Magnetite/Poly(ortho-anisidine) Composite Particles and Their Electrorheological Response

Magnetic and semiconducting Fe3O4/poly(o-anisidine) (POA) core/shell composite particles were fabricated by an oxidation process using Fe3O4 synthesized separately. The dispersion stability in a liquid medium and the electrical conductivity of synthesized particles were improved because of the conductive POA polymeric shell. The morphological, microstructural, compositional/elemental, and thermal behaviors of the particles were characterized using SEM with energy dispersive X-ray spectroscopy, TEM, XRD, and thermogravimetric analysis, respectively. A smart electro-magneto-rheological suspension containing Fe3O4/POA particles with two functionalities, magnetism and conductivity, was prepared. Its electrorheological properties were investigated at different electric field strengths using a rotational rheometer. Without an electric field, the sample demonstrated typical Newtonian fluid behavior, as expected. However, while under the electric field, it exhibited a solid-like behavior, and the dynamic (or elastic) yield stress of the ER fluid increased linearly as a function of the electric field strength in a power-law function with an index of 2.0, following the polarization mechanism.


Introduction
Electrorheological (ER) suspensions are smart materials that exhibit rapid changes in their rheological behaviors under an input electric field strength (E) [1,2], in which electroresponsive particles are dispersed in electrically insulating liquids, including mineral oil and silicone oil [3,4]. Their rheological behavior can be fine-tuned by adjusting the strength of the external electric field. Without an external E, they behave as Newtonian fluids [5]. However, when an E is applied, dipoles within the particles are driven [6][7][8]. Thus, the particles are aligned in the direction of the E owing to electric dipole-dipole interactions between the particles, forming a chain structure and changing its phase to a solid-like state within milliseconds [9][10][11]. This behavior is reversible when the E is removed again, wherein it returns to the liquid state and exhibits Newtonian fluid-like behavior [12][13][14][15][16][17]. Due to their artificial controllability and drastic responses and excellent mechanical properties with high yield stresses, ER suspensions have been adopted in various industrial fields such as clutches, brakes, dampers, and shock absorbers [18,19].
Among the various potential electro-responsive materials for ER suspensions, conducting polymers, such as polyaniline (PANI), polydiphenylamine (PDPA), and polypyrrole (PPy) [20][21][22][23], have been widely adopted because of their controllable electrical conductivity and dielectric properties. In addition, conductive polymer/inorganic composite particles with various shapes have been introduced to improve ER performance. In order to minimize the energy generated by their large surface volume ratio, nanoparticles tend to form aggregates, leading to a decrease in the efficiency in the ER fluids. However, by preparing the polymeric shell structure around the particles, the nanoparticles cannot be preparing the polymeric shell structure around the particles, the nanoparticles cannot be agglomerated and precipitated, keeping the dispersion stability for a long time [24][25][26]. In particular, particles with a variety of core-shell structured-combinations, including conductive shell/dielectric cores or conductive shell/magnetic cores, are widely used owing to their synergetic combination of the respective functional properties provided from the core and shell [27][28][29][30].
In contrast, soft-magnetic carbonyl iron (CI) spheres, used as cores of composite particles, have been widely applied to magnetorheological (MR) fluids because of their excellent controllable magnetic properties and suitable and tunable particle size [31][32][33]. Although CI particles have several such advantages, CI particle-based MR fluids face problems of sedimentation and re-dispersion owing to their high density (approximately 8.0 g/cm 3 ), which limits their engineering applications [34][35][36]. In order to overcome these problems, magnetite (Fe3O4) particles with relatively low density and sufficient magnetic responses can be selected. However, there are still problems which need to be improved, such as the Fe 2+ in Fe3O4 particles [37,38] being easily oxidized or corroded in the air. Covering the surface of Fe3O4 particles with organic polymers could help overcoming the problem of Fe 2+ being oxidized [39,40], and make Fe3O4 particles have better dispersion stability in ER fluids [41,42]. In particular, coating with conducting polymers can produce composite particles with conductive shell/magnetic core structures that can be used not only for MR, but also for ER suspensions [43,44].
