Synthesis and Characterization of Cu2FeSnS4–Cu2MnSnS4 Solid Solution Microspheres

In this study, we used a hydrothermal method to synthesize microspheres of Cu2(Mn1−xFex)SnS4 solid solution (X = 1, 0.8, 0.6, 0.4, 0.2, 0). The process was optimized to improve the crystallinity, morphology, and purity of the obtained materials. All samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Raman spectroscopy, and Fourier transform infrared (FTIR) spectroscopy. The following conditions were optimized: A mixture of water and ethylene glycol at the ratio of 1:7 as the reaction medium, polyvinylpyrrolidone (PVP) as the surface ligand, and reaction temperature of 195 °C for 7 days. The product of synthesis precipitated in the form of aggregates of nanocrystals, which form homogeneous, often concentric microspheres with a diameter of 1–1.5 μm. The chemical composition of the product can be well controlled by the chemical composition of the reactants. The compound Cu2(Mn1−xFex)SnS4 forms a continuous series of solid solutions.


Introduction
In the current era of thin-film solar cells, it is necessary to produce low-cost, high-performance single-connector solar cells with high conversion efficiency. In contrast to most thin-film solar technologies, chalcopyrite-based thin solar cells using CuIn x Ga 1−x S(Se) 2 (CIGS) solar panels offer a potentially competitive efficiency to traditional silicon panels [1][2][3]. The highest efficiency of this material achieves 23.35 [4], but they are currently very expensive to produce and the components are rare and not environment friendly. Therefore, quaternary chalcogenide semiconductors of I 2 -II-IV-VI 4 series (where I = Cu and Ag; II = Zn, Cd, Fe, and Mn; IV = Si, Ge, and Sn; and VI = S and Se) have drawn great interest as an alternative absorber material in thin film solar cells that have reached 10% efficiency, and contains only nontoxic and Earth-abundant elements. They have potential applications not only as photovoltaic materials [5][6][7][8][9][10][11][12][13].
In this group, extensive research has been conducted on kesterites (Cu 2 ZnSnS 4 (CZTS)) and stannites (Cu 2 FeSnS 4 (CFTS)) [14,15]. Extensive characterization of the synthetic stannite-type material namely, Cu 2 MnSnS 4 (CMTS), has also been conducted. Similar to CFTS, CMTS is also considered as possible photovoltaic materials, due to its suitable bandgap and the requisite optical characteristics [16]. Several methods have been developed to fabricate these materials [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36]. A previous review article has described various methods to achieve this goal [37], which need different synthesis times (for example liquid reflux method takes 6-12 h [23], synthesized via microwave needs irradiatiion for 5 min [18] or sonochemical synthesis takes 3 h [38]). Some of these techniques require additional thermal annealing [28], which takes extra time. There is no consensus on the optimal processing method. Among these methods, the hydrothermal method has been widely used due to a simpler procedure, which is eco-friendly and economical in nature. Hydrothermal reactions have been successfully employed in the synthesis of various chemicals. A number of microporous solids have been synthesized using hydrothermal reactions. Various groups of researchers, such as geologists and mineralogists have also been able to determine the conditions necessary for their formation in nature. The use of hydrothermal synthesis facilitates the production of crystals of substances that are usually unstable near the melting point. In addition, it allows for the synthesis of large crystals with high quality. Hydrothermal synthesis can be effective both, at temperatures and pressures below the critical point for a specific solvent and under supercritical conditions. This method allows to control the chemical composition of the final product. One of the disadvantages of this method is the inability to monitor crystals during the process of their growth. Despite this, it is still popular among the industries producing nanomaterials. Although, several studies have used the conventional or microwave solvothermal/hydrothermal route for the synthesis of CZTS or CFTS, this technique still requires more work and optimization [37]. In a typical procedure, the synthesis of quaternary chalcogenide semiconductors takes 24 h [39].
