Influence of Adding Modifying Elements and Homogenization Annealing on Laser Melting Process of the Modified AlZnMgCu with 4%Si Alloys

AlZnMgCu, the high-strength aluminum alloy, is unsuitable for laser melting applications due to its high hot cracking sensitivity and large solidification temperature range. Adapting this alloy for laser melting processing is a high-demand research issue for extending its use. Thus, this paper investigates the effect of adding 4%Si, 4%Si-Sc+Zr, 4%Si-Ti+B, and homogenization annealing on the laser melting process (LMP) of AlZnMgCu alloy. Homogenization annealing at 500 °C for 6.5 h was selected to dissolve most of the low melting temperature phases into the grain matrix and perform stable alloys for the LMP. The pulsed laser melting process (PLM) was performed on the as-casted and the homogenized samples. The microstructures of the as-casted, the homogenized alloys, and after the LMP were evaluated. In addition, the hardness of the base metal (BM) and laser melted zone (LMZ) were measured. The results revealed that the microstructure was enhanced and refined in the as-cast state by adding the modifiers due to the increasing nucleation potency of solidification sites and the formation of primary Al3(Ti, Zr, Sc) phases. The average grain size was decreased by 15.6 times when adding 4%Si + 0.4%Zr + 0.29%Sc, while it decreased by 10.2 times when adding 4%Si + 1%Ti + 0.2%B. The LMZ of the as-casted samples exhibited a non-uniform distribution of the grains and the elements after the LMP. This was attributed to the evaporation of Zn, Mg during the high laser power process besides the non-uniform distribution of elements and phases in samples during casting. After the laser treating of the homogenized samples with 4%Si-Sc + Zr, uniform columnar grains were formed in the direction of the laser. The presence of Ti and B changed the crystallization nature, resulting in the LMZ with very fine and equiaxed grains due to forming many nucleation centers during solidification. The hardness values have positively increased due to Si addition and adding a combination of Ti + B and Sc + Zr. The maximum hardness was 153.9 ± 5 HV achieved in the LMZ of the homogenized samples of 4%Si + 1%Ti + 0.2%B.


Introduction
Al 7XXX alloys are extensively used to manufacture structural components in various industries, including the aerospace industries, because of their excellent stiffness-to-weight ratios, good machinability, and strength-to-weight. The geometric complexity of many aerospace components posed challenges in conventional subtractive manufacturing methods. However, the LMP is extensively utilized in this field because of the small size, high value, and geometric complexity of the manufactured components. Furthermore, LMP techniques decrease the overall amount of aircraft parts by developing and producing complicated topologies [1][2][3].
were used for alloy preparation. The melted composition was stirred to homogenize the alloying elements with the base melt alloy, and then the melted metal was poured into a water-cooled copper mold. The THERMO-CALC software with TCAL4 database (Thermo-Calc Software, Stockholm, Sweden) was utilized to create phase mass fraction-temperature dependence diagrams for each alloy's nominal composition after the casting process. In an Argon environment, a Setaram Labsys (SETARAM Instrumentation, Caluire, France) calorimeter was used to perform a differential scanning calorimetry (DSC) analysis with a heating rate of 5 • C/min. Temperatures ranging from 20 • C to 1000 • C were used in the experiments. Before laser melting processing, the casted samples were homogeneously annealed at 500 • C for 6.5 h for modified alloys with 4%Si to ensure full dissolving of the intermetallic phases. For LMP, the samples were cut from the ingots with a thickness of 1.5-2 mm, were cleaned and polished using SiC papers with numbers P800-P1200 on Struers LaboPol-5 machine (Struers APS, Ballerup, Denmark), then were treated with a 10% aqueous solution of NaOH and a 15% aqueous solution of HNO 3 . After removing the oxide film and brightening the surface, rinsing was performed in running water and drying to remove moisture. A MUL-1-M-200 pulse-periodic laser welding machine (OOO Latikom, Moscow, Russia) with an Nd: YAG laser operating with a wavelength of 1064 nm under protective Argon gas was used laser melting process. The processing parameters for tracks were tabulated in Table 2. These parameters were used to melt the alloys with a single track. The laser-treated samples were polished in two positions for microstructure examinations: the first one, parallel to the surface melting tack. In the second position, the samples were cut and polished perpendicular to the laser melting tracks. The samples were polished using SiC papers with numbers ranging from P320 to P4000 using a Struers machine "Labopol-5" (Struers APS, Ballerup, Denmark). The polished surface was electrically etched at 18V using a 10% electrolyte (saturated solution of H 3 BO 3 in HF) in distilled water. Optical microscope (OM), Axiovert 200 MMAT, (Carl Zeiss, Oberkochen, Germany) and scanning electron microscope, Tescan-VEGA3, (Tescan Brno s.r.o., Kohoutovice, Czech Republic) were used to examine the microstructure of the as-cast and after the LMP. The linear intercept technique was used to calculate the average grain size. A Vickers hardness testing machine measured microhardness values of the LMZ with a load of 25 gf and a shutter speed of 15 s. Hardness results were obtained using an HVD-1000AP hardness tester machine (Wolpert Wilson Instruments, Aachen, Germany) with HV5, a load of 500 g, and a shutter speed of 10 s.

