Quantitative Evaluation of Underground Coal Gasiﬁcation Based on a CO 2 Gasiﬁcation Agent

: Using carbon dioxide as a gasiﬁcation agent for underground coal gasiﬁcation (UCG) can not only reduce carbon dioxide emissions but is also expected to lead to a new natural gas technology revolution and ensure national energy security. To explore the effect of the oxygen content in oxygen-enriched carbon dioxide gasiﬁcation agents on the results of gasiﬁcation experiments, underground gasiﬁcation experiments under different oxygen-enrichment conditions were designed, and quantitative parameters were used to analyze and evaluate the gas produced in the gasiﬁcation experiments. The results showed that as the oxygen content in the oxygen-enriched carbon dioxide gasiﬁcation agent increased, the CO and H 2 in the combustible gas gradually increased, and the caloriﬁc value of the combustible gas also slowly increased, reaching a peak value under the gasiﬁ-cation condition of 60% oxygen concentration, and then decreased slightly; the product formation rate and the gas production per unit mass of coal ﬂuctuated. The coal consumption rate increased with time and was relatively stable. According to theoretical calculations for the gasiﬁcation energy recovery evaluation system, the overall energy recovery rate was 56.34%, and the energy utilization rate was relatively high. Research on quantitative indicators based on gas production data has good practical signiﬁcance for evaluating the gasiﬁcation efﬁciency of UCG, which can be used to better evaluate and control the reaction process of UCG.


Introduction
With the continuous development of China's economy, the demand for oil and gas is increasing, the dependence on foreign oil and natural gas is increasing year by year, and the supply security situation is severe [1].China is rich in coal resources, but coal mining causes great pollution to the environment, and good clean development methods are lacking.As a subversive technology, underground coal gasification (UCG) enables the controlled combustion of coal by creating appropriate process conditions underground and generates hydrogen, carbon monoxide, and methane through coal pyrolysis and a series of chemical reactions between coal, oxygen, and water vapor.It is a clean coal utilization technology integrating the three major processes of well construction, coal mining, and gasification.UCG technology can ensure sufficient oil and gas production and reduce carbon emissions from coal mining and is expected to lead to a new natural gas technology revolution [2].According to estimates, China's onshore coal resources buried at a depth of 1000-3000 m are 3.77 × 10 12 t, and the equivalent methane resource is 272-332 × 10 12 m 3  Energies 2023, 16, 6993 2 of 10 based on a gasification production rate of 40%, which is a conventional natural gas resource.This is three times the amount of natural gas, which is greater than the total amount of natural gas resources that have been put into development (210 × 10 12 m 3 ).Calculated with a coal seam thickness of 5 m, the abundance of coal gasifiable resources is as high as 112 × 10 8 m 3 /km 2 [3].
The development of UCG technology was initiated more than 150 years ago when the German scientist William Siemens creatively proposed the underground gasification of coal in 1868 [4].A large number of field experiments have been carried out in many countries, including the former Soviet Union, the United States, the United Kingdom, Poland, Belgium, Spain, Australia, and China [5].There have also been many new developments and understandings in UCG in terms of technology, cost, and environmental impact [6,7].Although there have been small breakthroughs, it is still in the stage of industrial testing, has not yet been fully commercially developed, and has not formed a complete industrial chain [8][9][10].Therefore, exploring cost-effective gasification processes will be one of the key directions for commercial development.Using indoor simulation experiments to simulate the gas production of different gasification agents and mastering the gasification operation rules will provide guidance for the exploration of high-efficiency gasification processes.Researchers have also carried out gasification simulation experiments on air, oxygen, oxygen-enriched air, oxygen-enriched CO 2 , and pure oxygen water vapor [11].Air is used as a gasification agent, which eliminates the cost of air separation when the initial gasification agent is inflated; however, air gasification leads to a lower temperature, reaction intensity and gasification efficiency in the UCG reaction zone, especially in coal seams with a high ash content, and air gasification produces gas with a low calorific value [12,13].Oxygen-enriched air as a gasification medium can reduce the operating cost of gasification agent separation and further ensure the stability of the flame in the UCG process.However, the generated gas still contains nitrogen, which must be separated in a subsequent process.It is generally believed that pure oxygen gasification is suitable for coal with a high ash content, but pure oxygen gasification requires an expensive gasification agent and is difficult to control [14,15].Pure oxygen water vapor is used as a gasification agent.It reduces the temperature in the gasification chamber.However, due to the temperature reduction, some of the water vapor condenses into droplets; hence, the gasification agent cannot be evenly distributed onto the surface of the coal seam, which leads to gasification process instability and decreased gasification efficiency [16,17].O 2 /CO 2 is a better choice as a gasification agent; it can avoid the problem of transporting superheated steam to deep coal seams and can also resolve the carbon dioxide utilization issue.Chen et al. [18] found experimentally that compared with the existing oxygen-enriched underground gasification model test results, adding CO 2 to the gasification agent can inhibit the formation of CO 2 in the process of underground gasification, and the temperature field under O 2 /CO 2 gasification is relatively low, with a coal seam maximum temperature during gasification of only 1200 • C, which is favorable for generating effective components of coal gas.Zhao et al. [19] compared the O 2 /CO 2 and O 2 /air gasification methods and found that the presence of a high concentration of CO 2 can prolong the gasification time and make the temperature field in the furnace distribute in the vertical direction.However, the high concentration of the CO 2 gasification agent can cause the flame to cool down or even extinguish in the combustion air area of the underground gasifier.Therefore, in the process of oxygen-enriched gasification, maintaining the optimal O 2 /CO 2 ratio in the gasification agent delivery process seems to be especially critical.Moreover, the gasification efficiency under different ratios has been rarely evaluated quantitatively.
In this paper, on the basis of previous studies, experiments on carbon dioxide gasification under different oxygen-enrichment conditions were conducted, and the optimal O 2 /CO 2 injection ratio was determined.The gasification experimental method was compared and evaluated in stages to identify the influence laws of the oxygen concentration, gas-to-oxygen ratio, gas injection flow rate, and other parameters on the changes in the gas production components.Based on stoichiometric theory, the coal consumption, gas yield, Energies 2023, 16, 6993 3 of 10 combustible gas volume, calorific value of the gasification products, and energy recovery rate were evaluated by calculation.This study provides a theoretical basis for underground gasification field tests.