Most I 2 -II-IV-VI 4 compounds crystallize with a zinc-blende (ZB) or wurtzite (WS)-type superstructure, showing the tetragonal stannite (ZB-derived) or the orthorhombic wurtzite-stannite (WS-derived) structure [1]. The crystal structure of phases in the solid solution series of Cu 2 FeSnS 4 -Cu 2 MnSnS 4 has been thoroughly examined in a previous study [40]. The authors determined a continuous solid solution in the series. The structure was described in the tetragonal system (the space group I-42m), where each cation is tetrahedrally coordinated to four sulfur anions in a sphalerite-like arrangement. However, several previous investigations have indicated that the formation of a certain crystal structure can be closely related to the reaction conditions [see 1 and the literature cited, therein]. So far, the methods of synthesis of CFTS-CMTS solid solution series are poorly studied. In a previous study [40], the material was synthesized using quartz ampoules sealed under Ar atmosphere and heated to 850 • C for about 72 h. This method may have little use in future industrial applications.
In this study, we prepared a series of compounds of Cu 2 (Mn 1−x Fe x )SnS 4 (X = 1, 0.8, 0.6, 0.4, 0.2, 0) in the form of spherical microparticles by using the hydrothermal synthesis method requiring simple reactants and relatively low temperature. We experimentally identified the optimal conditions for the synthesis of these compounds. This method the morphology and chemical composition of the resulting material to be controlled, which precipitates in the form of uniform microspheres composed of nanocrystals. It contributes to the development of production of photovoltaic materials with the required stoichiometry by means of a convenient synthesis technique by controlling the ratio of precursors.

Synthesis of Microspheres
The solutions of 1 mmol copper (II) chloride dihydrate, 0.5 mmol tin (IV) chloride pentahydrate, 0.5 mmol ferrous chloride tetrahydrate, 0.5 mmol manganese chloride tetrahydrate, and 2.5 mmol Tu were mixed in the proportions resulting in a molar ratio of Cu, (Mn + Fe), Sn, and S equal to 2:1:1:4. To obtain solutions with different content of Fe and Mn, the molar ratio of Fe/(Mn + Fe) in the solution was varied (0.0, 0.2, 0.4, 0.6, 0.8, and 1). The solution was mixed with 1.68 g PVP, 24-96 mL EG, and 0-72 mL double distilled water under magnetic stirring. Various concentrations of EG and H 2 O were prepared in different ratios: 1:0, 7:1, 3:1, 5:3, 1:1, 3:5, and 1:3. The mixture (96 mL) was transferred to two Teflon-lined containers and maintained at various temperatures (in the range of 160-195 • C) for various time intervals (from 1 to 14 days). The products were washed several times with water and acetone, centrifuged, and air-dried at 60 • C.

Characterization of Microspheres
The morphology of CFTS microspheres was characterized by using scanning electron microscopy (SEM, FEI Quanta 200 FEG and FEI Sirion 200, FEI, Hillsboro, OR, USA) equipped with secondary electron (SE) and back-scattered electron (BSE) detectors. An energy dispersive spectrometer (EDS, FEI Quanta (FEI, Hillsboro, OR, USA) was employed to monitor variations in the chemical composition of the microspheres. Samples of microspheres were fixed on a substrate with double-sided sticky tape and imaged without coating in a low vacuum. The selected samples were immersed in epoxy and polished to reveal the internal structure of the particles. Powder X-ray diffraction (XRD) patterns were recorded with Rigaku SmartLab diffractometer (Neu-Isenburg, Tokyo, Japan) in the range of 2-75 • 2θ with a step size of 0.05 • using graphite-monochromatized Cu Kα radiation. The phases were identified using the International Centre for Diffraction Data (ICDD) database and XRAYAN software (v 4.0.5, "KOMA" -Henryk Marciniak, Warszawa, Poland) [41]. For Raman spectroscopy, Thermo Scientific DXR Raman Microscope (Thermo Fisher Scientific, Waltham, MA, USA) was used. Spectra were recorded at room temperature with a green laser (k = 532 nm, laser power of 10 mW, slit aperture of 25 µm, resolution of 1.9 cm −1 in the range between 100 and 3579 cm −1 ). A total of 10 exposures of 3 s were taken for each spectrum. Spectra were interpreted with the aid of OMNIC for Dispersive Raman software (v 8.3.103, Thermo Fisher Scientific, Waltham, MA, USA). Infrared spectra were acquired using Bruker Sensor 27 spectrometer (BRUKER, Ettlingen, Germany) in the range of 400-4000 cm −1 (64 scans at the resolution of 1 cm −1 ). Prior to analysis, KBr pellets were prepared by homogenizing 200 mg of ground KBr with 4 mg of the sample.

