Enhancing NIR Shielding Properties of Au/CsWO3 Composite via Physical Mixing and Solvothermal Processes

This research aims to enhance the near-infrared (NIR) shielding ability of cesium tungsten bronze (CsWO3) by increasing the spectral absorption in this region through the incorporation of gold nanorods (AuNR). Two approaches were used to prepare the composite materials: physical mixing and solvothermal process. The effects of gold nanorods content on the crystalline size, particle size, shape, and optical properties of the composite were investigated systematically using DLS, TEM, XRD, and UV–Vis spectroscopy techniques, respectively. The physical mixing process synergizes AuNR and CsWO3 into a composite which has better NIR absorption than that of neat AuNR and CsWO3 nanorods. A composite with 10 mol% of AuNR shows the highest NIR absorption ability due to the surface plasmon resonance and energy coupling between Au and CsWO3. With the solvothermal process, the CsWO3 nanorods grow up to 4–7 microns when the AuNR content increases to 0.8 mol% due to the incorporation of the Au atoms. The microsized CsWO3 rods have superior NIR shielding property compared to other conditions, including the AuNR+CsWO3 nanocomposite with 10 mol% of AuNR from the physical mixing process.


Introduction
The 2022 United Nations Environment Program Report stated that energy consumed in buildings accounted for around 34% of global energy consumption in 2021 [1], marking a 4% increase from 2020.The major energy-consuming activities in buildings include heating, cooling, ventilation, lighting, and cooking.Energy consumption for cooling has increased due to the increase in global temperature [2].During the day, indoor temperatures are elevated due to near-infrared light, which constitutes about half of solar energy.NIR light generates heat rays that can penetrate buildings, leading to increased energy consumption for air conditioning and subsequent rise in electricity demand.
In order to improve energy efficiency in buildings without losing human thermal comfort, the transfer of heat through the building envelope should be decreased.In this regard, NIR shielding materials have attracted more attention in recent years [3].In recent years, transparent conductive oxides such as indium tin oxide (ITO) [4,5], aluminum zinc oxide (AZO) [6], and antimony tin oxide (ATO) [7][8][9] have been developed for use as NIR shielding materials, owing to their high absorbance and/or reflectance in the NIR region.However, ITO and AZO only effectively shield the NIR radiation over the wavelength above 1500 nm [5,6], whereas ATO shows poor NIR shielding performance in the wavelength ranging between 700 and 1300 nm [3].
Cesium tungsten bronze (Cs x WO 3 ) with a hexagonal structure is a promising material for its interesting properties, including optical, heat-shielding, and electrical properties [10][11][12][13].It is particularly promising when compared to other types of tungsten bronze such as Na x WO 3 [14], K x WO 3 [15], and Rb x WO 3 [16], especially due to its ability to suppress spectral transmittance in the NIR region [17].
To enhance the optical properties of Cs x WO 3 , several preparation methods have been studied to control the size and morphology of the material.For example, Cs x WO 3 with irregular particles in the range of 0.1-5.0µm have been synthesized by solid state reaction and the hydrothermal method [14,18,19].These methods demonstrated poor control over the size of Cs x WO 3 nanoparticles, leading to low performance in terms of NIR shielding ability and visible light transmittance.Recently, Guo et al. [20] synthesized Cs x WO 3 nanorods with controlled dimensions (approximately 15 nm width and 50 nm length) via solvothermal process.They demonstrated that NIR shielding ability and visible light transparency of the nanorod were superior to those of irregular Cs x WO 3 particles.However, the NIR shielding ability of Cs x WO 3 over the wavelength ranging from 700 nm to 1100 nm has yet to be improved [20].
Several studies have paid attention to improve the NIR shielding ability of CsWO 3 by mixing or doping it with other materials.Xu et al. [21] synthesized CsWO 3 by hydrothermal process and mixed it with ATO nanoparticles via a ball milling process.The CsWO 3 /ATO composite with a weight ratio of 1/1 exhibited an increase in NIR absorption percentage of up to 90%, compared with neat CsWO 3 particles.In addition, Wu et al. [22] proposed CsWO 3 /ZnO composites to be used as a smart coating.The CsWO 3 was prepared by a solvothermal process, and then the ZnO was introduced via a mild chemical process.When the mass ratio of CsWO 3 /ZnO was 1/1, the composite coating possessed a high visible light transmittance of over 80% and great NIR shielding ability.Alternatively, the fluorine-doped CsWO 3 was synthesized by adding hydrofluoric acid into the mixture of CsWO 3 solution, prior to carrying out the hydrothermal process [23].As a result, the Cs 0.33 WO 3-x F x film with an F/W molar ratio of 0.45/1 exhibited a higher NIR shielding ability of 90% compared with the undoped Cs 0.33 WO 3 film.
In this study, attempts were made to enhance the NIR shielding ability of CsWO 3 by introducing gold nanorods (Au NR ) into the system.The absorbance spectrum of Au can be tuned by controlling the size, shape, and structure of materials [24].The absorption peak of gold nanoparticles can be shifted from visible region to NIR region (>780 nm) by increasing the aspect ratio of Au NR through localized surface plasmon resonance [25].This statement was confirmed by several studies, including the study by Makhsin et al., which demonstrated that the absorption peak of Au NR was shifted toward the long wavelength over 700 nm when the aspect ratio of Au NR was larger than 3.5 [26].
Despite the above progress and to the best of our best knowledge, the optical properties of a composite system containing a combination of Au NR with CsWO 3 have not been studied and reported in the open literature.This work aimed to investigate the effects of the Au NR content on the morphology, crystal structure, and optical structures of the resulting composite materials.Two different approaches were used to prepare the composites: a physical mixing process and an in situ mixing of Au NR with CsWO 3 via a solvothermal process, as illustrated in Figure 1.It was found that, by properly controlling the amount of Au NR , the composite materials prepared via the latter approach could exhibit enhanced optical properties.

