Development of Efficient Photocatalyst MIL-68(Ga)_NH2 Metal-Organic Framework for the Removal of Cr(VI) and Cr(VI)/RhB from Wastewater under Visible Light

Severe environmental pollution is caused by the massive discharge of complex industrial wastewater. The photocatalytic technology has been proved as an effective way to solve the problem, while an efficient photocatalyst is the most critical factor. Herein, a new photocatalyst MIL-68(Ga)_NH2 was obtained by hydrothermal synthesis and were characterized by PXRD, FTIR, 1H NMR, and TGA systematically. The result demonstrates that MIL-68(Ga)_NH2 crystallized in orthorhombic system and Cmcm space group with the unit cell parameters: a = 36.699 Å, b = 21.223 Å, c = 6.75 Å, V = 5257.6 Å3, which sheds light on the maintenance of the crystal structure of the prototype material after amino modification. The conversion of Cr(VI) and binary pollutant Cr(VI)/RhB in wastewater under visible light stimulation was characterized by the UV-vis DRS. Complementary experimental results indicate that MIL-68(Ga)_NH2 exhibits remarkable photocatalytic activity for Cr(VI) and the degradation rate reaches as high as 98.5% when pH = 2 and ethanol as hole-trapping agent under visible light irradiation with good reusability and stability. Owing to the synergistic effect between Cr(VI) and RhB in the binary pollutant system, MIL-68(Ga)_NH2 exhibits excellent catalytic activity for both the pollutants, the degradation efficiency of Cr(VI) and RhB was up to 95.7% and 94.6% under visible light irradiation for 120 min, respectively. The possible removal mechanism of Cr(VI)/RhB based on MIL-68(Ga)_NH2 was explored. In addition, Ga-based MOF was applied in the field of photocatalytic treatment of wastewater for the first time, which broadened the application of MOF materials in the field of photocatalysis.


Introduction
With growing industrialization and urbanization, the composition of industrial wastewater is becoming more and more complicated, usually containing a lot of heavy metal ions, such as Cr(VI), Pb(II), and organic dyes such as RhB, MG, and MB, which have high toxicity, teratogenicity, and carcinogenicity, and resulting in a large amount of emission causing great threat to the ecological system and human health [1][2][3][4]. It appears thereby urgent to find an effective way to treat industrial wastewater with complex systems. At present, the main processes aiming to enable this rely on three different types of ways [5]: physical adsorption, chemical precipitation, and reduction method. However, most of these traditional treatment methods are only for a single pollutant, and always with high cost and low efficiency. Owing to the infinite availability and sustainability of the solar energy, the photocatalytic technology has become an efficient and eco-friendly approach to deal with wastewater while avoiding the secondary pollution. The key of this technology lies in the choice of photocatalyst. At present, the photocatalysts used for water purification of multiple pollutants mainly focus on inorganic semiconductor photocatalysts (e.g., TiO 2 , ZnO, Fe 2 O 3 ) [6][7][8][9][10]. Although these systems have beneficial features, the application of Ga(NO 3 ) 3 ·xH 2 O (0.491 g, 1.92 mmol) and H 2 BDC-NH 2 (0.1165 g, 0.64 mmol) were mixed in DMF (6.18 mL), followed by HF (840 µL, 0.38 mmol). The uniformly mixed reactants were transferred to a 25 mL reaction kettle equipped with Teflon-liner, and heated at 125 • C for 5 h in a pre-heated oven. After cooling to room temperature, light-yellow crude product MIL-68(Ga)_NH 2 was filtered and washed by DMF with the yield of around 59%. Finally, the appropriate activation method was adopted to remove the H 2 O and DMF in the pores. The crude samples were immersed in anhydrous methanol for 72 h and the solvent was replaced with fresh anhydrous methanol three times a day. Then the soaked products were filtered and heated in a vacuum oven at 200 • C for 10 h to get activated MIL-68(Ga)_NH 2 . The yield was about 75%.

Synthesis of MIL-68(Ga)
MIL-68(Ga) was produced referring to a previously reported formula [36]. H 2 BDC (0.200 g, 1.20 mmol), Ga(NO 3 ) 3 ·xH 2 O (0.415 g, 1.60 mmol), and DMF (10.00 mL) were mixed uniformly. Then the mixture was shifted to a 25 mL reactor equipped with Teflon-liner, and heated at 100 • C for 10 h. After cooling to room temperature, white crude sample MIL-68(Ga) was filtered and washed by DMF. The yield was about 75%. The activated MIL-68(Ga) sample was obtained according to ref [36].

