Polypropylene/Lignin/POSS Nanocomposites: Thermal and Wettability Properties, Application in Water Remediation

Compositing is an interesting strategy that has always been employed to introduce or enhance desired functionalities in material systems. In this paper, sponges containing polypropylene, lignin, and octavinyl-polyhedral oligomeric silsesquioxane (OV-POSS) were successfully prepared via an easy and elegant strategy called thermally induced phase separation (TIPS). To fully explore the behaviour of different components of prepared sponges, properties were characterized by a thermogravimetric analyser (TGA), differential scanning calorimetry (DSC), Fourier transform infrared measurement (FTIR), and scanning electron microscopy (SEM). Furthermore, wettability properties toward an organic liquid and oil were investigated. The FTIR analysis confirmed the chemical modification of the components. TGA and DSC measurements revealed thermal stability was much better with an increase in OV-POSS content. OV-POSS modified sponges exhibited ultra-hydrophobicity and high oleophilicity with water contact angles of more than 125°. The SEM revealed that POSS molecules acted as a support for reduced surface roughness. Moreover, OV-POSS-based blend sponges showed higher sorption capacities compared with other blend sponges without OV-POSS. The new blend sponges demonstrated a potential for use as sorbent engineering materials in water remediation.


Introduction
Industrial wastewater and oil spillage are considered as the main source of water pollution, which threatens human life and the marine system [1][2][3][4][5]. Moreover, water pollution creates a great loss of energy resources if not properly treated [6]. Various methods have been widely adopted to remedy water pollution, including application of booms, in situ burning, skimmers, biological treatment, microorganisms, dispersants [7][8][9][10].
However, these methods had many disadvantages, such as that their application was limited, high-cost, poorly efficient, and had adverse effects on the environment. In this case, removing pollutants by low-cost and highly absorbent materials without generating by products that may cause further concern was the main target of material scientists for decades [11]. Different materials have been developed to face the great challenge of removing oil from water surfaces, such as a sponge [12], foam [13], carbon nanofiber aerogel [14], and carbon nanotubes [15]. These materials have useful common features such as being porous, hydrophobic, oleophilic, and making recovery possible by a simple squeeze procedure. However, most of the materials still had the significant problem of high cost in chemicals.
Polypropylene (PP) pellets, octavinyl-polyhedral oligomeric silsesquio ane (OV-POSS, Figure 1), lignin (L), acetone, decalin, 1-butanol, dichloromethane, and hexane were purchased from Aladdin (Shanghai, China) and used without further purification. Dichloromethane and hexane were used as organic solvents. Engine oil and soybean oil were bought at a local market (Shanghai, China) t. All reagents were used without further purification. Typical properties of the materials are reported in Table 1.
(TIPS), oil and organic liquid from water surfaces, using the three constituents-PP, lignin, and OV-POSS-. We then investigated the effect of OV-POSS nanoparticles with different levels (1 and 3 wt%), which were also used as compatibilizers, on the wettability and thermal properties of the blends.

Materials
Polypropylene (PP) pellets, octavinyl-polyhedral oligomeric silsesquio ane (OV-POSS, Figure 1), lignin (L), acetone, decalin, 1-butanol, dichloromethane, and hexane were purchased from Aladdin (Shanghai, China) and used without further purification. Dichloromethane and hexane were used as organic solvents. Engine oil and soybean oil were bought at a local market (Shanghai, China) t. All reagents were used without further purification. Typical properties of the materials are reported in Table 1.

Fabrication of Blend Sponge
To fabricate the target sponges, the typical process was done as follows: The solution of PP was prepared by completely dissolving 2.8 g of PP pellets in a mixed solvent containing decalin (16 mL) and 1-butanol (24 mL), heating at a temperature of 115 • C until the polymer was completely dissolved to form a homogenous solution. Afterward, lignin and OV-POSS were added to the solution and gentle stirring followed for 1 h to obtain a uniform mixture. The solution was then cooled at room temperature for 2 h. It should be noticed that the phase separation finished in a short time. During the cooling stage, phase separation took place, forming a sponge. After that, the obtained sponge was immersed into acetone to remove the embedded solvent and subsequently dried under vacuum. The general procedure for the fabrication of the target sponge is illustrated in Figure 2. The contents of all the composites are listed in Table 2. The added levels of dried lignin and POSS were set of the total weight of PP pellets. The dried lignin was added in two different amounts, 10 and 20 wt% (total mass percentages) of PP, and the corresponding composites were labelled PP10L and PP20L, respectively. The dried OV-POSS was also added in two different amount, 0.1 and 0.3 wt%. OV-POSS was abbreviated to POSS.