Synthesis of CsWO3 Nanorods
The rod-like CsWO3 nanoparticles were synthesized via a water-controlled release solvothermal process [27].In a typical experiment, 1.0 mmol of WCl6 powder and 0.5 mmol of CsOH•H2O powder were dissolved in 40 mL of absolute ethanol with constant stirring.Then, 10 mL of acetic acid was added and mixed into the prepared solution.Next, the solution was transferred into a Teflon-lined autoclave of 100 mL internal volume, followed by solvothermal treatment at 240 °C for 20 h.After that, dark blue powders were collected using centrifugation and washed with deionized water and ethanol three times, then dried at 60 °C for 12 h.

Synthesis of Gold Nanorods (AuNR)
Gold nanorods were synthesized via the seed-mediated growth method [28].First, the seed solution was prepared by dissolving 0.01 M of HAuCl4 into 0.1 M of CTAB solution by gently stirring for 5 min.After that, 0.01 M of ice-cold NaBH4 solution was added to the solution by vigorously stirring for 2 min.A color change in the solution, from yellow to brownish yellow, should be noticed.This CTAB-stabilized seed solution was kept at room temperature for 2 h.
The growth solution was prepared by mixing 0.1 M of CTAB with 0.006 M of AgNO3.Then, 0.01 M of HAuCl4 and 1.0 M of hydrochloric acid in aqueous solution were, respectively, added to the growth solution under gentle stirring.A total of 0.1 M of ascorbic acid in aqueous solution was added at once, and the growth solution became colorless.The CTAB-stabilized seed solution (10 µL) was added to the growth solution by gently mixing for 10 s.Then, the solution was kept at room temperature for 18 h.After 18 h, AuNR were centrifuged and washed with deionized water to remove some excess CTAB.The product was resuspended in 5 mL of deionized water and stored at room temperature before use.

Synthesis of CsWO 3 Nanorods
The rod-like CsWO 3 nanoparticles were synthesized via a water-controlled release solvothermal process [27].In a typical experiment, 1.0 mmol of WCl 6 powder and 0.5 mmol of CsOH•H 2 O powder were dissolved in 40 mL of absolute ethanol with constant stirring.Then, 10 mL of acetic acid was added and mixed into the prepared solution.Next, the solution was transferred into a Teflon-lined autoclave of 100 mL internal volume, followed by solvothermal treatment at 240 • C for 20 h.After that, dark blue powders were collected using centrifugation and washed with deionized water and ethanol three times, then dried at 60 • C for 12 h.

