortars designed herein have different properties than regular lightweight aggregates and mortars themselves.  Figure 8 presents the mortars' 7-and 28-day strength evolution as a function of the effective w/c ratio (see Table 3). As expected, an evolution of the compressive strength from 7 to 28 days occurs for all mixtures. In particular, we observe that increasing the amount of recycled aggregate increases the compressive strength of mortars, in opposition to other studies [47,48]. For instance, the mixture with the lower effective w/c ratio (M50) presents an average compressive strength of about 10 MPa higher than that of highest w/c (REF) at 7 days and around 7 MPa higher at 28 days. On the other hand, when substituting 15% of the natural by recycled aggregates, i.e., modifying the effective w/c ratio only at 0.01, the mortar M15 reached about half of the total increment achieved by the M50 (e.g., 5 and 3 MPa at 7 and 28 days, respectively). Overall, these strength improvements in comparison to REF represent 6, 13, and 15% for M15, M25, and M50, respectively, at 28 days. Let us note that this strength performance may be related to different mechanisms, such as the aggregate surface roughness and the effective w/c ratio that are going to be discussed in the next section.  Figures 9 and 10 show the normalized environmental impacts of the evaluated mixtures considering different scenarios: first, CPV-ARI (cement of 90% clinker content) coupled to a diesel-fueled recycling plant; and second, the CPII-E40 (about 70% clinker content) with an electricity recycling plant. The detailed information of the LCA results is given as Supplementary Material.  Increasing the substitution rate of aggregates improves the environmental performance at all environmental categories. The most considerable difference between M50 and the reference mixture occurred for the ODP and ADP-ff categories, reaching 14 and 13%, respectively, for the best scenario (smallest environmental impact for recycled aggregate treatment and highest avoided impact, considering the CPII-E40 cement). The differences also increase when normalizing the data by the compressive strength (Figures 9b and 10b). This is related to the satisfactory environmental and mechanical performance of mortars with recycled aggregates that increase 22% for both environmental categories.

Environmental Performance
It is worth noting that the source for powering the recycling process (diesel or electricity) showed irrelevant differences (less than 1% for all the mentioned categories) since the contribution of this process is insignificant. Concerning the avoided impacts, the inert landfill and solid waste transportation to landfills were the meaningful aspects for most of the categories. These results pointed out the importance of the logistics aspects in terms of recycling.
Moreover, the differences between the mixtures were trivial since the Portland cement is the main contributor for most of the environmental categories [24], particularly when adopting the attributional LCA. Indeed, the categories have their results smoothed when simulating mixtures with cement CPII-E40 instead of CPV-ARI, as the first one has a smaller impact.
The results of the sensitivity analysis in terms of the maximum supply distance of recycled aggregate (Figures 11 and 12) present values ranging from 200 km (best scenario) to 700 km (worst scenario) for most environmental impact categories, excluding only ADP-n. In particular, its maximum distances are even higher-from 600 to 850 km-as a result of the slight contribution of the diesel consumption in transportation for the ADP-n. Nevertheless, since diesel is a fossil fuel, it has also a noteworthy effect on ADP-f and ODP, which is in accordance with Pradhan et al. [44]. This analysis has been considered an efficient tool in the design guidelines for the environmental availability of recycled aggregates in recent LCA studies [24,49].

