The Application of Silica-Based Aerogel Board on the Fire Resistance and Thermal Insulation Performance Enhancement of Existing External Wall System Retroﬁt

: Due to the need of good thermal performance, external wall insulation (EWI) is usually made of materials that are not ﬁre resistant and sometimes ﬂammable. That restricts its application to a particular circumstance such as limited building height. Hence, a material with good thermal insulation and ﬁre resistance performance would allow EWI to be more widely applied. This paper introduces a novel material: a silica-based aerogel porous board, which differs itself from mainstream products available in the market because of its outstanding properties, such as low density, high surface area, low thermal conductivity and superhydrophobicity. Herein, its thermal insulation and ﬁre-resistant performance were tested and compared with commercial products. The cone calorimeter analysis results indicated that the aerogel porous board could improve the ﬁre resistance performance. Moreover, the evaluation of thermal insulation performance suggested that the application of an aerogel porous board on the external stone wall of existing buildings can decrease the U-value by 60%. Through the detailed insight into the case-study, it is quite clear that the carbon impact of building stock could be greatly reduced by means of a coherent set of building envelope retroﬁtting actions based on this innovative heat insulation material, without compromising the ﬁre safety. values show a signiﬁcant reduction compared with the rest of building insulation materials. It is worth noting that the THR value of the aerogel porous board was 3.0 MJ/m 2 , a drop of 77.4% compared with the ﬂame retardant rigid PU foam board (13.3 MJ/m 2 ). These results indicated that the aerogel porous board can dramatically inhibit the combustion intensity and restrict the heat release during combustion. It could reach the non-ﬂammable class 1 in accordance with CNS 14705-1-2013.


Introduction
Building energy retrofitting has become increasingly important as the energy consumption in the building sector represents a significant proportion in the overall energy consumption [1-3]. Hence, reducing the energy consumption in the building sector is highly necessary to decarbonize the sector. Delivering new low energy buildings and improving the energy efficiency of existing building stock are equally important to achieving that goal. External wall insulation (EWI) plays a very important role in building the energyretrofitting process because it is able to reduce the building energy demand, improve the indoor acoustic environment and extend the life span of the buildings by cutting down the heat loss through building fabric, filtering incoming external noises and preventing the formation of condensation in the wall [4][5][6]. Hence, as a low-hanging fruit, the measures of installing EWI has always been taken in building industries to cut down the carbon emission and in some occasion to improve the aesthetic of the buildings.
Currently, applying the thermal barrier coating on the outer surface of the wall or roof is a common solution to enhance the heat insulation performance of a building in the regions with a subtropical or tropical climate [5,7,8]. Alternatively, thermal insulation the interaction of external factors such as typhoons, earthquakes and dramatic temperature changes, problems such as falling and defects of tiles will affect the buildings' appearance and even endanger the safety of the people.
Cities in Taiwan are densely populated with 80 percent of the total population living in urban areas. Yet some 34,000 of the 86,000 buildings over 30 years old do not meet the latest building code and seismic resistance standards. In 2020, the Taiwan government launched a new statute for expediting the reconstruction of urban unsafe and old buildings to improve citizens' living environment and building safety in response to the potential climate change and disaster risk. It is a quite important issue to propose a building envelope retrofitting scheme for such existing buildings to meet the criteria of the latest building codes [30].
Extensive research and industrial practices related to building energy retrofitting have been carried out in countries with a large percentage of old housing stocks [31][32][33][34][35][36]. For instance, the large uptake of building energy technologies and policy have enabled many member states in Europe to carry out state-wide energy retrofitting to improve the overall building energy efficiency in the building sector with many lessons learnt and lots of relevant knowledge accumulated. However, buildings in Taiwan cannot follow the same paths identified in countries with cold or moderate climates to improve the energy efficiency due to its unique climate and building characteristics.
Based on the problems as mentioned above, developing an advanced dry-type EWI solution with good fire safety and thermal insulation performance is imminent.
In the study, we prepared the MTMS-based silica aerogel porous board via the emulsion method combined with ambient pressure drying (APD). In addition, a series of experiments have been conducted to examine the basic properties of the aerogel porous board and then compared the thermal and fire-resistant performance between the aerogel porous board and three kinds of typical insulation materials, including the rigid PU foam board, fire-retardant rigid PU foam board [37] and rigid PS foam board [38]. The final objective was to evaluate the energy efficiency of the aerogel porous board applied in the EWI system of a case study in Taiwan. By achieving these objectives, it was expected to reduce the operational energy consumption of either new or existing buildings without compromising the fire safety quality. Due to the integrated properties shown in this study, the as-formed aerogel porous board have demonstrated promising applications in delivering improved energy efficiency and fire safety in existing buildings.