Synthesis of Gold Nanorods (Au NR )
Gold nanorods were synthesized via the seed-mediated growth method [28].First, the seed solution was prepared by dissolving 0.01 M of HAuCl 4 into 0.1 M of CTAB solution by gently stirring for 5 min.After that, 0.01 M of ice-cold NaBH 4 solution was added to the solution by vigorously stirring for 2 min.A color change in the solution, from yellow to brownish yellow, should be noticed.This CTAB-stabilized seed solution was kept at room temperature for 2 h.
The growth solution was prepared by mixing 0.1 M of CTAB with 0.006 M of AgNO 3 .Then, 0.01 M of HAuCl 4 and 1.0 M of hydrochloric acid in aqueous solution were, respectively, added to the growth solution under gentle stirring.A total of 0.1 M of ascorbic acid in aqueous solution was added at once, and the growth solution became colorless.The CTAB-stabilized seed solution (10 µL) was added to the growth solution by gently mixing for 10 s.Then, the solution was kept at room temperature for 18 h.After 18 h, Au NR were centrifuged and washed with deionized water to remove some excess CTAB.The product was resuspended in 5 mL of deionized water and stored at room temperature before use.

Preparation of Au NR +CsWO 3 Composite Materials by Physical Mixing Method
CsWO 3 powder was added into an aqueous solution of Au NR in a beaker under constant stirring at room temperature for an hour.The molar ratios between Au NR and CsWO 3 varied from 0.8 to 20 mol%.

Preparation of Au NR @CsWO 3 Composite Materials by Solvothermal Method
Typically, 0.5 mmol of WCl 6 powder and 0.25 mmol of CsOH•H 2 O powder were dissolved in 20 mL absolute ethanol with constant stirring.Then, 5 mL of acetic acid was added to this solution, followed by adding 3 mL of a solution of Au NR (0.3, 0.6, 1.2, and 2.4 w/v% in ethanol) under stirring.These values are equivalent to 0.4, 0.8, 1.5, and 3.0 mol% Au NR .The solution was transferred into a Teflon-lined autoclave of 100 mL internal volume, followed by solvothermal treatment at 240 • C for 20 h.Next, the product was centrifuged and washed with deionized water and ethanol, respectively, several times.Finally, the product was dried at 60 • C for 12 h.

Characterizations
The X-ray diffraction (XRD) patterns of the CsWO 3 , Au NR , and the Au NR /CsWO 3 nanocomposites were recorded by using a Bruker D8 Advance X-ray diffractometer (Bruker, Billerica, MA, USA), using Cu Kα radiation (λ = 1.5406Å) and 2θ in the range of 20 • -90 • .The morphological structure of the materials was analyzed by transmission electron microscopy (TEM, Thermo scientific Talos F200X, Waltham, MA, USA) with an EDS attachment.TEM specimens were prepared by placing a drop of aqueous particle solution on a carbon-coated copper grid and then evaporating the solution at room temperature.The particle size distribution of the nanocomposites was measured by dynamic light scattering technique (DLS), using a Zetasizer instrument (Nano-ZS90, Malvern Instruments Ltd., Malvern, UK).The DLS samples were diluted with DI water and then sonicated to suspend the particles before testing.The average hydrodynamic diameter was evaluated by taking an average of 11 runs, with each run having a duration of 10 s.The optical properties of the samples were measured by a UV-Vis spectrophotometer (Thermo Scientific, Genesys 10S).The nanocomposites were suspended in DI water before testing.The absorbance and transmittance measurement of the nanocomposites was investigated over the wavelength ranged between 300 and 1100 nm at room temperature.

