Effect of Magnetic Stirring on Microstructures and Properties of Ag–1.5Cu–1.0Y Alloy

The microstructure of alloys is an important factor that affects their application. In this work, the Ag–1.5Cu–1.0Y alloys were prepared by the permanent magnet stirring method at different rates. The secondary dendrite arm spacing, dendritic segregation, density, microhardness, electrical resistivity, and sulfuration corrosion resistance were analyzed to investigate the effects of different rotation speeds on the microstructures and properties of the Ag–1.5Cu–1.0Y alloy. The results showed that the primary dendrite was refined and the secondary dendrite arm spacing decreased with the increase in the stirring rate of the permanent magnets. The Ag–1.5Cu–1.0Y alloys prepared with a 900 r/min stirring rate had the largest microhardness, relatively high density, and the best sulfuration corrosion resistance. However, the stirring rate had little effect on the electrical resistivity of the Ag–1.5Cu–1.0Y alloys. To sum up, the Ag–1.5Cu–1.0Y alloy had the best comprehensive properties when the permanent magnet stirring rate was 900 r/min, including the most refined dendrites, relatively high density, the largest microhardness, and the best sulfuration corrosion resistance. The study of the effects of permanent magnet stirring speed on the microstructures and properties of the Ag–1.5Cu–1.0Y alloy provides an experimental basis for future alloy casting optimization and property improvement of silver-based alloys.


Introduction
Silver (Ag) has been widely used in jewelry materials since ancient times and up until modern society, due to its high reflectivity and attractive bright white color [1]. More notably, Ag has the highest reflectance in the visible region, thermal conductivities, and the lowest resistivity among all metals [2,3]. Therefore, it is widely used in the field of target materials. The target materials were coated on the substrate by magnetron sputtering technology, used for the production of liquid crystal displays, optical recording media, low-radiation glass electrode films or reflective layers, etc. [4,5]. For instance, Ag-Yb and Ag-Mg alloys can be fabricated into plasmonic nanostructures and transparent organic light-emitting diodes [6]. A silver-antimony-boron alloy was applied to electrical contacts and it showed high wear resistance, sulfuration corrosion resistance, and microhardness [7]. Silver-tungsten refractory materials are mainly used in industrial and domestic circuitbreaker products, due to their good weld and erosion-resistant properties [8]. Furthermore, with the rapid development of modern electronic science and technology and the increase in target materials' market demand, the quality requirements of alloy target materials are getting higher and higher.
Ag-based alloys are the source material for magnetron sputtering. Pure Ag has the disadvantages of poor hardness, easy oxidation, and sulfuration. Copper (Cu) could increase the hardness [9,10], tensile strength [10], and oxidation resistance [11] of the alloy matrix. The addition of rare earth elements can significantly improve the mechanical These alloys were prepared by a self-designed open high-frequency induction furnace equipped with an argon (99.99%) atmosphere protection device at 0.1 MP and with permanent magnet stirring. Compared with traditional magnetic stirring, the casting equipment is a high-frequency induction furnace with not only permanent magnetic stirring, but also atmosphere protection, hot top protection, and directional forced condensation (Figure 1a). A graphite crucible was used for the preparation container of the alloys. The permanent magnet was a pair of NdFeB ( Figure 1b) with a magnetic field intensity of 2000 GS, and the stirring rate was 0, 300, 600, 900, and 1200 r/min, respectively. Table 1. Chemistry composition (weight percentage, wt%) of the Ag-1.5Cu-1.0Y alloys.

