Influence of Friction Stir Process on the Physical, Microstructural, Corrosive, and Electrical Properties of an Al–Mg Alloy Modified with Ti–B Additives

In this study, two successive methods were used to improve the grain structure and the mechanical and physical properties of Al 5052 aluminum alloy. The modifying elements, 0.99 wt.% of titanium (Ti) and 0.2 wt.% of boron (B), were added during the casting process. After solidification, single- and double-pass friction stir processing (FSP) were performed to achieve additional grain refinement and disperse the newly formed phases well. The addition of Ti–B modifiers significantly improved the mechanical and physical properties of the Al 5052 aluminum alloy. Nevertheless, only a 3% improvement in microhardness was achieved. The ultimate strength (US), yield strength (YS), and elastic modulus were investigated. In addition, the electrical conductivity was reduced by 56% compared to the base alloys. The effects of grain refinement on thermal expansion and corrosion rate were studied; the modified alloy with Ti–B in the as-cast state showed lower dimension stability than the samples treated with the FSP method. The grain refinement significantly affected the corrosion resistance; for example, single and double FSP passes reduced the corrosion rate by 11.4 times and 19.2 times, respectively. The successive FSP passes, resulting in a non-porous structure, increased the bulk density and formed precipitates with high bulk density.


Introduction
Aluminum alloys are widely used in many industrial applications because of their lightness and malleability. The marine, aerospace, automotive, medical, and chemical industries use these alloys. Many techniques can improve the mechanical properties of aluminum alloys. Reinforcing particles and additives are essential approaches for improving the performance of these alloys [1][2][3][4]. Modification elements such as Ti, B, and B 4 C have significantly affected the grain refinement's microstructure [5]. These modifiers are crucial for reducing the grain size and presenting a dendritic structure during the casting process, which helps in improving the characteristics of these alloys [6][7][8]. The modifiers improve the grain structure and reduce the cast alloys' porosity; grain refinement is inextricably linked to the nucleation and development of aluminum grains; hence, this is congruent the alloying elements with the base alloy during the casting process. An interior graphite mold measuring 250 × 70 × 15 mm 3 was used to pour the liquid metal at 800 • C. The remaining stresses from the ingots were removed by heating in the furnace for three hours at 200 • C, followed by air cooling. An automated vertical milling machine was used to perform friction stir processing (FSP), as seen in Figure 1a (Knuth-VFM5, Knuth, Wasbek, Germany). A great deal of trial and error went into determining the machining settings. Tilt angle was set to 1, rotational speed was set at 1080 rpm, and the traverse speed was set to 30 mm per minute. Figure 1b shows the friction-stirred sample after one and two passes of treatment. The hardened K-113 tool steel (K110 Bohler steel; DIN 1.2379, AISI D2) used in the FSP tool was based on references [34,35]. An equilateral triangle with a side length of 8 mm, a shoulder diameter of 25 mm, and a pin length of 8 mm was developed and constructed for the tool. The samples were ground using a set of silicon carbide papers with grit sizes of 320, 800, 1200, 2400, and 4000 for the metallographic process. All of the samples were electrically etched using 10% electrolytes (saturated solution of H 3 BO 3 in HF) and 90% distilled water at 18 V for 15 s. The microstructure of the specimens was studied by utilizing optical microscopy to investigate the grain microstructures (Olympus BX51, Miami, FL, USA) and scanning electron microscopy (SEM) using a Tescan-VEGA3 (model Vega 3, company TESCAN, Brno, Czech Republic, HV 20.0 kV) equipped with an X-MAX80 energy-dispersive spectroscopy (EDS) system (Oxford Instruments, Abingdon, UK). The grain size was determined using the typical linear intercept approach using the AxioVision 4.5 software attached to the microscope (Olympus BX51, Miami, FL, USA).   