Measurements
The scanning electron microscopy (SEM) photographs were taken by a Philips XL 30 FEG microscope. The 1 H NMR spectra were performed on a Bruker 400 UltraShield TM with tetramethylsilane as the standard. The powder XRD(PXRD) patterns were carried out on a STOE STADI-P diffractometer equipped with Cu K α1 radiation (α = 1.5406 Å). The FTIR spectra were performed on a BRUKER TENSOR II spectrometer by the means of KBr pellets. The thermogravimetric (TG) analysis was tested on a TA DSC/TGA Discovery SDT 650 simultaneous thermal analyzer at the heating rate of 5 • C min −1 from room temperature to 800 • C in N 2 atmosphere. Nitrogen adsorption isotherms were recorded on a Micromeritics Tristar II 3020 apparatus. The specific surface area was estimated according to the Brunauer-Emmett-Teller (BET) and Langmuir models [39,40]. The UV-vis diffuse reflectance spectra (UV-vis DRS) was recorded on a UV-vis spectrophotometer TU-1950. The samples were scanned in the region from 800 nm to 230 nm with the white BaSO 4 as the blank group. The Mott-Schottky measurement was tested on a CHI760D workstation. The study was conducted with a three electrodes system under four intermittent visible light exposures. The photocurrent measurement was carried out on a CHI1030B workstation. The sample was scanned at different frequencies (0.5 kHz, 1.0 kHz, 1.5 kHz) with a scanning voltage range of −0.6~0.8 V. A 300 W Xe lamp (Beijing Education Jinyuan Technology Co., Ltd., Beijing, China) with a 420 nm cut-off filter was used as a visible light source.

Photocatalytic Degradation Experiments
In order to analyze the photocatalytic activity of MIL-68(Ga)_NH 2 on Cr(VI), Cr 2 O 7 2− was used to simulate Cr(VI) contaminant in sewage. The degradation experiment of Cr(VI) was performed in a 250 mL three-port quartz reactor at room temperature and N 2 atmosphere under visible light irradiation. The distance between the light source and the solution level was fixed at 13 cm. A total of 50 mg of MIL-68(Ga)_NH 2 and different doses of hole-trapping agent were mixed into 50 mL of Cr(VI) aqueous solution (20 ppm). An appropriate amount of H 2 SO 4 (0.1 M) or NaOH (0.1 M) was added to regulate the pH values of reaction system. To achieve adsorption-desorption balance, the system was kept stirring for 1 h in the dark. Then, Xe lamp was turned on for visible light irradiation and about 2 mL of suspension was withdrawn from the beaker per 20 min. Finally, the supernatant was centrifuged and collected for measuring with a UV-vis spectrophotometer with a diphenylcarbazide method [39].
The study of the photocatalytic activity of MIL-68(Ga)_NH 2 for dual pollutants was similar to the aforementioned method, but the mixture of 25 mL of Cr 2 O 7 2− (20 ppm) and 25 mL of RhB (30 ppm) was used to simulate complex industrial wastewater instead of Cr 2 O 7 2− solution. About 4 mL of suspension was withdrawn from the beaker per 20 min for testing the concentration of two pollutants (Cr(VI) and RhB), with 2 mL for each one. The concentrations of RhB was measured with the TU-1950 UV-vis spectrophotometer, and the concentrations of Cr(VI) was measured with a diphenylcarbazide method.

Results and Discussion
Figure 1a displays the crystal morphology of the MIL-68(Ga)_NH 2 , which showed homogeneous hexagonal lumps and the particle size of approximately 3 × 5 µm. light exposures. The photocurrent measurement was carried out on a CHI1030B workstation. The sample was scanned at different frequencies (0.5 kHz, 1.0 kHz, 1.5 kHz) with a scanning voltage range of −0.6~0.8 V. A 300 W Xe lamp (Beijing Education Jinyuan Technology Co., Ltd., Beijing, China) with a 420 nm cut-off filter was used as a visible light source.

Photocatalytic Degradation Experiments
In order to analyze the photocatalytic activity of MIL-68(Ga)_NH2 on Cr(VI), Cr2O7 2was used to simulate Cr(VI) contaminant in sewage. The degradation experiment of Cr(VI) was performed in a 250 mL three-port quartz reactor at room temperature and N2 atmosphere under visible light irradiation. The distance between the light source and the solution level was fixed at 13 cm. A total of 50 mg of MIL-68(Ga)_NH2 and different doses of hole-trapping agent were mixed into 50 mL of Cr(VI) aqueous solution (20 ppm). An appropriate amount of H2SO4 (0.1 M) or NaOH (0.1 M) was added to regulate the pH values of reaction system. To achieve adsorption-desorption balance, the system was kept stirring for 1 h in the dark. Then, Xe lamp was turned on for visible light irradiation and about 2 mL of suspension was withdrawn from the beaker per 20 min. Finally, the supernatant was centrifuged and collected for measuring with a UV-vis spectrophotometer with a diphenylcarbazide method [39].