Au NR +CsWO 3 Nanocomposites by Physical Mixing Method
The precursors, CsWO 3 and Au nanorods, were separately synthesized by solvothermal and seed-mediated growth processes, respectively, under the aforementioned conditions.The TEM image in Figure 2a shows the sharp-ended CsWO 3 nanorod with 13.76 nm width and 48.71 nm length (aspect ratio 3.54), while Figure 2b shows the round-ended Au NR with 15.49 nm width and 52.82 nm length (aspect ratio 3.41).
After combining the precursors by a physical mixing process, the Au NR content of 0.8 and 1.5 mol% was not observed by TEM due to the low Au NR content.However, the appearance of a ring pattern of nanocomposites, corresponding to the Au nanostructure, was detected on the SAED pattern (Figure 2e).When the content of Au NR increased to 3.0 mol%, the size and shape of the round-ended Au NR and sharp-ended CsWO 3 nanorods were retained, as verified by TEM and elemental mapping analysis in Figure 2c and Figure 2f-h, respectively.
Moreover, a diffraction peak was observed at around 38.2°, corresponding to the (111) plane of face-centered cubic (fcc) crystalline lattice of Au, as indicated in JCPDS No. 04-0784.Furthermore, the intensity of Au peaks increased by increasing the content of AuNR.Apart from these, no new phase or impurity was observed from the XRD patterns of these nanocomposites.It was also noted that the increase in Au content did not alter the position of peaks at (002) and (200) of Cs0.32WO3 (Figure 3b).The top-left graph in Figure 4a shows the absorbance spectrum of AuNR, which exhibited two resonance modes, a transversal surface plasmon resonance (TSPR) and a longitudinal surface plasmon resonance (LSPR), which in turn determine the optical properties of this rod-shaped nanostructure.The TSPR and LSPR modes correspond to the electron oscillation associated with the short and long axes of the nanorod, respectively.The absorption spectrum of AuNR is related to the aspect ratio and shape, as shown in the TEM images (Figure 2b).The weak absorbance peaks corresponding to the TSPR bands are around 520 nm, while the strong LSPR peaks are around 800 nm, according to the horizontal dimension of AuNR.
Figure 4 shows the absorption and transmission spectra of CsWO3 nanorods and AuNR+CsWO3 nanocomposites synthesized by the physical mixing method.The CsWO3 Moreover, a diffraction peak was observed at around 38.2 • , corresponding to the (111) plane of face-centered cubic (fcc) crystalline lattice of Au, as indicated in JCPDS No. 04-0784.Furthermore, the intensity of Au peaks increased by increasing the content of Au NR .Apart from these, no new phase or impurity was observed from the XRD patterns of these nanocomposites.It was also noted that the increase in Au content did not alter the position of peaks at (002) and (200) of Cs 0.32 WO 3 (Figure 3b).
The top-left graph in Figure 4a shows the absorbance spectrum of Au NR , which exhibited two resonance modes, a transversal surface plasmon resonance (TSPR) and a longitudinal surface plasmon resonance (LSPR), which in turn determine the optical properties of this rod-shaped nanostructure.The TSPR and LSPR modes correspond to the electron oscillation associated with the short and long axes of the nanorod, respectively.The absorption spectrum of Au NR is related to the aspect ratio and shape, as shown in the TEM images (Figure 2b).The weak absorbance peaks corresponding to the TSPR bands are around 520 nm, while the strong LSPR peaks are around 800 nm, according to the horizontal dimension of Au NR .The AuNR+CsWO3 nanocomposite exhibited unique absorbance spectra, which differs from the optical properties of neat AuNR and CsWO3 nanorods.This was ascribed to surface plasmon resonance and energy coupling between Au and CsWO3 (Figure 5), which enhanced the NIR absorption by the nanocomposite.Similar behavior has been reported for Au/ZnO and Au/WO3 systems [30][31][32][33][34], which demonstrated the mechanism of a sequential energy transfer from ZnO or WO3 to Au and electron transfer from Au to ZnO or WO3.
As explained in Figure 5, when light is absorbed by electrons on the surface of CsWO3, these electrons are excited to the conduction band, while some electrons are trapped at the defect level, which is called small polaron.This contributes to the NIR absorption at 780-1100 nm [35].Subsequently, the electrons recombine with the holes in the valence band of CsWO3, resulting in energy emission.When CsWO3 is in contact with AuNR, the electrons on the surface of AuNR are elevated to a higher energy state, generating surface plasmon resonance (SPR) by absorbing light.Consequently, the hot energetic Au electrons are transferred to the conduction band of the adjacent CsWO3.This additional influx of electrons increases the charge carrier concentration in the conduction band and band structure, leading to an enhanced NIR absorption capability of the nanocomposite.
Moreover, with a higher AuNR content, more hot electrons from Au could be transferred into the conduction band of the adjacent CsWO3, resulting in an enhanced NIR absorption ability of the nanocomposite.This synergetic effect between CsWO3 and AuNR led to the enhancement in NIR absorption of the physically mixed composite.Figure 4 shows the absorption and transmission spectra of CsWO 3 nanorods and Au NR +CsWO 3 nanocomposites synthesized by the physical mixing method.The CsWO 3 nanorods exhibited high transmittance in the visible range (400-780 nm) and low transmittance in the NIR range (780-1100 nm), providing effective infrared shielding.The Au NR +CsWO 3 nanocomposites prepared by physical mixing method demonstrate improved NIR absorbance over CsWO 3 nanorods.The NIR absorbance increases as the Au NR content increases.Consequently, the visible transmittance of nanocomposites significantly decreases with the higher Au NR content.A 10 mol% Au NR content exhibited the lowest visible light transmittance while offering the highest NIR shielding properties.
The Au NR +CsWO 3 nanocomposite exhibited unique absorbance spectra, which differs from the optical properties of neat Au NR and CsWO 3 nanorods.This was ascribed to surface plasmon resonance and energy coupling between Au and CsWO 3 (Figure 5), which enhanced the NIR absorption by the nanocomposite.Similar behavior has been reported for Au/ZnO and Au/WO 3 systems [30][31][32][33][34], which demonstrated the mechanism of a sequential energy transfer from ZnO or WO 3 to Au and electron transfer from Au to ZnO or WO 3 .
As explained in Figure 5, when light is absorbed by electrons on the surface of CsWO 3 , these electrons are excited to the conduction band, while some electrons are trapped at the defect level, which is called small polaron.This contributes to the NIR absorption at 780-1100 nm [35].Subsequently, the electrons recombine with the holes in the valence band of CsWO 3 , resulting in energy emission.When CsWO 3 is in contact with Au NR , the electrons on the surface of Au NR are elevated to a higher energy state, generating surface plasmon resonance (SPR) by absorbing light.Consequently, the hot energetic Au electrons are transferred to the conduction band of the adjacent CsWO 3 .This additional influx of electrons increases the charge carrier concentration in the conduction band and band structure, leading to an enhanced NIR absorption capability of the nanocomposite.