Optimization of the EG:H 2 O Ratio
To obtain the optimum condition for the formation of isomorphic series of Cu 2 (Mn 1−x Fe x )SnS 4 microspheres, the effect of the reaction conditions (including the ratio of EG to H 2 O, the reaction temperature, and duration of the synthesis) on the morphological and structural properties of as-synthesized CFTS and CMTS microspheres was analyzed. In the next step, the optimum conditions were chosen to synthesize and characterize all the members of the stannite isomorphic series with Mn-Fe substitutions.
CFTS synthesized for 1 week at 195 • C with different proportions of EG and H 2 O were characterized by XRD and SEM-EDS. Figure 1 shows the diffraction patterns of the products of the synthesis. All XRD patterns are strongly influenced by the formation of small crystallites and amorphization. The position of main diffraction peaks in all samples correspond to the tetragonal structure of CFTS stannite (JCPDS 74-1025). In some samples, small admixtures of elementary sulfur, CuS, or SnS were detected as artifacts of incomplete reaction. The most intensive patterns with the sharpest peaks and the best match of reflections to the standard stannite pattern resulted from the EG:H 2 O ratio equal to 1:0 and 7:1, respectively. The products indicate the desired CFTS with the best crystallinity. Products synthesized from EG:H 2 O ratio of 3:1, 5:3. 1:1, and 3:5 show a good match of reflections with standard patterns but contain more impurities. Furthermore, the products synthesized from EG:H 2 O at a ratio of 1:3 consisted of a single-phase, but the peaks were of low intensity and their position was shifted toward the lower values of 2θ.  (Liang et al., 2012). The same can be observed for EG:H2O = 3:1. However, in this case the peaks are less intense and broad. As the water content increases, the peaks characteristic of hexagonal CMTS become clearer which indicates that the crystalline structure of CMTS is gradually transforming. Note that the optical band gaps for tetragonal CMTS and hexagonal CMTS are almost the same (ca. 1.1 eV as calculated by Liang et al. [42]) suggesting that both structures have the same potential application in solar cells.  (Liang et al., 2012). The same can be observed for EG:H 2 O = 3:1. However, in this case the peaks are less intense and broad. As the water content increases, the peaks characteristic of hexagonal CMTS become clearer which indicates that the crystalline structure of CMTS is gradually transforming. Note that the optical band gaps for tetragonal CMTS and hexagonal CMTS are almost the same (ca. 1.1 eV as calculated by Liang et al. [42]) suggesting that both structures have the same potential application in solar cells.
The dependence of CFTS particle morphology on the EG:H 2 O ratio is apparent in SEM images ( Figure 3). The products synthesized from EG:H 2 O ratios of 1:0 and 7:1 show spherical shapes ( Figure 3A,B), whereas those synthesized from 3:1, 5:3, and 1:1 ratio show more irregular morphology ( Figure 3C-E). The size of the CMTS particle is similar to that of CFTS (range = 2-3 µm). As the water content increases in the initial batch, two generations of crystallites appear that are characterized by more irregular edges and flower-like particles. This is shown in Figure 3G   The dependence of CFTS particle morphology on the EG:H2O ratio is apparent in SEM images ( Figure 3). The products synthesized from EG:H2O ratios of 1:0 and 7:1 show spherical shapes ( Figure  3A,B), whereas those synthesized from 3:1, 5:3, and 1:1 ratio show more irregular morphology ( Figure  3C-E). The size of the CMTS particle is similar to that of CFTS (range = 2-3 μm). As the water content increases in the initial batch, two generations of crystallites appear that are characterized by more irregular edges and flower-like particles. This is shown in Figure 3G and F (EG:H2O ratio of 3:5 and 1:3). Larger, flower-like particles, relatively uniform in size (2-3 μm), are accompanied by much smaller spherical particles (about 0.1 μm).   The dependence of CFTS particle morphology on the EG:H2O ratio is apparent in SEM images ( Figure 3). The products synthesized from EG:H2O ratios of 1:0 and 7:1 show spherical shapes ( Figure  3A,B), whereas those synthesized from 3:1, 5:3, and 1:1 ratio show more irregular morphology ( Figure  3C-E). The size of the CMTS particle is similar to that of CFTS (range = 2-3 μm). As the water content increases in the initial batch, two generations of crystallites appear that are characterized by more irregular edges and flower-like particles. This is shown in Figure 3G and F (EG:H2O ratio of 3:5 and 1:3). Larger, flower-like particles, relatively uniform in size (2-3 μm), are accompanied by much smaller spherical particles (about 0.1 μm).