Preparation of the Aerogel Porous Board
In this study, silica aerogel microspheres are prepared at two-step sol-gel synthesis, which is base-catalyzed condensation of methyltrimethoxysilane (MTMS) as the silica precursor [39]. The method for preparing the aerogel porous board includes the steps of: (a) adding a 50-70 vol.% MTMS containing methyl groups and a 0.1-0.3 vol.% surfactant into water, mixing evenly and carrying out hydrolysis to get a mixed aqueous solution; (b) mixing the 12-16 vol.% of mixed aqueous solution with 5-6 vol.% of 0.1-0.2 M ammonium hydroxide (NH 4 OH) and a remaining percentage of an organic solvent according to the percentage by volume (vol.%) and mixing by the magnetic stirrer until the solution obtained clear color in the hydrolysis reaction for emulsion polymerization to get a water-in-oil (w/o) lotion emulsion; (c) subsequently, the wet gels were shaped in a 10 cm × 10 cm × 1.5 cm steel mold at 150 • C in an oven for 24 h. The aerogel porous board was obtained by the ambient pressure drying (APD) method. Figure 1 shows the flow chart of the aerogel porous board manufacture via the sol-gel process.

Methods of Characterization
The morphology of the aerogel was observed by scanning electron microscopy (SEM). The SEM images were recorded on a FE-SEM microscope JEOL JSM-7001 operated at an accelerating voltage of 15 keV. The specimen was mounted on a metal stub using a conductive carbon adhesive disc with a 25 mm diameter. The samples' surfaces were sputter-coated with Pt prior to analysis. The surface area (the measurement range of the minimum: 0.01 m 2 /g) of samples was determined by a BET analysis from the amount of N2 gas adsorbed at various partial pressures (0.01 < P/P0 < 1) (NOVA 1000e, Quantachrome Instruments, Boynton Beach, FL, USA). Preheating of samples was performed in a nitrogen flow for 3 h at 200 °C to remove all the volatile materials. Additionally, the specific surface areas were determined by using the BET equation with an accuracy of ±10 m 2 /g. The pore volume (at STP the measurement range of minimum: 0.0001 cc/g) and pore size distributions (the measurement of range: 3.5-4000 Å) were measured using the BJH cumulative pore volume method. Fourier transform infrared spectroscopy (FTIR, Thermo iS50, Madison, WI, USA) with 4 cm −1 resolution and 40 scans for each curve was employed to investigate the molecular structure of the aerogel powder. The aerogel powder was mixed in the potassium bromide (KBr) powder matrix and then placed this in the sample cup. To determine the porosity, bulk density and contact angle, the mercury porosimeter (AutoPore IV 9520, Micromeritics) and contact angle meter (CAM-121, Creating Nano) were used.
The thermal conductivity of the aerogel particle and aerogel porous board at 25 °C ambient temperature were studied using a thermal conductivity analyzer (TCI-3-A, TCi) in accordance with ASTM D7984 [40]. This device employs the patented modified transient plane source (MTPS) technique, which is the only instrument engineered for evaluating the thermal conductivity of powder without sample preparation. Finally, the fire resistance of the commercial external wall insulation materials and aerogel porous board were analyzed by the cone calorimeter method in accordance with CNS 14705-1-2013 [41], respectively. The cone calorimeter method is commonly used to examine the reactions of materials in a fire by simulating different fire scenarios (ignition period radiant heat: 15 kW/m 2 ; growth period radiant

