Evaluation of Gas Emissions, Energy Consumption and Production Costs of Warm Mix Asphalt (WMA) Involving Natural Zeolite and Reclaimed Asphalt Pavement (RAP)

: Asphalt mixture is the most widely used material in road construction, and the industry is developing more sustainable technologies. Warm mix asphalt (WMA) is a promising alternative as it saves energy, reduces fuel consumption and generates fewer gas and fume emissions, while maintaining a similar performance to hot mix asphalt (HMA). This paper presents an evaluation of the gas emissions at laboratory scale, as well as the energy consumption and production costs, of ﬁve types of WMA with the addition of natural zeolite. The control mixture was a HMA manufactured at 155 ◦ C. The mixtures evaluated were two WMA manufactured at 135 ◦ C with 0.3% and 0.6% natural zeolite, and three WMA with partial replacement of raw materials by 10%, 20% and 30% of reclaimed asphalt pavement (RAP); these mixtures, called WMA–RAP, were manufactured at 125 ◦ C, 135 ◦ C and 145 ◦ C, respectively. The results indicated that all the mixtures evaluated reduced CO and CO 2 emissions by 2–6% and 17–37%, respectively. The energy consumption presented a 13% decrease. In the current situation, the production costs for WMA with 0.3 and 0.6% natural zeolite are slightly higher than the control mixture, because the saving achieved in fuel consumption is lower than the current cost of the additive. On the other hand, WMA manufactured with the addition of natural zeolite and RAP could produce cost savings of up to 25%, depending on the amounts of RAP and natural zeolite used. in the binder. These images show that the zeolite-binder mixture is quite homogeneous for 1%, 5% and 10% additions (over weight of binder).


Introduction
Worldwide, environmental awareness has forced governments and leaders to take action to protect the planet from global warming and climate chaos. This trend was formalized in the Kyoto protocol (1997), where the main goal was to reduce greenhouse gas emissions [1], and reaffirmed in the Paris Agreement. In this context, the asphalt industry is currently developing more sustainable technologies.
Hot mix asphalt (HMA) is the most widely used construction material for paving roads. Nearly 90% of paved roads in the world are made of asphalt mixtures [2]. In Europe, more than 90% of paved roads are made of asphalt materials. Similar levels are found in the United States, Canada and Mexico, where the use of asphalt for paved roads exceeds 92%, 90% and 96%, respectively [3]. Asphalt mixtures use asphalt binder, aggregates (sand and crushed rock) and mineral filler. This mixture is produced at high temperatures, between 150 • C and 190 • C, depending of the type of asphalt binder used. In the field, the mixture is spread and compacted on the road at high temperatures (120-140 • C). During these asphalt mixture [28,29]. A larger proportion of RAP can be included in foamed WMA [27] than in other WMA technologies. In this context, the Road Pavement Research Group at Universidad de La Frontera has carried out a project to design and develop asphalt mixtures with greater energy efficiency and lower environmental impact. These are WMA and WMA-RAP mixtures which use a local natural zeolite (clinoptilolite-modernite type), extracted from the central zone of Chile, as the additive. In the present work, we studied five WMA types: two WMA with 0.3% and 0.6% natural zeolite content, and three WMA-RAP with 0.6% natural zeolite and different RAP contents (10%, 20% and 30%). The control was a standard HMA. The first part of this study, published recently, concluded that these WMA and WMA-RAP performed well in rutting, cracking resistance, fatigue and moisture damage tests [30]. The present paper presents the second part of the study, the object of which is to assess emissions and energy consumption in the manufacturing process, including a cost analysis of the different mixtures.