Discussion
Several overlapping effects may lead to the strength improvements observed herein when increasing the recycled aggregate volume. For instance, the aggregates' surface roughness plays an important role in the compressive strength of mortars [50], such as it happens when comparing the recycled aggregates porous surface (i.e., greater surface area) to the natural ones. Furthermore, the grip between the paste and the aggregate at the interfacial transition zone will be improved when considering a rough aggregate, thereby leading to an improved compressive strength [51].
As one of the objectives of the study is to evaluate the mortars' properties after introducing recycled aggregates that absorb 4.5 times more water in their composition, no water compensation is performed, allowing us to understand the straight effect of this inclusion on the mortar's rheological behavior. Indeed, the mortars with recycled aggregates have less free water available, since the water is absorbed by the recycled aggregates. This leads to the reduction of the effective w/c ratio, determined by the relationship of the new water amount (after reducing the amount absorbed by the aggregates) and cement. Figure 5b displays that the decreasing effective w/c increases the yield stress and thus is correlated to the w/c ratio variations by an exponential function τ 0 = τ 1 × e (w 0 (w/c)) , where τ 1 = 79.3 and w 0 = 10.2 are fitting parameters. This evidences the profound effect of the water absorption capacity of the recycled aggregate on the fresh state behavior of mortars.
The above discussion relates to the understanding of the expected effect of the simple substitution of natural by recycled aggregate, which presents a relatively higher harshness, increasing the friction between the particles [52] and, consequently, improvement occurs in the mechanical behavior thereof. As can be seen in Figure 8, the compressive strength of the mortars is inversely proportional to the w/c ratio following a power law as follows as classically designed in concretes, where σ 0 and γ are fitting parameters. Interestingly, this approximation works at 7 days as well as at 28 days, confirming the presented trend and the expected effect of w/c on the compressive strength of the material.
Overall, the above discussion shows that the variations on the recycled concrete microaggregate ratio in the mixture proportioning of Portland cement mortars affect their rheological and mechanical performances. The general explanation for these changes is mainly related to water absorbed by the recycled microaggregates that decreases the w/c ratio of the mortars containing them. Another route is considering to correct the water absorption capacity of the aggregate in the mix-design [47], which led to the less expressive influence of the recycled microparticles on the mortars' properties. This particular point would deserve further work.
Therefore, considering the wide range of possibilities to the mortars' practical applications (rendering, plastering, structural, etc.), the approach presented here can be an interesting option to design cement mortar, giving a suitable destination to the concrete residue, maintaining (or even enriching) the strength performance of the material, and varying with its workability. This fact validates the adoption of recycled concrete microaggregate without correcting its absorption capacity, although a few more benefits are found in terms of environmental impact.
The evaluation of different scenarios in LCA (best, intermediate, and worst) is important when avoided impacts are accounted for due to high end-of-life uncertainties. For the best case, the avoided impacts resulted in negative impacts. In other words, increasing recycled aggregates replacement rates in mortars sharply decrease the results of some environmental categories as ODP and ADP-f. These different scenarios played an important role in the sensitivity analysis related to the maximum supply distance of recycled aggregate (see Figures 11 and 12). We observed that the allowed distances roughly triplicate, which, in practice, directly impacts the feasibility of using recycled aggregates. The values ranging from 200 to 300 km for the best scenario were in the same range as those found in previous studies (see Pradhan et al. [44] and Hossain et al. [41]). Even studies for countries of small territory size, where transportation distances are shorter (typically 50 km), have shown that the environmental impact of the aggregate replacement is still important (see Marinković et al. [53] and Knoeri et al. [54]). Hence, transportation plays an important role in the topic and might stand as a barrier to use recycled aggregates in some cases, particularly within large territory countries.
When considering time-consuming transportation distances of the other raw materials (e.g., cement and natural sand), the results show favorable prospects for using recycled aggregates from remote locations. In other words, the farther the source location of the raw materials, the steadier the scenario to RA acceptance. From a logistics point of view, this is a very advantageous feature.
Finally, the association between mechanical and environmental performance data, in a quantitative fashion, revealed the potentials of recycled aggregates in a micrometer scale to replace natural river sand in cement-based materials. In particular, to prevent the discarding of particles that represent usually unworkable solid waste fractions.

Conclusions
This study demonstrated the environmental performance of cement-based mortars containing recycled concrete particles from the demolition of a hospital building. LCA analysis was performed in addition to rheological and mechanical experiments that were discussed independently. Based on the results of the present research, it can be concluded that the mass replacement content of natural by recycled micro aggregates induces less workable yet more resistant and efficient mixtures.
The environmental performance assessment indicated that the mortars with the highest amount of recycled micro aggregate were less detrimental to the environment, especially for the ozone layer depletion potential and abiotic resource depletion potential categories. In this study, these environmental advantages were heavily influenced by the long transportation distances (related to all materials' origins) that went from 200 to 700 km, for most categories.
Finally, the noteworthy association between mechanical and environmental performances validated the possibility of developing eco-efficient materials using micrometer-scale recycled particles that are usually discarded.
The authors consider that this study provides insights for dealing with problems of such magnitude as the building demolition and the waste generated, which is becoming increasingly common worldwide; thus, assisting the implementation of a Circular Economy in the construction industry.