Methods of Characterization
The morphology of the aerogel was observed by scanning electron microscopy (SEM). The SEM images were recorded on a FE-SEM microscope JEOL JSM-7001 operated at an accelerating voltage of 15 keV. The specimen was mounted on a metal stub using a conductive carbon adhesive disc with a 25 mm diameter. The samples' surfaces were sputter-coated with Pt prior to analysis. The surface area (the measurement range of the minimum: 0.01 m 2 /g) of samples was determined by a BET analysis from the amount of N 2 gas adsorbed at various partial pressures (0.01 < P/P 0 < 1) (NOVA 1000e, Quantachrome Instruments, Boynton Beach, FL, USA). Preheating of samples was performed in a nitrogen flow for 3 h at 200 • C to remove all the volatile materials. Additionally, the specific surface areas were determined by using the BET equation with an accuracy of ±10 m 2 /g. The pore volume (at STP the measurement range of minimum: 0.0001 cc/g) and pore size distributions (the measurement of range: 3.5-4000 Å) were measured using the BJH cumulative pore volume method. Fourier transform infrared spectroscopy (FTIR, Thermo iS50, Madison, WI, USA) with 4 cm −1 resolution and 40 scans for each curve was employed to investigate the molecular structure of the aerogel powder. The aerogel powder was mixed in the potassium bromide (KBr) powder matrix and then placed this in the sample cup. To determine the porosity, bulk density and contact angle, the mercury porosimeter (AutoPore IV 9520, Micromeritics) and contact angle meter (CAM-121, Creating Nano) were used.
The thermal conductivity of the aerogel particle and aerogel porous board at 25 • C ambient temperature were studied using a thermal conductivity analyzer (TCI-3-A, TCi) in accordance with ASTM D7984 [40]. This device employs the patented modified transient plane source (MTPS) technique, which is the only instrument engineered for evaluating the thermal conductivity of powder without sample preparation. Finally, the fire resistance of the commercial external wall insulation materials and aerogel porous board were analyzed by the cone calorimeter method in accordance with CNS 14705-1-2013 [41], respectively. The cone calorimeter method is commonly used to examine the reactions of materials in a fire by simulating different fire scenarios (ignition period radiant heat: 15 kW/m 2 ; growth period radiant heat: 30 kW/m 2 ; growth period radiant heat: 50 kW/m 2 ). The specimens with a surface area of 88.4 cm 2 and 1.5 cm thick were heated by an incident radiant heat flux of 50.0 kW/m 2 (about 737 • C) in a horizontal orientation. The test duration was 20 min. The size of all specimens for thermal conductivity and fire resistance testing were 10 cm in length, 10 cm in width and 1.5 cm in height.
In order to evaluate the applicability of aerogel porous board under high humidity conditions. The water absorption of aerogel porous board was measured in accordance with ASTM D570-98 [42]. For the water absorption test, the aerogel porous board was dried in a chamber for a specified time and at temperature and then the aerogel porous board was weighed. The aerogel porous board was then submerged in water at 23 • C for 24 h. The specimen was removed, patted dry with a lint free cloth and weighed. Water absorption of the aerogel porous board can be calculated by (m 1 − m 0 )/A × 100%.
All these tests allowed evaluating the microstructural and physical performance, with the sample/test pairing summarized in Table 1.

Microstructural
Physical

R1 -
Caption: SEM-scanning electron microscope; BET-N 2 adsorption-desorption isotherms; BD-dry bulk density; CA-contact angle; FTIR-Fourier-transform infrared spectroscopy; λ-thermal conductivity; FR-cone calorimeter; WA-water absorption; Specimen size: P1-10 mg powder; P2-0.1 g powder; P3-5 g powder; R1-10 cm × 10 cm × 1.5 cm. Figure 2 shows the images of the aerogel porous board at various magnifications. As shown in Figure 2a, the aerogel porous board is white and opaque. The bulk density of the aerogel porous board is 0.0301 g/cm 3 . A SEM image shown in Figure 2b clearly illustrates the presence of the porous network structure with pores of different sizes.