AuNR@CsWO3 Nanocomposites Prepared by the Solvothermal Method
Figure 6 shows TEM images of the AuNR@CsWO3 nanocomposite with various AuNR contents.At the lowest AuNR content (0.4 mol%), the sample contains a mixture of rodshaped CsWO3 with two different longitudinal sizes (Figure 6a).Measurement using Im-ageJ software (version 1.53v) revealed that the majority of the AuNR@CsWO3 nanocomposites were around 12-15 nm in width and 50-100 nm in length, while a smaller number were approximately 40-80 nm in width and 0.5-1.2µm in length.
When the AuNR content increased to 0.8 mol%, the size of rod-shaped CsWO3 increased in both width and length.Most of the CsWO3 nanorods were approximately 16-60 nm in width and 70-600 nm in length, while around 5% were exceptionally long, measuring roughly 60-100 nm in width and 4-7 µm in length.This observation aligned with the DLS results shown in Figure 6f.For AuNR contents of 1.5 and 3.0 mol%, the CsWO3 nanorods were approximately 60-400 nm in length, and the longer micron-sized nanorods were no longer observed (Figure 6c,d).This suggests that the increase in the AuNR content led to a shift in the size distribution of the CsWO3 nanorods, favoring shorter lengths.
Although the AuNR could not be directly observed in the nanocomposites through TEM imaging, SAED pattern revealed the presence of a ring pattern corresponding to the Au nanostructure (Figure 6e).Moreover, with a higher Au NR content, more hot electrons from Au could be transferred into the conduction band of the adjacent CsWO 3 , resulting in an enhanced NIR absorption ability of the nanocomposite.This synergetic effect between CsWO 3 and Au NR led to the enhancement in NIR absorption of the physically mixed composite.