Sample Information
The coal seam used in this experiment was mined in the northern part of the Ordos Basin.Before the start of the experiment, industrial analysis and elemental analysis were performed on the experimental coal.The results are shown in Tables 1 and 2. The proximate analysis and elemental analysis results show that this area is of medium high volatile content and extremely low ash content, and has similar coal quality conditions to Swan Mountain [20], which is suitable for underground gasification experiment.

Experimental Setup
The equipment used in the experiment was self-developed equipment, including an oxygen generator, steam generator, gasifier, temperature sensor, filter box, and gas chromatograph.Figure 1 is a structural diagram of the device, and Figure 2 is a physical diagram.The size of the coal filling was 2150 mm long, 600 mm wide, and 550 mm high.
Energies 2023, 16, x FOR PEER REVIEW 3 of 10 gas production components.Based on stoichiometric theory, the coal consumption, gas yield, combustible gas volume, calorific value of the gasification products, and energy recovery rate were evaluated by calculation.This study provides a theoretical basis for underground gasification field tests.

Sample Information
The coal seam used in this experiment was mined in the northern part of the Ordos Basin.Before the start of the experiment, industrial analysis and elemental analysis were performed on the experimental coal.The results are shown in Tables 1 and 2. The proximate analysis and elemental analysis results show that this area is of medium high volatile content and extremely low ash content, and has similar coal quality conditions to Swan Mountain [20], which is suitable for underground gasification experiment.

Experimental Setup
The equipment used in the experiment was self-developed equipment, including an oxygen generator, steam generator, gasifier, temperature sensor, filter box, and gas chromatograph.Figure 1 is a structural diagram of the device, and Figure 2 is a physical diagram.The size of the coal filling was 2150 mm long, 600 mm wide, and 550 mm high.