Characterization of the Aerogel Porous Board
The FTIR characterization results of the aerogel porous board is shown in Figure 3. The peaks centered at 3445, 1632 and 952 cm −1 are attributed to the O-H stretching band of hydrogen-bonded water, respectively. The peak at 1050 and 758 cm −1 for Si-O-Si stretching vibration corresponds to the structure of the silica network. The peaks at 2963 cm −1 , 1380 cm −1 and 848 cm −1 can be attributed to the absorption of C-H. The presence of Si-CH 3 functionalities is confirmed by the Si-C mode at 1260 cm −1 . Furthermore, the aerogel porous board synthesized from MTMS is inherently hydrophobic in this study. Figure 4 indicated that the aerogel porous board is hydrophobic with a contact angle as high as 145 • , thus, water can form droplets on the surface of the aerogel porous board. In addition, the water absorption of aerogel porous board was 0.186 g/100 cm 2 .  Figure 2 shows the images of the aerogel porous board at various magnifications. As shown in Figure 2a, the aerogel porous board is white and opaque. The bulk density of the aerogel porous board is 0.0301 g/cm 3 . A SEM image shown in Figure 2b clearly illustrates the presence of the porous network structure with pores of different sizes.  The FTIR characterization results of the aerogel porous board is shown in Figure 3. The peaks centered at 3445, 1632 and 952 cm −1 are attributed to the O-H stretching band of hydrogen-bonded water, respectively. The peak at 1050 and 758 cm −1 for Si-O-Si stretching vibration corresponds to the structure of the silica network. The peaks at 2963 cm −1 , 1380 cm −1 and 848 cm −1 can be attributed to the absorption of C-H. The presence of Si-CH3 functionalities is confirmed by the Si-C mode at 1260 cm −1 . Furthermore, the aerogel porous board synthesized from MTMS is inherently hydrophobic in this study. Figure 4 indicated that the aerogel porous board is hydrophobic with a contact angle as high as 145°, thus, water can form droplets on the surface of the aerogel porous board. In addition, the water absorption of aerogel porous board was 0.186 g/100 cm 2 .   Figure 5 shows the nitrogen adsorption-desorption isotherm and pore size distribution (PSD) of the aerogel porous board, which are obtained by using the standard BET and BJH cumulative pore volume method, respectively. The aerogel porous board exhibited the type-IV adsorption isotherm according to the IUPAC classification [43], which is a characteristic feature of the mesoporous material. The average pore size was found to The FTIR characterization results of the aerogel porous board is shown in Figure 3. The peaks centered at 3445, 1632 and 952 cm −1 are attributed to the O-H stretching band of hydrogen-bonded water, respectively. The peak at 1050 and 758 cm −1 for Si-O-Si stretching vibration corresponds to the structure of the silica network. The peaks at 2963 cm −1 , 1380 cm −1 and 848 cm −1 can be attributed to the absorption of C-H. The presence of Si-CH3 functionalities is confirmed by the Si-C mode at 1260 cm −1 . Furthermore, the aerogel porous board synthesized from MTMS is inherently hydrophobic in this study. Figure 4 indicated that the aerogel porous board is hydrophobic with a contact angle as high as 145°, thus, water can form droplets on the surface of the aerogel porous board. In addition, the water absorption of aerogel porous board was 0.186 g/100 cm 2 .   Figure 5 shows the nitrogen adsorption-desorption isotherm and pore size distribution (PSD) of the aerogel porous board, which are obtained by using the standard BET and BJH cumulative pore volume method, respectively. The aerogel porous board exhibited the type-IV adsorption isotherm according to the IUPAC classification [43], which is a characteristic feature of the mesoporous material. The average pore size was found to  Figure 5 shows the nitrogen adsorption-desorption isotherm and pore size distribution (PSD) of the aerogel porous board, which are obtained by using the standard BET and BJH cumulative pore volume method, respectively. The aerogel porous board exhibited the type-IV adsorption isotherm according to the IUPAC classification [43], which is a characteristic feature of the mesoporous material. The average pore size was found to be approximately 2.47 nm in Figure 2b. The aerogel porous board prepared in this work had a specific surface area as high as 547 m 2 /g. The characteristics of the aerogel porous board compared with the Cabot P300 aerogel particle are summarized in Table 2. Considering that the required aerogel porous board must have low density and high porosity, it can be concluded that the performances of the aerogel porous board prepared via the emulsion method combined with APD are similar to that of the aerogel particle. Table 2. Comparison of the characteristics between the aerogel porous board and aerogel particle. The characteristics of the aerogel porous board compared with the Cabot P300 aerogel particle are summarized in Table 2. Considering that the required aerogel porous board must have low density and high porosity, it can be concluded that the performances of the aerogel porous board prepared via the emulsion method combined with APD are similar to that of the aerogel particle.