Polyaniline (PANI) is an attractive conducting polymer because of its higher corrosion resistance compared to other conducting polymers and its easily tunable conductivity [45]. However, its application is severely limited by its poor solubility, workability, and adhesion between the material and metal materials and pinhole defects [46,47]. The introduction of alkyl, alkoxy, amine, and imine groups on the benzene ring can significantly enhance the physical characteristics and anti-corrosion behavior of PANI, possibly due to both steric restrictions and phi-electron effects [48]. In addition, the increased molecular size of the substituted PANI can facilitate better surface coverage and lead to better adhesion of the metal substrate. One of the PANI derivatives, poly(o-anisidine) (POA), whose chemical structure is shown in Scheme 1, is soluble in various solvents because the methoxy group at the benzene ring of POA is connected to the amino group, which provides good solution processing properties. Related to its electrical conductivity, in particular, it can be directly applied to ER fluids owing to its semiconducting properties. Here, we prepared Fe3O4/POA (core/shell) composite particles by coating the synthesized Fe3O4 particles with POA, which has high reactivity and easily controllable conductivity, and fabricated a suspension with composite particles. Fe3O4/POA composite particles possessing a combination of dielectricity and magnetism particles showed dual stimuli responses. It can be further noted that our Fe3O4/POA (core/shell) composite particles possess advantages compared to previously reported Fe3O4/PANI [41] and Fe3O4/TiO2 [49] (core/shell) composite particles in which the PANI needs to be de-doped for ER measurements, and inorganic TiO2 might not provide a better dispersibility than POA in terms of its density. The morphologies and structures, sizes, compositions, and thermal stabilities of the Fe3O4/POA composite particles were tested using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). We discuss the ER behavior of the fabricated suspensions Here, we prepared Fe 3 O 4 /POA (core/shell) composite particles by coating the synthesized Fe 3 O 4 particles with POA, which has high reactivity and easily controllable conductivity, and fabricated a suspension with composite particles. Fe 3 O 4 /POA composite particles possessing a combination of dielectricity and magnetism particles showed dual stimuli responses. It can be further noted that our Fe 3 O 4 /POA (core/shell) composite particles possess advantages compared to previously reported Fe 3 O 4 /PANI [41] and Fe 3 O 4 /TiO 2 [49] (core/shell) composite particles in which the PANI needs to be de-doped for ER measurements, and inorganic TiO 2 might not provide a better dispersibility than POA in terms of its density. The morphologies and structures, sizes, compositions, and thermal stabilities of the Fe 3 O 4 /POA composite particles were tested using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). We discuss the ER behavior of the fabricated suspensions with the composite particles under various Es using a rotational rheometer in this paper, in addition to the MR characteristics demonstrated in a previous publication [50].

Preparation of Fe 3 O 4 and Fe 3 O 4 /POA Core-Shell Particles
The synthesis of Fe 3 O 4 particles and the fabrication process of Fe 3 O 4 /POA coreshell composite particles were described in detail in our previous publication [50]. Fe 3 O 4 particles were synthesized using a solvothermal process using a Teflon-coated stainlesssteel autoclave. The resulting Fe 3 O 4 particles were then placed in a reactor containing 0.1 M HCl under stirring for 10 h at 5 • C. Then, both ethanol (100 mL, DUCKSAN, Gwangju-si, Korea) and ortho-anisidine monomer (1 mL, DUCKSAN, Gwangju-si, Korea) were added to the reactor in a nitrogen atmosphere. After 8 h, 12 M HCl and ammonium persulfate were added dropwise to the mixture for 30 min. The resulting Fe 3 O 4 particles coated with POA were then cleaned with ethyl alcohol and distilled water several times and dried in an oven for 1 day.
Finally, an ER suspension with 10 vol% of the prepared Fe 3 O 4 /POA composite particles was fabricated and dispersed uniformly in silicone oil with a viscosity of 100 cSt.