Thermo-Calc Prediction
As stated above in the introduction, one of the main issues for LMP of the 7075 alloys is their high tendency of hot cracking, which is related to solidification shrinkage. Si is added initially to provide an additional liquid phase for reducing the tendency of solidification cracking and decreasing solidification shrinkage as shown in Si-rich Al alloys like Al-Si and AlSi10Mg alloys, which may be successfully additively manufactured [6,34,35]. Figure 1 illustrates the solidification curves with the predicted phases produced by the Thermo-Calc database of the investigated alloys. Figure 1a-d shows that adding 4%wt Si to the AlZnMgCu alloy would reduce the dfs/dt value (=slope of the solidification curve), where t is the solidification time, and fs is a solid phase fraction. Generally, according to the computed solidification curves, the inclusion of 4%wt Si reduces the temperature difference between solidus and liquidus temperatures. According to Kou et al. [36], a higher temperature difference between the liquidus and the solidus temperatures increases cracks. That is, the presence of Si decreased the susceptibility to cracks by altering the solidification behavior of the basic AlZnMgCu alloy, according to the researchers. Adding Ti + B, and Zr + Sc, insignificant affect the solidification curves (Figure 1c,d). The solidification range of the alloys after adding Sc + Zr and Ti + B to 7075-4%Si alloy was decreased by 8 • C and 12 • C respectively.   Figure 2 presents the microstructure and grains statistical of the as-cast modified alloys. The microstructure of the 7075-4%Si has a formation of primary dendrites of the Al-rich solid solution with a coarse-grained dendritic structure (Figure 2a) with an average grain size of 297 ± 90 µm. Adding 0.29%Sc and 0.4%Zr, the structure changed to a very fine nondendritic structure according to the effect of the primary Al 3 (Sc, Zr) phase as a refining source and the suppression of grain growth, shown in Figure 2b, with a grain size of 19 ± 3.9 µm. Adding 1% Ti-0.2% B resulted in uniform and fine dendritic grains due to the soluble Al 3 Ti and TiB 2 , which act as potential nuclei for primary phase nucleation. The average grain size was 29.2 ± 7.5 µm shown in Figure 2c. Figure 2d-f shows the grains size frequency of the investigated alloys. It was observed that the normal distribution of grains was narrower in the case of 7075-4%Si + ScZr (Figure 2e) than in those of the other alloys. The narrow normal distribution of grains confirms the equiaxed uniform grains. The as-cast 7075-4%Si alloy exhibited non-uniform equiaxed grains resulted in the wide normal distribution of grains. The grain size of 7075-4%Si is 297 ± 90 µm and 19 ± 3.9 µm in 7075-4%Si + ScZr, and from 29 ± 7.5 µm in 7075-4%Si + TiB. Grains morphology, size, and frequency play a significant role in the performance of the material under the different processes. According to SEM and EDS analysis in Figure 3, the bright zones are the non-equilibrium phases, and the dark zones are the primary solid solution. 7075-4%Si has a dendrite cell of Al solid solution with small amounts of Cu, Mg, Si, Cr, Mn, and Zn, as observed in Figure 3a. However, it can be observed that the intermetallic phases were formed in the inter-dendritic regions. The formed phases besides the Al solid solution and primary Si were Al2Cu, MgZn2, and Mg2Zn11. Adding Sc + Zr to 7075-4%Si can form the primary aluminide Al3(Sc, Zr) particles and the eutectic phase of Si, Mg, Cu, Mn, and Zn in the inter-dendritic areas (Figure 3b). The addition of Ti and B led to a uniform distribution of the liquid phase with the insoluble TiB2 particles and the soluble Al3Ti, which modified the grain structure ( Figure 3c). These formed phases were confirmed by Thermocalc data. The presence of Al3(Sc, Zr, Ti) enhanced the nature of the crystallization of the alloy. These nucleant particles lead to an equiaxed microstructure formation with a uniform distribution of small grains and porosity, leading to improved mechanical and fatigue properties [37]. During casting, grain refiners were added to the melt to reveal TiB2 and Al3Ti particles, which act as heterogeneous nuclei for the primary Al. The refiner particles should ideally be distributed uniformly in the melt, promoting as many nucleation events According to SEM and EDS analysis in Figure 3, the bright zones are the nonequilibrium phases, and the dark zones are the primary solid solution. 