Optimization of Time of Synthesis
Different times for the synthesis were studied to optimize the synthesis: 1 day, 3 days, 1 week, 2 weeks, and the synthesis repeated twice for 1 week each time in fresh solution. The temperature of the synthesis was maintained at 195 • C (except for 2 weeks experiment when the temperature was 160 • C for technical reasons) and the EG:H 2 O ratio was always equal to 7:1. Figure 4 shows the XRD patterns of the resulting CFTS particles. All experiments resulted in a tetragonal stannite identical to JCPDS standard No 74-1025. These patterns are similar in intensity and width of peaks. Small amounts of impurities (CuS, FeO, and FeS) were observed in samples synthesized for 2 weeks. Lower temperatures during synthesis (160 • C) also affected the product formation by decreasing crystallinity and forming impurities. This shows that 195 • C was an optimal temperature, although we found the formation of sulfur impurities in all the samples. After just one day of synthesis in 195 • C it is possible to obtain satisfactory purity and crystallinity of CFTS, but the optimal synthesis time is one week. There were no significant effects resulting from the prolongation of the time of synthesis of CFTS on XRD pattern.

Optimization of Time of Synthesis
Different times for the synthesis were studied to optimize the synthesis: 1 day, 3 days, 1 week, 2 weeks, and the synthesis repeated twice for 1 week each time in fresh solution. The temperature of the synthesis was maintained at 195 °C (except for 2 weeks experiment when the temperature was 160 °C for technical reasons) and the EG:H2O ratio was always equal to 7:1. Figure 4 shows the XRD patterns of the resulting CFTS particles. All experiments resulted in a tetragonal stannite identical to JCPDS standard No 74-1025. These patterns are similar in intensity and width of peaks. Small amounts of impurities (CuS, FeO, and FeS) were observed in samples synthesized for 2 weeks. Lower temperatures during synthesis (160 °C) also affected the product formation by decreasing crystallinity and forming impurities. This shows that 195 °C was an optimal temperature, although we found the formation of sulfur impurities in all the samples. After just one day of synthesis in 195 °C it is possible to obtain satisfactory purity and crystallinity of CFTS, but the optimal synthesis time is one week. There were no significant effects resulting from the prolongation of the time of synthesis of CFTS on XRD pattern.  Figure 5 shows the SEM images of CFTS microspheres synthesized at different times. All products consisted of spherical particles of relatively average size from 0.6 to 1.5 μm ( Figure 6). No changes were observed in the morphology of CFTS microparticles with extended synthesis time. This shows that CFTS microspheres of uniform particle size can be easily synthesized within 1 day. The exception is an experiment conducted twice for a week, which resulted in the two generations of sharp-edged particles.  Figure 5 shows the SEM images of CFTS microspheres synthesized at different times. All products consisted of spherical particles of relatively average size from 0.6 to 1.5 µm ( Figure 6). No changes were observed in the morphology of CFTS microparticles with extended synthesis time. This shows that CFTS microspheres of uniform particle size can be easily synthesized within 1 day. The exception is an experiment conducted twice for a week, which resulted in the two generations of sharp-edged particles.   In addition, small amounts of MnCO3 (rhodochrosite) were detected as undesirable contamination in the product of syntheses lasting 1 day and 3 days and in the product of synthesis at low temperature (160 °C for 2 weeks).   In addition, small amounts of MnCO3 (rhodochrosite) were detected as undesirable contamination in the product of syntheses lasting 1 day and 3 days and in the product of synthesis at low temperature (160 °C for 2 weeks).   In addition, small amounts of MnCO 3 (rhodochrosite) were detected as undesirable contamination in the product of syntheses lasting 1 day and 3 days and in the product of synthesis at low temperature (160 • C for 2 weeks).         In the products of the syntheses lasting 1 day, 3 days, and twice a week, the presence of an additional phase in the form of larger isometric crystals was observed. The result of elementary EDS (Figure 9) analysis is consistent with the composition of rhodochrosite, which is in line with the results of XRD analysis.
