Environmental Impact Analysis of Portland Cement (CEM1) Using the Midpoint Method

The cement industry confronts significant challenges in raw materials, energy demands, and CO2 emissions reduction, which are global and local environmental concerns. Life cycle assessment (LCA) has been used in many studies to assess the environmental impact of cement production and investigate ways to improve environmental performance. This study aims to analyse the environmental impact of Portland cement (CEM I) on the South African cement industry using the life cycle impact assessment (LCIA), based on the Recipe 2016 v 1.04 midpoint method. The study was conducted using data modeled after the South African cement plant, considered a cradle-to-gate system boundary, starting from the extraction of the raw material to the cement production process that produces cement as the main product. The data were obtained from the Ecoinvent database v3.7.1, integrated with SimaPro 9.1.1. software, used to assess the impact categories. For simplicity, the study merged the entire production process into five processes, i.e., raw materials usage, fuel consumption, clinker production, transportation and electricity. The impact categories of the five production stages were assessed using the LCA methodology. The impact categories investigated were classified into three categories: atmospheric, resource depletion and toxicity categories. According to the results, clinker production and electricity usage stages contribute the most to atmospheric impact (global warming, which causes climatic change due to high CO2 emissions), followed by raw materials and fuel consumption, contributing to the toxicity and resource depletion impact category. These stages contribute more than 76% of CO2 eq. and 93% of CFC-11 eq. In the midpoint method, CO2 is the most significant pollutant released. Therefore, replacing fossil fuels with alternative fuels can reduce fossil fuel use and the atmospheric impact of cement kilns.


Introduction
Cement demand in many developing countries has increased rapidly due to the continued expansion of the construction industry, driven by fast urbanization. Cement is among the most used and produced materials in construction globally [1,2]. Despite a significant increase in cement production, from 3280 Mt to 4290 Mt, between 2010 and 2014, it has remained relatively stable at approximately 4100 Mt since 2019 [3]. Recently, attention to environmental protection and interest in environmental issues related to construction grew rapidly, and environmental considerations have become one of the main criteria for formulating social and economic policies [4]. The majority of these efforts have centered on lowering greenhouse gas (GHG) emissions, particularly carbon dioxide (CO 2 ), which is responsible for absorbing heat from the atmosphere. Global warming and resource depletion are among the critical concerns of the cement industry. Cement production has many environmental impacts, varying from high levels of GHG to high resource usage and high energy consumption, i.e., fossil fuels and electricity. Measuring this impact is a such as steel slag in cement production, has already proven to be one of the most effective methods of reducing GHG emissions from cement production [73]. Steel slag showed good hydraulic properties and offered a standard-setting time, contributing to resource, energy, and environmental saving [74]. However, different functional units and impact assessment methods make it difficult to compare LCA studies [5,48,62,75,76]. This study aims to analyse the environmental impact of a cement plant in South Africa that produces Portland cement (CEM1), using life cycle assessment (LCA). The impact categories were classified into three categories: atmospheric, resource depletion, and toxicity categories to achieve this aim.
On average, the cement industry discharges about 500-950 kg of CO 2 /ton of cement produced [77]. This depends on many factors, including the amount of clinker in the cement, the type of fuel used, and the system's energy efficiency [78,79]. Approximately 60% of these emissions are caused by the process (limestone calcination), 35% by fuel combustion, and 5% by electricity application [79]. Wang, et al. [80] discovered five significant factors affecting GHG emissions from cement production, namely: energy emission factor, energy structure, energy intensity, cement production and clinker production. Cement and clinker production activities account for most of the increased GHG emissions. The cement industry contributes the most to global warming, with CO 2 emissions ranging from 98% to 100%. Despite higher characterization factors, other GHGs, for example, CH 4 and N 2 O, have less impact [40,81]. Tun, et al. [82] used the LCA method to evaluate the environmental impact of Myanmar's cement industry, using the Recipe 2016 method to identify the major contributors' environmental impacts. They discovered that the major environmental impacts are climate change, ecosystem damage, photochemical oxidant formation, fine particulate matter formation, terrestrial acidification, and fossil resource scarcity. These impacts are caused primarily by CO 2 , SO 2 , NO x and PM2.5 emissions during the clinker production stage and the use of fossil resources. Marceau, et al. [83] performed an LCI for Portland cement produced in the United States. They found that limestone calcination and fuel burning in the clinker production stage contributed about 60% of the total CO 2 emissions (553 kg per ton of cement) and 39% (365 kg per ton of cement) of total CO 2 emissions, respectively. Feiz, et al. [8] compared the Global Warming Potential (GWP) of three cement products with different clinker contents and found that the product with the least clinker had the lowest value. Thwe, et al. [84] used the LCA approach to assess the environmental impact of OPC production in Naypyitaw, Myanmar. They developed various alternative fuel scenarios for thermal energy consumption. Their study found that current cement production practices cause different environmental impacts, including GHG emissions, eutrophication and acidification, particulate matter formation, photochemical oxidant formation, fossil depletion, etc. These are due to the calcination (clinker production) stage. Rosyid, et al. [85] found that the kiln process activities were primarily responsible for global warming and acidification impact at an Indonesian cement plant. According to Chen, et al. [59], the cement industry has three significant environmental impacts: (1) global warming, (2) respiratory inorganics, which are related to direct emissions from coal and limestone consumption, and (3) non-renewable energy, which is related to energy consumption (i.e., electricity and coal).