Fabrication of Blend Sponge
To fabricate the target sponges, the typical process was done as follows: The solution of PP was prepared by completely dissolving 2.8 g of PP pellets in a mixed solvent containing decalin (16 mL) and 1-butanol (24 mL), heating at a temperature of 115 ˚C until the polymer was completely dissolved to form a homogenous solution. Afterward, lignin and OV-POSS were added to the solution and gentle stirring followed for 1 h to obtain a uniform mixture. The solution was then cooled at room temperature for 2 h. It should be noticed that the phase separation finished in a short time. During the cooling stage, phase separation took place, forming a sponge. After that, the obtained sponge was immersed into acetone to remove the embedded solvent and subsequently dried under vacuum. The general procedure for the fabrication of the target sponge is illustrated in Figure 2. The contents of all the composites are listed in Table 2. The added levels of dried lignin and POSS were set of the total weight of PP pellets. The dried lignin was added in two different amounts, 10 and 20 wt% (total mass percentages) of PP, and the corresponding composites were labelled PP10L and PP20L, respectively. The dried OV-POSS was also added in two different amount, 0.1 and 0.3 wt%. OV-POSS was abbreviated to POSS.   The molecular weight of PP was determined by polymer laboratory Gel permeation chromatography (PLGPC-220, Shropshire, UK) at 150 • C, using 1,2,4-trichlorobenzene as a solvent, and the calibration was made with polystyrene standards.

H NMR Spectroscopy
H NMR analysis was carried out to determine the chemical structure of the lignin, using a Bruker Avance 600 MHz spectrometer (Malaga, Spain) at a frequency of 600 MHz at 25 • C. The lignin samples were dissolved with DMSO to enhance their solubility.

Fourier Transform Infrared (FTIR) Measurement
The infrared spectra were obtained using an FTIR spectrometer (Nicolet 6700, Thermo Fisher, Freehold, NJ, USA). The spectra were recorded at the wavenumber range of 400-4000 cm −1 . The spectra were generated in the range of 400-5000 cm −1 using attenuated total reflection (ATR) technique. The test was used in 64 scans with a 8 cm −1 resolution.

Thermogravimetric Analysis
The thermal stability of PP, lignin, POSS, and obtained polypropylene/lignin blend monoliths were investigated using a thermogravimetric analyser (TGA 4000, PerkinElmer, Freehold, NJ, USA). Sample masses of~10 mg were heated at 30-700 • C at a heating rate of 10 • C/min under nitrogen flow (20 mL/min).

Differential Scanning Calorimetry (DSC) Analysis
DSC analyses were used to evaluate the effect of added lignin on the polypropylene thermal behaviour of the blend monoliths. The measurements were carried out using differential scanning calorimetry (DSC 4000, PerkinElmer, Freehold, NJ, USA). Samples of~3-5 mg in an aluminium container were carried out by heating/cooling at a rate of 10 • C/min under nitrogen atmosphere within a temperature range of 30-200 • C.

Scanning Electron Microscopy (SEM) Characterization
The surface morphology of polypropylene/lignin sponges and their modifications with POSS were characterized using scanning electron microscopy (FLEX SEM1000, Hitachi, Chuocho, Kagoshima, Japan). For SEM, samples were cut, fixed on double tape, and then plated with a thin film of gold before measurement.

Contact Angle Determination
The contact angles and surface free energies were measured by an optical contact angle meter (OCA15EC, DataPhysics, Filderstadt, Germany). In the testing process, double-sided tape attached the fibres to a glass slide, paved in the form of a plane [42]. Surface energies of the three samples were calculated based on the Owens-Wendt-Rabel-Kaelble (OWRK) method using three different liquids: water, ethylene glycol, and ethanol [21,43,44].