Au NR @CsWO 3 Nanocomposites Prepared by the Solvothermal Method
Figure 6 shows TEM images of the Au NR @CsWO 3 nanocomposite with various Au NR contents.At the lowest Au NR content (0.4 mol%), the sample contains a mixture of rodshaped CsWO 3 with two different longitudinal sizes (Figure 6a).Measurement using ImageJ software (version 1.53v) revealed that the majority of the Au NR @CsWO 3 nanocomposites were around 12-15 nm in width and 50-100 nm in length, while a smaller number were approximately 40-80 nm in width and 0.5-1.2µm in length.
When the Au NR content increased to 0.8 mol%, the size of rod-shaped CsWO 3 increased in both width and length.Most of the CsWO 3 nanorods were approximately 16-60 nm in width and 70-600 nm in length, while around 5% were exceptionally long, measuring roughly 60-100 nm in width and 4-7 µm in length.This observation aligned with the DLS results shown in Figure 6f.For Au NR contents of 1.5 and 3.0 mol%, the CsWO 3 nanorods were approximately 60-400 nm in length, and the longer micron-sized nanorods were no longer observed (Figure 6c,d).This suggests that the increase in the Au NR content led to a shift in the size distribution of the CsWO 3 nanorods, favoring shorter lengths.
Although the Au NR could not be directly observed in the nanocomposites through TEM imaging, SAED pattern revealed the presence of a ring pattern corresponding to the Au nanostructure (Figure 6e).
The high-resolution TEM image shows that the lattice fringe spacing of the (002) crystal plane is present at the end of the CsWO 3 nanorods, while the (200) plane is oriented perpendicular to the nanorod axis.This suggests that there are two possible growth orientations for the nanorods: along the [002] direction and the [200] direction, as depicted in Figure 7.This result is consistent with previous work by Guo et al. [18], which proposed that the (002) plane parallel to the nanorod is the primary growth direction for CsWO 3 nanorods.The high-resolution TEM image shows that the lattice fringe spacing of the (002) crystal plane is present at the end of the CsWO3 nanorods, while the (200) plane is oriented perpendicular to the nanorod axis.This suggests that there are two possible growth orientations for the nanorods: along the [002] direction and the [200] direction, as depicted in Figure 7.This result is consistent with previous work by Guo et al. [18], which proposed that the (002) plane parallel to the nanorod is the primary growth direction for CsWO3 nanorods.The high-resolution TEM image shows that the lattice fringe spacing of the (002) crystal plane is present at the end of the CsWO3 nanorods, while the (200) plane is oriented perpendicular to the nanorod axis.This suggests that there are two possible growth orientations for the nanorods: along the [002] direction and the [200] direction, as depicted in Figure 7.This result is consistent with previous work by Guo et al. [18], which proposed that the (002) plane parallel to the nanorod is the primary growth direction for CsWO3 nanorods.Although the Au NR content of 0.8 mol% was not directly observable using TEM, the SAED analysis revealed a ring pattern corresponding to the face-centered cubic (FCC) structure of Au.Elemental mapping further indicated that the Au phase was homogeneously distributed within the CsWO 3 nanorods (Figure 8a).This suggests that the high temperature (>250 • C) in the solvothermal process may have caused morphological changes to the original Au NR , leading to decomposition into atoms and dispersion in the solution, as reported by Petrova et al. [36], where some of these Au atoms may further attach to growing CsWO 3 , enhancing their growth mechanism of CsWO 3 .
with each other, transforming more thermodynamically stable spherical nanoparticles, as depicted in Figure 8b.Specifically, at an AuNR content of 3.0 mol%, the concentration of dissolved Au atoms reached the supersaturation point, leading to the formation of Au atom clusters.Due to the complete occupation of available sites within the CsWO3 structure, the excess Au ions underwent recombination, resulting in the formation of independent Au spheres.This decomposition of Au NR into atoms is supported by a previous study [37], where an Au NR suspension was subjected to solvothermal conditions without any precursors.This resulted in the formation of gold flakes, evidenced by the disappearance of the characteristic absorption peaks of Au NR in UV-Vis/NIR spectroscopy.Similarly, the growth enhancement of CsWO 3 nanorods during the solvothermal process is supported by another study [38], where dissolved Cobalt ions were incorporated at the end of iron oxide (FeOOH) nanorods during solvothermal process.The presence of cobalt ions during the growth process resulted in an increase in the length of the FeOOH nanorods.
Additionally, at sufficiently high Au concentrations, Au atoms tend to recombine with each other, transforming more thermodynamically stable spherical nanoparticles, as depicted in Figure 8b.Specifically, at an Au NR content of 3.0 mol%, the concentration of dissolved Au atoms reached the supersaturation point, leading to the formation of Au atom clusters.Due to the complete occupation of available sites within the CsWO 3 structure, the excess Au ions underwent recombination, resulting in the formation of independent Au spheres.
The XRD pattern in Figure 9 supports the elemental mapping results, indicating that Au atoms can be incorporated into the CsWO 3 nanorods.No impurities or any new phases were detected in the XRD analysis.However, a closer examination revealed shifting and broadening of the XRD peaks.Comparing the XRD peaks of neat CsWO 3 and the Au NR @CsWO 3 nanocomposites, the peaks corresponding to the 002 and 200 planes of Au NR @CsWO 3 (at 23.6 • and 27.7 • , respectively), were slightly shifted toward higher angles.This peak shifting confirms that the Au atoms can be incorporated into a CsWO 3 nanorod structure without creating any new phases, agreeing with the findings of Venkatesan et al. [39].They reported similar peak shifts in metal ion-doped V 2 O 5 samples, indicating the successful incorporation of the metal ion into the pure V 2 O 5 host structure.
