An N-type Naphthalene Diimide Ionene Polymer as Cathode Interlayer for Organic Solar Cells

: Polymer solar cells (PSCs) based on non-fullerene acceptors have the advantages of synthetic versatility, strong absorption ability, and high thermal stability. These characteristics result in impressive power conversion efﬁciency values, but to further push both the performance and the stability of PSCs, the insertion of appropriate interlayers in the device structure remains mandatory. Herein, a naphthalene diimide-based cathode interlayer (NDI-OH) is synthesized with a facile three-step reaction and used as a cathode interlayer for fullerene and non-fullerene PSCs. This cationic polyelectrolyte exhibited good solubility in alcohol solvents, transparency in the visible range, self-doping behavior, and good ﬁlm forming ability. All these characteristics allowed the increase in the devices’ power conversion efﬁciencies (PCE) both for fullerene and non-fullerene-based PSCs. The successful results make NDI-OH a promising cathode interlayer to apply in PSCs.


Introduction
Polymer solar cells (PSCs) have emerged as a promising renewable energy technology thanks to the low-cost solution processed methods, their characteristic light weight, and the possibility to realize flexible and semitransparent devices [1][2][3][4]. Thanks to continuous research efforts spanning from the design of donor and acceptor materials [5] to device architecture [6], in the last year, the power conversion efficiency (PCE) of PSCs has exceeded the incredible value of 18% [7] in single junction lab-scale device and 10% in large-area photovoltaic modules [8], improving the differences with other competitive technologies.
After many years spent on optimizing the fullerene acceptor (FA) structure, at present, much attention focuses on non-fullerene acceptor (NFA) materials; these are low band gap materials with easily tunable HOMO-LUMO values and strong absorption in the nearinfrared region [9][10][11][12]. The use of new acceptors led to higher performance when compared to FA organic solar cells but, beyond the photoactive film, other fundamental layers in solar cells are the anode interlayer (AIL) and the cathode interlayer (CIL), needed to improve device performance. Indeed, these are an effective tool to optimize charge extraction selectivity and to reduce recombination and contact resistance [13][14][15][16]. The increasing number of photoactive materials opens the urgent request to find universal interlayers for PSCs, efficient for a wide range of materials and thickness insensitive [17][18][19].
Beside polyfluorenes derivatives, perylene diimides-(PDIs) and naphthalene diimides-(NDIs) based compounds have recently received great attention thanks to the possibility to modify the electrodes' work function to easily transport carriers and self-doping behavior [24,25]. PDI polyelectrolytes already work efficiently as CIL in PSCs despite the high absorption in the visible range, [32] but only a few NDI-based polyelectrolytes have been used in NFA-based PSCs [33][34][35][36].
With the aim to combine the cathode engineering capability of the PDI polyelectrolytes with higher transmittance in the visible range, we have designed and synthetized a novel NDI-based polyelectrolyte.
Herein, we propose an NDI-based ionene polymer electrolyte (NDI-OH) with an easy three-step synthesis. This compound shows self-doping behavior, and it can be used as a transversal cathode interlayer, working efficiently both with fullerene-and non-fullerenebased solar cells. The polar hydroxyl group, introduced by an anionic exchange reaction, imparts water/alcohol solubility. Remarkably, upon NDI-OH insertion as CIL, both FAand NFA-based PSCs (i.e., PTB7-Th: PC 71 BM and PTB7-Th/ITIC) gained higher PCE with respect to no CIL and equated the optimized PFN and evaporated Ca used as a benchmark. Nevertheless, the NDI-OH interlayer does not suffer for thickness dependence, obtaining stable PCE by increasing the layer thickness in the device.
NMR spectra (1H at 400 MHz) were recorded on a Inova Varian NMR spectrometer equipped with a 5 mm ATB 1H/19F/X PFG Broadband Probe using standard pulse sequence and D 2 O or CDCl 3 as a solvent.