Figure 2 shows the microstructure and grain size distribution of the Al 5052 and Al 5052 alloys after casting. Al 5052 had large grains, with a coarse dendritic structure ( Figure  2a). The average grain size of Al 5052 after casting was 200 ± 15 µm. The grain size was broadly distributed around the mean, with a standard deviation (SD) of 80 µm ( Figure  2b). The inclusion of the Ti-B modifier during the casting process refined the grains and eliminated the dendritic structure (Figure 2c). The average grain size of Al 5052/TiB after casting was 18 ± 3 µm. The grain size was closely distributed around the mean, with a standard deviation of 5 µm (Figure 2d). The XRD method "Philips PW 1373" proved the presence of the various phases in the produced samples. Following ASTM: B962-08, samples were weighed using the Archimedes technique. Using a thermal dilatometer (NETZSCH DIL 402 PC, Selb, Germany) with a heating rate of 5 • C/min and rectangular bars, we measured the samples' thermal expansion from 25 to 500 • C, as detailed in our previous work [5]. The samples were tested for compressive strength using the ASTM E9-19 standard. As previously mentioned [36,37], the speed of longitudinal and shear waves at room temperature was measured using the pulse-echo method using an ultrasonic digital signal processing system (Model MBS8000 DSP, MATEC Instrument Companies, Northborough, USA) with 5 MHz resonance. Static immersion weight loss was used at ambient temperature (25 • C) to assess the corrosion rate of sintered samples. Diamond paste was used to provide a mirror-like finish on the samples' surfaces after being polished with SiC papers of different grit levels up to 2000 grits. Additionally, each sample was measured and placed into a 3.5 wt.% NaCl solution before being extracted after 1 to 8 days in the solution. Samples were also tested for electrical conductivity using a Keithley 6517B system (6517 B, Keithley Instruments, OH, USA) at ambient temperature (26 • C) and 40 V. Figure 2 shows the microstructure and grain size distribution of the Al 5052 and Al 5052 alloys after casting. Al 5052 had large grains, with a coarse dendritic structure ( Figure 2a). The average grain size of Al 5052 after casting was 200 ± 15 µm. The grain size was broadly distributed around the mean, with a standard deviation (SD) of 80 µm ( Figure 2b). The inclusion of the Ti-B modifier during the casting process refined the grains and eliminated the dendritic structure ( Figure 2c). The average grain size of Al 5052/TiB after casting was 18 ± 3 µm. The grain size was closely distributed around the mean, with a standard deviation of 5 µm (Figure 2d).     Figure 4 shows the micrographs and grain size frequency of the standard alloy Al 5052 and the modified alloy with 0.99%Ti + 0.2%B after the first pass of the friction stirring process in the stirred zone (SZ). After the first pass of FSP on Al 5052, the grains became homogeneous and equiaxed, and the dendritic structure disappeared from the SZ ( Figure  4a). The average grain size in the SZ decreased to 16 ± 3 µm, and the grains were normally distributed around the mean, with SD = 5.5 µm (Figure 4b). The grains were refined by 12.5 folds, showing the soundness of FSP in modifying the microstructure of the as-cast dendritic structure alloys. The modified Al 5052/TiB alloy grains were insignificantly refined after FSP, and the average grain size decreased to 13 ± 2 µm. The grains were distributed around the mean value, with SD = 3.5 µm.  Figure 4 shows the micrographs and grain size frequency of the standard alloy Al 5052 and the modified alloy with 0.99%Ti + 0.2%B after the first pass of the friction stirring process in the stirred zone (SZ). After the first pass of FSP on Al 5052, the grains became homogeneous and equiaxed, and the dendritic structure disappeared from the SZ (Figure 4a). The average grain size in the SZ decreased to 16 ± 3 µm, and the grains were normally distributed around the mean, with SD = 5.5 µm (Figure 4b). The grains were refined by 12.5 folds, showing the soundness of FSP in modifying the microstructure of the as-cast dendritic structure alloys. The modified Al 5052/TiB alloy grains were insignificantly refined after FSP, and the average grain size decreased to 13 ± 2 µm. The grains were distributed around the mean value, with SD = 3.5 µm. Figure 5 shows the micrographs and grain size abundance of the standard Al 5052 alloy and the modified alloy with 0.99%Ti + 0.2%B after the second pass of the friction stir process in the SZ. In general, the second pass of FSP resulted in greater refinement of the grains (Figure 5a,c). The average grains of the Al 5052 alloy and the modified Al 5052/TiB alloy were reduced to 12 ± 2 and 8 ± 2 µm, respectively. The grains of both alloys were normally distributed around the mean after the second pass, with SD of 2.5 and 1.7 µm, respectively (Figure 5b,d). After two FSP passes, the total grain refinement was 17 and 2.5 times, respectively, compared to the base alloys. The incremental refinement process for Al 5052/TiB was approximately 25 times; the first step in casting was 11-fold, and the second step after two FSP passes was 2.5-fold; therefore, the incremental refinement process for this alloy was approximately 25-fold.  