A Recipe
A Recipe is a method for LCIA. It was developed due to collaboration between PRé Sustainability, RIVM, Radboud University Nijmegen, and Leiden University, in 2008 [86]. In the Recipe, 18 midpoint indicators and three endpoint indicators are determined. Each method midpoint and endpoint include factors based on three cultural perspectives: individualistic, hierarchist and egalitarian perspectives. These perspectives signify a series of choices about issues, such as time or the expectation that proper management or future technology development can prevent future damage. The individualistic perspective relates to the short-term concern, impact types that are certain, and technological optimism about human adaptation. The hierarchist perspective relates to the scientific consensus model  [87]. Goedkoop et al. [88] developed ReCiPe2008, an LCIA method that includes harmonized category indicators and characterization factors at the midpoint and endpoint levels. Therefore, this study aims to analyse the environmental impact of the production of Portland cement (CEM I) in the South African cement industry, using the LCIA with the Recipe 2016 v 1.04 midpoint method, according to atmospheric, resource depletion and toxicity categories. The LCA methodology was used to estimate the 18 midpoint impact categories, except for water consumption and land use, due to minor impact. This method allows for the identification of environmental hotspots in the production process and compares them with similar production scenarios, assessed using LCA. All cement plants in South Africa are produced via a dry process.

Methodology
Life cycle assessment is a method that has been successfully used for assessing promising environmental impact and resource usage throughout the lifetime of a product, from the acquisition of raw material to the production stage and use phases to waste management [44]. LCA method considers the environmental impact of products, services, and processes. The analysis is conducted according to ISO/TS 14072 guidelines for organizational life cycle assessment. An LCA study must include four stages: goal and scope definition, inventory analysis, impact assessment, and interpretation, with all guidelines followed. Therefore, this section discusses the LCA method of cement production stages and explains how the impact assessment was conducted based on the above stages.

Goal and Scope Definition
The intended goal of this study is to investigate environmental impact based on data availability from a cement production unit. Regarding the system boundary, standard LCA is a cradle-to-grave method. In recent times, cradle-to-gate, gate-to-gate, gate-to-cradle are possible in some cases, even cradle-to-cradle methods. Most studies on the environmental impact of cement use the cradle-to-gate method. As shown in Figure 1, a cradle-to-gate analysis was considered in this study. Cradle-to-gate, includes the acquisition of raw material, transportation (within the plant) and production stages.
In this study, the system boundary was limited to raw material consumption, fuels, electricity use, transportation, production of Portland cement, the final product and emissions from the process. The boundary excluded the packaging unit, waste treatment, cement consumption, final cement disposal as waste due to the methodological issues. Furthermore, 1 kg of cement produced in South Africa was used as the functional unit to compare the results. To simplify the production process, the entire production process merged into five processes, i.e., raw material usage, fuels usage, electricity usage, transportation and clinker production. In this study, the system boundary was limited to raw material consumption, fuels, electricity use, transportation, production of Portland cement, the final product and emissions from the process. The boundary excluded the packaging unit, waste treatment, cement consumption, final cement disposal as waste due to the methodological issues. Furthermore, 1 kg of cement produced in South Africa was used as the functional unit to compare the results. To simplify the production process, the entire production process merged into five processes, i.e., raw material usage, fuels usage, electricity usage, transportation and clinker production.