The molar masses of the polymers were performed on Shimadzu system equipped with an RI detector, using a two-column configuration (8 × 300 mm PFG-type columns with 7 µm and porosity of 1000 Å and 100 Å, provided by Polymer Standards Services GmbH, Mainz, Germany). The system was operated in 2,2,2-trifluorethanol (TFE) at a flow rate of 1 mL/min and RT. PMMA (Polymer Standards Services GmbH, Mainz, Germany) calibration was used.
The absorption spectra were recorded using a Perkin Elmer Lambda 900 spectrometer. PL measurements were performed on a modified NanoLog-TCSPC (Horiba) with a monochromated Xenon lamp excitation source. All the PL spectra are corrected for the instrument response and measured in the backscattering mode in air at room temperature.
ATR-FTIR spectra were obtained on a spectrophotometer Nicolet 8700 (Thermo Fisher Scientific, Madison, WI, USA) using KBr, with a deuterated triglycine sulfate and thermo-electricity cooled (DTGS TEC) detector in the region of 4000-600 cm −1 at a resolution of 4 cm −1 using the absorbance mode.
The EPR analysis was made using Bruker WinEPR Processing (Billerica, MA, USA). The measurements were performed on a comparable amount (10.5 mg) of polyelectrolyte in the solid state and measured at RT and after heat treatment. The samples were heated to 120 • C for 1 h in the presence of argon.
The experimental conditions had an X-band frequency of 9.12 GHz, a power of 1 mW, Gain 20, and a temperature of 25 • C.
Cyclic voltammetry measurements were performed with a laboratory potentiostat/galvanostat Autolab PGSTAT 302N with an impedimetric module (Ecochemie, Utrecht, The Netherlands). A three-electrode system consisted of Ag/AgCl/3 M KCl reference electrode, a counter Pt electrode (Bioanalytical systems, USA), and the glassy carbon (d = 3 mm) as a working electrode (ProSense B.V., The Netherlands) was applied. All cyclic voltammetry (CV) measurements were recorded at a sweep rate of 100 mV s −1 . The electrochemical procedures were run under Nova Software 1.10, and the acquired data were evaluated using OriginPro 9.1. For analysis, tetrabutyl-ammonium hexafluorophosphate (Bu 4 NPF 6 , 0.1 M) in acetonitrile and polyelectrolyte with concentration 0.1% w/w was used. Ferrocene was used as the internal standard.
Atomic force microscopy (AFM) measurements were performed using a commercial AFM (NTMDT NTEGRA) used in tapping mode with a cantilever NSG10 operating at a typical resonance frequency of 140-390 kHz. The deposition of the films was identical to device fabrication. The thicknesses of the layers were obtained using a Bruker Dektak stylus profiler. All the reported values are the average of five measurements in different areas of the layer to check the uniformity of the deposited films. For the fabrication of PSCs, glass substrates (25 × 25 × 1.1 mm 3 ) coated with indium tin oxide (ITO) with a sheet resistance of 15 Ω/sq were used. After mechanical cleaning with fiberless paper, the substrates were sonicated at 50 • C in water, acetone, and finally in 2-propanol for 10 min each step. After being dried with an N 2 gun, the substrates were treated in ozone plasma for 2 min. Immediately after the plasma treatment, a solution of PEDOT:PSS (Heraeus, Al 4083) is filtered by using a 0.45 µm PVDF filter and deposed on ITO to obtain a 35 nm thick layer by spin coating (3500 rpm, 60 s). The films were thermally annealed at 150 • C for 10 min. After cooling down the substrates, a layer of active material was spin coated inside an N 2 -filled glovebox. PTB7-Th and PC 71 BM were dissolved at a composition of 1:1.5 weight ratio in chlorobenzene, with a solute concentration of 25 mg/mL. This solution was stirred overnight at 65 • C. Next, 10 min after adding 2% v/v of 4-methoxybenzaldehyde to the solution, the blend was spin coated at 1200 rpm in order to obtain films with a thickness of 100 nm. The samples were left at room temperature for 10 min and then annealed for 20 min at 60 • C. PTB7-Th and ITIC were dissolved at a composition of 1:1.2 weight ratio in a 20 mg/mL chlorobenzene solution and stirred overnight at 65 • C. The blend films were spin coated at 1500 rpm and annealed for 10 min at 120 • C, obtaining a film with 100 nm thickness. The NDI-OH was dissolved in MeOH with a concentration of 1 mg/mL and the deposition on top of the active layer is done by spin coating at different spin speeds (from 1000 to 4500 rpm, obtaining from ca. 35 nm to less than 10 nm of CIL). The PFN was dissolved at 0.2 mg/mL in methanol, with the addition of 0.25% v/v of acetic acid, to obtain CIL films of ca. 5 nm upon spin coating. The metal cathode consisting of 80 nm of Ag layer or Ca (10 nm)/Ag was finally thermally evaporated in high vacuum (8·10-7 bar) with a metal evaporator. The final device area is 6.1 mm 2 .