Materials and Mix Design
One type of aggregate and one type of conventional asphalt binder (CA-24) were used in this research. The aggregates, obtained from fluvial sand deposits, are composed mainly of dolomite, basalt, dacite, andesite, rhyolite, sandstone, quartz and quartzite. A semi-dense asphalt mixture type IV-A-12 was used, which complies with Chilean specifications [31]. The physical properties of the aggregates according to Chilean standards are shown in Table 1. The aggregate gradation is presented in Figure 1. The properties of asphalt binder are shown in Table 2. The specific gravity of asphalt binder is 1040 kg/m 3 , and the optimum mix temperature is 155 • C. The Marshall method was used to design the mixtures [32], appropriate for surface layers. This design method is the standard in Chile for asphalt pavements. As the objective is to promote massive use of this environmentally friendly alternative asphalt mixture, it was important follow the standards. The analyses of air voids (%), flow (0.25mm), stability (kN) and voids in mineral aggregates (%) were performed according to Chilean specifications [31]. The optimum asphalt binder content was 5.4% of aggregate weight for the reference HMA mixture. This optimal binder content was used in the manufacture of all asphalt mixtures studied in this research.   The natural zeolite used in this research is a clinoptilolite-modernite type, obtained from the Quinamávida quarry in the VII Region of Chile. This mineral is found mainly in areas of volcanic activity, and Chile has large deposits. This type of natural zeolite is composed of aluminosilicates that have a three-dimensional arrangement with an open, porous structure [33], and can release crystallized water at 100 °C without affecting its internal structure. When the zeolite comes into contact with hot asphalt binder, the water is released and generates a micro-foam that allows the asphalt binder to involve the aggregates at a lower temperature. Table 3 shows the characterization of the natural zeolite used in this study. Figure 2 shows the images of different contents of natural zeolite distributed in the asphalt binder obtained through a confocal microscope at two magnification levels. Epifluorescence images allow us to verify the dispersion of the natural zeolite in the binder. These images show that the zeolite-binder mixture is quite homogeneous for 1%, 5% and 10% additions (over weight of binder).   The natural zeolite used in this research is a clinoptilolite-modernite type, obtained from the Quinamávida quarry in the VII Region of Chile. This mineral is found mainly in areas of volcanic activity, and Chile has large deposits. This type of natural zeolite is composed of aluminosilicates that have a three-dimensional arrangement with an open, porous structure [33], and can release crystallized water at 100 • C without affecting its internal structure. When the zeolite comes into contact with hot asphalt binder, the water is released and generates a micro-foam that allows the asphalt binder to involve the aggregates at a lower temperature. Table 3 shows the characterization of the natural zeolite used in this study. Figure 2 shows the images of different contents of natural zeolite distributed in the asphalt binder obtained through a confocal microscope at two magnification levels. Epifluorescence images allow us to verify the dispersion of the natural zeolite in the binder. These images show that the zeolite-binder mixture is quite homogeneous for 1%, 5% and 10% additions (over weight of binder).  The RAP used comes from milling works on Route 5, IX Region of Chile. In order to reduce the heterogeneity of the WMA-RAP mixtures, they were manufactured with two fractions of RAP, as recommended by Solaimanian and Tahmoressi [34]. The RAP fractions used were 0/5 mm and 5/20 mm. Table 4 shows the RAP gradation and the bitumen content for both RAP fractions. The characteristics of binder recovered from the RAP before fractioning are shown in Table 5.    The RAP used comes from milling works on Route 5, IX Region of Chile. In order to reduce the heterogeneity of the WMA-RAP mixtures, they were manufactured with two fractions of RAP, as recommended by Solaimanian and Tahmoressi [34]. The RAP fractions used were 0/5 mm and 5/20 mm. Table 4 shows the RAP gradation and the bitumen content for both RAP fractions. The characteristics of binder recovered from the RAP before fractioning are shown in Table 5.  The asphalt mixtures evaluated are shown in Table 6 All these mixtures were evaluated for their resistance to moisture damage, low temperature cracking, fatigue and rutting, showing similar or better performance than the control HMA [30].

Test Methods for Gas Emission Evaluation
To manufacture the WMA, aggregates and asphalt binder were heated to the mixing temperature according to Table 3. In the case of WMA-RAP, the RAP temperature was 15 • C and the raw aggregates had to be overheated to achieve the final manufacturing temperature (Table 7). To obtain each gas sample, 4 kg of asphalt mixture were manufactured, maintaining the dosage of each mixture. The mixtures were manufactured in a hermetic chamber for 5 min, followed by 2 min resting time before gas capture. The gases (500 mL) were captured using a gas syringe and stored in hermetic Tedlar gas sample bags with a polypropylene valve ( Figure 3). Three gas samples were taken for each asphalt mixture. It is important to note that the gas samples did not include the gases emitted during the combustion process, and only considered the gases generated by heating asphalt binder, RAP, aggregates and natural zeolite because the heating process was carried out without combustion in the laboratory.  A gas chromatograph with TCD (thermal conductivity detector), Clarus 580 Perkin Elmer, with a packed column 60/80 carboxeen 1000 15ft × 1/8" (2.1 mm ID, internal diameter) was used to evaluate gas emissions. The gas samples were extracted from the gas storage bags and injected manually at a volume of 250 μL. The temperature of the detector was 250 °C and the injector temperature was 200 °C. Helium carrier gas was used, with a flow of 30 mL/min. The temperature ramp was 180 °C for 4.50 min. The working range was 0.05 to 1%, Figure 3. The gases evaluated were CO2, CO and SO2.
The methodology was divided into four phases ( Figure 4). The first phase consisted of a review of studies related to the project, combined with visits to different asphalt mixing plants to become familiar with each stage involved in the manufacturing process in order to determine the most significant variables. To complete the second phase, a cost table was generated by collecting data in the field provided by a local asphalt mixing company, incorporating the main costs related to the production of conventional asphalt mixtures. Additionally, energy consumption equations defined by Romier et al. [35] were used to determine the energy consumption during the production stage and to relate this variable to temperature changes (Equations (1)-(4)).
energy needed to heat aggregates (cal) (1) Study of the production process of HMA, WMA and WMA-RAP.