Element
Ag Cu Y wt% 97.5 1. 5 1 These alloys were prepared by a self-designed open high-frequency induction furnace equipped with an argon (99.99%) atmosphere protection device at 0.1 MP and with permanent magnet stirring. Compared with traditional magnetic stirring, the casting equipment is a high-frequency induction furnace with not only permanent magnetic stirring, but also atmosphere protection, hot top protection, and directional forced condensation (Figure 1a). A graphite crucible was used for the preparation container of the alloys. The permanent magnet was a pair of NdFeB ( Figure 1b) with a magnetic field intensity of 2000 GS, and the stirring rate was 0, 300, 600, 900, and 1200 r/min, respectively. Before melting, the graphite crucible was placed in the melting zone of equipment with the alloying elements loaded. Then, high purity argon was injected into the system for 10 min to ensure that the system was protected by inert gas. Subsequently, the highfrequency electromagnetic induction furnace was opened, and the temperature was slowly raised to 1773 K (1500 °C). The loaded alloy elements were alloyed in a crucible for 10 min when the temperature was stable. Then, the crucible was sent to the casting area and the permanent magnet stirring equipment started with different permanent magnet stirring rates. Each alloy was taken out of the electromagnetic induction furnace after complete cooling and the inert gas environment was maintained throughout the period, so as to prevent the alloy from gas absorption and oxidation during melting and solidification. Finally, the samples were cut, polished, and corroded, and the microstructures and properties of the samples were tested and analyzed using a metallographic microscope, scanning electron microscope (SEM), X-ray electron probe microanalyzer, hardness tester, micro-ohmmeter, and electrochemical workstation.

Microstructures
For microstructure observation, the alloy samples were wet ground with silicon carbide abrasive papers from P800 to P5000, followed by polishing with a solid-to-liquid ratio of 1:4 MgO suspension solution. Then, the polished alloys were corroded in the metallographic corrosive solution (30% H2O2: 25% NH3·H2O = 1:3) for 50-60 s to analyze the con- Before melting, the graphite crucible was placed in the melting zone of equipment with the alloying elements loaded. Then, high purity argon was injected into the system for 10 min to ensure that the system was protected by inert gas. Subsequently, the highfrequency electromagnetic induction furnace was opened, and the temperature was slowly raised to 1773 K (1500 • C). The loaded alloy elements were alloyed in a crucible for 10 min when the temperature was stable. Then, the crucible was sent to the casting area and the permanent magnet stirring equipment started with different permanent magnet stirring rates. Each alloy was taken out of the electromagnetic induction furnace after complete cooling and the inert gas environment was maintained throughout the period, so as to prevent the alloy from gas absorption and oxidation during melting and solidification. Finally, the samples were cut, polished, and corroded, and the microstructures and properties of the samples were tested and analyzed using a metallographic microscope, scanning electron microscope (SEM), X-ray electron probe microanalyzer, hardness tester, micro-ohmmeter, and electrochemical workstation.

Microstructures
For microstructure observation, the alloy samples were wet ground with silicon carbide abrasive papers from P800 to P5000, followed by polishing with a solid-to-liquid ratio of 1:4 MgO suspension solution. Then, the polished alloys were corroded in the metallographic corrosive solution (30% H 2 O 2 : 25% NH 3 ·H 2 O = 1:3) for 50-60 s to analyze the constituents of the alloys. Microstructure observation was conducted with a Leica optical microscope (Leica, Wetzlar, Germany). In order to illustrate the refining effect of different stirring rates on the dendrite structure of the alloys, the average value of the secondary dendrite arm spacing was generated from the 10 times measurement. Figure 2 shows the schematic diagram of secondary dendrite arm spacing (λ 2 ). λ 2 can be expressed by the average distance of multiple secondary dendrite arm spacing (L), as follows [28]: where λ 2 is the secondary dendrite arm spacing; L is the center-to-center distance of secondary ramifications, and n is the adopted number of ramifications.
stituents of the alloys. Microstructure observation was conducted with a Leica op croscope (Leica, Wetzlar, Germany). In order to illustrate the refining effect of d stirring rates on the dendrite structure of the alloys, the average value of the se dendrite arm spacing was generated from the 10 times measurement. Figure 2 sh schematic diagram of secondary dendrite arm spacing (λ2). λ2 can be expressed average distance of multiple secondary dendrite arm spacing (L), as follows [28]: where λ2 is the secondary dendrite arm spacing; L is the center-to-center distanc ondary ramifications, and n is the adopted number of ramifications.

X-ray Diffraction (XRD) Phase Constituent Analysis
An X′Pert Pro X-ray diffractometer (Panaco, Eindhoven, The Netherlands) w to investigate the phase constituents of the Ag-1.5Cu-1.0Y alloys at different speeds. The test temperature was room temperature. The voltage was 40 kV. A C was used. The scanning mode was continuous scanning, and the scanning angle ( 30-120°, the scanning step size was 0.02°, and the scanning time of each step was

SEM-EDS Analysis
The surface morphology observation, semi-quantitative analysis of the c composition, and element distribution of the alloy samples were conducted usin 8530F field emission electron probe ((JEOL, Tokyo, Japan)) under electron acceler 15 keV.