The current density-voltage measurements were performed in glovebox with a Keithley 2602 source meter under AM 1.5 G solar simulation (ABET 2000).
External quantum efficiency (EQE) spectral responses were recorded by dispersing an Xe lamp through a monochromator, using a Si solar cell with calibrated spectral response to measure the incident light power intensity at each wavelength. The devices were taken outside the glovebox for the EQE measurements, after mounting them on a sealed cell to avoid moisture and oxygen exposure.

Material Synthesis and Characterization
The synthesis of NDI-based ionene polymer is shown in Figure 1. The polymer is obtained through a quaternization reaction without the use of metallic catalysts, which is extremely important for ultimate applications in organic electronic devices. The resultant cationic polymer NDI-OH is a polyelectrolyte containing the charged units within the polymer backbone, assuring higher ionic density with respect to polymers containing pendant ionic moieties [37]. Moreover, it is soluble in alcohol, and thus it can be spin coated from orthogonal solvents with respect to the active layer. Synthesis of NDI-Br. To the previously prepared NDI (1.4 g, 3.4 mmol), 1,3-dibromopropane (0.68 g, 3.4 mmol) and DMF (40 mL) was added. After bubbling with Ar for 20 min, the reaction mixture was heated to 100 • C for 72 h. During the reaction 5 mL water was added gradually every 12 h. Then the reaction was cooled down, followed by the evaporation of water. The mixture was then precipitated into THF. Subsequently, the precipitate was collected and was extracted by acetone, ethanol, and water. The water fraction was then collected and precipitated into THF. The collected brown solid was then dried under a vacuum. The obtained product (1.5 g) was kept under argon. 1  Cyclic voltammetry (CV) measurements were carried out to determine the HOMO-LUMO energy levels. As shown in Figure S1, the reduction potential onset (E on red ) for NDI-OH is −0.70 V. From the empirical formula E LUMO = −e(E red −E ferr ) +4.8 eV and E HOMO = E g opt + E LUMO , the HOMO and LUMO energy levels of NDI-OH are calculated to be −6.80 eV and −3.69 eV, respectively.
The optical properties of NDI-OH as solid film were investigated by UV-Vis absorption spectroscopy. As depicted in Figure 2a, NDI-OH exhibits a broad absorption with a peak centered at 361 nm, which is assigned to the π-π* transition of the NDI's units. The absorption spectrum exhibits a tail above 400 nm that might be a hint of the presence in NDI-OH films of some delocalized radical anions due to a self-doping effect; i.e., an electron is transferred from the ionic moiety to the naphtalene units [35]. Upon thermal annealing under N 2 atmosphere for 10 min at 120 • C, a radical anion signature at 450 nm is observed [38], suggesting an increased electron transfer ability. The IR absorption spectrum of the NDI-OH film ( Figure S2) also shows some modifications, such as a decrease in the NDI's C = O modes and enhancement of the ring modes oscillator strengths after thermal treatment that are consistent with NDI's radical anions formation.