7075-4%Si has a dendrite cell of Al solid solution with small amounts of Cu, Mg, Si, Cr, Mn, and Zn, as observed in Figure 3a. However, it can be observed that the intermetallic phases were formed in the inter-dendritic regions. The formed phases besides the Al solid solution and primary Si were Al 2 Cu, MgZn 2 , and Mg 2 Zn 11 . Adding Sc + Zr to 7075-4%Si can form the primary aluminide Al 3 (Sc, Zr) particles and the eutectic phase of Si, Mg, Cu, Mn, and Zn in the inter-dendritic areas (Figure 3b). The addition of Ti and B led to a uniform distribution of the liquid phase with the insoluble TiB 2 particles and the soluble Al 3 Ti, which modified the grain structure ( Figure 3c). These formed phases were confirmed by Thermocalc data. The presence of Al 3 (Sc, Zr, Ti) enhanced the nature of the crystallization of the alloy. These nucleant particles lead to an equiaxed microstructure formation with a uniform distribution of small grains and porosity, leading to improved mechanical and fatigue properties [37]. During casting, grain refiners were added to the melt to reveal TiB 2 and Al 3 Ti particles, which act as heterogeneous nuclei for the primary Al. The refiner particles should ideally be distributed uniformly in the melt, promoting as many nucleation events on the TiB 2 particles as possible when solidification begins. As it can be observed, the presence of the non-equilibrium phases in inter-dendritic and around the grain structure due to the non-equilibrium solidification during casting led to the inhomogeneous chemical distribution and grain structure. It was previously established [38] that homogenization treatment could eliminate inhomogeneity of the chemical composition and microstructure inside the ingot. During homogenization, soluble intermetallic particles can dissolve into the matrix, forming a saturated grain with most elements. As a result, homogenization is an important process for ensuring alloys' performance.  Figure 4. The melting temperature of the second phase during the homogenization annealing process can be measured through this

DSC Analysis of the As-Casted Alloys
DSC curves of as-cast alloys are shown in Figure 4. The melting temperature of the second phase during the homogenization annealing process can be measured through this analysis. The figure shows that the low eutectic phase will be dissolved initially when the temperature for homogenization is 523 • C in the 7075-4%Si and with Sc + Zr and 521 • C in the 7075-4%Si-Ti + B. So, the homogenization temperature must not exceed those temperatures. So, the selected temperature of homogenization annealing is 500 • C for 6.5 h.  According to the DSC analysis, the investigated alloys were homogenized at 500 °C for 6.5 h to dissolve the low melting temperature phases and perform stable alloys for the laser melting process. The SEM and OM of the modified alloys after homogenization annealing 6.5h are shown in Figure 5. In the figure, the grain boundaries became noticeably clearer and thinner where most of the residual phases dissolved and the dendritic structure was reduced. The distribution of the second phases around the grain boundaries became discontinuous. Moreover, there were few dendrites, and intermetallics phases still existed. The main reason for performing homogenization annealing pre-laser melting is to eliminate low-temperature phases around the grain boundaries, which causes cracks formation [39]. Furthermore, dissolving these phases into the grains to be fully saturated with all elements can enhance the LMZ characteristics and properties during laser melting.  According to the DSC analysis, the investigated alloys were homogenized at 500 • C for 6.5 h to dissolve the low melting temperature phases and perform stable alloys for the laser melting process. The SEM and OM of the modified alloys after homogenization annealing 6.5h are shown in Figure 5. In the figure, the grain boundaries became noticeably clearer and thinner where most of the residual phases dissolved and the dendritic structure was reduced. The distribution of the second phases around the grain boundaries became discontinuous. Moreover, there were few dendrites, and intermetallics phases still existed. The main reason for performing homogenization annealing pre-laser melting is to eliminate low-temperature phases around the grain boundaries, which causes cracks formation [39]. Furthermore, dissolving these phases into the grains to be fully saturated with all elements can enhance the LMZ characteristics and properties during laser melting.  According to the DSC analysis, the investigated alloys were homogenized at 500 °C for 6.5 h to dissolve the low melting temperature phases and perform stable alloys for the laser melting process. The SEM and OM of the modified alloys after homogenization annealing 6.5h are shown in Figure 5. In the figure, the grain boundaries became noticeably clearer and thinner where most of the residual phases dissolved and the dendritic structure was reduced. The distribution of the second phases around the grain boundaries became discontinuous. Moreover, there were few dendrites, and intermetallics phases still existed. The main reason for performing homogenization annealing pre-laser melting is to eliminate low-temperature phases around the grain boundaries, which causes cracks formation [39]. Furthermore, dissolving these phases into the grains to be fully saturated with all elements can enhance the LMZ characteristics and properties during laser melting.