Density Test
The density of the alloy samples was tested using the Archimedes drainage Firstly, the weight W1 of the dry sample in the air was weighed on the precision and then the weight W2 of the sample in distilled water was weighed. The form calculating the density of the sample is as follows: where W1 is the mass of a dry sample in air, W2 is the mass of a sample in distille and ρ is the density of distilled water.

Microhardness Test
Microhardness tests were performed on an HXS-1000AK microhardnes (Jingda, Xi'an, China) with a load of 25 g and a holding time of 10 s at room temp In order to reduce the test error, five points were selected from the edge to the c

X-ray Diffraction (XRD) Phase Constituent Analysis
An X Pert Pro X-ray diffractometer (Panaco, Eindhoven, The Netherlands) was used to investigate the phase constituents of the Ag-1.5Cu-1.0Y alloys at different rotation speeds. The test temperature was room temperature. The voltage was 40 kV. A Cu target was used. The scanning mode was continuous scanning, and the scanning angle (2θ) was 30-120 • , the scanning step size was 0.02 • , and the scanning time of each step was 5 s.

SEM-EDS Analysis
The surface morphology observation, semi-quantitative analysis of the chemical composition, and element distribution of the alloy samples were conducted using a JXA-8530F field emission electron probe ((JEOL, Tokyo, Japan)) under electron acceleration of 15 keV.

Density Test
The density of the alloy samples was tested using the Archimedes drainage method. Firstly, the weight W 1 of the dry sample in the air was weighed on the precision balance, and then the weight W 2 of the sample in distilled water was weighed. The formula for calculating the density of the sample is as follows: where W 1 is the mass of a dry sample in air, W 2 is the mass of a sample in distilled water, and ρ is the density of distilled water.

Microhardness Test
Microhardness tests were performed on an HXS-1000AK microhardness tester (Jingda, Xi'an, China) with a load of 25 g and a holding time of 10 s at room temperature. In order to reduce the test error, five points were selected from the edge to the center of each sample for testing, and the final result was taken as the average value of the test.

Electrical Resistivity Test
Before the electrical resistivity test, the alloy samples were cut into wafers, with a diameter of 9.5 mm and a thickness of 1.5 mm. Electrical resistivity tests were then carried out on a ZY9858 digital micro-ohmmeter (Zhengyang, Shanghai, China) at room temperature.

Sulfuration Corrosion Resistance Test
Sulfuration corrosion resistance tests were conducted in a closed container with H 2 S and the changes were observed at 0.5, 1, 2, 4, 6, and 8 h.
The polarization test was carried out in sodium sulfide solution at the CHI600E electrochemical workstation (Chenhua, Shanghai, China). The concentration of sodium sulfide solution was 0.1mol·L −1 . A mercury-mercuric oxide electrode (standard electrode potential on a hydrogen scale was 0.098 V) and a platinum electrode were used as the reference electrode and the counter electrode, respectively. The as-cast samples were used as the working electrode. Prior to the testing, the surface of the alloy sample was ground with P5000 silicon carbide abrasive paper and then rinsed with distilled water. The polarization tests were conducted using polarization potential from −0.9 V to −0.6 V at a scan rate of 5 mV·s −1 .

Microstructures
The dendrites in the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring (at 0 r/min) were thicker, the primary dendrites were well developed, and the secondary dendrite arm spacing was large ( Figure 3a). The dendrites of the Ag-1.5Cu-1.0Y alloy were refined gradually with the increase in stirring rate (Figure 3b-e), and the dendrites were best refined in the Ag-1.5Cu-1.0Y alloy with a 900 r/min stirring rate ( Figure 3d). However, compared with the alloy at 900 r/min, larger dendrites and secondary dendrite arm spacing (λ 2 ) were found in the Ag-1.5Cu-1.0Y alloy with a 1200 r/min stirring rate ( Figure 3e). The λ 2 decreased with the increase in stirring rate (Figure 3f), and it reached the minimum value of 25.12 µm in the Ag-1.5Cu-1.0Y alloy with a 900 r/min stirring rate, then it increased in the Ag-1.5Cu-1.0Y alloy with a 1200 r/min stirring rate ( Figure 3f). This was in correspondence with the results of the coarsened dendrite in the Ag-1.5Cu-1.0Y alloy at 1200 r/min of permanent magnet stirring rate, compared with the alloys at 900 r/min.
Before the electrical resistivity test, the alloy samples were cut into wafers, with a diameter of 9.5 mm and a thickness of 1.5 mm. Electrical resistivity tests were then carried out on a ZY9858 digital micro-ohmmeter (Zhengyang, Shanghai, China) at room temperature.