Experimental Design
In this experiment, oxygen-enriched carbon dioxide was used as the gasification agent.The volume fraction of oxygen and carbon dioxide was adjusted with the same total injection rate.Under the same condition, we investigate to the composition of the gas generated by the corresponding gasification process and the pattern of changes in the result under different oxygen and carbon ratios.Compared with the conventional oxygen-enriched coal UCG process, the main significant difference of the oxygen-enriched carbon dioxide UCG process is the addition of CO2 to the conventional oxygen-enriched gasification agent, which not only changes the balance of the three-zone reaction in the gasification zone but also promotes the reduction reaction, which in turn affects the gas composition of the gasification product.The variation in the experimental gasification agent injection flow rate is shown in Figure 3.The total gasification agent injection flow rate was 25 m 3 /h, and six kinds of oxygen-rich carbon gasification agents with different oxygen-tocarbon ratios with oxygen concentrations of 30%, 40%, 50%, 60%, 70%, and 80% were used for the gasification experiment.These gasification agents were utilized in sequence for 2 h, and the total length of the experiment was 12 h.

Experimental Design
In this experiment, oxygen-enriched carbon dioxide was used as the gasification agent.The volume fraction of oxygen and carbon dioxide was adjusted with the same total injection rate.Under the same condition, we investigate to the composition of the gas generated by the corresponding gasification process and the pattern of changes in the result under different oxygen and carbon ratios.Compared with the conventional oxygen-enriched coal UCG process, the main significant difference of the oxygen-enriched carbon dioxide UCG process is the addition of CO 2 to the conventional oxygen-enriched gasification agent, which not only changes the balance of the three-zone reaction in the gasification zone but also promotes the reduction reaction, which in turn affects the gas composition of the gasification product.The variation in the experimental gasification agent injection flow rate is shown in Figure 3.The total gasification agent injection flow rate was 25 m 3 /h, and six kinds of oxygen-rich carbon gasification agents with different oxygen-to-carbon ratios with oxygen concentrations of 30%, 40%, 50%, 60%, 70%, and 80% were used for the gasification experiment.These gasification agents were utilized in sequence for 2 h, and the total length of the experiment was 12 h.

Experimental Design
In this experiment, oxygen-enriched carbon dioxide was used as the gasification agent.The volume fraction of oxygen and carbon dioxide was adjusted with the same total injection rate.Under the same condition, we investigate to the composition of the gas generated by the corresponding gasification process and the pattern of changes in the result under different oxygen and carbon ratios.Compared with the conventional oxygen-enriched coal UCG process, the main significant difference of the oxygen-enriched carbon dioxide UCG process is the addition of CO2 to the conventional oxygen-enriched gasification agent, which not only changes the balance of the three-zone reaction in the gasification zone but also promotes the reduction reaction, which in turn affects the gas composition of the gasification product.The variation in the experimental gasification agent injection flow rate is shown in Figure 3.The total gasification agent injection flow rate was 25 m 3 /h, and six kinds of oxygen-rich carbon gasification agents with different oxygen-tocarbon ratios with oxygen concentrations of 30%, 40%, 50%, 60%, 70%, and 80% were used for the gasification experiment.These gasification agents were utilized in sequence for 2 h, and the total length of the experiment was 12 h.

Experimental Procedure
After the experiment started, the gasification agent was blown into the gasifier, and the ignition device was turned on.After successful ignition, the experiment was carried out according to the experimental parameter settings of each experimental stage, and the data for each experimental subsystem were recorded regularly.Throughout the gasification process, the generated gas was collected and stored regularly, the temperature of the gasification area was monitored in real time, and the gas composition of the gasification product was tested using a gas chromatograph.
By comparatively evaluating each stage of the experiment, the influence laws of parameters such as the oxygen concentration, gas-to-oxygen ratio, and gas injection flow rate on the produced gas components were obtained.Based on stoichiometric theory, an improved method for calculating the calorific value of the gasification gas was developed, which was used to obtain the pilot experimental parameters and evaluate the gasification efficiency.The coal consumption, gas yield, combustible gas volume, calorific value of the gasification products, and energy recovery rate were evaluated by calculation.