Determination of costs and energy consumption of HMA production process
Determination of costs and energy consumption of WMA and WMA-RAP production process A gas chromatograph with TCD (thermal conductivity detector), Clarus 580 Perkin Elmer, with a packed column 60/80 carboxeen 1000 15ft × 1/8" (2.1 mm ID, internal diameter) was used to evaluate gas emissions. The gas samples were extracted from the gas storage bags and injected manually at a volume of 250 µL. The temperature of the detector was 250 • C and the injector temperature was 200 • C. Helium carrier gas was used, with a flow of 30 mL/min. The temperature ramp was 180 • C for 4.50 min. The working range was 0.05 to 1%, Figure 3. The gases evaluated were CO 2 , CO and SO 2 .

Comparison of energy consumption and production costs
The methodology was divided into four phases ( Figure 4). The first phase consisted of a review of studies related to the project, combined with visits to different asphalt mixing plants to become familiar with each stage involved in the manufacturing process in order to determine the most significant variables.  A gas chromatograph with TCD (thermal conductivity detector), Clarus 580 Perkin Elmer, with a packed column 60/80 carboxeen 1000 15ft × 1/8" (2.1 mm ID, internal diameter) was used to evaluate gas emissions. The gas samples were extracted from the gas storage bags and injected manually at a volume of 250 μL. The temperature of the detector was 250 °C and the injector temperature was 200 °C. Helium carrier gas was used, with a flow of 30 mL/min. The temperature ramp was 180 °C for 4.50 min. The working range was 0.05 to 1%, Figure 3. The gases evaluated were CO2, CO and SO2.
The methodology was divided into four phases ( Figure 4). The first phase consisted of a review of studies related to the project, combined with visits to different asphalt mixing plants to become familiar with each stage involved in the manufacturing process in order to determine the most significant variables. To complete the second phase, a cost table was generated by collecting data in the field provided by a local asphalt mixing company, incorporating the main costs related to the production of conventional asphalt mixtures. Additionally, energy consumption equations defined by Romier et al. [35] were used to determine the energy consumption during the production stage and to relate this variable to temperature changes (Equations (1)-(4)).
energy needed to heat aggregates (cal) (1) Study of the production process of HMA, WMA and WMA-RAP.

Determination of costs and energy consumption of HMA production process
Determination of costs and energy consumption of WMA and WMA-RAP production process Comparison of energy consumption and production costs To complete the second phase, a cost table was generated by collecting data in the field provided by a local asphalt mixing company, incorporating the main costs related to the production of conventional asphalt mixtures. Additionally, energy consumption equations defined by Romier et al. [35] were used to determine the energy consumption during the production stage and to relate this variable to temperature changes (Equations (1)-(4)).
energy needed to heat aggregates (cal) (1) energy needed to eliminate water vapor (cal) (4) where: C agr is the specific heat of aggregates (cal/kg −1• C −1 ); m agr is the mass of aggregates (kg); t agr is the aggregate heating temperature ( • C); t amb is the ambient temperature ( • C); C a is the specific heat of water; (cal/kg −1 * • C −1 ); h is the aggregate moisture content (%); clv is the latent heat of vaporization of the water (cal/kg); C v is the vapor-specific heat (cal/kg −1 * • C −1 ); and t agr is the aggregate heating temperature ( • C).
The parameters involved in calculating the energy and fuel consumption are shown in Tables 7 and 8. The moisture content was fixed according to the average moisture content reported by the production plant. To determine the cost and energy consumption of WMA and WMA-RAP, the cost table of the conventional asphalt mixture (previously generated and validated with information provided by the mixing plant) was modified by the inclusion of the new costs according to the different amounts of zeolites and RAP. In this stage, the energy consumption was calculated by the Romier equations, varied according to the changes in the manufacturing temperature. These modifications were caused by the variation in fuel consumption, and in the amount of virgin raw materials (binder and aggregates) used for each WMA-RAP mixture since these were reduced as a function of the amount of RAP included. Finally, the cost tables were compared with the reference mixture. The fuel consumption was calculated by converting the energy consumption to fuel, based on the heating power of fuel oil. The production costs of the different proposed mixtures were obtained by assessing the energy consumption and the costs associated with the raw materials and additive (natural zeolite).