Laser Melting Process
After laser melting of the as-casted 7075-4%Si, the coarse grains near edges that crystallized from the melt pool and grew on a substrate of large grains of the base metal with a coarse columnar grains formation at the center of the track arranged in the direction of

Laser Melting Process
After laser melting of the as-casted 7075-4%Si, the coarse grains near edges that crystallized from the melt pool and grew on a substrate of large grains of the base metal with a coarse columnar grains formation at the center of the track arranged in the direction of laser melting, as shown in Figure 6a. After laser melting the homogenized samples, a uniform structure was obtained due to dissolving most intermetallic phases into the matrix. The columnar grains were transformed into coarse grains at the center of the track (as shown in Figure 6d). In 7075-4%Si + ScZr, the modifying elements affected the structure, which the structure after laser fully transformed into columnar grains, but still, with different sizes. That's because of the non-uniform distribution of elements in the as-casted samples; in the case of the homogenized samples, the structure became uniform columnar grains in the direction of laser (Figure 6b,e). In 7075-4%Si + TiB, the presence of Ti and B changed the nature of crystallization, and the columnar grain zones disappeared. All grains inside the LMZ were fine uniform and equiaxed grains due to the nucleation centers during solidification. The main difference between the laser-treated casted and homogenized samples is the uniformity and the distribution of the grains inside the LMZ (Figure 6c,f). And it can be noticed, Si has a significant impact on the absence of solidification cracks during laser melting. It can be concluded that the presence of Si reduces the sensitivity of the formation of hot cracks during solidification; and by adding the improved elements, whether Sc, Zr, Ti, and B, the nature of the alloy has been changed due to the formation of many nucleation centers inside the molten pool, which suppressed the formation of the columnar grains and the columnar grain transformed to equiaxed grain due to the rapid increase of the nucleation and growth rate of the equiaxed grain. This way eliminates its tendency of hot crack formation during rapid solidification. laser melting, as shown in Figure 6a. After laser melting the homogenized samples, a uniform structure was obtained due to dissolving most intermetallic phases into the matrix. The columnar grains were transformed into coarse grains at the center of the track (as shown in figure 6d). In 7075-4%Si + ScZr, the modifying elements affected the structure, which the structure after laser fully transformed into columnar grains, but still, with different sizes. That's because of the non-uniform distribution of elements in the as-casted samples; in the case of the homogenized samples, the structure became uniform columnar grains in the direction of laser (Figure 6b,e). In 7075-4%Si + TiB, the presence of Ti and B changed the nature of crystallization, and the columnar grain zones disappeared. All grains inside the LMZ were fine uniform and equiaxed grains due to the nucleation centers during solidification. The main difference between the laser-treated casted and homogenized samples is the uniformity and the distribution of the grains inside the LMZ (Figure 6c,f). And it can be noticed, Si has a significant impact on the absence of solidification cracks during laser melting. It can be concluded that the presence of Si reduces the sensitivity of the formation of hot cracks during solidification; and by adding the improved elements, whether Sc, Zr, Ti, and B, the nature of the alloy has been changed due to the formation of many nucleation centers inside the molten pool, which suppressed the formation of the columnar grains and the columnar grain transformed to equiaxed grain due to the rapid increase of the nucleation and growth rate of the equiaxed grain. This way eliminates its tendency of hot crack formation during rapid solidification.