The study of the photocatalytic activity of MIL-68(Ga)_NH2 for dual pollutants was similar to the aforementioned method, but the mixture of 25 mL of Cr2O7 2− (20 ppm) and 25 mL of RhB (30 ppm) was used to simulate complex industrial wastewater instead of Cr2O7 2− solution. About 4 mL of suspension was withdrawn from the beaker per 20 min for testing the concentration of two pollutants (Cr(VI) and RhB), with 2 mL for each one. The concentrations of RhB was measured with the TU-1950 UV-vis spectrophotometer, and the concentrations of Cr(VI) was measured with a diphenylcarbazide method.  Because the size of the single crystal was inappropriate for performing SCXRD, the unit-cell parameters of MIL-68(Ga)_NH2 was determined by the approach of PXRD with DICVOL4 algorithm [41,42]. The result demonstrated that MIL-68(Ga)_NH2 crystallized in orthorhombic system and Cmcm space group. The unit cell parameters were as follows: Because the size of the single crystal was inappropriate for performing SCXRD, the unit-cell parameters of MIL-68(Ga)_NH 2 was determined by the approach of PXRD with DICVOL4 algorithm [41,42]. The result demonstrated that MIL-68(Ga)_NH 2 crystallized in orthorhombic system and Cmcm space group. The unit cell parameters were as follows:  Table 1. The comparison revealed that the two structures have little variation. In addition, the characteristic peaks in the PXRD pattern of MIL-68(Ga)_NH 2 well matched with the simulated one of MIL-68(Ga) without significant difference ( Figure 1b). Therefore, the results indicated that the insert of amino functional groups did not change the crystal structure of prototype MIL-68(Ga) and the Kagomé topological structure was sustained. MIL-68(Ga)_NH 2 was built up with gallium-oxygen octahedral units linked by µ-OH and the terephthalate ligands to establish two kinds of the channels in the skeleton. Table 1. Unit-cell dimensions of MIL-68(Ga) [34] and MIL-68(Ga)_NH 2 . The inset is the structure of MIL-68(Ga).

Func.
a The FTIR spectra of H 2 BDC-NH 2 , MIL-68(Ga), and MIL-68(Ga)_NH 2 were investigated as shown in Figure S1. Compared to the FTIR spectrum of MIL-68(Ga), two vibration peaks at 1626 and 1258 cm −1 clearly appeared in the spectrum of MIL-68(Ga)_NH 2 , which are assignable to the N-H bending vibration and C-N stretching of aromatic aminos, respectively [43]. Meanwhile, the two weak peaks at 3381 and 3483 cm −1 can be observed, which are considered as symmetric and asymmetric stretching vibrations of the aromatic aminos [44]. Because these two peaks are overlapped by a broad peak of H 2 O and the bridged hydroxyl of the skeleton, the intensity is much less than the ones in the FTIR spectrum of H 2 BDC-NH 2 . The results demonstrated that the amino functional groups have been successfully introduced into MIL-68(Ga) without coordination.
The three independent sets of signals at around δ = 7.87 ppm, 7.66 ppm, 7.36 ppm, which arFigure S2 displays the 1 H NMR spectra of H 2 BDC-NH 2 , as-synthesized MIL-68(Ga)_NH 2 and activated MIL-68(Ga)_NH 2 .e assigned to the phenyl protons of the organic ligand, can be found in all the spectra. It confirms the existence of the terephthalate ligand in the framework. Moreover, the three additional signals of the DMF molecules marked with asterisk can be clearly found in the 1 H NMR spectrum of the as-synthesized MIL-68(Ga)_NH 2 ( Figure S2b). The corresponding signals disappeared in the spectrum of the activated sample ( Figure S2c), which indicates no existence of guest DMF molecules in the activated samples. Therefore, the formula of as-synthesized MIL-68(Ga)_NH 2 can be derived by integrating these sets of signals, which is proposed as The TG curve of MIL-68(Ga)_NH 2 sample is shown in Figure S3. There are three obvious weight losses. The first weight loss occurs from 30 • C to 90 • C, which can be considered as the loss of trapped water (obs.: 7.3%; calc.: 7.1%). The second weight loss, between 90 • C and 315 • C, corresponds as the removal of residual DMF in the pores (obs.: 24.6%; calc.: 24.8%). Finally, the framework structure collapses from 350 • C, which indicates that MIL-68(Ga)_NH 2 has excellent thermal stability. In addition, combined with the analysis results of 1 H NMR, the derivation formula of MIL-68(Ga)_NH 2 is considered to be Ga(OH) (BDC- The N 2 adsorption behavior of MIL-68(Ga)_NH 2 activated in the aforementioned condition is depicted in Figure 2. The N 2 sorption isotherm showed a dramatic absorption behavior in the low-pressure region (10 −5 to 10 −1 atm), which is the characteristics of the I-type isotherm of microporous solids. Determined