Figure 5 shows the micrographs and grain size abundance of the standard Al 5052 alloy and the modified alloy with 0.99%Ti + 0.2%B after the second pass of the friction stir process in the SZ. In general, the second pass of FSP resulted in greater refinement of the grains (Figure 5a,c). The average grains of the Al 5052 alloy and the modified Al 5052/TiB alloy were reduced to 12 ± 2 and 8 ± 2 µm, respectively. The grains of both alloys were normally distributed around the mean after the second pass, with SD of 2.5 and 1.7 µm, respectively (Figure 5b,d). After two FSP passes, the total grain refinement was 17 and 2.5 times, respectively, compared to the base alloys. The incremental refinement process for Al 5052/TiB was approximately 25 times; the first step in casting was 11-fold, and the second step after two FSP passes was 2.5-fold; therefore, the incremental refinement process for this alloy was approximately 25-fold.

Hardness Behavior
Hardness is often used as a reference for other mechanical characteristics. Vickers hardness values for the standard alloy Al 5052 and the modified alloy with 0.99%Ti + 0.2%B in the as-cast condition and FSP after the first-and second-pass friction stir processing are shown in Figure 6. It can be observed that the modification of the Al 5052 alloy with Ti-B increased the hardness after casting. The increased hardness resulted from grain refinement and the formation of Al3Ti and TiB2. In general, the FSP showed a positive effect on the SZ hardness for the studied alloys. For Al 5052, the hardness increased from 56 ± 2 HV to 65 ± 2 HV after the first pass. After the second pass, further improvements in

Hardness Behavior
Hardness is often used as a reference for other mechanical characteristics. Vickers hardness values for the standard alloy Al 5052 and the modified alloy with 0.99%Ti + 0.2%B in the as-cast condition and FSP after the first-and second-pass friction stir processing are shown in Figure 6. It can be observed that the modification of the Al 5052 alloy with Ti-B increased the hardness after casting. The increased hardness resulted from grain refinement and the formation of Al 3 Ti and TiB 2 . In general, the FSP showed a positive effect on the SZ hardness for the studied alloys. For Al 5052, the hardness increased from 56 ± 2 HV to 65 ± 2 HV after the first pass. After the second pass, further improvements in hardness were recorded. Al 5052/TiB was also characterized in the same way.  (Figure 7b), the Al peaks appeared in addition to a small and weak TiB 2 peak, while, for Al 5052, after one pass of FSP, the same peaks appeared in addition to the weak Al 3 Ti peak; moreover, for double-pass FSP, the TiB 2 and Al 3 Ti peaks appeared clearly. After the addition of Ti-B, the Al 3 Ti phase was formed as a result of the reaction of the Al base with the Ti additive during the casting process and increased during the FSP process. The formation of these phases is important in influencing various properties, such as the mechanical properties, coefficient of thermal expansion, and corrosion behavior, which will be discussed in the following sections. Figure 8 shows the effects of Ti-B particles on the bulk density of the Al 5052 alloy before and after FSP. As can be seen, the density of the Al alloy increased not only due to the addition of the Ti-B content but also due to the increase in the passes of the FSP. Adding Ti-B leads to the refinement of the grains without forming any cavitation, resulting in higher bulk density compared to the Al 5052 alloy. The increase in the bulk density after the first-and second-pass friction stir processing can be better explained by the absence of voids and stir casting defects. On the one hand, FSP is responsible for a significant increase in the temperature at the surface contacts between the particles, which is associated with the formation of closed pores and grain growth. On the other hand, the bulk density of TiB 2 = 4.53 g/cm 3 is almost twice that of the Al alloy = 2.68 g/cm 3 . The sequential single-and double-pass FSP, resulting in a pore-free structure, led to an increase in the bulk density, in addition to forming high-bulk-density precipitates.