Thermal Conductivity
Thermal conductivity is the important indicator for evaluating the thermal performance of a material under constant conditions. The comparison of thermal conductivity between the aerogel porous board, silica aerogel particle (Cabot, P300) and several thermal insulation materials used commercially for building insulation, such as the rigid PU and PS foam board, are made in Figure 6. The thermal conductivity of each material was measured with three samples. As shown in Figure 6, the mean thermal conductivity of the aerogel porous board at 25 • C ambient temperature was 0.033 W/mK with a standard deviation of 0.00085 W/mK. At ambient temperature and pressure conditions, the trapped air within the mesoporous aerogel is a major contributor to its low thermal conductivity. The thermal conductivity (0.033 W/mK) of the proposed aerogel porous board was slightly lower than those of monolithic silica aerogels prepared with different surface modification procedures (0.036-0.0417 W/mK) [44]. However, 1 wt % of glass fiber added in the aerogel porous board for increasing its mechanical strength led to the thermal conductivity of the aerogel porous board higher than that of the commercially available aerogel particle (0.026 W/mK with a standard deviation of 0.002 W/mK).

Thermal Conductivity
Thermal conductivity is the important indicator for evaluating the thermal performance of a material under constant conditions. The comparison of thermal conductivity between the aerogel porous board, silica aerogel particle (Cabot, P300) and several thermal insulation materials used commercially for building insulation, such as the rigid PU and PS foam board, are made in Figure 6. The thermal conductivity of each material was measured with three samples. As shown in Figure 6, the mean thermal conductivity of the aerogel porous board at 25 °C ambient temperature was 0.033 W/mK with a standard deviation of 0.00085 W/mK. At ambient temperature and pressure conditions, the trapped air within the mesoporous aerogel is a major contributor to its low thermal conductivity. The thermal conductivity (0.033 W/mK) of the proposed aerogel porous board was slightly lower than those of monolithic silica aerogels prepared with different surface modification procedures (0.036-0.0417 W/mK) [44]. However, 1 wt % of glass fiber added in the aerogel porous board for increasing its mechanical strength led to the thermal conductivity of the aerogel porous board higher than that of the commercially available aerogel particle (0.026 W/mK with a standard deviation of 0.002 W/mK). The rigid PU foam board had the lowest thermal conductivity (0.0297 W/mK with a standard deviation of 0.0014 W/mK) among the three types of foam board. The thermal conductivity of the foam board was mainly density-dependent; the lower density foam board shows comparatively lower thermal conductivity than the higher density ones. The expandable graphite was added as an intumescent flame retardant into PUs, the density of the flame-retardant rigid PU foam board increased from 70 to 80 kg/m 3 . Thus, the thermal conductivity of the flame-retardant rigid PU foam board (0.040 W/mK with a standard deviation of 0.0024 W/mK) was 35% higher than that of the rigid PU foam board. Polystyrene foams (PSs) are also now widely used as thermal insulators in building and construction. The thermal conductivity of the PS board mainly depends on the blowing agent and the concentration of IR-attenuators. The measured thermal conductivity of the commercial PS board was in the range of 0.0295-0.035 W/mK.
Compared with the other typical foam boards, the thermal conductivity of the aerogel porous board was slightly higher than that of the other ones, but the U values of the EWI system with anyone should be similar to each other. In addition, the density of the aerogel porous board was the lightest of the three. These results imply that the aerogel The rigid PU foam board had the lowest thermal conductivity (0.0297 W/mK with a standard deviation of 0.0014 W/mK) among the three types of foam board. The thermal conductivity of the foam board was mainly density-dependent; the lower density foam board shows comparatively lower thermal conductivity than the higher density ones. The expandable graphite was added as an intumescent flame retardant into PUs, the density of the flame-retardant rigid PU foam board increased from 70 to 80 kg/m 3 . Thus, the thermal conductivity of the flame-retardant rigid PU foam board (0.040 W/mK with a standard deviation of 0.0024 W/mK) was 35% higher than that of the rigid PU foam board. Polystyrene foams (PSs) are also now widely used as thermal insulators in building and construction. The thermal conductivity of the PS board mainly depends on the blowing Compared with the other typical foam boards, the thermal conductivity of the aerogel porous board was slightly higher than that of the other ones, but the U values of the EWI system with anyone should be similar to each other. In addition, the density of the aerogel porous board was the lightest of the three. These results imply that the aerogel porous board prepared via the emulsion method combined with APD has potential application prospects in building thermal insulation.