in the 0.00433-0.04950 p/p 0 range, the BET and Langmuir surface areas of MIL-68(Ga)_NH 2 reached 790 and 840 m 2 g −1 (micropore volume: 0.33 cm 3 g −1 ), respectively. However, the corresponding values of MIL-68(Ga) were 1117 and 1410 m 2 g −1 (micropore volume: 0.46 cm 3 g −1 ) reported by Férey and coworkers [36]. It was found that the BET and Langmuir specific surface areas of MIL-68(Ga)_NH 2 lost 29% and 40%, respectively, and the pore volume lost about 28%, which may be considered as the partial occupation of pore by the insert of amino groups. Many instances displayed that substituting groups have great influence on the pore volume [45][46][47]. Nevertheless, MIL-68(Ga)_NH 2 possesses a considerably high porosity. 68(Ga)_NH2 lost 29% and 40%, respectively, and the pore volume lost about 28% may be considered as the partial occupation of pore by the insert of amino groups instances displayed that substituting groups have great influence on the pore volum 47]. Nevertheless, MIL-68(Ga)_NH2 possesses a considerably high porosity. The room temperature UV-vis DRS of MIL-68(Ga)_NH2 and MIL-68(Ga) sam well as the H2BDC-NH2 ligand are illustrated in Figure 3. The reflectance was con to absorbance by the Kubelka-Munk method. The primary optical absorptio around 365, 390 nm for MIL-68(Ga)_NH2 and H2BDC-NH2, respectively, should be from the n-π* transition of the lone pair electrons of -NH2 in the ligand [17,48]. Ow the perturbation of the transition metal, the blue shift of optical response region served for MIL-68(Ga)_NH2 versus free ligand [29]. Meanwhile, the optical respon of the MIL-68(Ga)_NH2 sample is evidently shifted to longer wavelength compare prototype MIL-68(Ga). The main absorption edges of MIL-68(Ga)_NH2 and MIL samples are 450 and 320 nm, respectively, corresponding to the band gaps (Eg) of 2 3.88 eV (Eg = 1240/wavelength). It reveals that both of the samples present semicon properties. The comparison of the two main absorption peaks shows that modifica the amino group is an effective means to expanding photoabsorption edge of MO the visible light region, which is reflected obviously in color changing of the sam illustrated in the inset of Figure 3. The room temperature UV-vis DRS of MIL-68(Ga)_NH 2 and MIL-68(Ga) samples as well as the H 2 BDC-NH 2 ligand are illustrated in Figure 3. The reflectance was converted to absorbance by the Kubelka-Munk method. The primary optical absorption band around 365, 390 nm for MIL-68(Ga)_NH 2 and H 2 BDC-NH 2 , respectively, should be arisen from the n-π* transition of the lone pair electrons of -NH 2 in the ligand [17,48]. Owing to the perturbation of the transition metal, the blue shift of optical response region is observed for MIL-68(Ga)_NH 2 versus free ligand [29]. Meanwhile, the optical response edge of the MIL-68(Ga)_NH 2 sample is evidently shifted to longer wavelength compared to the prototype MIL-68(Ga). The main absorption edges of MIL-68(Ga)_NH 2 and MIL-68(Ga) samples are 450 and 320 nm, respectively, corresponding to the band gaps (Eg) of 2.76 and 3.88 eV (Eg = 1240/wavelength). It reveals that both of the samples present semiconductor properties. The comparison of the two main absorption peaks shows that modification of the amino group is an effective means to expanding photoabsorption edge of MOFs into the visible light region, which is reflected obviously in color changing of the samples as illustrated in the inset of Figure 3. The room temperature UV-vis DRS of MIL-68(Ga)_NH2 and MIL-68(Ga) sam well as the H2BDC-NH2 ligand are illustrated in Figure 3. The reflectance was co to absorbance by the Kubelka-Munk method. The primary optical absorptio around 365, 390 nm for MIL-68(Ga)_NH2 and H2BDC-NH2, respectively, should b from the n-π* transition of the lone pair electrons of -NH2 in the ligand [17,48]. O the perturbation of the transition metal, the blue shift of optical response regio served for MIL-68(Ga)_NH2 versus free ligand [29]. Meanwhile, the optical respon of the MIL-68(Ga)_NH2 sample is evidently shifted to longer wavelength compare prototype MIL-68(Ga). The main absorption edges of MIL-68(Ga)_NH2 and MIL samples are 450 and 320 nm, respectively, corresponding to the band gaps (Eg) of 2 3.88 eV (Eg = 1240/wavelength). It reveals that both of the samples present semicon properties. The comparison of the two main absorption peaks shows that modific the amino group is an effective means to expanding photoabsorption edge of MO the visible light region, which is reflected obviously in color changing of the sam illustrated in the inset of Figure 3. The photochemical