Sulfuration Corrosion Resistance Test
Sulfuration corrosion resistance tests were conducted in a closed container with H2S and the changes were observed at 0.5, 1, 2, 4, 6, and 8 h.
The polarization test was carried out in sodium sulfide solution at the CHI600E electrochemical workstation (Chenhua, Shanghai, China). The concentration of sodium sulfide solution was 0.1mol·L −1 . A mercury-mercuric oxide electrode (standard electrode potential on a hydrogen scale was 0.098 V) and a platinum electrode were used as the reference electrode and the counter electrode, respectively. The as-cast samples were used as the working electrode. Prior to the testing, the surface of the alloy sample was ground with P5000 silicon carbide abrasive paper and then rinsed with distilled water. The polarization tests were conducted using polarization potential from −0.9 V to −0.6 V at a scan rate of 5 mV·s −1 .

Microstructures
The dendrites in the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring (at 0 r/min) were thicker, the primary dendrites were well developed, and the secondary dendrite arm spacing was large (Figure 3a). The dendrites of the Ag-1.5Cu-1.0Y alloy were refined gradually with the increase in stirring rate (Figure 3b-e), and the dendrites were best refined in the Ag-1.5Cu-1.0Y alloy with a 900 r/min stirring rate (Figure 3d). However, compared with the alloy at 900 r/min, larger dendrites and secondary dendrite arm spacing (λ2) were found in the Ag-1.5Cu-1.0Y alloy with a 1200 r/min stirring rate ( Figure  3e). The λ2 decreased with the increase in stirring rate (Figure 3f), and it reached the minimum value of 25.12 μm in the Ag-1.5Cu-1.0Y alloy with a 900 r/min stirring rate, then it increased in the Ag-1.5Cu-1.0Y alloy with a 1200 r/min stirring rate (Figure 3f). This was in correspondence with the results of the coarsened dendrite in the Ag-1.5Cu-1.0Y alloy at 1200 r/min of permanent magnet stirring rate, compared with the alloys at 900 r/min.   To further explore the phase constituents and analyze the effect of permanent magnet stirring on the dendrite refinement of the Ag-1.5Cu-1.0Y alloys, the XRD patterns of the as-cast samples with different rotation speeds are presented in Figure 4. As shown in Figure 4, the observed phases are all Ag, and no other phase was observed. This may be due to the low addition of Cu (1.5 wt%) and Y (1.0 wt%) to the Ag-based alloy, which means that the new phase is unable to be detected by XRD. The new phase formed by this small addition of element may need to be further observed by electron microscopy or transmission electron microscopy. To further explore the phase constituents and analyze the effect of permanent magnet stirring on the dendrite refinement of the Ag-1.5Cu-1.0Y alloys, the XRD patterns of the as-cast samples with different rotation speeds are presented in Figure 4. As shown in Figure 4, the observed phases are all Ag, and no other phase was observed. This may be due to the low addition of Cu (1.5 wt%) and Y (1.0 wt%) to the Ag-based alloy, which means that the new phase is unable to be detected by XRD. The new phase formed by this small addition of element may need to be further observed by electron microscopy or transmission electron microscopy. Permanent magnet stirring has a series of benefits compared with the traditional casting process. It makes heat and mass transfer more uniform, primary dendrite growth restrained, secondary dendrite arm spacing shortened, dendrite size refined, and the refining effect becomes more obvious with the increase in stirring rate [29,30].
The refined grains could be explained in the following two ways: first, strong convection occurs in the melt stirred by Lorentz force, resulting in the secondary dendrite root breaking and leading to new crystal core formation, which then contributes to the refined grains; second, the dendrite branching often results in some necking due to segregation, whereas the permanent magnet stirring will lead the branching to break off from the necking. In the subsequent solidification process, residual parts larger that are than critical nuclei will form new crystalline nuclei, which increase the number of effective crystalline nuclei [31,32], thus reducing the grain size. However, the weaker permanent magnet stirring speed effect on the grain refinement in alloys with 1200 r/min compared to alloys with 900 r/min could be explained by the fact that the high speed resulted in the sharp decrease in magnetic flux density, which subsequently weakened the refinement effect of permanent magnet stirring.

