Selection of Novel Geopolymeric Mortars for Sustainable Construction Applications Using Fuzzy Topsis Approach

: Construction is recognized as one of the most polluting and energy consuming industries worldwide, especially in developing countries. Therefore, Research and Development (R&D) of novel manufacturing technologies and green construction materials is becoming extremely compelling. This study aims at evaluating the reuse of various wastes, originated in the Kraft pulp-paper industry, as raw materials in the manufacture of novel geopolymeric (GP) mortars whose properties fundamentally depend on the target application (e.g., insulating panel, partition wall, structural element, furnishing, etc.). Five di ﬀ erent wastes were reused as ﬁller: Two typologies of Biomass Fly Ash, calcareous sludge, grits, and dregs. The produced samples were characterized and a multi criteria analysis, able to take into account not only the engineering properties, but also the environmental and economic aspects, has been implemented. The criteria weights were evaluated using the Delphi methodology. The fuzzy Topsis approach has been used to consider the intrinsic uncertainty related to unconventional materials, as the produced GP-mortars. The computational analysis showed that adding the considered industrial wastes as ﬁller is strongly recommended to improve the performance of materials intended for structural applications in construction. The results revealed that the formulations containing 5 wt.% of calcareous sludge, grits, and dregs and the one containing 7.5 wt.% of calcareous sludge, grits, dregs, and Biomass Fly Ash-1 have emerged as the best alternatives. Furthermore, it resulted that the Biomass Fly Ash-2 negatively inﬂuences the structural performance and relative rank of the material. Finally, this case study clearly shows that the fuzzy Topsis multi-criteria analysis represents a valuable and easy tool to investigate construction materials (either traditional and unconventional) when an intrinsic uncertainty is related to the measurement of the quantitative and qualitative characteristics.


Introduction
The increasing pressure from worldwide environmental agencies to adopt an accurate waste management system is generating a growing interest in searching for sustainable alternatives to traditional disposal systems. The exploitation of non-renewable raw materials and the considerable production of wastes and greenhouse gases make the current global industrial system highly unsustainable. defining some appropriate criteria of decision, evaluating their relative importance. The advantage of using the fuzzy Topsis mainly consists in allowing us to obtain a rank of the different alternatives expressed by means of fuzzy sets. In this way, the intrinsic uncertainty related to the measurement of the quantitative and qualitative criteria of unconventional materials can be considered. Moreover, the proposed method is compensative, meaning that the scores of the alternatives-with regard to the different criteria-are balanced. That does not happen, for instance, in the ELimination Et Choice Translating Reality (ELECTRE) methods [19]. Anyway, it must be pointed out that the obtained rank is strictly related to the specific considered application. This case study reports the analysis carried out on the formulations of mortars intended for structural application only.
At the best of our knowledge, the fuzzy Topsis approach has never been applied on any construction material and, moreover, on a geopolymeric material intended with specific uses in construction. That provides a fundamental advance in both the GP science and technology and the discipline of multicriteria analysis, providing a scheme of application, a selection of criteria and variables, and the related uncertainties, taken into account by the fuzzy approach.
Biomass Fly Ash, typology 1, (BFA-1) derives from the main chemical recovery boiler in the biomass thermoelectric plant, and its average particle size is 60 µm; the Biomass Fly Ash, typology 2, (BFA-2) is generated in the auxiliary boiler of the steam cogeneration plant and presents an average particle size of 29 µm. Both the BFAs presented a negligible moisture content (~0.5 wt.%) and were used as received without performing any processes of drying, sieving, or milling. That improves the materials sustainability, as less energy is required.
Calcareous sludge (CalS) is an inorganic alkali residue made of calcite. It is produced from the chemical recovery circuit (White Bleach Clarifier) of the Kraft process as the molten inorganic salts are passed into the dissolution tank to be clarified. CalS was furnished in the form of powdery sludge characterized by an average particle size of 23 µm and an average moisture content of~10.5 wt.% at mill site [23,24].
Grits (grits) also are an inorganic alkali residue mainly made of calcite. They are generated during the liquefied inorganic salts clarification by means of a lime slaker during the recovery of the chemical liquor that is used to digest wood. Grits were furnished in a granular form, with a particle size distribution ranging 1-12.5 mm and a negligible dust fraction (<2 wt.%), and an average moisture content of~10 wt.% at mill site. This residue was investigated by the authors as coarse aggregate [25,26].
Dregs (dregs) are mainly made of sodium, calcium carbonates, and sulphides, and contains an organic fraction. They are generated by the separation of calcium carbonate and oxide during the clarification of the green liquor in the form of sludge, as furnished, with an average moisture content of~25 wt.% and an average particle size of 11 µm [27,28].
All the considered wastes are classified as "non-hazardous" according to European Committe (2000) [29], then their reuse in construction is feasible. The most common method to handle these wastes is disposing of them in landfills. Nevertheless, according to European Committee (1975) [30] it should be avoided, as it might generate a negative impact on the environment, resulting in groundwater pollution from toxic components leaching, soil contamination, and the emission of ugly odors [31]. Moreover, the economical disadvantages of this methodology should be considered due to the increasing costs of the disposal as consequence of the most recent regulations aimed at protecting the environment and the decreasing of available landfilling areas [32,33].