Life Cycle Inventory
The inventory was developed using average South African cement production data between the 2017-2019 operations. The inventory data for the system background were obtained from the Ecoinvent database v3.7.1 [89]. Ecoinvent's inventory data for South African cement production were primary data collected from five cement plants that characterized 90% of the country's cement industry's market share. The inventory input/output data for 1 kg of the South African Portland cement are included in Table 1.

Life Cycle Inventory
The inventory was developed using average South African cement production data between the 2017-2019 operations. The inventory data for the system background were obtained from the Ecoinvent database v3.7.1 [89]. Ecoinvent's inventory data for South African cement production were primary data collected from five cement plants that characterized 90% of the country's cement industry's market share. The inventory input/output data for 1 kg of the South African Portland cement are included in Table 1. According to Petek Gursel, et al. [46], developing a life cycle inventory includes quantifying and gathering all inputs, outputs, energy consumption and waste generation related data to make a functional unit of the product within the system boundary investigated. The data include all raw materials and energy used in the production process. The figures are computed based on original data on South African cement production.

Life Cycle Impact Assessment
The LCIA process combines the inputs and outputs quantified in an Inventory Analysis to estimate their potential environmental impact. There are a variety of LCIA methodologies available, with some of them being included in commercial software [90]. Most methods are based on impact categories and characterization factors and include the following steps: classification, normalization, characterization and valuation. In classification, the environmental impact measured in the inventory is grouped into a limited set of recognized environmental impact categories considering the scientific information available about the processes. The study's goal guides selecting correct impact categories and practical considerations should limit their number. In the LCIA methodology, the characterization step assessed the relative contribution of each environmental impact [91]. The characterization is done by multiplying each substance's amount by its characterization factor and adding all of the figures together. Characterization factors are substance-specific, measurable interpretations of a substance's potential impact per unit emission. They determined each impact category that a substance/process could possibly contribute to [92]. Equation (1) represents generic factors while Equation (2) represents non-generic factors; the former factor is usually the outputs of characterization models and is accessible in the literature as a database.
where S j = impact category j indicator m i = size of the intervention of type i Q j,i = characterization factor that links intervention i to impact category j [93].
Equation (2) represents some non-generic characterization factors potential variables in the human health and the natural environment impacts setting [93].
where subscript i = substance, s = location of the emission, l = related exposure area of the receptor t = period during which the potential contribution to the impact is considered [93].
The normalization stage of the LCIA method refers to a process used to compare impacts across impact categories and protected areas to prioritize product alternatives or resolve trade-offs between them [93]. This stage also discovers an impact category that has little or no impact on the overall environmental impact, reducing the number of factors that must be evaluated. According to Finnveden, et al. [94], normalization has two goals: placing LCIA indicator results in a broader context and adjusting the results to have common dimensions. A reference value is used to divide the sum of each category indicator result.
where k = impact category N = normalized indicator S = category indicator from the characterization phase R = reference value.
The reference system is generally selected by considering the result of the overall indicator for a specific country or region for a particular year. In an LCA study, the results of the normalization can allow input grouping or weighting impact categories or directly  Table 1. The method is known as Recipe because it offers a "recipe" for calculating impact category indicators. Furthermore, this method combines two well-known techniques, resulting in a unified and consistent impact assessment structure. For simplicity, the impact categories investigated were grouped into atmospheric, resource depletion, and toxicity categories. These impact categories are affected by the substances listed in the inventory. Table 2 includes the midpoint impact categories and they can be classified as local, regional, and global impact of cement production. The inputs and outputs in the cement production system shown in Figure 2 are divided into five production stages: raw materials consumption, production fuels consumption, clinker production, transportation and electricity. Each stage is linked to the impact categories studied using the LCA methodology. All calculations were done using SimaPro 9.1.1 software application [87,95]. Table 3 shows all processes studied in each production stage.     Table 3. Processes studied in each production stage of Portland cement in South Africa.

Raw materials Limestone and steel. Clinker and ethylene glycol, including the inputs and outputs Fossil fuels
Diesel, coal, light fuel oil and lubrication oil, including inputs and outputs. Electricity Electricity used in mills and other equipment, in agreement with South Africa production and distribution regulation Transportation The transportation of raw materials, fuels and energy resources from the extraction site up to the gate of the plant Clinker production Particulate matter, NO x , CO 2 , emitted by the kiln during clinker production Figure 2 presents the contribution of each of the five production stages to atmospheric impact categories. Global warming is the most studied impact related to cement production and is measured in kg CO 2 eq [8,59,78,[96][97][98][99][100].