. In the case of the as-casted samples, the SEM structure of the LMZ shows a freedefects structure but with nonuniformity in elemental distribution such Si, Cu, Zn, and Mg due to the melting structure with inhomogeneity distribution of elements and also evaporating Zn and Mg during the laser processing ( Figure 7a) and this also affected the crystallization behavior as shown in the previous figure. The presence of the modifying elements positively affected the crystallization behavior, the amount of evaporation Zn and Mg, and the distribution of elements inside the melt pool due to the high amount of the nucleation centers such as Al3(Sc, Zr) and TiB2 (Figure 7b,c). However, the non-homogeneity of elements and intermetallic phases in the base alloy can affect the final properties and the new crystallized structure of the LMZ. In the case of the as-casted samples, the SEM structure of the LMZ shows a freedefects structure but with nonuniformity in elemental distribution such Si, Cu, Zn, and Mg due to the melting structure with inhomogeneity distribution of elements and also evaporating Zn and Mg during the laser processing ( Figure 7a) and this also affected the crystallization behavior as shown in the previous figure. The presence of the modifying elements positively affected the crystallization behavior, the amount of evaporation Zn and Mg, and the distribution of elements inside the melt pool due to the high amount of the nucleation centers such as Al 3 (Sc, Zr) and TiB 2 (Figure 7b,c). However, the non-homogeneity of elements and intermetallic phases in the base alloy can affect the final properties and the new crystallized structure of the LMZ. After the laser melting of the homogenized samples (Figure 8a-c), the nature of the structure became more uniform, as mentioned above due to dissolving the low-temperature phases and the saturated grains with the most elements. As shown in Figure 8d-f in the EDS map analysis, the LMZ has a fully uniform distribution of elements in all modified alloys and the presence of TiB2 particles in 7075-4%Si + TiB alloy, which enhanced the properties of the LMZ. So, the SEM and EDS analysis confirmed the idea that the laser treating of the homogenized samples performed more uniform and stable LMZ than the LMZ of the as-casted samples. This can be attributed to the LMZ of the homogenized samples having saturated grains with all elements. After the laser melting of the homogenized samples (Figure 8a-c), the nature of the structure became more uniform, as mentioned above due to dissolving the low-temperature phases and the saturated grains with the most elements. As shown in Figure 8d-f in the EDS map analysis, the LMZ has a fully uniform distribution of elements in all modified alloys and the presence of TiB 2 particles in 7075-4%Si + TiB alloy, which enhanced the properties of the LMZ. So, the SEM and EDS analysis confirmed the idea that the laser treating of the homogenized samples performed more uniform and stable LMZ than the LMZ of the as-casted samples. This can be attributed to the LMZ of the homogenized samples having saturated grains with all elements.