Wastes Treatments and Mortars Production
Prior to use, depending on the wastes' nature, some treatments may be necessary as follows: • Washing: Baths in distilled water may be necessary in the presence of salts, hazardous elements, or impurities (i.e., chlorides). Hot water would boost the action, but the cost will consequently increase. The number of required baths depends on the substances' solubility and the possible materials loss (wt.%). In this work, the considered wastes were not washed.

•
Drying: Is necessary in the case of high moisture content as it might influence the final GP-material molar ratios. In this study, drying was performed at 60 • C for 24 h (until reaching constant mass) in a conventional oven to remove the content of moisture. The manufacture efficiency could be improved if the waste is dried naturally at the mill site (i.e., under the direct sun exposure or in a ventilated space). That would lessen the employed energy for a more sustainable material manufacture.

•
Milling: Is necessary to break the lumps or crush granular materials to ensure a better mixing uniformity and materials reactivity. In this study, it was performed in a ceramic mortar at lab scale. An industrial large-scale ball-milling would decrease the cost associated to this treatment.

•
Sieving: Separation of the particles depending on the desired granulometry. In the case of the filler, the desired dimension is ≤63 µm. An industrial automated mesh strainer would reduce the timing of the operation and decrease the overall cost associated with manufacturing.
For each considered waste, the necessary treatment is specified in Table 1. The GP-mortars were prepared according to EN 998-2:2016 [34], the manufacturing steps are listed in Table 2.

Hypothesised Applications in Construction
GP-mortars can be used in a variety of applications in construction that may necessitate different requirements in terms of engineering performance, environmental impact, admissible load, cost, durability, etc.
The first step of the proposed method is the selection of the target possible applications and the specification of the characteristics required to optimize the GP-formulations. For this reason, four different applications have been initially selected for the novel GP-mortars: • Structure: GP-mortars can be used to manufacture supporting (structural) elements such as pillars, beams, walls, preformed ashlars, bricks, etc. • Insulation: GP-mortars can be used to manufacture technical elements (i.e., panels) useful to reduce the thermal exchange though the building envelope.

•
Internal partitions: GP-mortars can be used to build technical elements useful to divide the inner space (internal walls).

•
Finishing: GP-mortars can be used to realize surface coatings (i.e., plaster) or decorative elements.
These selected applications have been hypothesized in order to cover a vast range of possible uses in construction.