Materials 2020, 13, x FOR PEER REVIEW 9 of 18 In the products of the syntheses lasting 1 day, 3 days, and twice a week, the presence of an additional phase in the form of larger isometric crystals was observed. The result of elementary EDS (Figure 9) analysis is consistent with the composition of rhodochrosite, which is in line with the results of XRD analysis.

Synthesis of Cu2(Mnx-1Fex)SnS4 Solid Solution Series
For the synthesis of solid solutions of Cu2(Mn1−xFex)SnS4 series, the synthesis time and EG:H2O ratio have been chosen to obtain the best crystalline products with the least amount of impurities. The EG:H2O ratio of 7:1 and a reaction time of one week at 195 °C met these expectations. The diffraction peaks for both this product and CFTS were the sharpest and most intense. The results are shown in Figure 10. Similar to Lopez-Vergara et al. [40], all samples showed tetragonal structure although the synthesis of CMTS under these conditions resulted in a product composed of a mixture of two phases (tetragonal and hexagonal). The unit cell parameters increased linearly with the increase in Mn content ( Figure 11). This is manifested by the systematic shift in the position of diffraction peaks toward lower angles 2θ (from 28.8° 2θ to 28.2° 2θ for the main peak). In addition, the peaks became sharper, indicating an improvement in crystallinity. As the Mn content decreased, the hexagonal phase in the CMTS mixture disappeared. The peaks associated with the hexagonal structure can be observed in samples with Mn:Fe ratios of 1:1, 0.8:0.2, and 0.6:0.4. This suggests that CMTS formed by this method of synthesis can easily form tetragonal and hexagonal forms, whereas CFTS is more likely to precipitate in tetragonal structure.
The morphology of all samples in the series was very similar (Figure 12). They consisted of relatively uniform microspheres, ca. 1-1.5 μm in diameter, with a rough surface. The internal structure of the microspheres appeared to be concentric. The outer rim was made of aggregates of small crystals, whereas the core was much more homogeneous. The elemental composition of the members of the series as determined with the use of SEM/EDS microanalysis ( Figure 13, Table 1) is very close to what was expected from the synthesis. This indicates that the composition of the synthesis can be precisely controlled by the conditions of the experiment. There was no difference in elemental composition between the rim and the core. However, with Mn-rich samples, it is hypothesized that the structure of the core and the rim may be different. Tiong et al. [39] reported that the material consisting of both hexagonal and tetragonal crystalline structures was obtained by using an organic sulfur precursor such as thioacetamide and Tu in the precursor solution of the hydrothermal reaction. They obtained pure tetragonal kesterite nanocrystals when Na2S was employed as the precursor of sulfur. A mixture of both tetragonal and hexagonal crystalline structure was obtained by using organic Tu as the precursor for sulfur [39,43,44].

Synthesis of Cu 2 (Mn 1−x Fe x )SnS 4 Solid Solution Series
For the synthesis of solid solutions of Cu 2 (Mn 1−x Fe x )SnS 4 series, the synthesis time and EG:H 2 O ratio have been chosen to obtain the best crystalline products with the least amount of impurities. The EG:H 2 O ratio of 7:1 and a reaction time of one week at 195 • C met these expectations. The diffraction peaks for both this product and CFTS were the sharpest and most intense. The results are shown in Figure 10. Similar to Lopez-Vergara et al. [40], all samples showed tetragonal structure although the synthesis of CMTS under these conditions resulted in a product composed of a mixture of two phases (tetragonal and hexagonal). The unit cell parameters increased linearly with the increase in Mn content ( Figure 11). This is manifested by the systematic shift in the position of diffraction peaks toward lower angles 2θ (from 28.8 • 2θ to 28.2 • 2θ for the main peak). In addition, the peaks became sharper, indicating an improvement in crystallinity. As the Mn content decreased, the hexagonal phase in the CMTS mixture disappeared. The peaks associated with the hexagonal structure can be observed in samples with Mn:Fe ratios of 1:1, 0.8:0.2, and 0.6:0.4. This suggests that CMTS formed by this method of synthesis can easily form tetragonal and hexagonal forms, whereas CFTS is more likely to precipitate in tetragonal structure.