Measurements of Oil Sorption Capacity and Reusability
The sorption capacity Q (%) was calculated from the mass gain after the obtained samples were weighed and placed in a beaker containing a 5 mm layer of liquid (oilorganic solvents) floating on an 80 mm layer of water for a duration of 30 min to reach saturation. After that, the saturated materials were weighed again; the sorption capacity was calculated by Equation (1) [45], where Wi and Wt are the weights before and after absorption, respectively.
The reusability of sorbent was estimated by repeated sorption and squeezing processes. The sorbent material was soaked into liquid, and the absorbed liquid within the sample was recovered by manual squeezing. The process was repeated for several cycles [46].

H NMR Spectroscopy for Lignin
The chemical structure of lignin was assessed by H NMR (Figure 3). The obtained spectra showed that the sample of lignin had signals in the range of 2.5-3.5 ppm, which Materials 2021, 14, 3950 6 of 17 was assigned to DMSO (solvent). It also displayed signals in the range of 4.0-3.5 ppm, assigned to protons in methoxyl groups. Furthermore, lignin had the most important of all signals in the range between 6 and 8 ppm, which could be attributed to aromatic protons. The signals in ranges of 7.4-7.5, 7.3-6.8, and 6-6.8 ppm were attributed to p-hydroxyphenyl (H), guaicyl (G), and syringyl (S) units, respectively [47,48].
cesses. The sorbent material was soaked into liquid, and the absorbed liquid within the sample was recovered by manual squeezing. The process was repeated for several cycles [46].

H NMR Spectroscopy for Lignin
The chemical structure of lignin was assessed by H NMR (Figure 3). The obtained spectra showed that the sample of lignin had signals in the range of 2.5-3.5 ppm, which was assigned to DMSO (solvent). It also displayed signals in the range of 4.0-3.5 ppm, assigned to protons in methoxyl groups. Furthermore, lignin had the most important of all signals in the range between 6 and 8 ppm, which could be attributed to aromatic protons. The signals in ranges of 7.4-7.5, 7.3-6.8, and 6-6.8 ppm were attributed to p-hydroxyphenyl (H), guaicyl (G), and syringyl (S) units, respectively [47,48].

FTIR Analysis
The Fourier transform infrared spectra (FTIR) method was used to describe the characteristics of functional groups present in the structure of the blend sponge with and without POSS ( Figure 4). Polypropylene showed peaks at 2949, 2916, 2866, 2837, and 1375 cm −1 that were attributed to the C-H stretching. The peaks at 1375, 1358 and 1330 cm −1 represent the syringyl group, the -CH 3 bonding, and the C-O stretch, respectively [18]. The spectra of all the blends had these peaks, as can be seen in Figure 4a.
Further, it was observed that the lignin peak at 3500 cm −1 corresponded to hydroxyl groups. This vibration of hydroxyl groups was visible also in PP10L and PP20L. On the other hand, with the addition of lignin to PP, a peak of aromatic skeletal vibrations was found at 1510 cm −1 , which was more intense at higher lignin content. Anther essential structure in lignin was a weak shoulder at 1710 cm −1 , which is associated with conjugated carbonyl stretching [49].
The FT-IR spectra of blend sponges with POSS are shown in Figure 4b. Strong peaks at 1060 and 1003 cm −1 were observed, characteristic of the Si-O-Si stretching. The peak at 1603 cm −1 was associated with C=C stretching vibration of the vinyl group, besides peaks around 1410 cm −1 assigned to C=C stretching [50]. The peak at 779 cm −1 was related to Si-C stretching vibration [51]. The peaks at 1595 cm −1 (aromatic C=C stretching), 1513 cm −1 (aromatic skeletal vibration rings), and 1455 cm −1 (C-H deformation) were visible in all the composites [16]. the composites [16].
It was observed the above peaks, representing bonds in POSS, appeared in all blend polymers after modification with POSS. The modification of the blended sponge with POSS is based on the interaction between the POSS molecule and the hydroxyl groups in lignin, which was proven by the disappearance of the peaks of hydroxyl groups in the range of 3400-3600 cm −1 . This indicated that lignin and POSS were successfully incorporated into the composites [52,53].

Thermal Gravity Analysis
Thermal gravity analysis (TGA) is a widely used tool to evaluate the thermal degradation behaviour of tested samples. The mass loss of the tested sponges was shown as a function of temperature on thermogravimetric (TG) and derivative of thermogravimetric (DTG) curves ( Figures 5-7). The corresponding data, such as the temperature at 5% mass It was observed the above peaks, representing bonds in POSS, appeared in all blend polymers after modification with POSS. The modification of the blended sponge with POSS is based on the interaction between the POSS molecule and the hydroxyl groups in lignin, which was proven by the disappearance of the peaks of hydroxyl groups in the range of 3400-3600 cm −1 . This indicated that lignin and POSS were successfully incorporated into the composites [52,53].