Evaluation Criteria
Generally, several criteria may be considered to optimize the formulation of a material depending on a specific application [35,36]. Subsequently, the GP mixes were related and analyzed on the basis of a selection of properties. Therefore, this methodology is used to optimize the GP blends analyzing some important categories such as materials' properties (fresh and hardened states), economic, environmental, and safety performance, that are presented in Figure 1.
The selected criteria are defined as follows: • Workability [cm] returns the consistency of the fresh mortar and indicates the material attitude to be homogenously mixed and conveniently placed. It is related to the slurry properties and the specific considered application. In this study, workability was estimated by flow  [13]. The EI was estimated basing on the non-renewable energy (PE-NRe) and the Global Warming Potential (GWP). This criterion was evaluated with the qualitative scale as used in [13]. • Toxicity [qualitative] was considered regarding the safety aspect for human health [39,40].
In this paper, toxicity is defined as the dangerousness of handling the raw materials during the GP production. This criterion was evaluated with a qualitative scale. The selected criteria are defined as follows: • Workability [cm] returns the consistency of the fresh mortar and indicates the material attitude to be homogenously mixed and conveniently placed. It is related to the slurry properties and the specific considered application. In this study, workability was estimated by flow

Fuzzy Topsis Technique
In this study, a multicriteria methodology was used to determine the correlations between the analyzed criteria (cf. 2.4 Evaluation criteria) and the different GP-mortar formulations. In order to consider the data imprecision, the fuzzy logic was then introduced. Hence, fuzzy numbers were used to express some of the aforesaid criteria; the membership functions were embodied by Triangular Fuzzy Numbers (TFNs). A schematic visualization is presented in Figure 2.
In this study, a multicriteria methodology was used to determine the correlations between the analyzed criteria (cf. 2.4 Evaluation criteria) and the different GP-mortar formulations. In order to consider the data imprecision, the fuzzy logic was then introduced. Hence, fuzzy numbers were used to express some of the aforesaid criteria; the membership functions were embodied by Triangular Fuzzy Numbers (TFNs). A schematic visualization is presented in Figure 2.  triplet (a1, a2, a3). The values a1 and a3 represent the lower and the upper bounds of a real number, whose weight (membership) is 0, while all the numbers between a1 and a3 have a weight in the interval ]0-1] (membership function).
Some preliminary information on the relative importance of each criterion are required by the fuzzy Topsis methodology. Consequently, each considered criterion wj was assigned a weight that represents its importance. In this study, the criteria weights have been evaluated by a panel of experts using the Delphi methodology [41]. The panel was composed by four university professors whose scientific interests are in the field of construction technology, materials, and architectural design; three professional engineers; and two technicians working in material science laboratories. The criteria weights have been defined for each selected application in order to optimize the GP mixes based on it as reported in Table 3. For some specific applications, the relative criteria were considered negligible. The first step of the Topsis methodology consists in building a fuzzy decision matrix � , where the m rows represent the GP formulations and the n columns the considered criteria (Equation (1)). The value located at the intersection of a row with a column embodies the performance of a decision alternative according to a criterion. A Triangular Fuzzy Number (TFN) is denoted as a triplet (a 1 , a 2 , a 3 ). The values a 1 and a 3 represent the lower and the upper bounds of a real number, whose weight (membership) is 0, while all the numbers between a 1 and a 3

have a weight in the interval [0-1] (membership function).
Some preliminary information on the relative importance of each criterion are required by the fuzzy Topsis methodology. Consequently, each considered criterion w j was assigned a weight that represents its importance. In this study, the criteria weights have been evaluated by a panel of experts using the Delphi methodology [41]. The panel was composed by four university professors whose scientific interests are in the field of construction technology, materials, and architectural design; three professional engineers; and two technicians working in material science laboratories. The criteria weights have been defined for each selected application in order to optimize the GP mixes based on it as reported in Table 3. For some specific applications, the relative criteria were considered negligible. The first step of the Topsis methodology consists in building a fuzzy decision matrix R, where the m rows represent the GP formulations and the n columns the considered criteria (Equation (1)). The value located at the intersection of a row with a column embodies the performance of a decision alternative according to a criterion.
where r ij directly represents the fuzzy values of the uncertain criteria, because the correspondent fuzzy numbers range in the interval 0-1. On the contrary, for the crisp criteria, additional operations of normalization and fuzzification are necessary. Functions of linear normalization are applied to each criterion. At the same time, each obtained value was triplicated in order to represent the three vertices of the TFN. In this way, the related fuzzy number is obtained.
The second step of the fuzzy Topsis is constructing the weighted normalized fuzzy decision matrix V. Each element of the normalized decision matrix v is multiplied by the weights w j of the corresponding criteria (Equation (2)).
w 1 r 11 w 2 r 12 w 3 r 13 · · · w n r 1n . . . . . . . . . w 1 r m1 w 2 r m2 w 3 r m3 · · · w n r mn Afterwards, as the Topsis methodology suggests, the positive ideal solution Azimuth (A*) and negative ideal solution Nadir (A -) were identified. These solutions, that in our case were represented by fuzzy numbers, can be defined in different ways.
In the fuzzy context presented in this work, an ideal positive value v * j = (1,1,1) and an ideal negative value v − j = (0,0,0) were considered. The third step of the methodology consists in the calculation of the positive and negative relative distances (Equations (2) and (3)). In this study, a fuzzy rectilinear distance has been employed, thus considering the fuzzy distance function as the sum of the differences of fuzzy homologous components (Equations (3) and (4)): The final step combines the two distances in order to obtain the relative closeness coefficient. The following Equation (5) was used: ) and d * is the triangular fuzzy number.