Hardness Behavior
Hardness is often used as a reference for other mechanical characteristics. Vickers hardness values for the standard alloy Al 5052 and the modified alloy with 0.99%Ti + 0.2%B in the as-cast condition and FSP after the first-and second-pass friction stir processing are shown in Figure 6. It can be observed that the modification of the Al 5052 alloy with Ti-B increased the hardness after casting. The increased hardness resulted from grain refinement and the formation of Al3Ti and TiB2. In general, the FSP showed a positive effect on the SZ hardness for the studied alloys. For Al 5052, the hardness increased from 56 ± 2 HV to 65 ± 2 HV after the first pass. After the second pass, further improvements in hardness were recorded. Al 5052/TiB was also characterized in the same way.  peared in addition to the weak Al3Ti peak; moreover, for double-pass FSP, the TiB2 and Al3Ti peaks appeared clearly. After the addition of Ti-B, the Al3Ti phase was formed as a result of the reaction of the Al base with the Ti additive during the casting process and increased during the FSP process. The formation of these phases is important in influencing various properties, such as the mechanical properties, coefficient of thermal expansion, and corrosion behavior, which will be discussed in the following sections.  Figure 8 shows the effects of Ti-B particles on the bulk density of the Al 5052 alloy before and after FSP. As can be seen, the density of the Al alloy increased not only due to the addition of the Ti-B content but also due to the increase in the passes of the FSP. Adding Ti-B leads to the refinement of the grains without forming any cavitation, resulting in higher bulk density compared to the Al 5052 alloy. The increase in the bulk density after the firstand second-pass friction stir processing can be better explained by the absence of voids and stir casting defects. On the one hand, FSP is responsible for a significant increase in the temperature at the surface contacts between the particles, which is associated with the formation of closed pores and grain growth. On the other hand, the bulk density of TiB2 = 4.53 g/cm 3 is almost twice that of the Al alloy = 2.68 g/cm 3 . The sequential singleand double-pass FSP, resulting in a pore-free structure, led to an increase in the bulk density, in addition to forming high-bulk-density precipitates.

Thermal Expansion
The relative thermal expansion (∆L/L) of the Al 5052 and Al 5052/TiB alloys before and after a single and double pass of FSP, measured at temperatures between 25 and 500 °C, is shown in Figure 9. As expected, the results illustrate that the relative thermal expansion of Al 5052 and Al 5052/TiB alloys increased with increasing temperature, consid-

Thermal Expansion
The relative thermal expansion (∆L/L) of the Al 5052 and Al 5052/TiB alloys before and after a single and double pass of FSP, measured at temperatures between 25 and 500 • C, is shown in Figure 9. As expected, the results illustrate that the relative thermal expansion of Al 5052 and Al 5052/TiB alloys increased with increasing temperature, considering that their values were not strongly affected by the single and double passes of FSP compared to the samples before FSP treatment. It can be observed that the addition of Ti-B had a significant effect on the relative thermal expansion since it caused a decrease in the ∆L/L value, which was more pronounced with increasing temperature. This can contribute to the grain refinement after casting and highly thermally stable elements, Ti and B, compared with the other elements. For alloy Al 5052, measured at 200 • C, the ∆L/L value was 4.75 × 10 −3 . After single and double passes, the ∆L/L values increased to 4.12 × 10 −3 and 3.91 × 10 −3 , respectively. If the temperature was increased to 500 • C for the same sample, the ∆L/L value was 11.22 × 10 −3 , and after single and double passes, it was 10.36 × 10 −3 and 9.64 × 10 −3 , respectively. For the Al 5052/TiB sample measured at 200 • C, the ∆L/L value was 3.77 × 10 −3 , and after one and two passes, it was 3.49 × 10 −3 and 3.23 × 10 −3 , respectively. On the other hand, if the measurement temperature for the same sample was increased to 500 • C, the ∆L/L value changed to 8.91 × 10 −3 , and after one and two passes, it was 8.53 × 10 −3 and 7.83 × 10 −3 , respectively. the CTE values showed the same trend of thermal expansion as the CTE value of the base alloy, which slightly decreased after FSP due to the formation of the Mg2Si and Al3Fe phases, which are characterized by a lower CTE compared to the Al 5052 alloy. On the other hand, for the Al 5052/TiB sample, the significant decrease in the CTE value occurred due to the formation of the highly thermally stable phase TiB2 (CTE ≈ 7.1 × 10 −6 /°C) [38]. Moreover, residual stresses caused by thermal mismatch between the Al 5052 alloy and TiB2 phase play an important role in determining the thermal expansion behavior of alloys [39]. Thus, the thermal stability in the dimensions of aluminum alloys can be increased by adding Ti-B elements and using FSP. The Ti-B elements have low thermal expansion, and the FSP forms highly stable phases.  