Thermal Gravity Analysis
Thermal gravity analysis (TGA) is a widely used tool to evaluate the thermal degradation behaviour of tested samples. The mass loss of the tested sponges was shown as a function of temperature on thermogravimetric (TG) and derivative of thermogravimetric (DTG) curves ( Figures 5-7). The corresponding data, such as the temperature at 5% mass loss (T5%), at 10% mass loss (T10%), and at 50% mass loss (T50%), the initial decomposition temperature (Tonset), the peak of DTG, and charred residue at 600 • C are listed in Table 3. Figure 5a, b displays the TG and DTG curves of lignin and POSS. The thermal degradation of lignin was divided into three distinct regions ( Figure 5). In the first one, degradation occurred between 30 and 100 • C, where mainly the gradual evaporation of moisture can explain the weight loss. In the second region, the heavy loss of lignin degradation process occurred between 182 and 500 • C, and the DTG peak for lignin occurred at 360 • C. The third region ranged from 510 to 700 • C. According to the TG curve, the onset degradation temperature of lignin was at 225 • C, and the charred yield was found at 54.56%. Lignin has high thermal stability, which is attributed to the presence of a complex phenyl propanoid unit [54].
The thermal stability of POSS is shown in Figure 5. It was observed that POSS followed one single step with degradation starting at 263.50 • C with DTG at 311.12 • C and the char yield at 600 • C was around 8.88% [55].
Moreover, it was observed that PP exhibited a one-step degradation process in the temperature range of 30 to 700 • C ( Figure 6). Meanwhile, a modified blend sponge with lignin content 10%, with and without POSS, showed similar degradation behaviour in the same temperature range. In contrast, the blend sponges with a lignin content of 20% had two strong peaks (the corresponding DTG curves are in Figure 7 and all parameters in Table 3). This suggests that the chemical modification does not change the degradation mechanism.           Polypropylene started to degrade at 468.92 • C, the degradation continued until 497.65 • C with a remarkable char residue (1.40%) at 600 • C. Moreover, this behaviour was also observed in the thermal behaviour of composites blended with 10-20 wt% lignin. However, the results showed clearly that the addition of lignin at 10% would increase the onset of the temperature of the thermal degradation more than PP itself. In comparison, the thermal test analysis showed that a higher content of lignin in the blend matrix would reduce its thermal stability, as it was apparent on the tested sample PP20L, where the onset of the temperature of the thermal degradation was lower than the one of PP [56]. At the same time, the percentage of charred residues of the blend monolith at 600 • C was of 2.63 and 3.47% higher than for PP itself. This result is explained by the aromatic chemical structure of lignin in the blends, which gives high amounts of char at the evaluated temperature [57].
The influence of POSS on the thermal behaviour of blends was also investigated. In the case of the work carried out under nitrogen atmosphere, it was notable the addition of POSS into the matrix of the sponge caused an increase in T5%, T10%, and T50% compared with a blended sponge without POSS (Table 3). Increasing POSS content in the matrix increased these values.
Generally, there was an increase in the Tonset under the nitrogen atmosphere, which w attributed to possible cross-linking between blend chains and the POSS silicone core, and a thermally stable ceramic char surface layer was formed by POSS cage and acted as a thermal barrier for materials. The amounts of POSS present in the blends also affected the thermal stability due to significant enhancement with POSS. The increases in decomposition temperatures of PP10L-0.1P and PP20L-0.1P were 455.61 and 388.22 • C, whereas in the case of PP10L-0.3P and PP20L-0.3P, they were 463.78 and 399.50 • C, respectively.
Further, all POSS used here improved the temperature of the maximum weight loss rate ( Figure 6). Another essential factor that was observed in the TG analysis was the charred residue yield. With an increase in the quantity of the inorganic additive POSS in the blend sponge, the percentage of charred residues increased [58]. The increase in char residue yield with increasing POSS content was of 4.55% (PP10L-0.1P), 7.11% (PP20L-0.1P), 5.30% (PP10L-0.3P), and 10.56% (PP20L-0.3P), as listed in Table 3.