Characterization
The morphology and elemental component of the Fe 3 O 4 /POA composite particles were characterized by high-resolution SEM ((HR-SEM, SU-8010, Hitachi, Tokyo, Japan) at 15 kV, 8.0 mm × 120 k (magnification) SE (U) coupled with energy-dispersive X-ray spectroscopy (EDS) peaks ranging from 0 to 8 keV (EX-250, HORIBA, Kyoto, Japan) at 15 kV, 15.0 mm × 2 k SE (U). TEM (CM-220, Phillips, Amsterdam, The Netherlands) was used to observe the core-shell structure of the composite particles, while XRD (DMax-2500, Rigaku, Tokyo, Japan, 2θ range from 10 to 80 degree) analysis was used to study the crystal structures of the fabricated particles. The thermal stabilities of the Fe 3 O 4 and POA/Fe 3 O 4 particles were further measured and compared with those of pure POA molecules using TGA (TG 209 F3, NETZSCH, Gebrüder, Germany) by heating to 800 • C (heating rate: 10 • C/min) in nitrogen environment. The ER characteristics of the smart suspension with the prepared Fe 3 O 4 /POA composite particles were obtained using a rotational rheometer (MCR300, Anton Paar, Graz, Austria) with an electric field from 0 to 2 kV/mm, which was connected to a high-voltage supplier (HCN 7E-12500, FuG Elektronik, Germany) along with a concentric cylinder mode (CC 17/E). The tables indicate that the carbon content increased from 15.11% to 29.74%, due to the shell portion formed by coating the pure Fe 3 O 4 particles with POA. Figure 3 display the TEM images of the fabricated Fe 3 O 4 and Fe 3 O 4 /POA composite particles, respectively. It can be observed that the Fe 3 O 4 /POA particles are in the core-shell type that was most probably induced by absorbing ortho-anisidine monomers on the surface of the Fe 3 O 4 particles through hydrogen bonding and electrostatic attraction after acidification of the Fe 3 O 4 spheres with HCl. The surface of the Fe 3 O 4 particles was modified only through the acidification step, and no other surface treatments were necessary. The average diameter of the Fe 3 O 4 particles was estimated to be roughly 300 nm, and the mean thickness of the POA shell was around 60 nm. The observed core-shell form of the composite particles indicates that the Fe 3 O 4 particles were successfully coated with the conducting POA molecules and exhibited electric and magnetic properties concurrently. Furthermore, an FT-IR analysis of the POA-coated spheres confirming their synthesis can be found in our previous report [50].   Figure 3 display the TEM images of the fabricated Fe3O4 and Fe3O4/POA composite particles, respectively. It can be observed that the Fe3O4/POA particles are in the core-shell type that was most probably induced by absorbing ortho-anisidine monomers on the surface of the Fe3O4 particles through hydrogen bonding and electrostatic attraction after acidification of the Fe3O4 spheres with HCl. The surface of the Fe3O4 particles was modified only through the acidification step, and no other surface treatments were necessary. The average diameter of the Fe3O4 particles was estimated to be roughly 300 nm, and the mean thickness of the POA shell was around 60 nm. The observed core-shell form of the composite particles indicates that the Fe3O4 particles were successfully coated with the conducting POA molecules and exhibited electric and magnetic properties concurrently. Furthermore, an FT-IR analysis of the POA-coated spheres confirming their synthesis can be found in our previous report [50].   Figure 3 display the TEM images of the fabricated Fe3O4 and Fe3O4/POA composite particles, respectively. It can be observed that the Fe3O4/POA particles are in the core-shell type that was most probably induced by absorbing ortho-anisidine monomers on the surface of the Fe3O4 particles through hydrogen bonding and electrostatic attraction after acidification of the Fe3O4 spheres with HCl. The surface of the Fe3O4 particles was modified only through the acidification step, and no other surface treatments were necessary. The average diameter of the Fe3O4 particles was estimated to be roughly 300 nm, and the mean thickness of the POA shell was around 60 nm. The observed core-shell form of the composite particles indicates that the Fe3O4 particles were successfully coated with the conducting POA molecules and exhibited electric and magnetic properties concurrently. Furthermore, an FT-IR analysis of the POA-coated spheres confirming their synthesis can be found in our previous report [50].   