Results and Discussion
Global warming potential (GWP): Clinker production showed a high contribution, with 7.63 × 10 kg CO 2 eq, to those impact in this study due to the high CO 2 emissions associated with clinker production. This means 1 kg of cement produced emitted 1 kg CO 2 eq, whereas other compounds, such as 1 kg of methane is equal to 25 kg of CO 2 eq. According to earlier studies, CO 2 emissions from cement production (calcination reaction and coal burning) are major GWP contributors [8,40,48,76,101]. Cement production emitted an average of around 0.8-1.0-ton CO 2 /1 ton of Portland cement globally [8,11,102].
Furthermore, global warming has been one of the most widely studied impact categories in the broader LCA literature. This study discovered that the clinker production stage is the primary source of GHG emissions and this is consistent with most studies [8,59,78,96,99,100,103]. According to Wang et al. [80], the clinker production stage is the primary source of GHG emissions in the cement industry. In this study, the South African cement industry contributed 9.93 × 10 −1 kg of CO 2 eq to GWP. This result is consistent with the values reported in the literature, ranging from 0.628 kg to 0.92 kg CO 2 eq per 1 kg of cement [40,59,104,105].
Ozone depletion (OD) happens when the rate of ozone destruction is accelerated by recalcitrant chemicals from anthropogenic emissions containing chlorine or bromine atoms [88,106]. The OD impact is measured in kg CFC11 eq (trichlorofluoromethane or Freon11) and contributed to all the stages, except clinker production. The raw materials consumption and electricity usage were due to limestone extraction and raw material transportation to the plant. The 1.90 kg CO 2 eq value can be explained by the different fuel mix and the effect of transportation considered. The ozone depletion value from this study is 1.94 × 10 −7 kg CFC11 eq. The result is in line with previous studies, i.e., 3.97 × 10 −6 to 2.54 × 10 −4 kg CFC11 eq [57,59].
The electricity usage contributes to all atmospheric impact categories, except Ionizing radiation, as shown in Figure 2. The highest harmful atmospheric impact category of the raw material consumption stage was ionizing radiation impact, due to the limestone extraction. Furthermore, emissions from other production stages contributed to atmospheric impacts.
The ozone formation (terrestrial ecosystems and human health) contributed to all the production stages. It is affected by the atmospheric impact, mainly on clinker production and electricity usage. The contribution of the obtained clinker, which is considered a raw material in cement production, cannot be overlooked when it comes to transportation.
Fine particulate matter (FPM) is measured in kg PM2.5 eq and it contributes to atmospheric impact production stages. The FPM contribution is due to the coal used in electricity production during the raw material consumption stage. The atmospheric impact from the clinker production and fuel consumption stage also contributed to the calculation. The size of CO 2 released from cement production clarifies why CH 4 and N 2 O have more significant characterization factors among GHGs pollutants and leading causes of climate change. Figure 3 presents the contribution of each of the five production stages to resource depletion impact categories impact from the clinker production and fuel consumption stage also contributed to the calculation. The size of CO2 released from cement production clarifies why CH4 and N2O have more significant characterization factors among GHGs pollutants and leading causes of climate change. Figure 3 presents the contribution of each of the five production stages to resource depletion impact categories Terrestrial acidification (TA) contributed to all production stages. Electricity usage is the main contributor due to the mix, dominated by fossil fuel, followed by clinker production and other resource depletion impacts. TA is a regional environmental impact, primarily related to the SO2 and NOx emissions during fuel burning for calcination and transport, as identified in other cement LCAs [11,82]. The result of the Terrestrial acidification 2.44 × 10 −3 kg SO2 eq in this study is in line with Li et al. [105], in the range of 1.144-1.467 kg SO2 eq and Josa et al. [40], in the range of 0.71-3.33 kg SO2 eq. Clinker production due to coal burning contributed to the value of 3.60 × 10 in the resource depletion category. Terrestrial acidification (TA) contributed to all production stages. Electricity usage is the main contributor due to the mix, dominated by fossil fuel, followed by clinker production and other resource depletion impacts. TA is a regional environmental impact, primarily related to the SO 2 and NO x emissions during fuel burning for calcination and transport, as identified in other cement LCAs [11,82]. The result of the Terrestrial acidification 2.44 × 10 −3 kg SO 2 eq in this study is in line with Li et al. [105], in the range of 1.144-1.467 kg SO 2 eq and Josa et al. [40], in the range of 0.71-3.33 kg SO 2 eq. Clinker production due to coal burning contributed to the value of 3.60 × 10 in the resource depletion category.