Gas Emissions
Before we analyze the results, it is important to remember that this study considers only the emissions generated by heating the asphalt binder in contact with the raw aggregates, and, in some cases, natural zeolite and varying percentages of RAP (i.e., combustion emissions produced by aggregate heating, such as those produced during the production process in asphalt plants, were isolated). In this context, it is observed that the SO 2 emission level was outside the detection ranges for all the mixtures studied. This implies that the SO 2 emissions were less than 0.05%, considered as null for all the mixtures evaluated. These results may be because SO 2 is generated by the combustion process [16] and is highly dependent on fuel type, with fuel oil and recycled fuel oil causing the most pollution. On the other hand, natural gas seems to be an environmentally friendly fuel alternative, since it has a lower sulphur content [16]. This agrees with the results obtained by Lecomte et al. [37], who compared the SO 2 emissions between HMA (180 • C) and WMA foam (125-130 • C). They observed a 35% reduction in fuel consumption, obtaining a reduction in SO 2 emissions between 25% and 30%. On the other hand, Hurley et al. [38] analyzed the natural gas consumption in three WMA mixtures (Evotherm ® , Aspha-min ® and Sasobit ® ). The fuel consumption results were + 15.4%, − 8.8% and − 17.9% (Control, HMA, WMA), respectively, while the SO 2 emissions were + 54%, − 83% and − 83% (Control, HMA, WMA), respectively. These results suggest that fuel consumption is the greatest contributing factor to SO 2 emissions.
Similar levels of CO emissions were observed between HMA and WMA. The reduction percentage of CO concentration was 2% for Z-0.3-135, while for Z-0.6-135 the CO emission level was similar to that of P-155 ( Figure 5). When HMA-RAP is compared to WMA-RAP ( Figure 5), reductions in CO emissions of 6%, 5% and 4% were detected (R10-Z0.6-125, R20-Z0.6-135 and R30-Z0.6-145 respectively). Some researchers suggest that CO emissions are associated with fuel consumption and depend on the type of fuel, reporting that WMA manufactured in a plant powered with natural gas emitted eighteen times less CO than a plant with fuel oil under the same conditions [3]. However, Anderson et al. [39] concluded that CO emissions are more closely related to burner maintenance. Lecomte et al. [37] obtained CO reductions of around 8% when comparing measurements made in the chimney of the mixing plant during the manufacture of HMA (180 • C) and WMA foam mixture (125-130 • C). These findings are consistent with this study, as the effects of fuel burning or burner maintenance are not considered for any of the mixtures evaluated. However, it is remarkable that CO emissions are not correlated exclusively with fuel burning, since CO emissions were detected in this study. Before we analyze the results, it is important to remember that this study considers only the emissions generated by heating the asphalt binder in contact with the raw aggregates, and, in some cases, natural zeolite and varying percentages of RAP (i.e., combustion emissions produced by aggregate heating, such as those produced during the production process in asphalt plants, were isolated). In this context, it is observed that the SO2 emission level was outside the detection ranges for all the mixtures studied. This implies that the SO2 emissions were less than 0.05%, considered as null for all the mixtures evaluated. These results may be because SO2 is generated by the combustion process [16] and is highly dependent on fuel type, with fuel oil and recycled fuel oil causing the most pollution. On the other hand, natural gas seems to be an environmentally friendly fuel alternative, since it has a lower sulphur content [16]. This agrees with the results obtained by Lecomte et al. [37], who compared the SO2 emissions between HMA (180 °C) and WMA foam (125-130 °C). They observed a 35% reduction in fuel consumption, obtaining a reduction in SO2 emissions between 25% and 30%. On the other hand, Hurley et al. [38] analyzed the natural gas consumption in three WMA mixtures (Evotherm ® , Aspha-min ® and Sasobit ® ). The fuel consumption results were + 15.4%, − 8.8% and − 17.9% (Control, HMA, WMA), respectively, while the SO2 emissions were + 54%, − 83% and − 83% (Control, HMA, WMA), respectively. These results suggest that fuel consumption is the greatest contributing factor to SO2 emissions.
Similar levels of CO emissions were observed between HMA and WMA. The reduction percentage of CO concentration was 2% for Z-0.3-135, while for Z-0.6-135 the CO emission level was similar to that of P-155 ( Figure 5). When HMA-RAP is compared to WMA-RAP ( Figure 5), reductions in CO emissions of 6%, 5% and 4% were detected (R10-Z0.6-125, R20-Z0.6-135 and R30-Z0.6-145 respectively). Some researchers suggest that CO emissions are associated with fuel consumption and depend on the type of fuel, reporting that WMA manufactured in a plant powered with natural gas emitted eighteen times less CO than a plant with fuel oil under the same conditions [3]. However, Anderson et al. [39] concluded that CO emissions are more closely related to burner maintenance. Lecomte et al. [37] obtained CO reductions of around 8% when comparing measurements made in the chimney of the mixing plant during the manufacture of HMA (180 °C) and WMA foam mixture (125-130 °C). These findings are consistent with this study, as the effects of fuel burning or burner maintenance are not considered for any of the mixtures evaluated. However, it is remarkable that CO emissions are not correlated exclusively with fuel burning, since CO emissions were detected in this study. Additionally, the reference mixtures with RAP (PR-10-155, PR-20-155, PR-30-155) showed more CO emissions than the reference mixture without RAP (P-155). However, the reduction in CO Additionally, the reference mixtures with RAP (PR-10-155, PR-20-155, PR-30-155) showed more CO emissions than the reference mixture without RAP (P-155). However, the reduction in CO emissions in WMA-RAP manufactured at a lower temperature than the reference mixtures with RAP was larger than the difference between WMA and the reference mixture without RAP ( Figure 5).
In the analysis of CO 2 emissions, 90% were found to occur directly during the asphalt mixing process [14]. The complete production process includes aggregate heating, asphalt heating, and mixing. In these stages, the carbon emissions observed reached values of 67%, 14% and 12%, respectively [14]. This study focuses on the third stage, the mixing process. The results for CO 2 emissions showed a reduction for all mixtures evaluated; emissions were higher for WMA-RAP ( Figure 6). These results are similar to those presented by Sharma et al. [40], who observed CO 2 emission reductions of between 2.5% and 35%, respectively, in a comparison of HMA (180 • C) with WMA (140 • C) with 2%-6% addition of synthetic zeolite (over binder content). Lecomte et al. [37] also observed CO 2 emission reductions of around 35% in a comparison between HMA manufactured at 180 • C and WMA foam at 125-130 • C, both measured in the chimney of the mixing plant. Comparable results were obtained by Mallik et al. [12], who reported a direct reduction in CO 2 emissions of around 32% by decreasing the mixing temperatures by between 10 and 30 • C.
Sustainability 2020, 12, x FOR PEER REVIEW 10 of 16 emissions in WMA-RAP manufactured at a lower temperature than the reference mixtures with RAP was larger than the difference between WMA and the reference mixture without RAP ( Figure 5). In the analysis of CO2 emissions, 90% were found to occur directly during the asphalt mixing process [14]. The complete production process includes aggregate heating, asphalt heating, and mixing. In these stages, the carbon emissions observed reached values of 67%, 14% and 12%, respectively [14]. This study focuses on the third stage, the mixing process. The results for CO2 emissions showed a reduction for all mixtures evaluated; emissions were higher for WMA-RAP ( Figure 6). These results are similar to those presented by Sharma et al. [40], who observed CO2 emission reductions of between 2.5% and 35%, respectively, in a comparison of HMA (180 °C) with WMA (140 °C) with 2%-6% addition of synthetic zeolite (over binder content). Lecomte et al. [37] also observed CO2 emission reductions of around 35% in a comparison between HMA manufactured at 180 °C and WMA foam at 125-130 °C, both measured in the chimney of the mixing plant. Comparable results were obtained by Mallik et al. [12], who reported a direct reduction in CO2 emissions of around 32% by decreasing the mixing temperatures by between 10 and 30 °C. In this study, the CO2 emission reductions were obtained by comparing HMA manufactured at 155 °C with WMA at 135 °C. The emissions were reduced by 17% and 23%, respectively, with the addition of 0.3% and 0.6% natural zeolite ( Figure 6). Larger reductions were obtained in WMA-RAP with the addition of 0.6% natural zeolite (R10-Z0.6-125, R20-Z0.6-135, R30-Z0.6-145), which were compared with the reference mixtures manufactured with RAP (PR-10-155, PR-20-155, PR-30-155). These WMA-RAP mixtures showed reductions in CO2 emissions in the range of 30% to 37%, the largest reduction being obtained with R20-Z0.6-135 ( Figure 6). This may be related to the results obtained by Giani et al. [41], who indicated that WMA produced using RAP instead of virgin raw materials may mean a reduction in CO2 emissions of approximately 12% over the whole life cycle.