Figure 4 shows an XRD pattern between 10° and 80° for the POA molecules and Fe3O4/POA and pure Fe3O4 particles. The peaks in the pattern (Figure 4a) for the pure conducting POA molecules are also similar to those of other typical polymers exhibiting    Figure 4 shows an XRD pattern between 10° and 80° for the POA molecules and Fe3O4/POA and pure Fe3O4 particles. The peaks in the pattern (Figure 4a) for the pure conducting POA molecules are also similar to those of other typical polymers exhibiting broad peaks at low angles. The pattern of the Fe3O4/POA composite particles (Figure 4b) showed more amorphous peaks in the low 2θ range (20-30° 2θ) due to the POA shell part compared to the pure Fe3O4 particles, for which the peaks of the crystal structure at 2θ were 18.31°, 30.11°, 36.51°, 43.21°, 53.51°, 57.11°, and 62.61° [51] (Figure 4c). When the Fe3O4/POA, pure Fe3O4 particles, and pure POA were heated under a 99% nitrogen environment, their weight changed with temperature, as shown in Figure 5. The TGA curve of the fabricated Fe3O4 particles showed a slight weight loss over the entire temperature range, as expected ( Figure 5a). The weight loss at approximately 100 °C was caused by moisture evaporation. Above that, the decomposition of the POA steadily reduced the weight up to 600 °C and 800 °C for Fe3O4/POA and Fe3O4 particles, respectively, owing to the large-scale thermal decomposition of the POA chains [52] (Figure 5b,c). Moreover, at temperatures up to 800 °C, 63.5% of the POA and 44.8% of the Fe3O4/POA composite particles were decomposed. The interaction between the Fe3O4 particles and the POA chains probably limited the thermal motion of the Fe3O4 particles and could provide thermal stability to the composite particles. These results also indicate that the mag- When the Fe 3 O 4 /POA, pure Fe 3 O 4 particles, and pure POA were heated under a 99% nitrogen environment, their weight changed with temperature, as shown in Figure 5. The TGA curve of the fabricated Fe 3 O 4 particles showed a slight weight loss over the entire temperature range, as expected ( Figure 5a). The weight loss at approximately 100 • C was caused by moisture evaporation. Above that, the decomposition of the POA steadily reduced the weight up to 600 • C and 800 • C for Fe 3 O 4 /POA and Fe 3 O 4 particles, respectively, owing to the large-scale thermal decomposition of the POA chains [52] (Figure 5b,c). Moreover, at temperatures up to 800 • C, 63.5% of the POA and 44.8% of the Fe 3 O 4 /POA composite particles were decomposed. The interaction between the Fe 3 O 4 particles and the POA chains probably limited the thermal motion of the Fe 3 O 4 particles and could provide thermal stability to the composite particles. These results also indicate that the magnetic properties of the coated Fe 3 O 4 /POA composite particles decreased due to the decrease in saturation magnetization resulting from the addition of a non-magnetic POA shell. Their densities, measured using a gas pycnometer (AccuPyc 1130), also decreased, from 4.34 g/cm 3 to 2.52 g/cm 3 [50].

Electrorheological (ER) Characteristics
The ER behavior of the suspension with the 10 vol% Fe 3 O 4 /POA composite particles suspended in silicone oil (100 cSt at 25 • C) under various electric fields was scrutinized using a rheometer equipped with a concentric cylinder (CC) mode at room temperature. Constant steady shear flow tests of the Fe 3 O 4 /POA-based ER suspension were performed as the E increased from 0 to 2 kV/mm. The shear stress (τ) and shear viscosity of the ER fluid are shown as a function of the shear rate in Figure 6a,b, respectively. Without an electric field, its viscosity over the shear rate was shown to change slightly, and its shear stress increased linearly with increased shear rate. These results indicate that the Fe 3 O 4 /POA-based ER suspension behaved as a Newtonian fluid without an applied external E. In addition, the shear viscosity of the overall suspension was slightly higher than that of pure silicone oil because of the addition of 10 vol% Fe 3 O 4 /POA particles. Meanwhile, when an E was applied, the suspension showed both a solid-like behavior with a yield stress and the shear stress with a flat region over the entire shear rate. The yield stress, which is the minimum shear stress needed to break a particle chain-like structure formed under an electric field applied between cylinders, viscosity, and the flat region of shear stress of the suspension increased with increasing the applied E. As for the shear viscosity of the sample suspension, due to the application of the electric field, the dispersed particles in the fluid formed a chain-like structure; thus, the overall viscosity increased with the increase in the electric field. netic properties of the coated Fe3O4/POA composite particles decreased due to the decrease in saturation magnetization resulting from the addition of a non-magnetic POA shell. Their densities, measured using a gas pycnometer (AccuPyc 1130), also decreased, from 4.34 g/cm 3 to 2.52 g/cm 3 [50].