properties of the samples have been explored (Figure 4a). When MIL-68(Ga)_NH 2 is an electrode under intermittent illumination of visible light, it showed an apparent photocurrent response. When the light was turned on, the current density rapidly increased and gradually tended to saturation after a period of time. When the excitation light source was turned off, the current returned to the initial state due to the recombination of the photoelectrons and holes. Instead, MIL-68(Ga) showed almost no photocurrent response during the test procedure. This phenomenon indicated that MIL-68(Ga)_NH 2 could generate photoelectrons and holes under the stimulation of visible light. In addition, the Mott-Schottky was measured in darkness to further explore the electrochemical properties of MIL-68(Ga)_NH 2 (Figure 4b). The slope of C −2 -E is positive which confirms MIL-68(Ga)_NH 2 was an n-type semiconductor [29]. From the x-intercept of the oblique line, the reduction potential of MIL-68(Ga)_NH 2 was about ca. −0.9 V vs. Ag/AgCl pH = 6.8, estimated to be about −0.7 V vs. NHE pH = 6.8, which was much lower than the value of Cr(VI)/Cr(III) (+0.51 V, pH = 6.8) [49]. This indicates that it is thermodynamically possible for MIL-68(Ga)_NH 2 to reduce Cr(VI) to Cr(III). The photochemical properties of the samples have been explored (Figure 4a). When MIL-68(Ga)_NH2 is an electrode under intermittent illumination of visible light, it showed an apparent photocurrent response. When the light was turned on, the current density rapidly increased and gradually tended to saturation after a period of time. When the excitation light source was turned off, the current returned to the initial state due to the recombination of the photoelectrons and holes. Instead, MIL-68(Ga) showed almost no photocurrent response during the test procedure. This phenomenon indicated that MIL-68(Ga)_NH2 could generate photoelectrons and holes under the stimulation of visible light. In addition, the Mott-Schottky was measured in darkness to further explore the electrochemical properties of MIL-68(Ga)_NH2 (Figure 4b). The slope of C −2 -E is positive which confirms MIL-68(Ga)_NH2 was an n-type semiconductor [29]. From the x-intercept of the oblique line, the reduction potential of MIL-68(Ga)_NH2 was about ca. −0.9 V vs. Ag/AgCl pH = 6.8, estimated to be about −0.7 V vs. NHE pH = 6.8, which was much lower than the value of Cr(VI)/Cr(III) (+0.51V, pH = 6.8) [49]. This indicates that it is thermodynamically possible for MIL-68(Ga)_NH2 to reduce Cr(VI) to Cr(III). The photocatalytic properties of MIL-68(Ga)_NH2 were studied under visible light illumination with Cr(VI) solution in the form of Cr2O7 2-as a simulated pollutant. As displayed in Figure 5a, almost no removal of Cr(VI) without light stimulation or catalyst was seen, which illustrated that MIL-68(Ga)_NH2 was a photocatalyst. Compared with commercial TiO2 (P25), MIL-68(Ga)_NH2 showed higher catalytic activity, which suggested MIL-68(Ga)_NH2 was an efficient catalyst in response to visible light. As displayed in Figure 5b, the conversion rate of Cr(VI) in the presence of MIL-68(Ga)_NH2 without hole trapping agent was only 53% after 180 min of visible light stimulus. However, the conversion rate increased in varying degrees with the addition of different types of hole trapping agent, which confirmed that MIL-68(Ga)_NH2 was an electronic photocatalyst. Amongst different hole trapping agents, ethanol exhibited the highest effect as a hole trapping agent. When 200 μL ethanol hole trapping agent was added, the conversion rate of Cr(VI) reached up to 95.9% after 120 min of visible light irradiation. The reason may be that the ethanol hole trapping agent is easier to be adsorbed on the surface of the catalyst to form reductive free radicals, which react with the hole generated by the catalyst to effectively separate the electron-hole pairs [31]. As the amount of ethanol increased (Figure 5c), the removal rate of Cr(VI) speeded up, accompanied by the maximum rate of 98.5% with 300 The photocatalytic properties of MIL-68(Ga)_NH 2 were studied under visible light illumination with Cr(VI) solution in the form of Cr 2 O 7 2− as a simulated pollutant. As displayed in Figure 5a, almost no removal of Cr(VI) without light stimulation or catalyst was seen, which illustrated that MIL-68(Ga)_NH 2 was a photocatalyst. Compared with commercial TiO 2 (P25), MIL-68(Ga)_NH 2 showed higher catalytic activity, which suggested MIL-68(Ga)_NH 2 was an efficient catalyst in response to visible light. As displayed in Figure 5b, the conversion rate of Cr(VI) in the presence