Electron paramagnetic resonance (EPR) spectroscopy measurements were conducted to further investigate the interaction between the ionic moieties and naphthalene units in solid state. The results are reported in Figure 2b. After heat treatment, the singlet of NDI-OH sample increased its intensity, which confirms the higher self-doping ability. Note that in the solid state, an enhancement of the self-doping ability after a thermal treatment under a dry atmosphere was already observed in a perylene diimide-(PDI)based electrolyte bearing -N(CH 3 ) 3 + OH − polar groups [39]. With PDIs, this effect was ascribed to a dehydration of the −N(CH 3 ) 3 + OH − group, which favors the electron transfer from the OH − to PDIs. The same effect can reasonably occur also in NDI-OH. Such dehydration is triggered by the thermal treatment, but might also naturally occur in the drybox, where the solar cells are assembled and tested. To understand whether NDI-OH has suitable properties for use as cathode interlayer in PSCs, we probed its energy level alignment to the PC 71 BM and ITIC acceptors by steady state photoluminescence measurements (PL) ( Figure S3). For these experiments, the photoluminescence of the acceptor films here under study were recorded with a thin layer of NDI-OH deposited on top of the acceptor. For comparative studies, thin layers of PFN were also used. The PL spectra of ITIC are reduced in intensity when in contact to the NDI-OH interlayer when compared to the PFN. This suggests that an electron transfer from the ITIC to the interlayer is facilitated with NDI-OH.
With the NFA, the lower LUMO level of NDI-OH (−3.69 eV) compared to PFN (−2.14 eV) forms a better energy-level alignment at the cathode interface with ITIC (LUMO −3.78 eV). Indeed, a smaller energy offset between ITIC and NDI-OH compared to PFN, facilitates the electron transfer which is clearly demonstrated by the ITIC PL quenching in the NDI-OH/ITIC films. Moreover, the low-lying HOMO value of −6.80 eV for NDI-OH means that holes from various donors will be blocked sufficiently at the cathodes, with the NDI-OH derivative used as CIL.
This is not the case for PC 71 BM in contact with PFN or NDI-OH, in which the PL spectra seems pretty similar. Even though the PC 71 BM exhibits a relatively low intensity, such behavior is anyhow different from the ITIC one. This might arise from a higher energy offset that hinders the electron transfer from the PC 71 BM to both the interlayers.
These results encouraged us to explore NDI-OH as a cathode interlayer not only in FA-PSCs, but also in NFA-PSCs, where having a good energy level alignment among the acceptor and the interlayer is particularly important [40].
We fabricated conventional devices with a structure of ITO/PEDOT:PSS/Active Layer/NDI-OH/Ag, as shown in Figure 3. The active layer contains PTB7-Th as the donor component and fullerene (PC 71 BM) or non-fullerene (ITIC) as acceptors. Figure 3 shows the chemical structures of the photoactive materials. To investigate the NDI-OH performance in PSCs, some reference CIL have been chosen. The NDI-OH layer has been compared with no IL and some benchmarks in the literature such as evaporated Calcium (Ca) and spin coated PFN by using the same solar cell geometry.
The photovoltaic performances of the fabricated PSCs were evaluated under AM 1.5 G solar simulation at one sun (100 mW cm −2 ). The J-V curves of the devices in light conditions are shown in Figure 4 and their PV characteristics are resumed in Tables 1 and 2 for clarity. The external quantum efficiency (EQE) spectra are measured on the best devices obtained and shown in Figure 4b,d. For both FA and NFA PSCs, the use of NDI-OH as CIL brings better device performance in comparison with those without IL and improved or similar performance with devices containing PFN. For fullerene-based PSCs, the use of NDI-OH as CIL provides encouraging results. The devices' performances are similar to those obtained with the PFN benchmark and exhibits an improvement compared to the interlayer-free device. Indeed, the presence of the IL permits to enhance V OC from 0.66 V without CIL to 0.73 and 0.74 V in the case of PFN and NDI-OH, respectively.
When NFA-based solar cells are studied, the PCE enhancement upon IL addition is relevant. The comparison between the different interlayers is shown in Figure 4c. The V OC is improved from 0.58 V without CIL to 0.73 V for PFN and 0.79 V in the case of Ca and NDI-OH.