Fire Resistance
It is observed from Figure 7 and Table 3 that the rigid PU foam board burned very fast after ignition, the pk-HRR value of the rigid PU foam board was 388.3 kW/m 2 and the whole combustion time of the rigid PU foam board was 182 s. The flame-retardant rigid PU foam board due to the addition of EG could depress the HRR value to 83.25 kW/m 2 , which was 78.6% lower than that of the rigid PU foam board. The HRR curve of the flameretardant rigid PU foam board is typical of an intumescent system, exhibiting two peaks. The first peak is related to the fast formation of an expanded protective layer structure on the surface of PU that prevents heat penetration, while the second peak is due to the destruction of the intumescent structure and the formation of a carbonaceous residue [45]. The effective heat of combustion (EHC) also revealed the burning degree of volatile gases in the gas phase during combustion. The av-EHC value of the flame-retardant rigid PU foam board was 16.12 MJ/kg, which decreased by 25.1% compared to that of the rigid PU foam board. The HRR curve of the aerogel porous board in Figure 8 indicates that the HRR values increased rapidly to the peak and then declined slowly to near 0. It is generally believed that heat generated when the organic materials, such as n-hexane, trapped in aerogel were evaporated. The HRR, pk-HRR and THR values show a significant reduction compared with the rest of building insulation materials. It is worth noting that the THR value of the aerogel porous board was 3.0 MJ/m 2 , a drop of 77.4% compared with the flame retardant rigid PU foam board (13.3 MJ/m 2 ). These results indicated that the aerogel porous board can dramatically inhibit the combustion intensity and restrict the heat release during combustion. It could reach the non-flammable class 1 in accordance with CNS 14705-1-2013.

Fire Resistance
It is observed from Figure 7 and Table 3 that the rigid PU foam board burned ve fast after ignition, the pk-HRR value of the rigid PU foam board was 388.3 kW/m 2 and th whole combustion time of the rigid PU foam board was 182 s. The flame-retardant rig PU foam board due to the addition of EG could depress the HRR value to 83.25 kW/m which was 78.6% lower than that of the rigid PU foam board. The HRR curve of the flam retardant rigid PU foam board is typical of an intumescent system, exhibiting two peak The first peak is related to the fast formation of an expanded protective layer structure o the surface of PU that prevents heat penetration, while the second peak is due to the d struction of the intumescent structure and the formation of a carbonaceous residue [45 The effective heat of combustion (EHC) also revealed the burning degree of volatile gas in the gas phase during combustion. The av-EHC value of the flame-retardant rigid P foam board was 16.12 MJ/kg, which decreased by 25.1% compared to that of the rigid P foam board. The HRR curve of the aerogel porous board in Figure 8 indicates that th HRR values increased rapidly to the peak and then declined slowly to near 0. It is gene ally believed that heat generated when the organic materials, such as n-hexane, trappe in aerogel were evaporated. The HRR, pk-HRR and THR values show a significant redu tion compared with the rest of building insulation materials. It is worth noting that th THR value of the aerogel porous board was 3.0 MJ/m 2 , a drop of 77.4% compared with th flame retardant rigid PU foam board (13.3 MJ/m 2 ). These results indicated that the aerog porous board can dramatically inhibit the combustion intensity and restrict the heat r lease during combustion. It could reach the non-flammable class 1 in accordance wi CNS 14705-1-2013.