Freshwater is measured in phosphorous (kg P eq) and Marine Eutrophication (ME) is measured in nitrogen (kg N eq) equivalent. They are primary contributors to clinker production and raw material consumption due to SO 2 and fewer NO x emissions. The ME contribution to the raw material consumption stage is due to ammonia emissions from explosives, with 2.67 kg N eq. Marine eutrophication is influenced by nitrogen compounds, produced primarily by the oxidation of molecular nitrogen in combustion air (thermal NO x ) and the nitrogen compounds oxidation in fuel (fuel NO x ) [107].
Fossil resource scarcity is measured in oil equivalent (kg oil eq) and contributes mostly to fuel consumption. However, if fossil fuels control the fuel mix used to generate electricity, this can affect terrestrial acidification. In addition, mineral and fossil resources scarcity contribute to raw material consumption and clinker production due to fuel burning and the explosives used, as identified by Stafford et al. [57].
The contribution of the transportation stage to the terrestrial acidification (3.40 kg SO 2 eq) value was due to the transportation of raw materials and fossil fuels in clinker production. Fuels used as primary energy sources in cement production, such as crude oil, natural gas, and coal, contributed to the value of fossil resource scarcity (1.39 × 10 −1 kg oil eq) in cement plants.
The freshwater ecotoxicity and marine ecotoxicity impact categories showed similar profiles. The main contributors to the toxicity impact are raw material and fuel consumption due to fossil fuel extraction and raw material extraction, obtained with the values of 4.19 × 10. Fossil consumption contribution is attributed to coal burning. The low toxicity in transportation was due to energy usage during raw material transportation.
The human carcinogenic toxicity contribution to the fuel consumption stage was due to the coal burning in the kiln and electricity generation for the process. Human non-carcinogenic toxicity is also crucial in fuel consumption and raw material. Due to the efficient use of electricity in South African cement plants, electricity usage makes no significant contribution to any impact category. The average consumption in the United States is 142 kWh/ton of cement, while 110 kWh is consumed in South Africa [108,109]. Figure 4 presents the contribution of each of the five production stages to the toxicity impact categories. scarcity contribute to raw material consumption and clinker production due to fuel burning and the explosives used, as identified by Stafford et al. [57].
The contribution of the transportation stage to the terrestrial acidification (3.40 kg SO2 eq) value was due to the transportation of raw materials and fossil fuels in clinker production. Fuels used as primary energy sources in cement production, such as crude oil, natural gas, and coal, contributed to the value of fossil resource scarcity (1.39 × 10 −1 kg oil eq) in cement plants. Figure 4 presents the contribution of each of the five production stages to the toxicity impact categories. The freshwater ecotoxicity and marine ecotoxicity impact categories showed similar profiles. The main contributors to the toxicity impact are raw material and fuel consumption due to fossil fuel extraction and raw material extraction, obtained with the values of 4.19 × 10. Fossil consumption contribution is attributed to coal burning. The low toxicity in transportation was due to energy usage during raw material transportation.
The human carcinogenic toxicity contribution to the fuel consumption stage was due to the coal burning in the kiln and electricity generation for the process. Human non-carcinogenic toxicity is also crucial in fuel consumption and raw material. Due to the efficient use of electricity in South African cement plants, electricity usage makes no significant contribution to any impact category. The average consumption in the United States is 142 kWh/ton of cement, while 110 kWh is consumed in South Africa [108,109].
Although there are some differences in the methods, it is widely agreed that the atmospheric category from the kiln is the primary cause of impact in the cement industry. As shown in Figure 4, these impacts depend on the fuels used, raw materials and installed technology. The Cement Sustainability Initiative states that replacing fossil fuels in cement production could reduce atmospheric emissions, if well controlled, and can be an excellent Although there are some differences in the methods, it is widely agreed that the atmospheric category from the kiln is the primary cause of impact in the cement industry. As shown in Figure 4, these impacts depend on the fuels used, raw materials and installed technology. The Cement Sustainability Initiative states that replacing fossil fuels in cement production could reduce atmospheric emissions, if well controlled, and can be an excellent means of reducing fossil fuel usage [110]. According to Ecoinvent, extracting 100 kg of diesel oil can release 62.7 kg CO 2 eq and contribute 127 kg oil eq to fossil depletion [89].
The heavy use of traditional fuels (coal) in the South African cement kiln can be replaced with alternative fuels, for example, waste-derived fuels. Using waste-derived fuels instead of traditional fuel reduces emissions and fossil resources used in the cement industry, making it a sustainable method for recycling various waste materials [111,112]. Hence, it could be agreed that the choice of materials and fuels directly influence the relationship between the cement plant and the environment.