The morphology of all samples in the series was very similar (Figure 12). They consisted of relatively uniform microspheres, ca. 1-1.5 µm in diameter, with a rough surface. The internal structure of the microspheres appeared to be concentric. The outer rim was made of aggregates of small crystals, whereas the core was much more homogeneous. The elemental composition of the members of the series as determined with the use of SEM/EDS microanalysis ( Figure 13, Table 1) is very close to what was expected from the synthesis. This indicates that the composition of the synthesis can be precisely controlled by the conditions of the experiment. There was no difference in elemental composition between the rim and the core. However, with Mn-rich samples, it is hypothesized that the structure of the core and the rim may be different. Tiong et al. [39] reported that the material consisting of both hexagonal and tetragonal crystalline structures was obtained by using an organic sulfur precursor such as thioacetamide and Tu in the precursor solution of the hydrothermal reaction. They obtained pure tetragonal kesterite nanocrystals when Na 2 S was employed as the precursor of sulfur. A mixture of both tetragonal and hexagonal crystalline structure was obtained by using organic Tu as the precursor for sulfur [39,43,44].             Figure 14 shows the infrared absorption spectra for the six members of the CFTS-CMTS series from 400 to 3600 cm −1 . Table 2  . The intensity of the bands is not very high, but their position is clear. FTIR analysis is very sensitive and allows for the identification of small amounts of contaminants. Therefore, in the presented spectra, many bands do not come directly from the synthesis products, but are an artifact of a small amount of impurity arising from the unreacted components used in the experiments. These reagents are not crystalline and were not detected in XRD analysis. The absorption peak at 3435 cm -1 corresponds to the presence of water, probably from the presence of humidity in the air. Similarly, small amount of CO 2 adsorbed from the air results in bands at 2351 cm -1 . The characteristic bands at 720 cm -1 are assigned to metal-O-H bending vibrations. The vibration band observed at 2935 cm -1 refers to the tensile strength of C-H bond, whereas the band at 1020 cm -1 corresponds to the tensile strength of C-S bond. The bands observed at 1651, 1424, and 1183 cm -1 were assigned to metal-Tu complexes. A more complete assignment of these peaks was proposed based on the study performed on metal-Tu complexes involving δN-H bending deformation (1651 cm −1 ), NH 2 rocking vibration, C-S stretching vibration or N-C-N stretching vibration (1424 cm −1 ), C=S, C-N, or NH 2 rocking vibration (1185 cm −1 ). The C=S stretching vibration mode of the Tu molecule is found at 668 cm −1 .