The measured coefficient of thermal expansion (CTE) values for the same samples are shown in Figure 10. The CTE value showed the same trend for ∆L/L, where there was a slight decrease after FSP for the base alloy, while it decreased significantly with the addition of Ti-B (Al 5052/TiB samples). The CTE value for Al 5052 and Al 5052/TiB was 21.6 and 17.2, respectively. After one pass, the values were 20.8 and 16.8, respectively. However, after two passes, the values were 19.1 and 15.3, respectively. The results indicate that the CTE values showed the same trend of thermal expansion as the CTE value of the base alloy, which slightly decreased after FSP due to the formation of the Mg 2 Si and Al 3 Fe phases, which are characterized by a lower CTE compared to the Al 5052 alloy.
On the other hand, for the Al 5052/TiB sample, the significant decrease in the CTE value occurred due to the formation of the highly thermally stable phase TiB 2 (CTE ≈ 7.1 × 10 −6 / • C) [38]. Moreover, residual stresses caused by thermal mismatch between the Al 5052 alloy and TiB 2 phase play an important role in determining the thermal expansion behavior of alloys [39]. Thus, the thermal stability in the dimensions of aluminum alloys can be increased by adding Ti-B elements and using FSP. The Ti-B elements have low thermal expansion, and the FSP forms highly stable phases.   Figure 11a,b show the stress-strain curves of the Al 5052 and Al 5052/TiB alloys for one and two passes of FSP. Moreover, based on the compressive yield curves in Figure 12, the main compressive properties such as yield strength (YS), ultimate strength (US), and elongation (E), were determined for the prepared specimens at different FSP passes (see Figure 12a-c). This figure shows that the alloy Al 5052 exhibited values of 86.8 MPa, 191.5 MPa, and 23.7% for YS, US, and E, respectively. After the FSP process, both YS and US were improved and increased to 92.8 and 205.2 MPa, respectively, after one pass, while E decreased by 22%. After two passes, the results show a further significant improvement in the strength, with values of 101.7 and 232, respectively. Surprisingly, these passes led to a 21.3% decrease in strain. In fact, the TiB 2 phase was very hard in the Al 5052/TiB alloy and greatly impacted the compressive properties, except for the strain. The ultimate strength of the Al 5052/TiB alloy, after the first pass and the second pass, amounted to 211.6, 238.6, and 267.6 MPa, respectively, which are equal to 10.5, 16.3, and 15.3% increases compared to the Al 5052 alloy, while the elongation for the same specimens amounted to 20.8, 19.4, and 16.8%, respectively.  Figure 11a,b show the stress-strain curves of the Al 5052 and Al 5052/TiB alloys for one and two passes of FSP. Moreover, based on the compressive yield curves in Figure 12, the main compressive properties such as yield strength (YS), ultimate strength (US), and elongation (E), were determined for the prepared specimens at different FSP passes (see Figure 12a-c). This figure shows that the alloy Al 5052 exhibited values of 86.8 MPa, 191.5 MPa, and 23.7% for YS, US, and E, respectively. After the FSP process, both YS and US were improved and increased to 92.8 and 205.2 MPa, respectively, after one pass, while E decreased by 22%. After two passes, the results show a further significant improvement in the strength, with values of 101.7 and 232, respectively. Surprisingly, these passes led to a 21.3% decrease in strain. In fact, the TiB2 phase was very hard in the Al 5052/TiB alloy and greatly impacted the compressive properties, except for the strain. The ultimate strength of the Al 5052/TiB alloy, after the first pass and the second pass, amounted to 211.6, 238.6, and 267.6 MPa, respectively, which are equal to 10.5, 16.3, and 15.3% increases compared to the Al 5052 alloy, while the elongation for the same specimens amounted to 20.8, 19.4, and 16.8%, respectively.     Figure 13e) for Al 5052. It can be seen that the values of the elastic modulus experienced the same trend as the yield strength and ultimate strength when both Ti-B and FSP were added. For example, the longitudinal modulus of the Al 5052 alloy was 95.5 GPa, and after FSP was added twice, the value was 117, which is equal to a 22% increase. With the addition of Ti-B, the value of the elastic modulus increased to 75 GPa, which corresponds to an increase of approximately 16% compared to the Al alloy. After FSP, the value was 88 GPa, which corresponds to an increase of approximately 35.7% compared to the Al alloy after FSP.