Electrorheological (ER) Characteristics
The ER behavior of the suspension with the 10 vol% Fe3O4/POA composite particles suspended in silicone oil (100 cSt at 25 °C) under various electric fields was scrutinized using a rheometer equipped with a concentric cylinder (CC) mode at room temperature. Constant steady shear flow tests of the Fe3O4/POA-based ER suspension were performed as the E increased from 0 to 2 kV/mm. The shear stress (τ) and shear viscosity of the ER fluid are shown as a function of the shear rate in Figure 6a,b, respectively. Without an electric field, its viscosity over the shear rate was shown to change slightly, and its shear stress increased linearly with increased shear rate. These results indicate that the Fe3O4/POA-based ER suspension behaved as a Newtonian fluid without an applied external E. In addition, the shear viscosity of the overall suspension was slightly higher than that of pure silicone oil because of the addition of 10 vol% Fe3O4/POA particles. Meanwhile, when an E was applied, the suspension showed both a solid-like behavior with a yield stress and the shear stress with a flat region over the entire shear rate. The yield stress, which is the minimum shear stress needed to break a particle chain-like structure formed under an electric field applied between cylinders, viscosity, and the flat region of shear stress of the suspension increased with increasing the applied E. As for the shear viscosity of the sample suspension, due to the application of the electric field, the dispersed particles in the fluid formed a chain-like structure; thus, the overall viscosity increased with the increase in the electric field. The viscoelastic behavior of the Fe 3 O 4 /POA-based ER suspension was analyzed by measuring the storage modulus (G ) and loss modulus (G ) through dynamic oscillatory tests. The evaluation of the behaviors of ER fluids at sufficiently low oscillating strain amplitudes has been established as an adequate method to examine their dynamic deformation behaviors when their structures are not destroyed in the linear viscoelastic region (LVE). Figure 7 shows the G and G of the ER suspension at a fixed angular frequency of 1 Hz as a function of strain. The G and G of the suspension in the absence of an E exhibited similar values in the initial shear strain range. However, under an applied E, the G was much larger than the G . This implies that a strong phase transition in the suspension occurred under an applied E. The LVE of the suspension widened with increasing electric field strength. This indicated the solidification ability of the EP particles. When the strain exceeded the LVE, its storage modulus decreased because the chain-like microstructure of the ER suspension was deformed and broken, decreasing the G and G ; this is known as strain softening, also called the Payne effect [53,54]. In the high strain region, its G was larger than its G , which meant that the ER suspension exhibited viscoelastic fluid properties. A strain of 0.004% from the LVE was selected for frequency sweep tests of the suspension, and at a constant strain of 0.004%, the G and G values of the Fe 3 O 4 /POA-based suspension under four different Es were determined as functions of angular frequency (see Figure 8). Its G values were higher than the G values over the whole angular frequency range, indicating that the elastic behavior of the ER suspension dominated its viscous behavior. In addition, both moduli almost showed a plateau and increased with increasing E over the entire frequency range, which indicated that the elastic and viscous properties of the ER suspension increased when a higher E was applied. In other words, the stronger the E produced, the stronger the chain-like structure and damping property of the ER fluid. The viscoelastic behavior of the Fe3O4/POA-based ER suspension was analyzed by measuring the storage modulus (G′) and loss modulus (G″) through dynamic oscillatory tests. The evaluation of the behaviors of ER fluids at sufficiently low oscillating strain am-  Figure 9 presents the elastic stress, τ , obtained through a subsequent analysis using the relationship τ = G · γ, where γ is the strain amplitude of the suspension under various Es (from 0.5 to 2.0 kV/mm). The elastic yield stress was determined from the point where the τ approached the highest stress value just before decreasing because the chain-like structure formed in the ER suspension began to be destroyed; this point is indicated by a red circle for each curve.
quency range, indicating that the elastic behavior of the ER suspension dominated its viscous behavior. In addition, both moduli almost showed a plateau and increased with increasing E over the entire frequency range, which indicated that the elastic and viscous properties of the ER suspension increased when a higher E was applied. In other words, the stronger the E produced, the stronger the chain-like structure and damping property of the ER fluid. Figure 9 presents the elastic stress, , obtained through a subsequent analysis using the relationship = · , where is the strain amplitude of the suspension under various Es (from 0.5 to 2.0 kV/mm). The elastic yield stress was determined from the point where the approached the highest stress value just before decreasing because the chain-like structure formed in the ER suspension began to be destroyed; this point is indicated by a red circle for each curve.         (1)) [55]. The G(t) of the ER suspension under an E showed a plateau over time, due to the solid-like behavior of the suspension, while G(t) decreased linearly because of its fluid-like behavior without an E.
The dynamic yield stress, which was determined by extrapolating the τ to the zerolimit shear rate in the flow curve (see Figure 6), and the elastic yield stress determined from the red circle in the elastic stress curve (see Figure 9) for the Fe 3 O 4 /POA-based ER fluid, are shown as a function of E in Figure 11. When an E was applied, the plot of yield stress τ y versus the electric field E typically showed an exponential relationship as follows: In general, the power-law index is 1.5 for a conduction mechanism and 2.0 for a polarization mechanism. The index for the Fe 3 O 4 /POA-based ER suspension was determined to be approximately 2, which indicated that the suspension followed the polarization model [23,56,57].