Differential Scanning Calorimetry (DSC)
The DSC curves of polypropylene and its blends with and without POSS are shown in Figure 8. The relative parameters, such as melting temperature (Tm), melting enthalpy (∆Hm), and degree of crystallinity (X C ), are summarized in Table 4. The percentage crystallinity (Xc) of PP and its blends with lignin and POSS was calculated according to the following Equation (2).
where W is the mass of the PP in the blends, ∆H m is the melting enthalpy of PP and their blends, ∆H o m (209 J/g) is the reference value that denotes the melting enthalpy of PP crystals [59]. blend sponge with lignin had lower melting enthalpy values; this was due to the incorporation of lignin. Furthermore, the melting temperature of the blend was lower than that of neat PP, which might be explained by the low molecular weight of lignin which acts as a plasticizer [60]. However, the addition of POSS to the mixture imparted a slight increase in relative parameters. The melting temperature of the blend sponge increased with increasing the POSS content. This demonstrated that the heterogeneous crystal nucleation of the blend can be enhanced by the silica nanoparticle content of POSS [61].   It was observed that neat PP had a melting enthalpy ∆H m of 101 J/g, whereas the blend sponge with lignin had lower melting enthalpy values; this was due to the incorporation of lignin. Furthermore, the melting temperature of the blend was lower than that of neat PP, which might be explained by the low molecular weight of lignin which acts as a plasticizer [60]. However, the addition of POSS to the mixture imparted a slight increase in relative parameters. The melting temperature of the blend sponge increased with increasing the POSS content. This demonstrated that the heterogeneous crystal nucleation of the blend can be enhanced by the silica nanoparticle content of POSS [61].

Morphology Observation
Surface topography is an important factor for studying the wettability of materials surfaces. Figure 9 shows the SEM images of PP, PP10L, and their forms modified with POSS. The surface of the blend sponge without POSS seemed to be rough due to lignin aggregations (Figure 9b). The tested sponge also displayed a turbid nature due to the phase separation. However, the surface of the blend sponge with POSS was rather smooth with no detected POSS particles on the surface (Figure 9c,d). With increasing POSS content in the blend sponge, its surface became smoother [62]. In this case, the nanoparticles of POSS improved the dispersed lignin particles in the sponges and formed a good surface condition [63].
POSS. The surface of the blend sponge without POSS seemed to be rough due to lignin aggregations (Figure 9b). The tested sponge also displayed a turbid nature due to the phase separation. However, the surface of the blend sponge with POSS was rather smooth with no detected POSS particles on the surface (Figure 9c,d). With increasing POSS content in the blend sponge, its surface became smoother [62]. In this case, the nanoparticles of POSS improved the dispersed lignin particles in the sponges and formed a good surface condition [63].

Surface Properties
The surface wettability of the samples is another interesting factor; it was studied by measuring the static contact angles between samples and water. The measured surface free energies are summarized in Table 5. The incorporation of POSS within the blends was essential to the surface energy and surface hydrophobicity [64]. It can be deduced from Figure 10 and Table 5 that with an increase in the POSS content, the hydrophobicity of tested samples was clearly enhanced. The water contact angle of PP20L increased from 107° to 128.51° with 0.1% POSS and increased to 139.67° with 0.3% POSS, which meant

Surface Properties
The surface wettability of the samples is another interesting factor; it was studied by measuring the static contact angles between samples and water. The measured surface free energies are summarized in Table 5. The incorporation of POSS within the blends was essential to the surface energy and surface hydrophobicity [64]. It can be deduced from Figure 10 and Table 5 that with an increase in the POSS content, the hydrophobicity of tested samples was clearly enhanced. The water contact angle of PP20L increased from 107 • to 128.51 • with 0.1% POSS and increased to 139.67 • with 0.3% POSS, which meant more hydrophobic POSS molecules migrated to the surface of the samples as POSS content increased. Incidentally, the incorporation of POSS in PP10L and PP20L was necessary to lower the surface free energy, as already stated in Table 5. The presence of the Si-O-Si network structures in the blend matrix provided thermodynamic motion from the inside to outside and a smoother surface, resulting in reduced surface free energy. more hydrophobic POSS molecules migrated to the surface of the samples as POSS content increased. Incidentally, the incorporation of POSS in PP10L and PP20L was necessary to lower the surface free energy, as already stated in Table 5. The presence of the Si-O-Si network structures in the blend matrix provided thermodynamic motion from the inside to outside and a smoother surface, resulting in reduced surface free energy.