Corrosion Behavior
The weight loss approach was considered better than other approaches to evaluate metal corrosion in an immersion test. Figures 14 and 15 show the weight loss variation and corrosion rate of Al 5052 and Al 5052/TiB before and after FSP with an exposure time of 3.5 wt.% NaCl solution at room temperature. In this context, the weight loss The apparent improvement in the mechanical properties of the Al 5052 alloy was represented by the US, YS, and elastic moduli after the FSP process. Interestingly, this improvement can be attributed to grain fragmentation, work hardening, and precipitates' partial formation. Thus, with the increase in grain boundaries and recrystallized grains in the SZ of Al 5052 and Al 5052/TiB, the maximum mechanical properties were observed in one and two passes, respectively [40,41]. On the other hand, the addition of reinforcing agents from the ceramic phase (TiB) within Al 5052 by the FSP process improved the final US and YS according to the strengthening mechanisms. Nevertheless, a decrease followed it in L, which is consistent with much of the literature dealing with the improvement of the mechanical properties of Al alloys by the addition of different ceramics [4,5,42]. Moreover, the homogeneous distribution of TiB 2 particles in the Al alloy may obstruct the dislocation motion. As a result, dislocation loops are formed around the TiB 2 particles, which increase the stress required for further deformation (Orowan strengthening mechanism) [43].

Corrosion Behavior
The weight loss approach was considered better than other approaches to evaluate metal corrosion in an immersion test. Figures 14 and 15 show the weight loss variation and corrosion rate of Al 5052 and Al 5052/TiB before and after FSP with an exposure time of 3.5 wt.% NaCl solution at room temperature. In this context, the weight loss measurements were studied at intervals of 1, 2, 3, 4, 5, 6, and 7 days. The weight loss of the Al 5052 sample immersed for 1, 4, and 7 days was 0.317, 0.450, and 0.515 mg, respectively; after the single pass at the same immersion times, values were 0.281, 0.411, and 0.479 mg, respectively, and after the double pass, they were 0.256, 0.372 and 0.441 mg, respectively. On the other hand, for the Al 5052/TiB sample, the weight loss for the same immersion time was 0.244, 0.357, and 0.384 mg, respectively; after the single pass, values were 0.28115, 0.314, and 0.370 mg, respectively, and after the double pass, they were 0.194, 0.292 and 0.355 mg, respectively. Figure 14 shows the change in the corrosion rate of Al 5052 and Al 5052/TiB before and after FSP at the above exposure times. It can be seen that the corrosion rate of Al 5052 alloy after one day of immersion was 0.317 mmpy (Figure 15a). In the case of single and double immersion, the corresponding corrosion rates were 0.281 and 0.256 mmpy, respectively. This shows that the corrosion rate was reduced by 11.4 times in the case of a single pass and 19.2 times in the case of a double pass compared to the corrosion rate of the starting alloy. Al 5052/TiB was found to have a corrosion rate of 0.244 mmpy (Figure 15b), an increase of~123% over Al 5052. After single and double passes, the corrosion rate was 0.215 and 0.194 mmpy, respectively, which corresponds to a reduction of~32.2% for a single pass and 38.8% for double passes compared to the corrosion rate of the Al 5052 alloy. Since the corrosion process generally takes place on the surfaces of samples, it is interesting to note that the weight loss increased at the beginning of the test. As a result of passivation, it tended to remain stable at the end of the test.