Experimental Results
The content of each component of the gas produced by oxygen-enriched carbon dioxide gasification is shown in Figure 4.The main gas components of the gasification coal gas included H 2 , CO, CH 4 , and CO 2 .With increasing oxygen concentration injected by the gasification agent, the CO 2 content gradually decreased from 78.09% and reached its lowest value at approximately 8 h, at which time the CO content in the generated gas also reached its peak value of 29.73%.The H 2 content reached its peak value of 27.63% at approximately 8.5 h, and the CH 4 content was relatively stable without obvious fluctuations.
out according to the experimental parameter settings of each experimental stage, and the data for each experimental subsystem were recorded regularly.Throughout the gasification process, the generated gas was collected and stored regularly, the temperature of the gasification area was monitored in real time, and the gas composition of the gasification product was tested using a gas chromatograph.
By comparatively evaluating each stage of the experiment, the influence laws of parameters such as the oxygen concentration, gas-to-oxygen ratio, and gas injection flow rate on the produced gas components were obtained.Based on stoichiometric theory, an improved method for calculating the calorific value of the gasification gas was developed, which was used to obtain the pilot experimental parameters and evaluate the gasification efficiency.The coal consumption, gas yield, combustible gas volume, calorific value of the gasification products, and energy recovery rate were evaluated by calculation.

Experimental Results
The content of each component of the gas produced by oxygen-enriched carbon dioxide gasification is shown in Figure 4.The main gas components of the gasification coal gas included H2, CO, CH4, and CO2.With increasing oxygen concentration injected by the gasification agent, the CO2 content gradually decreased from 78.09% and reached its lowest value at approximately 8 h, at which time the CO content in the generated gas also reached its peak value of 29.73%.The H2 content reached its peak value of 27.63% at approximately 8.5 h, and the CH4 content was relatively stable without obvious fluctuations.
During the gasification process, due to the low oxygen concentration in the initial period, the oxidation reaction intensity in the gasification reaction was also low, and the high concentration of CO2 hindered the forward progress of the oxidation reaction.Therefore, the production temperature of the oxidation reaction in the early stage did not reach the temperature required for the reduction reaction in the later stage, and the intensity of the entire gasification process was relatively weak, resulting in low levels (approximately 10%) of all major gas components except for CO2 in the initial stage.With increasing oxygen concentration, the contents of CO and H2 gradually increased and peaked under the gasification condition of 60% oxygen concentration.As the oxygen concentration continued to rise, the CO2 content began to increase, and the H2 content began to decrease.The calorific value is an index for measuring the quality of the produced gas, and it also indirectly reflects the quality of the gasification effect [20].The change in the calorific value of the gas produced in this experiment is shown in Figure 5.The average calorific value was 6.17 MJ/m 3 .During the initial period of this stage (oxygen concentration of 30%), the calorific value of the generated gas began to increase slowly, rising from 3.23 During the gasification process, due to the low oxygen concentration in the initial period, the oxidation reaction intensity in the gasification reaction was also low, and the high concentration of CO 2 hindered the forward progress of the oxidation reaction.Therefore, the production temperature of the oxidation reaction in the early stage did not reach the temperature required for the reduction reaction in the later stage, and the intensity of the entire gasification process was relatively weak, resulting in low levels (approximately 10%) of all major gas components except for CO 2 in the initial stage.With increasing oxygen concentration, the contents of CO and H 2 gradually increased and peaked under the gasification condition of 60% oxygen concentration.As the oxygen concentration continued to rise, the CO 2 content began to increase, and the H 2 content began to decrease.
The calorific value is an index for measuring the quality of the produced gas, and it also indirectly reflects the quality of the gasification effect [20].The change in the calorific value of the gas produced in this experiment is shown in Figure 5.The average calorific value was 6.17 MJ/m 3 .During the initial period of this stage (oxygen concentration of 30%), the calorific value of the generated gas began to increase slowly, rising from 3.23 MJ/m 3 to 4.32 MJ/m 3 within 2 h.At 2 h, the oxygen concentration of the injected gasification agent was adjusted to 40%, and the calorific value of the generated gas began to rise rapidly, increasing by 1.96 MJ/m 3 over 2 h, and increased nearly twice as much as that under the gasification condition of 30% oxygen concentration.In the subsequent 4 h gasification process, with increasing oxygen concentration, the calorific value of the generated gas also increased continuously, but the rate of increase gradually decreased.When the O 2 concentration in the gasification agent component reached 60%, the flow of the combustible gas in the generated gas reached its peak value.At 8 h, the oxygen concentration changed from 60% to 70%, and the calorific value of the generated gas began to decrease slowly.
Energies 2023, 16, x FOR PEER REVIEW 6 of 10 MJ/m 3 to 4.32 MJ/m 3 within 2 h.At 2 h, the oxygen concentration of the injected gasification agent was adjusted to 40%, and the calorific value of the generated gas began to rise rapidly, increasing by 1.96 MJ/m 3 over 2 h, and increased nearly twice as much as that under the gasification condition of 30% oxygen concentration.In the subsequent 4 h gasification process, with increasing oxygen concentration, the calorific value of the generated gas also increased continuously, but the rate of increase gradually decreased.When the O2 concentration in the gasification agent component reached 60%, the flow of the combustible gas in the generated gas reached its peak value.At 8 h, the oxygen concentration changed from 60% to 70%, and the calorific value of the generated gas began to decrease slowly.