AuNR@CsWO3 nanocomposites, the peaks corresponding to the 002 and 200 planes of AuNR@CsWO3 (at 23.6° and 27.7°, respectively), were slightly shifted toward higher angles.This peak shifting confirms that the Au atoms can be incorporated into a CsWO3 nanorod structure without creating any new phases, agreeing with the findings of Venkatesan et al. [39].They reported similar peak shifts in metal ion-doped V2O5 samples, indicating the successful incorporation of the metal ion into the pure V2O5 host structure.Figure 10 shows the absorbance and transmittance spectra of CsWO3 nanorods and the AuNR@CsWO3 nanocomposites synthesized by the solvothermal method.The incorporation of AuNR had a significant impact on the optical properties of the nanocomposites.The absorption value at a wavelength of 400 nm increased significantly with the addition of 0.4 and 0.8 mol% of AuNR.This increase in absorption was due to the growing length of the CsWO3 nanorods, which reached up to 4-7 µm after the incorporation of Au.Interestingly, the nanocomposite with 0.8 mol% of AuNR exhibited much higher NIR absorption compared to that with 0.4 mol% of AuNR, due to the presence of a larger number of CsWO3 in the micrometer size range, as confirmed by the DLS results shown in Figure 6f.However, as the AuNR content was further increased to 1.5 mol% and 3.0 mol%, the absorption in both the visible and NIR regions demonstrated a tendency to decrease, which can be ascribed to the presence of shorter CsWO3 rods within the nanocomposites.The nanocomposites with 3.0 mol% of AuNR exhibited the highest transmittance in visible region.
Notably, the absorbance spectrum revealed the presence of a minor peak at 540 nm, indicating the formation of Au nanospheres, which corresponded to the absorption of Au nanospheres.This was supported by the work of Altunbek et al. [40].This result confirms the presence of excessive dissolved Au atoms, which preferred to accumulate rather than incorporate into the CsWO3 nanostructure, resulting in the formation of Au nanospheres.Figure 10 shows the absorbance and transmittance spectra of CsWO 3 nanorods and the Au NR @CsWO 3 nanocomposites synthesized by the solvothermal method.The incorporation of Au NR had a significant impact on the optical properties of the nanocomposites.The absorption value at a wavelength of 400 nm increased significantly with the addition of 0.4 and 0.8 mol% of Au NR .This increase in absorption was due to the growing length of the CsWO 3 nanorods, which reached up to 4-7 µm after the incorporation of Au.Interestingly, the nanocomposite with 0.8 mol% of Au NR exhibited much higher NIR absorption compared to that with 0.4 mol% of Au NR , due to the presence of a larger number of CsWO 3 in the micrometer size range, as confirmed by the DLS results shown in Figure 6f.However, as the Au NR content was further increased to 1.5 mol% and 3.0 mol%, the absorption in both the visible and NIR regions demonstrated a tendency to decrease, which can be ascribed to the presence of shorter CsWO 3 rods within the nanocomposites.The nanocomposites with 3.0 mol% of Au NR exhibited the highest transmittance in visible region.According to the results, the solvothermal method enhanced the NIR absorption ability of the nanocomposites compared to those derived from the physical mixing process.Specifically, the solvothermal approach increased the length of the CsWO3 nanorods, leading to improved NIR absorption properties.In fact, the nanocomposite synthesized via Notably, the absorbance spectrum revealed the presence of a minor peak at 540 nm, indicating the formation of Au nanospheres, which corresponded to the absorption of Au nanospheres.This was supported by the work of Altunbek et al. [40].This result confirms the presence of excessive dissolved Au atoms, which preferred to accumulate rather than incorporate into the CsWO 3 nanostructure, resulting in the formation of Au nanospheres.
According to the results, the solvothermal method enhanced the NIR absorption ability of the nanocomposites compared to those derived from the physical mixing process.Specifically, the solvothermal approach increased the length of the CsWO 3 nanorods, leading to improved NIR absorption properties.In fact, the nanocomposite synthesized via the solvothermal process with just 0.8 mol% Au NR exhibited superior NIR shielding and visible transmission performance over the composite made by physical mixing with a much higher 10 mol% Au NR content, as shown in Figure 11.Furthermore, the solvothermal process requires fewer steps and a smaller amount of Au NR compared to the physical mixing process.Therefore, the Au NR @CsWO 3 composite materials produced via the solvothermal process are an efficient alternative for use in energy-saving applications that require effective NIR shielding properties.According to the results, the solvothermal method enhanced the NIR absorption ability of the nanocomposites compared to those derived from the physical mixing process.Specifically, the solvothermal approach increased the length of the CsWO3 nanorods, leading to improved NIR absorption properties.In fact, the nanocomposite synthesized via the solvothermal process with just 0.8 mol% AuNR exhibited superior NIR shielding and visible transmission performance over the composite made by physical mixing with a much higher 10 mol% AuNR content, as shown in Figure 11.Furthermore, the solvothermal process requires fewer steps and a smaller amount of AuNR compared to the physical mixing process.Therefore, the AuNR@CsWO3 composite materials produced via the solvothermal process are an efficient alternative for use in energy-saving applications that require effective NIR shielding properties.