Energy Consumption
Energy consumption assessment of the production processes of different pavement types may constitute an important tool for engineers and legislators in selecting the type of pavement and technology to use in infrastructure design, in terms of both environmental impact and economic investment [2]. In this context, the manufacture of HMA requires higher energy consumption during asphalt mixing and aggregate heating; the latter process accounts for 53% of energy consumption [2]. Several researchers have concluded that the lower production temperature of WMA technologies may reduce the energy consumption compared to HMA [42,43]. This is consistent with the results shown in Figure 7, which show a reduction in energy consumption due to the lower production In this study, the CO 2 emission reductions were obtained by comparing HMA manufactured at 155 • C with WMA at 135 • C. The emissions were reduced by 17% and 23%, respectively, with the addition of 0.3% and 0.6% natural zeolite ( Figure 6). Larger reductions were obtained in WMA-RAP with the addition of 0.6% natural zeolite (R10-Z0.6-125, R20-Z0.6-135, R30-Z0.6-145), which were compared with the reference mixtures manufactured with RAP (PR-10-155, PR-20-155, PR-30-155). These WMA-RAP mixtures showed reductions in CO 2 emissions in the range of 30% to 37%, the largest reduction being obtained with R20-Z0.6-135 ( Figure 6). This may be related to the results obtained by Giani et al. [41], who indicated that WMA produced using RAP instead of virgin raw materials may mean a reduction in CO 2 emissions of approximately 12% over the whole life cycle.