Generation Rate of the Product Gas
The gas generation rate of UCG reflects the activity of the gasification process [21].Figure 6 shows that the product generation rate fluctuated, mainly due to the change in the dominance of the oxidation reaction and the reduction reaction during the gasification process.When the oxidation reaction was dominant, the gas production was larger, and when the reduction reaction was dominant, the gas production decreased.In the early stage of the experiment (oxygen concentration of 30%), the production rate of the product gas was low and slowly increasing.Due to the low concentration of O2 injected into the gasification agent in the initial stage, the oxidation reaction in the gasification reaction was relatively gentle, and consequently, the overall temperature in the gasifier was low, resulting in the inability of CO2 to effectively participate in the reduction reaction; moreover, because the gasification process was relatively weak, the amount of gas generated at this time was low.At 2 h, the oxygen concentration of the injected gasification agent increased to 40%.At this time, the production rate of the product gas increased rapidly, rising to 39.11 m 3 /h within 0.5 h, and then began to decline.The decline stopped at 4 h, and within the following 4 h, the generation rate of the product gas had two large fluctuations again, decreasing overall.This overall decrease occurred because when the O2 concentration in the gasification agent reached 40%, the oxidation reaction in the gasification reaction was enhanced, resulting in an increase in the overall temperature in the gasifier; in addition, CO2 participated in the reduction reaction more effectively, and the gasification process was relatively active.The amount of gas produced by the gasification reaction peaked.Under oxygen concentrations of 40-70%, the gas volume of the generated gas decreased overall because the reduction reaction intensity at this time continued to increase, and the participation of CO2 in the reduction reaction decreased the generated gas volume.When the O2 concentration in the gasification agent exceeded 70%, the oxidation reaction in the gasification reaction was enhanced, the amount of CO2 gas in the generated gas increased, and then the amount of generated gas appeared to rebound, so the product gas generation

Generation Rate of the Product Gas
The gas generation rate of UCG reflects the activity of the gasification process [21].Figure 6 shows that the product generation rate fluctuated, mainly due to the change in the dominance of the oxidation reaction and the reduction reaction during the gasification process.When the oxidation reaction was dominant, the gas production was larger, and when the reduction reaction was dominant, the gas production decreased.In the early stage of the experiment (oxygen concentration of 30%), the production rate of the product gas was low and slowly increasing.Due to the low concentration of O 2 injected into the gasification agent in the initial stage, the oxidation reaction in the gasification reaction was relatively gentle, and consequently, the overall temperature in the gasifier was low, resulting in the inability of CO 2 to effectively participate in the reduction reaction; moreover, because the gasification process was relatively weak, the amount of gas generated at this time was low.At 2 h, the oxygen concentration of the injected gasification agent increased to 40%.At this time, the production rate of the product gas increased rapidly, rising to 39.11 m 3 /h within 0.5 h, and then began to decline.The decline stopped at 4 h, and within the following 4 h, the generation rate of the product gas had two large fluctuations again, decreasing overall.This overall decrease occurred because when the O 2 concentration in the gasification agent reached 40%, the oxidation reaction in the gasification reaction was enhanced, resulting in an increase in the overall temperature in the gasifier; in addition, CO 2 participated in the reduction reaction more effectively, and the gasification process was relatively active.The amount of gas produced by the gasification reaction peaked.Under oxygen concentrations of 40-70%, the gas volume of the generated gas decreased overall because the reduction reaction intensity at this time continued to increase, and the participation of CO 2 in the reduction reaction decreased the generated gas volume.When the O 2 concentration in the gasification agent exceeded 70%, the oxidation reaction in the gasification reaction was enhanced, the amount of CO 2 gas in the generated gas increased, and then the amount of generated gas appeared to rebound, so the product gas generation rate started to increase after 8 h.The average production rate of the product gas was 34.65 m 3 /h.