A common feature for FA and NFA PSCs is the increase in V OC when NDI-OH is used as an interlayer, thanks to the enhanced built-in voltage, as shown with the dark J-V curves of the devices in Figure S4 [41]. This behavior is typical for polar/ionic organic semiconductors interlayers and it is due to the cationic groups of NDI-OH, forming dipoles at the active layer/electrode interface, that induce an up-shift of the cathode electrode work function [26,42]. This is unable to enhance the electron selectivity of the Ag electrode, leading to an improvement of the Voc parameter. Such enhancement of the Voc by the insertion of the NDI-OH interlayer is particularly noticeable in NFA PSCs. This is because the increase in the Ag cathode electrode's selectivity imparted by the interlayer is becoming particularly important when using ITIC as an acceptor, due to its lower LUMO level as compared to fullerene.
Interestingly, the photovoltaic performance of the NDI-OH based NFA PSCs exhibit good tolerance to the NDI-OH thickness variation in fabricating the OSC devices, which is important for large area fabrication of the OSCs. While the commonly used PFN CIL works well with very thin thicknesses [43], when the NDI-OH thickness rises up to 35 nm, the PCE of the devices has very small variations and maintains values around 5% (Table S1). Impressively, the V OC still maintains a high value of 0.76-0.77 V when the NDI-OH thickness is further increased to 35 nm, indicating a good electron-transport and collection ability of the NDI-OH CIL. Table S1 shows the effect of CIL thickness on the photovoltaic performance of the NDI-OH-based OSCs. The PCE decreased from 5.22% for the optimized device with NDI-OH thickness of <10 nm to 4.73% for the OSC with NDI-OH thickness of 35 nm.
From the above findings, we can safely conclude that NDI-OH interlayer exhibits the right PV functionality to increase the Ag electrode selectivity and enables a suitable energy level alignment at the NFA/IL interface. Moreover, the NDI-OH also function as an electron transport layer, as supported by the good tolerance to the NDI-OH thickness variation. These factors contribute to a reduction in the contact resistance at both interfaces and favor charge extraction. In this condition, we would expect an increase in the FF parameter and a reduction in the series resistance (Rs).
As shown in Table 2, the FF is indeed increasing by NDI-OH IL, but no changes are observed in the series resistance. Furthermore, as depicted in Table 1, when going to FA devices, the Rs also stays unmodified and the FF is not improving.
To get some insight, we performed atomic force microscopy (AFM) analysis, shown in Figure 5. From these images, it is possible to appreciate the different morphology between PFN and NDI-OH, compared with the bare active layer. Reported on the images, the RMS values are almost identical and lower than 1.5 nm, meaning a good film-forming ability and a complete coverage of the CILs on the photoactive blend. Small holes can be identified in NDI-OH layer, meaning a slight dewetting of the layer. This dewetting might reduce the quality of the interfaces, thus affecting the Rs. We suppose that the same dewetting is present also when NDI-OH is deposited onto PC 71 BM and this could be consistent with the slight FF reduction reported in Table 1.

Conclusions
In summary, we have designed and synthesized an n-type self-doped naphthalene diimide ionene polymer (NDI-OH), containing the ion moiety in the backbone. NDI-OH has all the excellent chemical and electronic features: PFN, NDI-OH has good solubility in alcoholic solvents, it is less reactive than Ca, it has suitable HOMO-LUMO energy levels, and it is prone to thickness insensitivity when used as CIL. EPR measurements indicate self-doping properties of NDI-OH, which are enhanced upon annealing. Importantly, the interaction between NDI-OH and the acceptor component in NFA PSC is more evident, demonstrated by photoluminescence quenching. Indeed, the photovoltaic performances of NFA PSCs containing NDI-OH as cathode interlayer have comparable efficiencies with those containing the optimized PFN and the evaporated Ca, while for the FA the device performances increased with respect to no IL. Moreover, the NDI-OH demonstrates a good tolerance to interlayer thicknesses, which is an advantage to envisage the scaling-up to industrial application for OSCs.

Data Availability Statement:
The data presented in this study are available in the article and Supporting Information.