Energy Consumption
Energy consumption assessment of the production processes of different pavement types may constitute an important tool for engineers and legislators in selecting the type of pavement and technology to use in infrastructure design, in terms of both environmental impact and economic investment [2]. In this context, the manufacture of HMA requires higher energy consumption during asphalt mixing and aggregate heating; the latter process accounts for 53% of energy consumption [2]. Several researchers have concluded that the lower production temperature of WMA technologies may reduce the energy consumption compared to HMA [42,43]. This is consistent with the results shown in Figure 7, which show a reduction in energy consumption due to the lower production temperature. The reference HMA was produced at 155 • C, while the study mixtures were produced at lower temperatures (125 • C, 135 • C and 145 • C). These temperature reductions account for decreases in energy consumption of 13%, 9% and 5%, respectively. These findings are similar to those reported by Anderson et al. [39], who described an energy saving of about 10% using WMA with water-injection foaming systems. Croteau and Tessier [10], in their study of the WMA state-of-practice, indicated energy savings ranging from 20 to 35% according to the reports of WMA trials in an asphalt plant. Similarly, Harder et al. [44] observed reductions in energy consumption of between 10% and 30%. These variations are dependent on the WMA system, moisture content of the aggregates and the type/efficiency of the plant. Expressed in terms of kcal, a reduction of 2051 kcal/ton per 10 • C decrease in temperature is observed. A similar result was reported by Peinado et al. [42], who noted an extra energy demand of about 2253 Kcal for an increase of 10 • C in the mixture temperature.
Sustainability 2020, 12, x FOR PEER REVIEW 11 of 16 temperature. The reference HMA was produced at 155 °C, while the study mixtures were produced at lower temperatures (125 °C, 135 °C and 145 °C). These temperature reductions account for decreases in energy consumption of 13%, 9% and 5%, respectively. These findings are similar to those reported by Anderson et al. [39], who described an energy saving of about 10% using WMA with water-injection foaming systems. Croteau and Tessier [10], in their study of the WMA state-ofpractice, indicated energy savings ranging from 20 to 35% according to the reports of WMA trials in an asphalt plant. Similarly, Harder et al. [44] observed reductions in energy consumption of between 10% and 30%. These variations are dependent on the WMA system, moisture content of the aggregates and the type/efficiency of the plant. Expressed in terms of kcal, a reduction of 2051 kcal/ton per 10 °C decrease in temperature is observed. A similar result was reported by Peinado et al. [42], who noted an extra energy demand of about 2253 Kcal for an increase of 10 °C in the mixture temperature. Figure 7. Energy consumption in reference to production temperature.

Evaluation of Production Cost
Energy savings are related to cost reductions because they imply a reduction in fuel consumption. Several researchers have reported economic benefits from the use of WMA. The different quantities of fuel required to produce all mixtures evaluated in this study were calculated, based on the energy consumption results of the asphalt mixtures produced at different temperatures and the heating power of the fuel. Parameters such as ambient temperature (15 °C), aggregate moisture content (3%) and RAP moisture content (0.3%) were fixed (Table 8), since the focus of the present study was on the energy and cost savings achievable by reducing the manufacturing temperature during the production stage. A reduction in fuel consumption of about 10% was observed for WMA at 135 °C, while for WMA-RAP the reduction in fuel consumption reached 15% for R10-Z0.6-125, R20-Z0.6-135 and R30-Z0.6-145 (Figure 8). These results are similar to those reported by Anderson et al., who indicated that a temperature reduction of 27 °C resulted in an average fuel saving of 22%, with data drawn from 13 projects [39].

Energy consumption (kCal)
Mix production Temperature (°C) Figure 7. Energy consumption in reference to production temperature.