Coal Consumption Rate
The coal consumption rate, as a basic variable for evaluating the gasification effect, directly reflects the coal consumption in the gasification process and indirectly reflects the coal gasification rate [22].The overall coal consumption rate of the experiment fluctuated minimally, the coal consumption rate increased with time, and the average coal consumption rate was 15.46 kg/h (Figure 7).During the initial 2 h of the experiment, the coal consumption rate was stable at approximately 13.7 kg/h without a significant change, because in the early stage of the experiment, under 30% oxygen concentration gasification, the oxidation reaction was weak, the temperature field in the gasification zone was low, and the reaction intensity was low.At 2 h, the oxygen concentration of the gasification agent rose to 40%, the oxidation reaction in the gasification reaction began to increase in intensity, and the coal consumption rate began to rise slowly.In the subsequent gasification process, with the continuous increase in the injected oxygen concentration of the gasification agent, the oxidation reaction became increasingly intense, and the coal consumption per unit time also increased continuously.When the oxygen concentration of the gasification agent exceeded 70%, the coal consumption rate also increased correspondingly under gasification conditions with an excessively high oxygen concentration; thus, the coal consumption rate started to increase rapidly after 8 h.

Gas Production Per Unit Mass of Coal
As an important index for evaluating the quality of UCG, the gas production per unit mass of coal can indirectly reflect the change trend of the gasification efficiency in the

Coal Consumption Rate
The coal consumption rate, as a basic variable for evaluating the gasification effect, directly reflects the coal consumption in the gasification process and indirectly reflects the coal gasification rate [22].The overall coal consumption rate of the experiment fluctuated minimally, the coal consumption rate increased with time, and the average coal consumption rate was 15.46 kg/h (Figure 7).During the initial 2 h of the experiment, the coal consumption rate was stable at approximately 13.7 kg/h without a significant change, because in the early stage of the experiment, under 30% oxygen concentration gasification, the oxidation reaction was weak, the temperature field in the gasification zone was low, and the reaction intensity was low.At 2 h, the oxygen concentration of the gasification agent rose to 40%, the oxidation reaction in the gasification reaction began to increase in intensity, and the coal consumption rate began to rise slowly.In the subsequent gasification process, with the continuous increase in the injected oxygen concentration of the gasification agent, the oxidation reaction became increasingly intense, and the coal consumption per unit time also increased continuously.When the oxygen concentration of the gasification agent exceeded 70%, the coal consumption rate also increased correspondingly under gasification conditions with an excessively high oxygen concentration; thus, the coal consumption rate started to increase rapidly after 8 h.

Coal Consumption Rate
The coal consumption rate, as a basic variable for evaluating the gasification effect, directly reflects the coal consumption in the gasification process and indirectly reflects the coal gasification rate [22].The overall coal consumption rate of the experiment fluctuated minimally, the coal consumption rate increased with time, and the average coal consumption rate was 15.46 kg/h (Figure 7).During the initial 2 h of the experiment, the coal consumption rate was stable at approximately 13.7 kg/h without a significant change, because in the early stage of the experiment, under 30% oxygen concentration gasification, the oxidation reaction was weak, the temperature field in the gasification zone was low, and the reaction intensity was low.At 2 h, the oxygen concentration of the gasification agent rose to 40%, the oxidation reaction in the gasification reaction began to increase in intensity, and the coal consumption rate began to rise slowly.In the subsequent gasification process, with the continuous increase in the injected oxygen concentration of the gasification agent, the oxidation reaction became increasingly intense, and the coal consumption per unit time also increased continuously.When the oxygen concentration of the gasification agent exceeded 70%, the coal consumption rate also increased correspondingly under gasification conditions with an excessively high oxygen concentration; thus, the coal consumption rate started to increase rapidly after 8 h.