Consequently, an increase in the exposure time led to a decrease in the corrosion rate. Obviously, after a single pass, the possibility of corrosion decreases because significant grain boundaries have formed during FSP due to grain refinement. However, the passive surface film consists of high-density grain boundaries in refined grain regions, resulting in a lower corrosion rate [44]. Moreover, the formation of the perceptual phase (Mg 2 Si and Al 3 Fe) during FSP is expected to contribute to the decrease in the CTE values, thus improving the thermal stability of the samples. There were significant improvements in the CTE value after adding Ti-B reinforcement to the Al 5052 alloy due to the formation of the TiB 2 ceramic phase, where the ceramic particles remained intact, i.e., with no discernible corrosion behavior, and the samples protect the surface layer in an acidic medium [39,45].
Al3Fe) during FSP is expected to contribute to the decrease in the CTE values, thus improving the thermal stability of the samples. There were significant improvements in the CTE value after adding Ti-B reinforcement to the Al 5052 alloy due to the formation of the TiB2 ceramic phase, where the ceramic particles remained intact, i.e., with no discernible corrosion behavior, and the samples protect the surface layer in an acidic medium [39,45].

Electrical Conductivity
The electrical conductivity of the samples before and after FSP is shown in Figure 16. The results show that the electrical conductivity of the Al 5052 alloy in the as-cast state was 1.82 × 10 7 S/m and slightly decreased after FSP, reaching 1.51 × 10 7 and 1.35 × 10 7 S/m for the single-and double-pass FSP, respectively. This decrease in conductivity value could be related to the increase in the number of grain boundaries caused by the finegrained Al alloy due to FSP, which hinders the electron flow and thus decreases the conductivity. Another possible reason is the formation of precipitate phases, i.e., Mg2Si and Al3Fe (as seen in the X-ray image), which reduce the conductivity due to the lack of electrical conductivity of the Al alloy. On the other hand, the conductivity of the Al 5052/TiB sample decreased by 20% to 1.01 × 10 7 S/m compared to the Al alloy. After one and two passes, the conductivity decreased by 20 and 30% to 8.10 × 10 6 and 7.08 × 10 6 S/m, respectively, compared to the Al alloy after FSP. This decrease in conductivity due to the presence of ceramic TiB2 leads to an increase in the number of electron-scattering interfaces between the Al alloy and TiB2 phase. Moreover, the presence of this phase increases the number of pores that act as barriers to electron flow, thus decreasing the electrical conductivity.

Electrical Conductivity
The electrical conductivity of the samples before and after FSP is shown in Figure 16. The results show that the electrical conductivity of the Al 5052 alloy in the as-cast state was 1.82 × 10 7 S/m and slightly decreased after FSP, reaching 1.51 × 10 7 and 1.35 × 10 7 S/m for the single-and double-pass FSP, respectively. This decrease in conductivity value could be related to the increase in the number of grain boundaries caused by the fine-grained Al alloy due to FSP, which hinders the electron flow and thus decreases the conductivity. Another possible reason is the formation of precipitate phases, i.e., Mg 2 Si and Al 3 Fe (as seen in the X-ray image), which reduce the conductivity due to the lack of electrical conductivity of the Al alloy. On the other hand, the conductivity of the Al 5052/TiB sample decreased by 20% to 1.01 × 10 7 S/m compared to the Al alloy. After one and two passes, the conductivity decreased by 20 and 30% to 8.10 × 10 6 and 7.08 × 10 6 S/m, respectively, compared to the Al alloy after FSP. This decrease in conductivity due to the presence of ceramic TiB 2 leads to an increase in the number of electron-scattering interfaces between the Al alloy and TiB 2 phase. Moreover, the presence of this phase increases the number of pores that act as barriers to electron flow, thus decreasing the electrical conductivity.