Organic Solvents/Oil Sorption
The blended sponges fabricated using the TIPS method can be considered as promising sorbents for oil spillage clean-up due to their 3D interconnected macroporous structures, hydrophobicity, and oleophilicity, resulting from mixing of lignin and POSS support micro/nanoscale structures, as discussed above. For further investigation of the absorption capacities of these blends of polypropylene/lignin with and without POSS for potential application in the clean-up of polluted oil spills, more experiments were set up using oils and organic solvents. The results are demonstrated in Figure 11 and Table 6.

Organic Solvents/Oil Sorption
The blended sponges fabricated using the TIPS method can be considered as promising sorbents for oil spillage clean-up due to their 3D interconnected macroporous structures, hydrophobicity, and oleophilicity, resulting from mixing of lignin and POSS support micro/nanoscale structures, as discussed above. For further investigation of the absorption capacities of these blends of polypropylene/lignin with and without POSS for potential application in the clean-up of polluted oil spills, more experiments were set up using oils and organic solvents. The results are demonstrated in Figure 11 and Table 6.
The synthesized sponges displayed good absorption capability for the various liquids and oils used. Their absorption capacity was evaluated as follows: A piece of the sponge was placed in contact with liquids dispersed on a water surface, as shown in Figure 12. The floating liquid was absorbed into the sponge via capillary forces in only a few minutes. Showing the excellent sorption capacity of the blend sponge.
Further, it was noticed that sponges modified with POSS exhibited higher sorption capacity due to the improved hydrophobicity, which ensured that water was completely rejected. It was also evident that there was a clear correlation between the volume of absorbed oil and the POSS content, which could be attributed to the increased lipophilic properties with an increase in POSS content. For example, sponges with 0.3% POSS absorbed oil more than sponges with 0.1% POSS [65]. When the sorbent sample was placed on the water surface, it floated. The absorbed oil was easily recovered by repeatedly squeezing the oil-laden sorbent without losing its excellent hydrophobicity. The absorbed solvent was collected by simple manual squeezing repeatedly, as seen in Figure 13. Furthermore, the sponge could be reused after easy washing with volatile liquid and then drying at room temperature. The sorption capacities of these blend sponges was further compared with those from previous studies (Table 7).  Further, it was noticed that sponges modified with POSS exhibited higher sorption capacity due to the improved hydrophobicity, which ensured that water was completely rejected. It was also evident that there was a clear correlation between the volume of absorbed oil and the POSS content, which could be attributed to the increased lipophilic properties with an increase in POSS content. For example, sponges with 0.3% POSS absorbed oil more than sponges with 0.1% POSS [65]. When the sorbent sample was placed  on the water surface, it floated. The absorbed oil was easily recovered by repeate squeezing the oil-laden sorbent without losing its excellent hydrophobicity. The absor solvent was collected by simple manual squeezing repeatedly, as seen in Figure 13. F thermore, the sponge could be reused after easy washing with volatile liquid and t drying at room temperature. The sorption capacities of these blend sponges was fur compared with those from previous studies ( Table 7).

Conclusions
In summary, we presented a facile method of fabrication eco-friendly blend sponges from PP, lignin, and POSS using an efficient way, namely, the thermally induced phase separation (TIPS). The influence of POSS on the surface wettability and thermal properties was deeply studied. The newly prepared sponges displayed high thermal stability with POSS compared with one without POSS. A DSC analysis showed that POSS had a significant influence on melting temperatures. SEM results indicated that the addition of POSS nanoparticles could enhance the dispersion and compatibility of the lignin in matrix systems by making the surface smoother.
Meanwhile, POSS formed silicon bonds that protected the sponges from water penetration with water contact angles more than 125 • , combined with improving oleophilicity, which significantly enhanced with increasing POSS content. The sorption tests for obtained sponges showed that POSS-based sponge absorbed oils and organic solvents more, and the sponge with POSS content exhibited higher sorption compared to the one without POSS. The experimental results of the sorption test also indicated that the blend sponge with an addition of 10% lignin and 0.3% POSS had the best performance. Hence, the proposed eco-friendly and inexpensive sponges with good thermal stability and wettability could be feasibly applied in water cleanup operations on an industrial scale.