Hardness Characteristics
Hardness and microhardness values of the base metal and LMZ of the modified alloys in the as-cast and homogenized conditions were illustrated in Figure 9a-c. The hardness of the as-cast standard alloy with the addition of 4%Si was 125 ± 2.9 HV, and by adding 4%Si + TiB and 4%Si-ScZr, the hardness of the base metal increased to 134.9 ±3.4 and 131.2 ± 5 HV, respectively. After homogenization of 500 °C for 6.5 h for all alloys, the hardness of the base metal was decreased to 123.2, 118.1, and 111.3 HV for 7075-4%Si, 7075-4%Si + ScZr, and 7075-4%Si + TiB, respectively, due to the dissolving of the lowtemperature intermetallic phases during homogenization. After laser melting, the microhardness values of the LMZ of the as-casted and the homogenized samples were increased as compared to the base metal in all conditions. In the 7075-4%Si, the microhardness of the LMZ of the as-casted sample has an insignificant change, and the value is 125.7 ± 3.5 HV, but the LMZ of the homogenized samples was increased to 131.2 ± 3.9 HV. In 7075-4%Si + ScZr alloy, the LMZ increased compared to the base metal by 142.3 ± 5 and 128.7 ± 5.8 HV in the as-casted and homogenized conditions. After adding Ti and B to the 7075-4%Si, the LMZ increased to 133.8 ± 4.3 and 153.9 ± 5 HV in as-casted and homogenized conditions, respectively. The hardness values have positively increased due to Si addition and addition a combination of Ti + B and Sc + Zr.

Hardness Characteristics
Hardness and microhardness values of the base metal and LMZ of the modified alloys in the as-cast and homogenized conditions were illustrated in Figure 9a-c. The hardness of the as-cast standard alloy with the addition of 4%Si was 125 ± 2.9 HV, and by adding 4%Si + TiB and 4%Si-ScZr, the hardness of the base metal increased to 134.9 ± 3.4 and 131.2 ± 5 HV, respectively. After homogenization of 500 • C for 6.5 h for all alloys, the hardness of the base metal was decreased to 123.2, 118.1, and 111.3 HV for 7075-4%Si, 7075-4%Si + ScZr, and 7075-4%Si + TiB, respectively, due to the dissolving of the low-temperature intermetallic phases during homogenization. After laser melting, the microhardness values of the LMZ of the as-casted and the homogenized samples were increased as compared to the base metal in all conditions. In the 7075-4%Si, the microhardness of the LMZ of the as-casted sample has an insignificant change, and the value is 125.7 ± 3.5 HV, but the LMZ of the homogenized samples was increased to 131.2 ± 3.9 HV. In 7075-4%Si + ScZr alloy, the LMZ increased compared to the base metal by 142.3 ± 5 and 128.7 ± 5.8 HV in the as-casted and homogenized conditions. After adding Ti and B to the 7075-4%Si, the LMZ increased to 133.8 ± 4.3 and 153.9 ± 5 HV in as-casted and homogenized conditions, respectively. The hardness values have positively increased due to Si addition and addition a combination of Ti + B and Sc + Zr.

Conclusions
Aluminum alloy, AlZnMgCu (7075), was modified by adding 4%Si, 4%Si + ScZr, and 4%Si + TiB elements, then homogenized at 500 °C for 6.5 h. The effect of composition modification and homogenization annealing on the LMZ was studied. Microstructure analysis and microhardness evolution were investigated. From the results, we concluded that; In the as-cast state, the addition of 4%Si forms primary dendrites of the Al-rich solid solution with a coarse-grained dendritic structure with an average grain size of 297 ± 90 µm. After adding 4%Si-ScZr, the structure changed to a very fine nondendritic structure and decreased about 15.6 times according to the effect of the primary Al3(Sc, Zr) phase as a refining source and the suppression of grain growth. Similarly, adding 4%Si-Ti + B resulted in fine and uniform dendritic grains decreasing 10.2 times due to the soluble Al3Ti and TiB2, which act as potential nuclei for the primary phase nucleation.
After homogenization annealing, the grain boundaries became clearer and thinner where most of the residual phases dissolved, and the dendritic structure was reduced. The distribution of the second phases around the grain boundaries became discontinuous. After LMP of the as-casted samples, the 7075-4%Si exhibited coarse grains near edges that were crystallized from the melt pool. It grew on a substrate of large grains of the base metal with coarse columnar grains formation at the center of the track arranged in the direction of laser melting. In 7075-4%Si + ScZr, the structure after laser completely transformed into columnar grains, but in different sizes, because of the non-uniform distribution of elements of the as-casted samples. In 7075-4%Si + TiB, the presence of Ti and B changed the nature of crystallization, and the columnar grain zones disappeared.