Gas Production Per Unit Mass of Coal
As an important index for evaluating the quality of UCG, the gas production per unit mass of coal can indirectly reflect the change trend of the gasification efficiency in the

Gas Production Per Unit Mass of Coal
As an important index for evaluating the quality of UCG, the gas production per unit mass of coal can indirectly reflect the change trend of the gasification efficiency in the gasification process [23].The gas production rate per unit mass of coal fluctuates but is generally in the range of 2-3 m 3 /kg.In this experiment, the average gas production rate of coal was 2.35 m 3 /kg.Figure 8 shows that at the initial stage of the reaction, since Energies 2023, 16, 6993 8 of 10 the oxygen concentration of the injected gasification agent was not high at this time, the oxidation reaction intensity was low, and the gas production per unit mass of coal was low.When the oxygen concentration of the injected gasification agent was adjusted to 40%, the gas production per unit mass of coal increased rapidly to a maximum value of 2.82 m 3 /kg and then began to decline due to the increase in the oxygen concentration of the gasification agent, which provided more oxygen for the oxidation reaction.As the oxidation reaction intensified, the temperature of the gasification zone increased, and the concentration of CO 2 also increased, which further promoted the reduction reaction.As the reduction reaction intensity increased, the temperature field in the gasification zone became increasingly low and could not provide the temperature environment required for the reduction reaction, which in turn promoted the intensification of the oxidation reaction.Thus, the gas production per unit mass of coal declined.Therefore, in the gasification process, there is a cyclic process in which the gas production initially increases, then decreases, and finally increases again.
Energies 2023, 16, x FOR PEER REVIEW 8 of 10 gasification process [23].The gas production rate per unit mass of coal fluctuates but is generally in the range of 2-3 m 3 /kg.In this experiment, the gas production rate of coal was 2.35 m 3 /kg.Figure 8 shows that at the initial stage of the reaction, since the oxygen concentration of the injected gasification agent was not high at this time, the oxidation reaction intensity was low, and the gas production per unit mass of coal was low.When the oxygen concentration of the injected gasification agent was adjusted to 40%, the gas production per unit mass of coal increased rapidly to a maximum value of 2.82 m 3 /kg and then began to decline due to the increase in the oxygen concentration of the gasification agent, which provided more oxygen for the oxidation reaction.As the oxidation reaction intensified, the temperature of the gasification zone increased, and the concentration of CO2 also increased, which further promoted the reduction reaction.As the reduction reaction intensity increased, the temperature field in the gasification zone became increasingly low and could not provide the temperature environment required for the reduction reaction, which in turn promoted the intensification of the oxidation reaction.Thus, the gas production per unit mass of coal declined.Therefore, in the gasification process, there is a cyclic process in which the gas production initially increases, then decreases, and finally increases again.

Energy Recovery Rate
As an important indicator in the gasification energy recovery evaluation system, the gas production per unit mass of coal can indirectly reflect the quality of the gasification effect in the gasification process.In this paper, it is proposed that the energy recovery rate is the ratio of the actual gas energy produced to the heat generated by the coal itself.This experiment was evaluated according to the theoretical calculation of the gasification energy recovery evaluation system [24,25].The calculated energy recovery rate was 56.34%.The energy utilization rate was high.

Conclusions
(1) In the oxygen-enriched carbon dioxide gasification experiment, with increasing oxygen content, the effective product and calorific value of the gasification product increased.The best gas production effect was obtained when the oxygen concentration was 50-60%.The content of active components in the generated gas was the highest under gasification conditions, with a hydrogen content of 25.1%, CO content of 29.6%, and calorific value of 7.3 MJ/m 3 , indicating that the redox reaction in the gasification reaction was close to equilibrium.(2) The gas production rate and the gas production per unit mass of coal fluctuated, mainly due to the change in the dominance of the oxidation reaction and the reduction reaction during the gasification process.When the oxidation reaction was dominant, the gas production was larger, and when the reduction reaction was dominant,

Energy Recovery Rate
As an important indicator in the gasification energy recovery evaluation system, the gas production per unit mass of coal can indirectly reflect the quality of the gasification effect in the gasification process.In this paper, it is proposed that the energy recovery rate is the ratio of the actual gas energy produced to the heat generated by the coal itself.This experiment was evaluated according to the theoretical calculation of the gasification energy recovery evaluation system [24,25].The calculated energy recovery rate was 56.34%.The energy utilization rate was high.