Conclusions
In the current work, the Al 5052 alloy was modified using two successive methods: Ti-B modification and surface refinement using the FSP technique. The study showed that the surface is finer and has better mechanical and physical properties. In addition, the resulting surface was studied using the sequential method after each of the above refinement methods.
Al 5052 alloy contains large grains, with a coarse dendritic structure and an average grain size of 200 ± 15 µm. The addition of Ti-B to the Al 5052 alloy resulted in creating Al3Ti and TiB, which serve as nucleation nuclei during solidification. After the first FSP pass, the grains in Al 5052 were homogeneous and equiaxed, and the dendritic structure had vanished in the stirred zone (SZ). After the second FSP pass, the overall grain refinement was 17 and 2.5 times that of the basic alloys.
After stir casting, the addition of Ti-B to the Al 5052 alloy enhanced the hardness. The rise in hardness was caused by grain refinement and the production of Al3Ti and Ti-B. In general, the FSP enhanced the SZ hardness of the alloys examined.
The FSP enhanced the mechanical characteristics of the Al alloys following grain refinement by raising the US, YS, and Young's moduli. When Al 5052/TiB was exposed to double FPS passes, the mechanical characteristics were improved.
The successive first and second FSP passes, leading to a non-porous structure, caused an increase in bulk density and the formation of high-bulk-density precipitates. In addition, the inclusion of Ti-B constituents and the use of FSP can improve the thermal stability in aluminum alloy dimensions. Ti-B elements have low thermal expansion and FSP leads to the formation of very stable phases.
The electrical conductivity of the Al 5052 alloy was 1.82 × 10 7 S/m, which was reduced somewhat after FSP. The increase in the number of grain boundaries induced by the finegrained Al alloy might account for the drop in conductivity. Another factor might be the production of precipitate phases, such as Mg2Si and Al3Fe, which reduce conductivity.
With one pass, corrosion was decreased by 11.4 times, and with two passes, the corrosion rate was reduced by a factor of almost 20.

Conclusions
In the current work, the Al 5052 alloy was modified using two successive methods: Ti-B modification and surface refinement using the FSP technique. The study showed that the surface is finer and has better mechanical and physical properties. In addition, the resulting surface was studied using the sequential method after each of the above refinement methods.
Al 5052 alloy contains large grains, with a coarse dendritic structure and an average grain size of 200 ± 15 µm. The addition of Ti-B to the Al 5052 alloy resulted in creating Al 3 Ti and TiB, which serve as nucleation nuclei during solidification. After the first FSP pass, the grains in Al 5052 were homogeneous and equiaxed, and the dendritic structure had vanished in the stirred zone (SZ). After the second FSP pass, the overall grain refinement was 17 and 2.5 times that of the basic alloys.
After stir casting, the addition of Ti-B to the Al 5052 alloy enhanced the hardness. The rise in hardness was caused by grain refinement and the production of Al 3 Ti and Ti-B. In general, the FSP enhanced the SZ hardness of the alloys examined.
The FSP enhanced the mechanical characteristics of the Al alloys following grain refinement by raising the US, YS, and Young's moduli. When Al 5052/TiB was exposed to double FPS passes, the mechanical characteristics were improved.
The successive first and second FSP passes, leading to a non-porous structure, caused an increase in bulk density and the formation of high-bulk-density precipitates. In addition, the inclusion of Ti-B constituents and the use of FSP can improve the thermal stability in aluminum alloy dimensions. Ti-B elements have low thermal expansion and FSP leads to the formation of very stable phases.
The electrical conductivity of the Al 5052 alloy was 1.82 × 10 7 S/m, which was reduced somewhat after FSP. The increase in the number of grain boundaries induced by the finegrained Al alloy might account for the drop in conductivity. Another factor might be the production of precipitate phases, such as Mg 2 Si and Al3Fe, which reduce conductivity.
With one pass, corrosion was decreased by 11.4 times, and with two passes, the corrosion rate was reduced by a factor of almost 20.

Data Availability Statement:
The data presented in this study are available on request from the corresponding author.