of MIL-68(Ga)_NH 2 without hole trapping agent was only 53% after 180 min of visible light stimulus. However, the conversion rate increased in varying degrees with the addition of different types of hole trapping agent, which confirmed that MIL-68(Ga)_NH 2 was an electronic photocatalyst. Amongst different hole trapping agents, ethanol exhibited the highest effect as a hole trapping agent. When 200 µL ethanol hole trapping agent was added, the conversion rate of Cr(VI) reached up to 95.9% after 120 min of visible light irradiation. The reason may be that the ethanol hole trapping agent is easier to be adsorbed on the surface of the catalyst to form reductive free radicals, which react with the hole generated by the catalyst to effectively separate the electron-hole pairs [31]. As the amount of ethanol increased (Figure 5c), the removal rate of Cr(VI) speeded up, accompanied by the maximum rate of 98.5% with 300 µL ethanol consumption. However, the degradation rate gradually decreased when ethanol consumption reached 400 µL, which may be owing to too much ethanol trapping agent adsorbed on the surface of catalyst covering the reactive site. μL ethanol consumption. However, the degradation rate gradually decreased when ethanol consumption reached 400 μL, which may be owing to too much ethanol trapping agent adsorbed on the surface of catalyst covering the reactive site. The pH value of the system showed a significant effect on removal efficiency of Cr(VI). As shown in Figure 5d, with pH = 6, the adsorption efficiency of the catalyst in the dark reaction was observed as only 7% and the conversion rate of Cr(VI) was only 67% under the stimulus of visible light for 180 min. As the pH value decreased from 6 to 2, the adsorption efficiency in the dark reaction and the removal rate of Cr(VI) in the light reaction increased gradually. Accompanied by the degressive pH value, the surface zeta potential of MIL-68(Ga)_NH2 increased, which caused the surface of MIL-68(Ga)_NH2 to be more electropositive. It was conducive to adsorption of Cr2O7 2− , which greatly improved the adsorption capacity and catalytic efficiency [50]. When pH = 2, the adsorption capacity of catalytic reached 25%, the degradation rate of Cr(VI) was up to 98.5% under visible light irradiation for 120 min.
The reusability and stability are important performance evaluation indexes of the photocatalyst. Four cycles of photocatalytic degradation of Cr(VI) were tested and the crystal structures of MIL-68(Ga)_NH2 before and after Cr(VI) reduction were character- The pH value of the system showed a significant effect on removal efficiency of Cr(VI). As shown in Figure 5d, with pH = 6, the adsorption efficiency of the catalyst in the dark reaction was observed as only 7% and the conversion rate of Cr(VI) was only 67% under the stimulus of visible light for 180 min. As the pH value decreased from 6 to 2, the adsorption efficiency in the dark reaction and the removal rate of Cr(VI) in the light reaction increased gradually. Accompanied by the degressive pH value, the surface zeta potential of MIL-68(Ga)_NH 2 increased, which caused the surface of MIL-68(Ga)_NH 2 to be more electropositive. It was conducive to adsorption of Cr 2 O 7 2− , which greatly improved the adsorption capacity and catalytic efficiency [50]. When pH = 2, the adsorption capacity of catalytic reached 25%, the degradation rate of Cr(VI) was up to 98.5% under visible light irradiation for 120 min.
The reusability and stability are important performance evaluation indexes of the photocatalyst. Four cycles of photocatalytic degradation of Cr(VI) were tested and the crystal structures of MIL-68(Ga)_NH 2 before and after Cr(VI) reduction were characterized by PXRD. After each cyclic test, the catalyst was centrifugal separation and washed, and then added to the equal-concentration Cr(VI) aqueous. Because the amount of catalyst used in the cycle experiment was too small to meet the requirements of PXRD, the amount of catalyst and Cr(VI) aqueous was proportionally increased during the actual operation process. Meanwhile, the irradiation time was prolonged as well. The results of the four cycles are depicted in Figure 6a. The conversion rate of Cr(VI) remained at about 98.5% under visible light irradiation for 180 min. PXRD results (Figure 6b) confirmed that the crystal structure of the MIL-68(Ga)_NH 2 was almost intact before and after the cycle experiment. This proved the good structural stability and recyclability of MIL-68(Ga)_NH 2 . Slight loss of activity may be attribute to the loss of catalyst during centrifugation and washing.