Element Distribution
As shown in Table 2, a large amount of Cu and Y elements are enriched in the intergranular region of the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring. This is interpreted as the lack of stirring leading to a fast solidification rate, which resulted in the insufficient diffusion of solute elements and then the enrichment of the added alloy elements in the intergranular. With the increase in stirring rate, the distribution of alloying elements is more uniform, and the segregation rate decreases. Moreover, with the increase in rotation speed, the content of element Y in the crystal increases, and the distribution of element Y is more uniform ( Table 2). Especially when the stirring rate is 900 r/min, the Y Permanent magnet stirring has a series of benefits compared with the traditional casting process. It makes heat and mass transfer more uniform, primary dendrite growth restrained, secondary dendrite arm spacing shortened, dendrite size refined, and the refining effect becomes more obvious with the increase in stirring rate [29,30].
The refined grains could be explained in the following two ways: first, strong convection occurs in the melt stirred by Lorentz force, resulting in the secondary dendrite root breaking and leading to new crystal core formation, which then contributes to the refined grains; second, the dendrite branching often results in some necking due to segregation, whereas the permanent magnet stirring will lead the branching to break off from the necking. In the subsequent solidification process, residual parts larger that are than critical nuclei will form new crystalline nuclei, which increase the number of effective crystalline nuclei [31,32], thus reducing the grain size. However, the weaker permanent magnet stirring speed effect on the grain refinement in alloys with 1200 r/min compared to alloys with 900 r/min could be explained by the fact that the high speed resulted in the sharp decrease in magnetic flux density, which subsequently weakened the refinement effect of permanent magnet stirring.

Element Distribution
As shown in Table 2, a large amount of Cu and Y elements are enriched in the intergranular region of the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring. This is interpreted as the lack of stirring leading to a fast solidification rate, which resulted in the insufficient diffusion of solute elements and then the enrichment of the added alloy elements in the intergranular. With the increase in stirring rate, the distribution of alloying elements is more uniform, and the segregation rate decreases. Moreover, with the increase in rotation speed, the content of element Y in the crystal increases, and the distribution of element Y is more uniform ( Table 2). Especially when the stirring rate is 900 r/min, the Y element content in the crystal is the largest, indicating that the diffusion effect of the element is the best when the stirring rate is 900 r/min. However, an amount of Y enrichment was still observed at the grain boundary no matter how the rotation speed changes, which is may due to the low solid solubility (1.0 wt%) of Y in Ag. We then conducted a surface scanning analysis of the Ag-1.5Cu-1.0Y alloy sample with a permanent magnet stirring rate of 900 r/min ( Figure 5). The results showed that there is micro-segregation in the element Cu (Figure 5c), and the element Y mainly segregates between crystals and only a small amount of Y exists within the crystals (Figure 5d). element content in the crystal is the largest, indicating that the diffusion effect of the element is the best when the stirring rate is 900 r/min. However, an amount of Y enrichment was still observed at the grain boundary no matter how the rotation speed changes, which is may due to the low solid solubility (1.0 wt%) of Y in Ag. We then conducted a surface scanning analysis of the Ag-1.5Cu-1.0Y alloy sample with a permanent magnet stirring rate of 900 r/min ( Figure 5). The results showed that there is micro-segregation in the element Cu (Figure 5c), and the element Y mainly segregates between crystals and only a small amount of Y exists within the crystals (Figure 5d).