Numerical Application: GP Mortars Mix Design
In this work, a numerical example is reported on the use of the considered wastes generated in the Kraft pulp industry. These wastes were used to prepare the GP-mortars intended for applications in construction. In this paper, structural applications only (i.e., pillars subjected to axial compression) were considered.
The GP-mortar formulations were designed on the base of previous studies [9,20]. The binder, made of a mixture of BFA (70 wt.%) and MK (30 wt.%) activated by the alkaline solution, was admixed with the sand (binder to aggregate ratio equal to 1:3). Three different mixtures of the analyzed residues, used as filler, were added to the mortar's slurry with the following quantities: 2.5, 5.0, 7.5, 10.0 wt.%. The produced specimens are detailed in Table 4.
To build the decision matrix, all the criteria related to fresh and hardened properties, except for the compressive strength, are reported as crisp values as well as the costs. UCS is, in fact, affected by a measurement error that can be directly translated through the use of fuzzy membership functions. As reported in Caleca [42], these data are transformed in the related TFN in the following way: The mean value µ corresponds to the triangle vertex (a 2 ), the upper bound (a 3 ) is calculated adding the error to the mean value, and similarly, the lower bound (a 1 ) is calculated by subtracting it. The values of the toxicity criterion were obtained by interviewing the panel of experts, as suggested by the Delphi described in Section 3. The experts' qualitative judgements have been converted into fuzzy numbers, as reported in Table 5. More particularly, the employed linguistic scale was translated into the corresponding fuzzy membership functions. There, the first and the third numbers represent the corners at the base of the triangle, while the second number is the vertex (cfr. "3. Results and discussion", Figure 3). Five linguistic variables-ranging between very low (VL) and very high (VH)-have been employed. A smaller number of values would have resulted in a less precise definition of the concepts expressed by the experts, while a more detailed scale would have not allowed to achieve the full agreement among them. The used scale approach directly derives from the Saaty's scale [43].  The same table was implemented to translate in fuzzy numbers the values of the LCA criterion. In particular, the intervals reported in Kurda et al. [13] were used to define the corresponding qualitative variable.
The criteria of water absorption and axial strain are to be minimized; the others maximized. The score of workability criterion is represented by means of a trapezoidal membership function. The maximum score (1) is achieved in the range of values 16-22 cm, which represents the most suitable values of slurry workability considering the target application [9,44], whereas in the intervals [10-16[ and ] [22][23][24][25][26][27][28][29][30] the score was calculated with the following Equations (6) and (7): For external values of the above-mentioned intervals, the score is equal to 0. Table 6 shows the criteria values related to the different GP-mortars formulations. Accordingly, with the fuzzy Topsis procedure, criteria have been normalized and fuzzified, as reported in Table 7. For this kind of application, the criteria weights have been set using the results reported in Table 3.  Preference rank was obtained considering the coefficient of closeness associated to each GPmortar formulation. The triangles spread represents the amount of uncertainty. Consequently, when two triangles overlap, a weak rank can be still defined and the related uncertainty is expressed by the ordinate of the intersection between the two triangles. A wide area of overlapping can be explained by a high uncertainty that is, conversely, related to the rank itself. That ultimately means that the uncertainty in the input data is too much to define an absolute preference.   Figure 3 shows the results obtained with the fuzzy Topsis procedure, Table 8 the relative rank.  Preference rank was obtained considering the coefficient of closeness associated to each GP-mortar formulation. The triangles spread represents the amount of uncertainty. Consequently, when two triangles overlap, a weak rank can be still defined and the related uncertainty is expressed by the ordinate of the intersection between the two triangles. A wide area of overlapping can be explained by a high uncertainty that is, conversely, related to the rank itself. That ultimately means that the uncertainty in the input data is too much to define an absolute preference.