Materials 2022, 15, x FOR PEER REVIEW 9 of 14 crystal structure of the MIL-68(Ga)_NH2 was almost intact before and after the cycle experiment. This proved the good structural stability and recyclability of MIL-68(Ga)_NH2. Slight loss of activity may be attribute to the loss of catalyst during centrifugation and washing. In the REDOX process of Cr(VI) to Cr(III), Cr(VI) capture photogenerated electrons as oxidant. Ethanol as the hole-trap-agent can promote electron-hole separation, so as to improve the photocatalytic efficiency of Cr(VI). However, ethanol as an organic solvent is less environmentally friendly. Therefore, it is necessary to find a better way to promote the separation of electrons and holes instead of the addition of ethanol. RhB is a typical organic dye pollutant in industrial wastewater. Many studies have shown that RhB can be oxidized and decomposed into water and CO2 by hole generated by photocatalysis. Inspired by this, RhB was introduced into the system to replace ethanol as a hole trapping agent. The degradation efficiency of unitary pollutant and dual pollutants are shown in Figure 7. In the dual pollutants system, Cr(VI) and RhB captures electrons and holes during the photocatalytic reaction process, respectively. The synergistic effect between the two pollutants leads to the rapid separation of photocarriers, which makes the photocatalytic degradation efficiency of RhB and Cr(VI) significantly higher than that of the unitary pollutant system. When pH = 2, MIL-68(Ga)_NH2 showed excellent activity on Cr(VI), and the degradation efficiency was as high as 95.7% under visible light irradiation for 2 h, which held twice efficiency compare with the system without RhB. Although it is not as effective as ethanol as trapping agent, this system is much more environmentally friendly. Not only does not introduce organic matter, but also degrade the organic dye pollutant RhB with the considerable efficiency of 94.6% as well as the efficient degradation of Cr(VI). The degradation efficiency of dual pollutants is higher than the reported porous inorganic composites g-C3N4/Na-bentonite, ZnFe2O4/Na-bentonite, ZnTiO3/Zn2Ti3O8/ZnO, TiO2, RP0.01TiO2, g-C3N4/TiO2 nanorods [51][52][53][54]. In the REDOX process of Cr(VI) to Cr(III), Cr(VI) capture photogenerated electrons as oxidant. Ethanol as the hole-trap-agent can promote electron-hole separation, so as to improve the photocatalytic efficiency of Cr(VI). However, ethanol as an organic solvent is less environmentally friendly. Therefore, it is necessary to find a better way to promote the separation of electrons and holes instead of the addition of ethanol. RhB is a typical organic dye pollutant in industrial wastewater. Many studies have shown that RhB can be oxidized and decomposed into water and CO 2 by hole generated by photocatalysis. Inspired by this, RhB was introduced into the system to replace ethanol as a hole trapping agent. The degradation efficiency of unitary pollutant and dual pollutants are shown in Figure 7. In the dual pollutants system, Cr(VI) and RhB captures electrons and holes during the photocatalytic reaction process, respectively. The synergistic effect between the two pollutants leads to the rapid separation of photocarriers, which makes the photocatalytic degradation efficiency of RhB and Cr(VI) significantly higher than that of the unitary pollutant system. When pH = 2, MIL-68(Ga)_NH 2 showed excellent activity on Cr(VI), and the degradation efficiency was as high as 95.7% under visible light irradiation for 2 h, which held twice efficiency compare with the system without RhB. Although it is not as effective as ethanol as trapping agent, this system is much more environmentally friendly. Not only does not introduce organic matter, but also degrade the organic dye pollutant RhB with the considerable efficiency of 94.6% as well as the efficient degradation of Cr(VI). The degradation efficiency of dual pollutants is higher than the reported porous inorganic composites g-C 3 N 4 /Na-bentonite, ZnFe 2 O 4 /Na-bentonite, ZnTiO 3 /Zn 2 Ti 3 O 8 /ZnO, TiO 2 , RP 0.01 TiO 2 , g-C 3 N 4 /TiO 2 nanorods [51][52][53][54]. Furthermore, the mechanism of MIL-68(Ga)_NH2 photocatalytic treat containing Cr(VI) and RhB was explored as shown in Figure 8. The galliu ganic clusters of MIL-68(Ga)_NH2 framework act as quantum dots connec terephthalic acid and these organic ligands can perform as a light-absorbi fectively transferring energy to the inorganic clusters [32,50]. When visible MIL-68(Ga)_NH2, the electrons in the conduction band are excited to jum band, generating electrons and holes that have strong REDOX performa