Density
As shown in Figure 6, the density of the Ag-1.5Cu-1.0Y alloy samples increased gradually with the increase in stirring rate. When the stirring rate is 900 r/min, the density of the Ag-1.5Cu-1.0Y alloy sample reaches a maximum value of 10.32 g/cm 3 , which is close to the theoretical density value of 10.34 g/cm 3 ( Figure 6). However, the density value does not increase anymore when the stirring rate increases higher than 900 r/min ( Figure  6). These results indicated that the density of the Ag-1.5Cu-1.0Y alloy can be improved by the permanent magnet stirring rate. However, the density was not increased with the rotation speed when it arrived at a platform period. This may be explained by the fact that the density is closely related to the compactness of the alloy. Grain refinement improved the strength, altering both the bulk and the surface of alloys [33]. When the rotating speed reaches 900 r/min, the diffusion effect of alloy elements reaches its highest and the dendrite refinement degree is the highest, which leads to the highest density; the diffusion effect and dendrite refinement decrease when the rotating speed reaches 1200 r/min, resulting in the decrease in density of the Ag-1.5Cu-1.0Y alloy.

Density
As shown in Figure 6, the density of the Ag-1.5Cu-1.0Y alloy samples increased gradually with the increase in stirring rate. When the stirring rate is 900 r/min, the density of the Ag-1.5Cu-1.0Y alloy sample reaches a maximum value of 10.32 g/cm 3 , which is close to the theoretical density value of 10.34 g/cm 3 ( Figure 6). However, the density value does not increase anymore when the stirring rate increases higher than 900 r/min ( Figure 6). These results indicated that the density of the Ag-1.5Cu-1.0Y alloy can be improved by the permanent magnet stirring rate. However, the density was not increased with the rotation speed when it arrived at a platform period. This may be explained by the fact that the density is closely related to the compactness of the alloy. Grain refinement improved the strength, altering both the bulk and the surface of alloys [33]. When the rotating speed reaches 900 r/min, the diffusion effect of alloy elements reaches its highest and the dendrite refinement degree is the highest, which leads to the highest density; the diffusion effect and dendrite refinement decrease when the rotating speed reaches 1200 r/min, resulting in the decrease in density of the Ag-1.5Cu-1.0Y alloy.

Microhardness
The microhardness of the alloys increases first and then decreases with the increase in stirring rate (Figure 7a). In detail, the microhardness value of the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring is the smallest (58.41 ± 1.34 HV), and it reaches the maximum value (69.82 ± 1.58 HV) in the alloy with the stirring rate of 900 r/min, then it decreases in the alloy with the stirring rate of 1200 r/min (68.63 ± 1.47 HV) (Figure 7a). The relationship between the microhardness and λ2 could be well fitted to the Hall-Petch type relationship [34], which is expressed by the following formula: where HV0 and k are material constants.
As the results show in Figure 7b, the microhardness has a relatively fine correlation with the λ2 (R 2 = 0.878), indicating that the smaller the secondary dendrite arm spacing, the higher the microhardness of the Ag-1.5Cu-1.0Y alloy. As shown, the microhardness and λ2 of the alloys follow the Hall-Petch type relationship, except for the alloy without PMS, indicating the microhardness increases with the decrease in λ2. The dendrite refinement increased with the permanent magnet stirring rotating speed, and it reached the most refinement at 900 r/min rotating speed. The λ2 decreased with rotating speed, and it reached the minimum value of alloys at 900 r/min, then it increased at 1200 r/min, leading to the trend of microhardness increase in alloys under 900 r/min and a decrease in alloys at 1200 r/min.

Microhardness
The microhardness of the alloys increases first and then decreases with the increase in stirring rate (Figure 7a). In detail, the microhardness value of the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring is the smallest (58.41 ± 1.34 HV), and it reaches the maximum value (69.82 ± 1.58 HV) in the alloy with the stirring rate of 900 r/min, then it decreases in the alloy with the stirring rate of 1200 r/min (68.63 ± 1.47 HV) (Figure 7a). The relationship between the microhardness and λ 2 could be well fitted to the Hall-Petch type relationship [34], which is expressed by the following formula: where HV 0 and k are material constants.