Results and Discussion
Results clearly show that the mortar formulations could be classified into four different groups (cfr. Table 8): The best formulations intended for structural application, included indifferently in the first group, are numbers 3 (CalS + Grits + Dregs − 5 wt.%) and 8 (CalS + Grits + Dregs + BFA-1 − 7.5 wt.%). That is in line with the laboratory results: Good workability, high mechanical strength, low axial strain, low water absorption. However, the triangle that represents its fuzzy score almost overlaps the triangle corresponding to the sample containing 7.5 wt.% of all the wastes (second group). That is due to a high mechanical resistance that is counterbalanced (fuzzy approach) by a higher axial strain and slightly lower workability. Conversely, the last group includes the worst GP-mortars formulations. It is observed that adding the BFA-2 generally decreases the material rank. Indeed, a part from formulation n. 12 (CalS + Grits + Dregs + BFA-1 + BFA-2 − 7.5 wt.%) that is included in the second group (due to the very high mechanical resistance), all the other formulations resulted in the lower part of the rank. Even though a very high mechanical resistance was measured, highly convenient for the considered application, the very low workability along with the high water absorption strongly reduce the materials performance, and consequently discourage their use for the selected application (structural). Among the worst formulations (group 4), the unmodified material (n. 1) is included showing-among the others-the lowest UCS and the highest water absorption. Indeed, these are fundamental parameters for the materials selection intended for real applicability. In any case, it is quite expectable that adding the wastes as filler is aimed at improving the materials overall performance. This outcome clearly demonstrates the convenience in the wastes' reuse to manufacture novel sustainable GP materials for applications in construction.

Conclusions
This paper demonstrates that the fuzzy Topsis can be considered a valuable decision-making support tool in selecting novel GP-mortars for sustainable construction applications, in the specific case of considering both quantitative and qualitative criteria. This technique allows the decision maker to define some appropriate criteria of decision and to evaluate their relative importance, that is judged by a panel of experts (Delphi technique). This methodology ensures the employment of a structured procedure for the decision process, in such a context where the presence of multiple conflicting objectives allows us to select the best compromise rather than the best alternative. The decision-making process provides a solution which is strictly related to the specific applications. In the case study, we analyzed novel green mortars intended for structural application. The rank obtained by means of the fuzzy Topsis procedure was reported as a fuzzy set. This fact principally allows us to establish a general rank among the different considered formulations defining, at the same time, the level of confidence which in fuzzy terms is measured by the possibility value.
For the considered study, it is clearly shown that adding the proposed industrial wastes as filler is strongly recommended to improve the materials' performance toward an efficient use in construction. The GP-mortars n. 3 (containing 5 wt.% of CalS + Grits + Dregs) and n. 8 (containing 7.5 wt.% of CalS + Grits + Dregs + BFA-1) have emerged as the best alternatives. Furthermore, it resulted that adding BFA-2 as filler in the structural mortar negatively influences the material performance, and the relative rank.
To conclude, the approach proposed in this study allows us to take into account the uncertainty related to qualitative judgments, as well as those that may exist in the measurement of quantitative parameters.
Further works foresee the application of the fuzzy Topsis methodology to other sets of construction materials, adding other criteria of evaluation to generalize its usage. Furthermore, other applications will be considered to make the presented approach a valid decision-making support tool useful for a vast range of situations.