Materials 2020, 13, x FOR PEER REVIEW 12 of 18 Figure 14 shows the infrared absorption spectra for the six members of the CFTS-CMTS series from 400 to 3600 cm −1 . Table 2 shows the band assignments and literature sources. Samples of Cu2MnSnS4, Cu2(Mn0.8Fe0.2)SnS4, and Cu2(Mn0.6Fe0.4)SnS4 show characteristic peaks at 617, 860, and 1114 cm −1 associated with specific Mn-S vibrations. These bands are assigned to the resonance interaction between the vibration modes of the sulfide ions in the crystal. As the Fe content increases, these bands disappear and bands at 880 and 1142 cm −1 show up which corresponds to Fe-S specific vibrations (samples Cu2(Mn0.4Fe0.6)SnS4, Cu2(Mn0.2Fe0.8)SnS4, and Cu2FeSnS4). The intensity of the bands is not very high, but their position is clear. FTIR analysis is very sensitive and allows for the identification of small amounts of contaminants. Therefore, in the presented spectra, many bands do not come directly from the synthesis products, but are an artifact of a small amount of impurity arising from the unreacted components used in the experiments. These reagents are not crystalline and were not detected in XRD analysis. The absorption peak at 3435 cm -1 corresponds to the presence of water, probably from the presence of humidity in the air. Similarly, small amount of CO2 adsorbed from the air results in bands at 2351 cm -1 . The characteristic bands at 720 cm -1 are assigned to metal-O-H bending vibrations. The vibration band observed at 2935 cm -1 refers to the tensile strength of C-H bond, whereas the band at 1020 cm -1 corresponds to the tensile strength of C-S bond. The bands observed at 1651, 1424, and 1183 cm -1 were assigned to metal-Tu complexes. A more complete assignment of these peaks was proposed based on the study performed on metal-Tu complexes involving δN-H bending deformation (1651 cm −1 ), NH2 rocking vibration, C-S stretching vibration or N-C-N stretching vibration (1424 cm −1 ), C=S, C-N, or NH2 rocking vibration (1185 cm −1 ). The C=S stretching vibration mode of the Tu molecule is found at 668 cm −1 .   The Raman spectra of the samples analyzed ( Figure 15) show bands characteristic of stannite in the range of 200-500 cm −1 [54]. Experimental Raman scattering spectra were analyzed by the deconvolution to Lorentzian curves. The dominant structure at about~330 cm −1 in the experimental spectra is the vibration of pure anion mode of S anions around solid Sn cations, whereas the mode at about~290 cm −1 can be considered as the pure S anion mode around Cu cation. Deconvolution shows an additional weaker band at 352-366 cm −1 , which is in good agreement with the frequencies reported for this compound [54]. As the Mn content in the samples increases, shifts in positions of some bands toward lower wavenumbers are observed (from 366 to 352 and from 291 to 283 cm −1 ). This may be related to a slight change in the length and force of the length of the metal-S bond or due to the two kinds of anionic mode of S anions around fixed Sn cations related to a different structure in a single crystal [55]. There is also a variation in the frequency of the main A1 vibration mode at 330 cm −1 . The broadening of the main peaks found in the solid solution with the increasing content of Fe is attributed to disorder effects due to chemical substitutions in M crystallographic positions [56]. The spectrum of CMTS ( Figure 12F) shows the splitting of the main peak into 323 and 334 cm −1 . This is consistent with XRD results. Typically, the main Raman peak of stannite structure CZTS is reported at 330-339 cm −1 matching the values well reported for crystals and films. Nevertheless, frequencies in the range of 320-334 cm −1 can also be found in the literature for CZTS in the same range where the strongest Raman features of wurtzite and stannite CZTS were often reported [57].

Conclusions
In this study, a low-cost and environmentally friendly method of preparation of semiconductors was successfully tested. The hydrothermal synthesis method, requiring simple reactants, and relatively low temperature and reasonable time can be used to obtain CFTS, CMTS, and their solid solutions on a larger scale. Optimal conditions for the synthesis are as follows: A mixture of H2O:EG at the ratio of 1:7 as the reaction medium, PVP as the surface ligand, and temperature of 195 °C for 7

Conclusions
In this study, a low-cost and environmentally friendly method of preparation of semiconductors was successfully tested. The hydrothermal synthesis method, requiring simple reactants, and relatively low temperature and reasonable time can be used to obtain CFTS, CMTS, and their solid solutions on a larger scale. Optimal conditions for the synthesis are as follows: A mixture of H 2 O:EG at the ratio of 1:7 as the reaction medium, PVP as the surface ligand, and temperature of 195 • C for 7 days. The synthesis product precipitates as aggregates of nanocrystals. The aggregates form uniform, often concentric microspheres that are 1-1.5 µm in diameter. The chemical composition of the product can be well controlled by the chemical composition of the reactants, and the compound Cu 2 (Mn 1−x Fe x )SnS 4 forms a continuous solid solution series. Lopez-Vergara et al. [40] have drawn similar conclusions. If the series members rich in Fe are produced, then the product has a tetragonal structure. However, if the series members rich in Mn are produced, then the product is a mixture of phases with a tetragonal and hexagonal structure. We believe this material is a good candidate for the alternative at semiconductor and can be used as an adequate absorber in solar cells or catalyzation in photocatalysis.

Conflicts of Interest:
The authors declare no conflict of interest.