Conclusions
AuNR/CsWO3 nanocomposites were successfully prepared by two different methods: a physical mixing process and a solvothermal process.In the physical mixing approach,

Conclusions
Au NR /CsWO 3 nanocomposites were successfully prepared by two different methods: a physical mixing process and a solvothermal process.In the physical mixing approach, the enhancement of NIR absorption of Au NR +CsWO 3 was promoted through the surface plasmon resonance phenomena and the energy coupling between Au and CsWO 3 components.In contrast, in the solvothermal approach, Au atoms were incorporated into the CsWO 3 structure, leading to the increase in the longitudinal axis of CsWO 3 nanorods.The composite prepared by the solvothermal method exhibits better NIR absorption and visible transmission compared to that obtained from the physical mixing process.This latter Au NR @CsWO 3 nanocomposite prepared by the solvothermal method may efficiently be a good candidate in energy-saving window applications.

Figure 1 .
Figure 1.Schematic of preparation of AuNR/CsWO3 composites via two different approaches.

Figure 1 .
Figure 1.Schematic of preparation of Au NR/ CsWO 3 composites via two different approaches.

Figure 3 .
Figure 3. (a) XRD patterns of AuNR, CsWO3, and AuNR+CsWO3 nanocomposites synthesized by physical mixing method with different AuNR content and (b) magnified XRD patterns in the region of 2θ from 20° to 32°.

Figure 3 .
Figure 3. (a) XRD patterns of Au NR , CsWO 3 , and Au NR +CsWO 3 nanocomposites synthesized by physical mixing method with different Au NR content and (b) magnified XRD patterns in the region of 2θ from 20 • to 32 • .

Figure 4 .
Figure 4. (a) Absorbance and (b) transmittance spectra of CsWO 3 nanorods and Au NR +CsWO 3 nanocomposites synthesized by physical mixing method with different Au NR content.

Figure 5 .
Figure 5. Schematic illustration of the energy coupling and plasmonic hot electron transfer in Au NR +CsWO 3 nanocomposites.

Figure 9 .
Figure 9. (a) XRD patterns of Au NR , CsWO 3 , and Au NR @CsWO 3 nanocomposites synthesized by solvothermal mixing method with different Au NR content and (b) magnified XRD patterns in the region of 2θ from 20 • to 32 • .