Evaluation of Production Cost
Energy savings are related to cost reductions because they imply a reduction in fuel consumption. Several researchers have reported economic benefits from the use of WMA. The different quantities of fuel required to produce all mixtures evaluated in this study were calculated, based on the energy consumption results of the asphalt mixtures produced at different temperatures and the heating power of the fuel. Parameters such as ambient temperature (15 • C), aggregate moisture content (3%) and RAP moisture content (0.3%) were fixed (Table 8), since the focus of the present study was on the energy and cost savings achievable by reducing the manufacturing temperature during the production stage. A reduction in fuel consumption of about 10% was observed for WMA at 135 • C, while for WMA-RAP the reduction in fuel consumption reached 15% for R10-Z0.6-125, R20-Z0.6-135 and R30-Z0.6-145 ( Figure 8). These results are similar to those reported by Anderson et al., who indicated that a temperature reduction of 27 • C resulted in an average fuel saving of 22%, with data drawn from 13 projects [39]. The cost evaluation of WMA with the addition of natural zeolite included the cost of the additive and the savings related to reduced fuel consumption. For the WMA-RAP with natural zeolite, the cost evaluation considered the cost of the additive and the savings due to reduced fuel consumption and raw materials (aggregates and asphalt binder). The cost evaluations consider the production temperature for all the mixtures evaluated, including the aggregate overheating temperature required for the WMA with RAP, as well as the reduced consumption of virgin asphalt binder due to the incorporation of RAP ( Table 7).
The current cost of natural zeolite reported by the supplier is US$1.03 per kg. This is a high cost, much higher than the cost of lime (US$0.11 per kg), probably due to the lack of development of this industry. The production process of natural zeolite includes the same steps as the production of lime: extraction of natural stone, grinding, sieving and finally packaging for commercialization; however, lime production requires an important extra step: mineral calcination at 900 °C. This process implies a major additional cost that is not required to obtain natural zeolite. Nevertheless, the cost of lime continues to be considerably lower than that of natural zeolite. In consideration of the above, two cost evaluations were carried out based on two scenarios: the current situation, when the cost of natural zeolite is US$1.03 per kg; and a hypothetical future situation, in the expectation that the natural zeolite industry is likely to grow to meet demand, when the cost of natural zeolite will fall to a similar level to that of lime (US$0.11 per kg). The results shown in Figure 9 indicate that in the current situation, the production cost of manufacturing WMA is higher than the production cost of HMA by a factor ranging from 5% for WMA with 0.3% of natural zeolite to 12% for WMA with 0.6% of natural zeolite. These results were higher than the cost of the reference mixture (P-155) because the savings in fuel costs were lower than the extra cost of the additive. Similar findings were reported by EAPA, which described the production cost of WMA as being similar to or slightly higher than that of HMA [45]. Almeida et al. [46] obtained similar results, comparing rough asphalt concrete with WMA (Sasobit ® ); they reported little difference in the total costs of the two mixtures. When the hypothetical situation The cost evaluation of WMA with the addition of natural zeolite included the cost of the additive and the savings related to reduced fuel consumption. For the WMA-RAP with natural zeolite, the cost evaluation considered the cost of the additive and the savings due to reduced fuel consumption and raw materials (aggregates and asphalt binder). The cost evaluations consider the production temperature for all the mixtures evaluated, including the aggregate overheating temperature required for the WMA with RAP, as well as the reduced consumption of virgin asphalt binder due to the incorporation of RAP ( Table 7).
The current cost of natural zeolite reported by the supplier is US$1.03 per kg. This is a high cost, much higher than the cost of lime (US$0.11 per kg), probably due to the lack of development of this industry. The production process of natural zeolite includes the same steps as the production of lime: extraction of natural stone, grinding, sieving and finally packaging for commercialization; however, lime production requires an important extra step: mineral calcination at 900 • C. This process implies a major additional cost that is not required to obtain natural zeolite. Nevertheless, the cost of lime continues to be considerably lower than that of natural zeolite. In consideration of the above, two cost evaluations were carried out based on two scenarios: the current situation, when the cost of natural zeolite is US$1.03 per kg; and a hypothetical future situation, in the expectation that the natural zeolite industry is likely to grow to meet demand, when the cost of natural zeolite will fall to a similar level to that of lime (US$0.11 per kg). The results shown in Figure 9 indicate that in the current situation, the production cost of manufacturing WMA is higher than the production cost of HMA by a factor ranging from 5% for WMA with 0.3% of natural zeolite to 12% for WMA with 0.6% of natural zeolite. These results were higher than the cost of the reference mixture (P-155) because the savings in fuel costs were lower than the extra cost of the additive. Similar findings were reported by EAPA, which described the production cost of WMA as being similar to or slightly higher than that of HMA [45].
Almeida et al. [46] obtained similar results, comparing rough asphalt concrete with WMA (Sasobit ® ); they reported little difference in the total costs of the two mixtures. When the hypothetical situation projected above is analyzed, the cost of WMA with 0.3% and 0.6% natural zeolite may be similar to that of HMA.
Sustainability 2020, 12, x FOR PEER REVIEW 13 of 16 projected above is analyzed, the cost of WMA with 0.3% and 0.6% natural zeolite may be similar to that of HMA. When the cost of WMA with the addition of natural zeolite and RAP is analyzed (Figure 9), all the asphalt mixtures evaluated in this study present reduced costs. In the current situation, WMA with 30% RAP and 0.3% natural zeolite presented cost savings of about 25%, while the cost savings for WMA with 30% RAP and 0.6% natural zeolite were 19% (both manufactured at 145 °C). For WMA with 10% RAP produced at 125 °C, the cost savings were 7% and 1% for the addition of 0.3% and 0.6% of natural zeolite respectively. Finally, if a balance is sought between incorporating RAP and reducing temperature, the best alternative might be WMA with 20% RAP produced at 135 °C, which gives cost savings of 17% and 11% for the addition of 0.3% and 0.6% natural zeolite respectively. Analyzing the WMA-RAP mixtures in the hypothetical future situation, the cost savings may be higher, achieving a cost reduction of 30% for R30-Z0.6-145, 21% for R20-Z0.6-135 and 11% for R10-Z0.6-125 ( Figure 9). These results are consistent with the report by Kristjánsdóttir et al. [43], who showed that RAP incorporation may be a good approach to cost savings; they concluded that in the project evaluated, increasing the RAP content from 25% to 40% would result in a net saving of US$4.55/ton.