Electrical Resistivity
The electrical resistivity of the Ag-1.5Cu-1.0Y alloys increases with the increase in stirring rate (Figure 8), leading to a decreased electrical conductivity. However, the overall effect of permanent magnet stirring on the electrical resistance of the alloy sample is not very large, with values ranging from 3.05 × 10 −8 to 3.39 × 10 −8 Ω·m. The main reason for the slight increase in electrical resistance may lie in the relationship between electrical resistance and electron transfer. Electrical resistivity is affected by many factors, which can be expressed in the following formula: As the results show in Figure 7b, the microhardness has a relatively fine correlation with the λ 2 (R 2 = 0.878), indicating that the smaller the secondary dendrite arm spacing, the higher the microhardness of the Ag-1.5Cu-1.0Y alloy. As shown, the microhardness and λ 2 of the alloys follow the Hall-Petch type relationship, except for the alloy without PMS, indicating the microhardness increases with the decrease in λ 2 . The dendrite refinement increased with the permanent magnet stirring rotating speed, and it reached the most refinement at 900 r/min rotating speed. The λ 2 decreased with rotating speed, and it reached the minimum value of alloys at 900 r/min, then it increased at 1200 r/min, leading to the trend of microhardness increase in alloys under 900 r/min and a decrease in alloys at 1200 r/min.

Electrical Resistivity
The electrical resistivity of the Ag-1.5Cu-1.0Y alloys increases with the increase in stirring rate (Figure 8), leading to a decreased electrical conductivity. However, the overall effect of permanent magnet stirring on the electrical resistance of the alloy sample is not very large, with values ranging from 3.05 × 10 −8 to 3.39 × 10 −8 Ω·m. The main reason for the slight increase in electrical resistance may lie in the relationship between electrical resistance and electron transfer. Electrical resistivity is affected by many factors, which can be expressed in the following formula: where ρ is total resistance, ρ 1 is the neutron scattering resistance, ρ 2 is dislocation scattering resistance, ρ 3 is interface scattering resistance and ρ 4 is impurity scattering resistance [35,36].

Sulfuration Corrosion Resistance
Sulfuration is a significant factor that could degrade the conductivity and reflectance of Ag-based alloy products [3]. Therefore, in this study, the effect of permanent magnet stirring on sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloy was tested.
As shown in Figure 9 and Table 3, the sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloys with permanent magnet stirring is better than that of non-permanent magnet stirring alloys. The alloys with a stirring rate of 600 r/min and 900 r/min have better sulfuration corrosion resistance than others. The increased sulfuration corrosion resistance could be explained by the fact that the permanent magnet stirring resulted in the uniform distribution of element Y in alloys under the rotation speeds of 600 r/min and 900 r/min, and that the uniform element Y in the alloys improved the sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloy. The refined dendrite increased electron scattering [37], and the higher content of Y (the electrical resistivity of Y and Ag were 5.95 × 10 −7 Ω·m and 1.65 × 10 −8 Ω·m, respectively) in the grain boundary also resulted in the increase in electrical resistivity of the Ag-1.5Cu-1.0Y alloy. Compared with the alloys at 900 r/min, the refined dendrite decreased and intergranular Y decreased in alloys at 1200 r/min, which means that the electrical resistivity experiences a slight decrease in the Ag-1.5Cu-1.0Y alloy under 1200 r/min stirring speed.