(G′(ω) and G″(ω), respectively) using the Schwarzl equation (Equation (1)) [55]. The G(t) of the ER suspension under an E showed a plateau over time, due to the solid-like behavior of the suspension, while G(t) decreased linearly because of its fluid-like behavior without an E.  Figure 10. Relaxation modulus, G(t), of the core-shell particle-based ER suspension, obtained by the storage and loss modulus obtained from a frequency sweep test and using Equation (2), as a function of time.
The dynamic yield stress, which was determined by extrapolating the to the zerolimit shear rate in the flow curve (see Figure 6), and the elastic yield stress determined from the red circle in the elastic stress curve (see Figure 9) for the Fe3O4/POA-based ER fluid, are shown as a function of E in Figure 11. When an E was applied, the plot of yield stress τy versus the electric field E typically showed an exponential relationship as follows: In general, the power-law index is 1.5 for a conduction mechanism and 2.0 for a polarization mechanism. The index for the Fe3O4/POA-based ER suspension was determined to be approximately 2, which indicated that the suspension followed the polarization model [23,56,57]. Figure 10. Relaxation modulus, G(t), of the core-shell particle-based ER suspension, obtained by the storage and loss modulus obtained from a frequency sweep test and using Equation (2), as a function of time. . Dynamic and elastic yield stresses of the core-shell particle (10 vol%)-based ER suspension as a function of an electric field.

Conclusions
New core-shell-type Fe3O4/POA composite particles were fabricated by coating Fe3O4 particles with a conductive POA to enhance the dispersion stability of the particles and provide electrical conductivity to the particles based on our previously published results [50]. The Fe3O4 particles were synthesized via a hydrothermal method, and the core-shellstructured Fe3O4/POA composite particles were fabricated via the in situ oxidation polymerization of POA onto the surface of Fe3O4 particles. The POA shell not only effectively prevented the aggregation tendency of internal Fe3O4 particles, but also protected the internal particles from external oxidation and prevented changes in the original structure that might have occurred in the presence of other external magnetic fields. Their suc- Figure 11. Dynamic and elastic yield stresses of the core-shell particle (10 vol%)-based ER suspension as a function of an electric field.

Conclusions
New core-shell-type Fe 3 O 4 /POA composite particles were fabricated by coating Fe 3 O 4 particles with a conductive POA to enhance the dispersion stability of the particles and provide electrical conductivity to the particles based on our previously published results [50]. The Fe 3 O 4 particles were synthesized via a hydrothermal method, and the core-shell-structured Fe 3 O 4 /POA composite particles were fabricated via the in situ ox-idation polymerization of POA onto the surface of Fe 3 O 4 particles. The POA shell not only effectively prevented the aggregation tendency of internal Fe 3 O 4 particles, but also protected the internal particles from external oxidation and prevented changes in the original structure that might have occurred in the presence of other external magnetic fields. Their successful production of the core-shell form was confirmed by SEM and TEM analyses. The core size of the Fe 3 O 4 particles and shell thickness of the POA in the spherical composite core/shell particles were about 300 nm and 60 nm, respectively. This suitable and small particle size not only improved the stability of ER suspension, but also improved the ER effect when the electric field was applied.
The ER properties of the suspension prepared by dispersing the composite particles in an insulating silicone oil were studied using a rheometer for various electric field strengths. The G and G of the ER suspension displayed typical Newtonian fluid characteristics without an E, and increased with increasing E. The relaxation modulus obtained using the Schwarzl equation clearly showed a solid-like behavior under applied electric fields, compared to a liquid-like behavior without an E. Furthermore, the suspension also exhibited a yield stress because the higher electric field induced a more robust, chain-like structure. The apparent yield stress of the suspension was determined to be approximately 200 Pa at 2 kV/mm, and both dynamic and elastic yield stresses increased linearly with the E in a power-law function with a slope of 2.0, following the polarization mechanism.
The findings of this study suggest that a smart suspension containing Fe 3 O 4 /POA composite particles composed of a conducting shell and magnetic core under an applied external field exhibits significant ER properties. In addition, this Fe 3 O 4 /POA composite has a great possibility to be applied in various fields including brakes, dampers, elastomers, flexible tactile sensors, and advanced medical instruments, because of the high yield stress under weak electric fields.

Data Availability Statement:
The data presented in this study are available on request from the corresponding author.