Conclusions
The present study focused on the gas emissions, energy consumption and production costs of WMA and WMA-RAP, in comparison with a reference mixture. In terms of gas emissions, all the WMA showed reductions in direct CO2 emissions of 17% and 23%, respectively with the addition of 0.3% and 0.6% natural zeolite. The CO2 reductions for WMA-RAP were higher, reaching 37% for WMA-RAP with 20% RAP manufactured at 135 °C and 35% for WMA-RAP with 30% RAP manufactured at 145 °C. The reductions in CO emissions were smaller than those achieved for CO2: for WMA, the CO reduction was not statistically significant, whereas for WMA-RAP the CO emissions decreased by nearly 6%. On this point, it is remarkable that the CO emissions are not only correlated to fuel burning; in this research CO emissions were detected although the fuel burning When the cost of WMA with the addition of natural zeolite and RAP is analyzed (Figure 9), all the asphalt mixtures evaluated in this study present reduced costs. In the current situation, WMA with 30% RAP and 0.3% natural zeolite presented cost savings of about 25%, while the cost savings for WMA with 30% RAP and 0.6% natural zeolite were 19% (both manufactured at 145 • C). For WMA with 10% RAP produced at 125 • C, the cost savings were 7% and 1% for the addition of 0.3% and 0.6% of natural zeolite respectively. Finally, if a balance is sought between incorporating RAP and reducing temperature, the best alternative might be WMA with 20% RAP produced at 135 • C, which gives cost savings of 17% and 11% for the addition of 0.3% and 0.6% natural zeolite respectively. Analyzing the WMA-RAP mixtures in the hypothetical future situation, the cost savings may be higher, achieving a cost reduction of 30% for R30-Z0.6-145, 21% for R20-Z0.6-135 and 11% for R10-Z0.6-125 ( Figure 9). These results are consistent with the report by Kristjánsdóttir et al. [43], who showed that RAP incorporation may be a good approach to cost savings; they concluded that in the project evaluated, increasing the RAP content from 25% to 40% would result in a net saving of US$4.55/ton.

Conclusions
The present study focused on the gas emissions, energy consumption and production costs of WMA and WMA-RAP, in comparison with a reference mixture. In terms of gas emissions, all the WMA showed reductions in direct CO 2 emissions of 17% and 23%, respectively with the addition of 0.3% and 0.6% natural zeolite. The CO 2 reductions for WMA-RAP were higher, reaching 37% for WMA-RAP with 20% RAP manufactured at 135 • C and 35% for WMA-RAP with 30% RAP manufactured at 145 • C.
The reductions in CO emissions were smaller than those achieved for CO 2 : for WMA, the CO reduction was not statistically significant, whereas for WMA-RAP the CO emissions decreased by nearly 6%. On this point, it is remarkable that the CO emissions are not only correlated to fuel burning; in this research CO emissions were detected although the fuel burning process was excluded. For all asphalt mixtures evaluated, SO 2 emissions were out of the detection ranges (0.05%); this could be because SO 2 is generated by the combustion process and is highly dependent on fuel type, which was not considered here.
Reductions in energy consumption were found in the range of 5% to 13%, similar to the reductions reported by other researchers.
Finally, in the cost evaluation, the cost reduction for WMA achieved by reduced fuel consumption was not enough to compensate the current additional cost of the additive; these mixtures are still slightly more expensive than the reference mixture. The situation for WMA-RAP was different: production cost savings close to 25% were achieved for the mixtures with 30% RAP and 0.3% natural zeolite.
Our results show that all the asphalt mixtures evaluated presented reduced gas emissions and energy/fuel consumption, with a cost similar to the control HMA. In addition, if the mixtures are manufactured with RAP, the benefits will be greater thanks to the energy and cost savings; mixtures containing RAP also offer environmental benefits, which include lower emissions and the use of recycled asphalt pavement materials.