Thermal Transmittance
In order to evaluate the impact of the application of the aerogel porous board on the thermal insulation performance of the external wall, the thermal transmittance, also known as the U-value, was used in this study. The thermal transmittance calculated by the formula in accordance with ISO 10292 [46] is shown in Equation (1): where he (W/m 2 K) and hi (W/m 2 K) are the external and internal heat transfer coefficients respectively. λ (W/mK) and di (m) are the thermal conductivity and thickness of each material. The external heat transfer coefficient is a function of the wind speed, v, near the outdoor surface of the wall system given by the following approximate formula: h 10.0 4.1 . The internal heat transfer coefficient was given by h 3.9 6.3ε. The value he and hi equal to 23 and 9 W/m 2 K were used in this study. Table 4 lists the thermal transmittance of dry stone cladding with the aerogel porous board alongside two typical external wall types including 15 cm of RC external wall and dry stone cladding on the external wall. U-value rates in dry construction technologies were comparatively low when compared to traditional wall systems, such as reinforced concrete structure (15 cm thickness, 3.495 W/m 2 K). The U value of the dry construction system for 2 cm stone cladding on the 15 cm RC wall contained in a gap of 8 cm could decrease to 2.413 W/m 2 K. The utilization of dry construction with stone cladding on the

Thermal Transmittance
In order to evaluate the impact of the application of the aerogel porous board on the thermal insulation performance of the external wall, the thermal transmittance, also known as the U-value, was used in this study. The thermal transmittance calculated by the formula in accordance with ISO 10292 [46] is shown in Equation (1): where h e (W/m 2 K) and h i (W/m 2 K) are the external and internal heat transfer coefficients respectively. λ i (W/mK) and d i (m) are the thermal conductivity and thickness of each material. The external heat transfer coefficient is a function of the wind speed, v, near the outdoor surface of the wall system given by the following approximate formula: h e = 10.0 + 4.1v. The internal heat transfer coefficient was given by h i = 3.9 + 6.3ε. The value h e and h i equal to 23 and 9 W/m 2 K were used in this study. Table 4 lists the thermal transmittance of dry stone cladding with the aerogel porous board alongside two typical external wall types including 15 cm of RC external wall and dry stone cladding on the external wall. U-value rates in dry construction technologies were comparatively low when compared to traditional wall systems, such as reinforced concrete structure (15 cm thickness, 3.495 W/m 2 K). The U value of the dry construction system for 2 cm stone cladding on the 15 cm RC wall contained in a gap of 8 cm could decrease to 2.413 W/m 2 K. The utilization of dry construction with stone cladding on the external wall with an additional aerogel porous board unit demonstrated its capacity to reduce the U-value to as low as 1.394 W/m 2 K, representing a promising assembly for insulating purposes when its overall thickness is not a restriction for building implementation. The thermal transmittance of this proposed dry construction wall system was already lower than the evaluation criterial (1.8 W/m 2 K) of the green building materials rating system in Taiwan.

Case Study: The Retrofitting of a Typical Multistory Building
In this case study, the selected residential building for retrofitting is located in downtown Kaohsiung, an area with extremely high real estate values. Therefore, the retrofit interventions have to include only the compact and easy/fast-to-install building envelope system. This building is representative of typical residential buildings in Taiwan, thereby presenting an exemplary retrofitting case study for potential wide applications in the Taiwanese context.