Conclusions
(1) In the oxygen-enriched carbon dioxide gasification experiment, with increasing oxygen content, the effective product and calorific value of the gasification product increased.The best gas production effect was obtained when the oxygen concentration was 50-60%.The content of active components in the generated gas was the highest under gasification conditions, with a hydrogen content of 25.1%, CO content of 29.6%, and calorific value of 7.3 MJ/m 3 , indicating that the redox reaction in the gasification reaction was close to equilibrium.(2) The gas production rate and the gas production per unit mass of coal fluctuated, mainly due to the change in the dominance of the oxidation reaction and the reduction reaction during the gasification process.When the oxidation reaction was dominant, the gas production was larger, and when the reduction reaction was dominant, the gas production decreased.The overall coal consumption rate in the experiment fluctuated minimally, the coal consumption rate increased with time, and the average coal consumption rate was 15.46 kg/h.The gas production rate of coal in this experiment showed a cyclic process of gas production increasing first and then decreasing, and Energies 2023, 16, 6993 9 of 10 then increasing again, with an average value of 2.35 m 3 /kg.According to the theoretical calculation of the gasification energy recovery evaluation system, the overall energy recovery rate was 56.34%.The energy utilization rate was high.(3) Various quantitative parameters, namely, the product generation rate, coal consumption rate, gas production per unit mass of coal, and energy recovery rate, have good practical significance for evaluating the gasification efficiency of UCG.The energy recovery evaluation method of the gasification process can be used to better evaluate the reaction process of UCG.

Figure 1 .
Figure 1.Composition diagram of the underground gasification simulation device.Figure 1. Composition diagram of the underground gasification simulation device.

Figure 1 .
Figure 1.Composition diagram of the underground gasification simulation device.Figure 1. Composition diagram of the underground gasification simulation device.

Figure 2 .
Figure 2. Physical map of the underground gasification simulation device.

Figure 3 .
Figure 3. Injection flow rate of the gasification agent.

Figure 2 .
Figure 2. Physical map of the underground gasification simulation device.

Figure 3 .
Figure 3. Injection flow rate of the gasification agent.Figure 3. Injection flow rate of the gasification agent.

Figure 3 .
Figure 3. Injection flow rate of the gasification agent.Figure 3. Injection flow rate of the gasification agent.

Figure 4 .
Figure 4. Variation curves of the oxygen-rich carbon dioxide gas components.

Figure 4 .
Figure 4. Variation curves of the oxygen-rich carbon dioxide gas components.

Figure 5 .
Figure 5. Variation curve of the generated gas.

Figure 5 .
Figure 5. Variation curve of the generated gas.
16,  x FOR PEER REVIEW 7 of 10 rate started to increase after 8 h.The average production rate of the product gas was 34.65 m 3 /h.

Figure 6 .
Figure 6.Variation curve of the product rate.

Figure 7 .
Figure 7. Variation curve of the coal consumption rate.

Figure 6 .
Figure 6.Variation curve of the product rate.

Energies 2023 ,
16,  x FOR PEER REVIEW 7 of 10 rate started to increase after 8 h.The average production rate of the product gas was 34.65 m 3 /h.

Figure 6 .
Figure 6.Variation curve of the product rate.

Figure 7 .
Figure 7. Variation curve of the coal consumption rate.

Figure 7 .
Figure 7. Variation curve of the coal consumption rate.

Figure 8 .
Figure 8. Variation curve of the gas production per unit mass of coal.

Figure 8 .
Figure 8. Variation curve of the gas production per unit mass of coal.

Table 2 .
Analysis of coal elements.

Table 2 .
Analysis of coal elements.