Sulfuration Corrosion Resistance
Sulfuration is a significant factor that could degrade the conductivity and reflectance of Ag-based alloy products [3]. Therefore, in this study, the effect of permanent magnet stirring on sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloy was tested.
As shown in Figure 9 and Table 3, the sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloys with permanent magnet stirring is better than that of non-permanent magnet stirring alloys. The alloys with a stirring rate of 600 r/min and 900 r/min have better sulfuration corrosion resistance than others. The increased sulfuration corrosion resistance could be explained by the fact that the permanent magnet stirring resulted in the uniform distribution of element Y in alloys under the rotation speeds of 600 r/min and 900 r/min, and that the uniform element Y in the alloys improved the sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloy.  The potential dynamic polarization test was carried out in order to better evaluate the effect of different stirring rates on the sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloy samples.
Among them, the corrosion current of the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring is the smallest, which is 2.61 × 10 −5 . The corrosion current of the Ag-1.5Cu-1.0Y alloy increased with stirring rate, and it reached the largest in alloys with 900 r/min stirring rate (3.78 × 10 −5 ), then decreased in alloys with 1200 r/min (2.66 × 10 −5 ) ( Figure 10, Table 4). Studies have proved that grain refinement would alter both the bulk and the surface of alloys, including changes in grain boundary density and orientation. These surface changes could affect electrochemical behavior [33]. The better grain refinement of the alloy, the greater the corrosion current [38,39]. Therefore, in this study, the dendrite refinement increased with the stirring rate, leading to the increased corrosion current of the  The potential dynamic polarization test was carried out in order to better evaluate the effect of different stirring rates on the sulfuration corrosion resistance of the Ag-1.5Cu-1.0Y alloy samples.
Among them, the corrosion current of the Ag-1.5Cu-1.0Y alloy without permanent magnet stirring is the smallest, which is 2.61 × 10 −5 . The corrosion current of the Ag-1.5Cu-1.0Y alloy increased with stirring rate, and it reached the largest in alloys with 900 r/min stirring rate (3.78 × 10 −5 ), then decreased in alloys with 1200 r/min (2.66 × 10 −5 ) ( Figure 10, Table 4). Studies have proved that grain refinement would alter both the bulk and the surface of alloys, including changes in grain boundary density and orientation. These surface changes could affect electrochemical behavior [33]. The better grain refinement of the alloy, the greater the corrosion current [38,39]. Therefore, in this study, the dendrite refinement increased with the stirring rate, leading to the increased corrosion current of the Ag-1.5Cu-1.0Y alloy. The corrosion current reached the largest with the most dendrite refinement. Subsequently, the decreased dendrite refinement of the Ag-1.5Cu-1.0Y alloy results in a decreased corrosion current in alloys with a stirring rate of 1200 r/min.

Conclusions
The microstructure and property defects of Ag-based alloys limit their applications to a great extent. The performance improvement of their microstructures and properties has become an effective way to expand their applications. In this study, we investigated the effects of permanent magnet stirring on the microstructures and properties of the Agalloys based on the Ag-1.5Cu-1.0Y alloy. The results showed that the primary dendrite was shortened and the secondary dendrite arm spacing was reduced to a minimum of 25.12 μm at 900 r/min, indicating that permanent magnet stirring refined the dendrite structure of Ag-1.5Cu-1.0Y alloys. This may be a result of the more uniform distribution of alloy elements by permanent magnet stirring. With regard to the properties, permanent magnet stirring improved the density and microhardness of the Ag-1.5Cu-1.0Y alloys, and the maximum density and microhardness were achieved at 10.32 g/cm 3 and 69.82 HV, respectively, under the rotation speed of 900 r/min. However, the electrical resistivity of the Ag-1.5Cu-1.0Y alloy increases with the increase in the stirring rate of permanent magnets. It may be caused by the uniform distribution of elements Cu and Y in the matrix, which increased the scattering of electrons and then resulted in the increase in the electrical resistivity of the alloy. The sulfuration corrosion resistance was also enhanced by permanent magnet stirring, with better performance under the rotation speed of 900 r/min. The application of the Ag-1.5Cu-1.0Y alloys prepared by permanent magnet stirring needs further study.

Conclusions
The microstructure and property defects of Ag-based alloys limit their applications to a great extent. The performance improvement of their microstructures and properties has become an effective way to expand their applications. In this study, we investigated the effects of permanent magnet stirring on the microstructures and properties of the Ag-alloys based on the Ag-1.5Cu-1.0Y alloy. The results showed that the primary dendrite was shortened and the secondary dendrite arm spacing was reduced to a minimum of 25.12 µm at 900 r/min, indicating that permanent magnet stirring refined the dendrite structure of Ag-1.5Cu-1.0Y alloys. This may be a result of the more uniform distribution of alloy elements by permanent magnet stirring. With regard to the properties, permanent magnet stirring improved the density and microhardness of the Ag-1.5Cu-1.0Y alloys, and the maximum density and microhardness were achieved at 10.32 g/cm 3 and 69.82 HV, respectively, under the rotation speed of 900 r/min. However, the electrical resistivity of the Ag-1.5Cu-1.0Y alloy increases with the increase in the stirring rate of permanent magnets. It may be caused by the uniform distribution of elements Cu and Y in the matrix, which increased the scattering of electrons and then resulted in the increase in the electrical resistivity of the alloy. The sulfuration corrosion resistance was also enhanced by permanent magnet stirring, with better performance under the rotation speed of 900 r/min. The application of the Ag-1.5Cu-1.0Y alloys prepared by permanent magnet stirring needs further study.