generated electrons (e − ) are transferred and react with the adsorbed Cr2O7 2 while h + reacts with H2O in the system to form hydroxyl radical (·OH), w RhB to form H2O and CO2 and intermediates. Meanwhile, the photocata MIL-68(Ga)_NH2 is also consistent with the rapid separation of electron large specific surface area of MIL-68(Ga)_NH2 and the existence of polar groups are conducive to improving the interaction between adsorbents a that the electrons can transfer rapidly, greatly improving the photocatalyti possible reaction mechanism equations are as follows:  Furthermore, the mechanism of MIL-68(Ga)_NH 2 photocatalytic treatment of sewage containing Cr(VI) and RhB was explored as shown in Figure 8. The gallium-oxygen inorganic clusters of MIL-68(Ga)_NH 2 framework act as quantum dots connected by 2-amino-terephthalic acid and these organic ligands can perform as a light-absorbing antennae effectively transferring energy to the inorganic clusters [32,50]. When visible light irradiates MIL-68(Ga)_NH 2 , the electrons in the conduction band are excited to jump to the valence band, generating electrons and holes that have strong REDOX performance. The photogenerated electrons (e − ) are transferred and react with the adsorbed Cr 2 O 7 2− to form Cr(III), while h + reacts with H 2 O in the system to form hydroxyl radical (·OH), which reacts with RhB to form H 2 O and CO 2 and intermediates. Meanwhile, the photocatalytic activity of MIL-68(Ga)_NH 2 is also consistent with the rapid separation of electron and hole. The large specific surface area of MIL-68(Ga)_NH 2 and the existence of polar -NH 2 functional groups are conducive to improving the interaction between adsorbents and catalysts, so that the electrons can transfer rapidly, greatly improving the photocatalytic efficiency. The possible reaction mechanism equations are as follows:

Conclusions
In conclusion, amino modified MIL-68(Ga) was successfully synthesized. The structure of prototype MIL-68(Ga) has been sustained after amino modified, despite the slight loss of apparent surface areas. Notably, UV-vis DRS shows that MIL-68(Ga)_NH2 has obvious visible light response. When pH = 2 and ethanol as hole-trapping agent, MIL-68(Ga)_NH2 exhibits remarkable photocatalytic activity and the degradation rate of Cr(VI) is as high as 98.5% under visible light irradiation holding outstanding stability and recyclability, which is far beyond the degradation efficiency of commercial TiO2(P25) for Cr(VI) under the same conditions. Meanwhile, MIL-68(Ga)_NH2 can also effectively degrade RhB and Cr(VI) simultaneously due to the existence of the synergistic effect between heavy metals and dyes. When pH = 2, the concentration ratio of Cr(VI) and RhB was 1:1.5, the degradation efficiency of Cr(VI) and RhB is up to 95.7% and 94.6%, respectively, under visible light irradiation for 120 min. In this work, Ga-based MOFs were applied in the field of photocatalytic treatment of wastewater for the first time and can be utilized as promising photocatalysts for the environmental cleanup and show great application prospect. It is expected that this work could expand the exploration, the utilization, and the property-control of MOFs as photocatalyst.

Conclusions
In conclusion, amino modified MIL-68(Ga) was successfully synthesized. The structure of prototype MIL-68(Ga) has been sustained after amino modified, despite the slight loss of apparent surface areas. Notably, UV-vis DRS shows that MIL-68(Ga)_NH 2 has obvious visible light response. When pH = 2 and ethanol as hole-trapping agent, MIL-68(Ga)_NH 2 exhibits remarkable photocatalytic activity and the degradation rate of Cr(VI) is as high as 98.5% under visible light irradiation holding outstanding stability and recyclability, which is far beyond the degradation efficiency of commercial TiO 2 (P25) for Cr(VI) under the same conditions. Meanwhile, MIL-68(Ga)_NH 2 can also effectively degrade RhB and Cr(VI) simultaneously due to the existence of the synergistic effect between heavy metals and dyes. When pH = 2, the concentration ratio of Cr(VI) and RhB was 1:1.5, the degradation efficiency of Cr(VI) and RhB is up to 95.7% and 94.6%, respectively, under visible light irradiation for 120 min. In this work, Ga-based MOFs were applied in the field of photocatalytic treatment of wastewater for the first time and can be utilized as promising photocatalysts for the environmental cleanup and show great application prospect. It is expected that this work could expand the exploration, the utilization, and the property-control of MOFs as photocatalyst.

Conflicts of Interest:
The authors declare no conflict of interest.