Conclusions
In this study, the cement production stages, i.e., raw materials consumption, production fuels consumption, clinker production, transportation and electricity, were analyzed using the life cycle assessment method. The findings show that each process impacted the environmental categories, according to atmospheric, resource depletion and toxicity categories. The environmental impact of each process of cement production was proportional to the related inputs and outputs. In terms of the atmospheric impact of cement production, the kiln affected all impact categories, except ozone depletion and ionizing radiation. The kiln caused most of the global warming impact. This was expected, as limestone calcination, the primary source of CO 2 emissions, is known to contribute to global warming. The clinker production stage produces the most significant environmental emissions due to calcium carbonate decomposition and coal consumption, particularly GHG emissions. Global warming is affected by GHGs emission.
The study's findings show that massive raw materials consumption and fossil fuels are the factors that have the most impact on the resource depletion and toxicity categories. The production of fossil fuels significantly contributed to the atmospheric impact category. In addition, the consumption of electricity was also a significant factor, contributing to the atmospheric impact from fossil fuels used in generating electricity. Thus, using alternative raw materials and fuel could be a sustainable way to reduce environmental emissions. According to the characterization results of the mid-term analysis, the highest environmental impact of cement production was on global warming, terrestrial ecotoxicity, human non-carcinogenic toxicity and fossil resource scarcity. For each 1 kg of Portland cement produced, the highest environmental impact values were 9.93 × 10 −1 kg CO 2 eq (global warming), 1.04 kg 1.4-DCB (terrestrial ecotoxicity), 4.97 × 10 −1 kg 1.4-DCB (human non-carcinogenic toxicity), and 1.39 × 10 −1 kg oil eq (fossil resource scarcity).
Apart from the fossil resources' scarcity, which is linked to the consumption of fossil resources, other impacts are related to direct emissions from the clinker production stage. In this situation, measures to improve the South African cement industry's sustainability should focus primarily on reducing emissions from the clinker production stage by upgrading the production process, increasing the ratio of clinker substitutes, such as slag and fly ash, the use of alternative fuels to reduce coal and fossil fuel use, and improving energy efficiency. Finally, further research is recommended concerning efficiency measures to reduce the environmental impact, using energy-efficient technologies in the kilns and implementing on-site energy recovery technologies.
This study indicated that the South African cement industry is responsible for significant environmental impacts, including global warming, terrestrial ecotoxicity, human non-carcinogenic toxicity and fossil resource scarcity, all identified as hotspots in the midpoint method. The main factors contributing to these impacts are CO 2 , NO x , SO 2 , and PM2.5 emissions. These are direct emissions from the clinker production and fuel consumption stage for energy (electricity and transportation). As the main impact hotspots have been identified, the options of implementing energy-efficient technologies and on-site energy recovery technologies can be considered, including fuel and energy-saving approaches and alternative fuels and materials. With the energy-efficient technologies option, fossil resource scarcity can effectively reduce and encourage the utilization of scarce resources sustainably. There are many ways to implement energy-efficient technologies options, including process integration and modification, proper maintenance, plant optimization, and energy recovery. For example, process modifications, switching from a wet to dry process, using a pre-calciner, could reduce thermal energy consumption in cement kilns by about 50%, resulting in a 20% reduction in CO 2 emissions [78]. Another promising way to reduce CO 2 emissions is through energy recovery from exhaust streams. During the clinker production stage, there are thermal heat losses in pyro-processing due to the flue gas and hot air streams. The heat losses can be recaptured to produce electricity using steam turbines [78]. On-site energy recovery technology options include using alternative materials, fuels and the clinker used during the cement production process [78]. The chemical decomposition of CaCO 3 in the clinker production stage contributes the most to CO 2 emissions. It is possible to reduce CO 2 emissions during this stage by reducing the amount of clinker and replacing it with other supplementary cement materials, such as natural pozzolana (fly ash, slag, etc.). The high process temperature in cement kilns can help burn waste efficiently. Using waste co-burning or biomass material as a fuel substitute can, thus, reduce the amount of coal or fossil fuels needed in the clinker production stage (the kiln), thereby reducing CO 2 and other emissions. Furthermore, it provides a sustainable waste management solution, as it contributes to GHGs reduction and other air pollutants released by the open burning of waste [15].