After laser melting processing of the homogenized samples, homogenization 6.5 h of 7075-4%Si resulting in uniform structure and transform the columnar grains to coarse equiaxed grains in the center of the track, in the case of the homogenized 7075-4%Si + ScZr samples, the structure became uniform columnar grains in the direction of the laser. For 7075-4%Si + TiB, all grains inside the LMZ were small fine and equiaxed grains due to the nucleation centers during solidification. Generally, the hardness values of the BM and LMZ were increased by adding 4%Si, 4%Si + ScZr, and 4%Si-TiB compared to the same alloys without 4% Si and the modifiers. The LMP didn't soften the LMZ of the as-casted samples; on the contrary, the hardness was slightly increased, and the hardness of the BM of the homogenized samples decreased. The LMZ exhibited higher hardness compared to the as-cast.
Finally, adding 4% Si with a combination of 1Ti + 0.2B and 0.29Sc + 0.4Zr to AlZ-nMgCu and homogenization annealing significantly enhanced the base alloy and the LMZ.

Conclusions
Aluminum alloy, AlZnMgCu (7075), was modified by adding 4%Si, 4%Si + ScZr, and 4%Si + TiB elements, then homogenized at 500 • C for 6.5 h. The effect of composition modification and homogenization annealing on the LMZ was studied. Microstructure analysis and microhardness evolution were investigated. From the results, we concluded that; In the as-cast state, the addition of 4%Si forms primary dendrites of the Al-rich solid solution with a coarse-grained dendritic structure with an average grain size of 297 ± 90 µm. After adding 4%Si-ScZr, the structure changed to a very fine nondendritic structure and decreased about 15.6 times according to the effect of the primary Al 3 (Sc, Zr) phase as a refining source and the suppression of grain growth. Similarly, adding 4%Si-Ti + B resulted in fine and uniform dendritic grains decreasing 10.2 times due to the soluble Al 3 Ti and TiB 2 , which act as potential nuclei for the primary phase nucleation.
After homogenization annealing, the grain boundaries became clearer and thinner where most of the residual phases dissolved, and the dendritic structure was reduced. The distribution of the second phases around the grain boundaries became discontinuous. After LMP of the as-casted samples, the 7075-4%Si exhibited coarse grains near edges that were crystallized from the melt pool. It grew on a substrate of large grains of the base metal with coarse columnar grains formation at the center of the track arranged in the direction of laser melting. In 7075-4%Si + ScZr, the structure after laser completely transformed into columnar grains, but in different sizes, because of the non-uniform distribution of elements of the as-casted samples. In 7075-4%Si + TiB, the presence of Ti and B changed the nature of crystallization, and the columnar grain zones disappeared.
After laser melting processing of the homogenized samples, homogenization 6.5 h of 7075-4%Si resulting in uniform structure and transform the columnar grains to coarse equiaxed grains in the center of the track, in the case of the homogenized 7075-4%Si + ScZr samples, the structure became uniform columnar grains in the direction of the laser. For 7075-4%Si + TiB, all grains inside the LMZ were small fine and equiaxed grains due to the nucleation centers during solidification. Generally, the hardness values of the BM and LMZ were increased by adding 4%Si, 4%Si + ScZr, and 4%Si-TiB compared to the same alloys without 4% Si and the modifiers. The LMP didn't soften the LMZ of the as-casted samples; on the contrary, the hardness was slightly increased, and the hardness of the BM of the homogenized samples decreased. The LMZ exhibited higher hardness compared to the as-cast.
Finally, adding 4% Si with a combination of 1Ti + 0.2B and 0.29Sc + 0.4Zr to AlZnMgCu and homogenization annealing significantly enhanced the base alloy and the LMZ.

Data Availability Statement:
The data presented in this study are available on request from the corresponding author. The data are not publicly available due to privacy.