Case Study: The Retrofitting of a Typical Multistory Building
In this case study, the selected residential building for retrofitting is located in downtown Kaohsiung, an area with extremely high real estate values. Therefore, the retrofit interventions have to include only the compact and easy/fast-to-install building envelope system. This building is representative of typical residential buildings in Taiwan, thereby presenting an exemplary retrofitting case study for potential wide applications in the Taiwanese context.

Case Study: The Retrofitting of a Typical Multistory Building
In this case study, the selected residential building for retrofitting is located in downtown Kaohsiung, an area with extremely high real estate values. Therefore, the retrofit interventions have to include only the compact and easy/fast-to-install building envelope system. This building is representative of typical residential buildings in Taiwan, thereby presenting an exemplary retrofitting case study for potential wide applications in the Taiwanese context.

Case Study: The Retrofitting of a Typical Multistory Building
In this case study, the selected residential building for retrofitting is located in downtown Kaohsiung, an area with extremely high real estate values. Therefore, the retrofit interventions have to include only the compact and easy/fast-to-install building envelope system. This building is representative of typical residential buildings in Taiwan, thereby presenting an exemplary retrofitting case study for potential wide applications in the Taiwanese context.

Climatic and Environmental Conditions
Retrofitting this residential building is challenged by its climate and site conditions, which are associated with dynamic and variable weather conditions in a humid subtropical climate, with abundant local rains, sunny days and brief periods of overcast skies. The location of this building lies above the 22.4 • north latitude, a degree south of the Tropic of Cancer in Kaohsiung, Taiwan. This region experiences temperatures ranging from an average low of 10 • C (50 • F) in January to the average high of 33 • C (91 • F) in July, with a consistent daytime length throughout the year, approximately 13.5 h of daylight on the summer solstice and 10.5 h on the winter solstice. With more than 2210 h of bright sunshine, the city is one of the sunniest areas in Taiwan. The noon temperature reaches 35 • C in the summer and 25 • C in winter. The high summer sun angles emphasize the need to provide a sheltering roof to control light levels, solar gains and temperatures in the indoor environment. Despite about 225 bright sunny days per year, there remains a monthly rhythm of overcast or rainy days, including an average of 2-3 typhoons per month during summer time. The annual mean solar irradiation and precipitation are 3896 MJ/m 2 and 1968.2 mm, respectively [29].

Case Study Building
Multistory buildings are commonly seen in urban areas of Taiwan and they are usually built alongside streets to provide spaces for multiple uses. For instance, the ground floor is usually used for retail or a restaurant, with upper floors being used as residential units or offices. This typical building typology represents 90% of Taiwanese building stock and contributes to 15.3% of energy consumption [47]. Mostly built in the 90s, they have poor energy efficiency due to the absence of a stringent building code. Being built adjacently to other buildings in a long stretch, they also represent a great potential of widespread fire hazard. Therefore, a building of this type is selected in the case study to explore a retrofitting approach to improve its energy efficiency with improved fire safety.
As shown in Figure 8, this east facing building is a 13.45-m tall reinforced concrete building composed of four floors. The total building area is about 347.15 square meters, and the floor-to-ceiling height of each story is 3.3 m, with a 60% window-to-wall ratio on the glazed building façade. This large window-to-wall ratio design ensures an even distribution of natural light. However, it leads to a strong greenhouse effect throughout the day. This greenhouse effect accumulates a lot of solar heat during the summer and leads to an overheated indoor environment. Although there is a ceiling-level solar shading design on each floor, the solar heat gain via the glazing and wall still represents a significant cooling load and must be reduced.
As shown in Figure 9, this building has a rectangular floor plan with a length of 19.73 m and a width of 4.74 m. The building offers spaces for both residential and commercial uses. The first floor is rented out by the owner as a shop and the second to fourth floors are for residential use. Since the building faces east and the homeowner adheres the opaque film on the glass in order to reduce the solar radiation in the morning. Thus, there was insufficient penetration of natural light, leading to poorly lit indoor space before the retrofit. The results of measuring indoor illuminance by the illuminometer indicated that at 10:00 in the morning, the illuminance near the window can reach up to 1050 Lux. The daylight can only diffuse to the indoor depth of 2 m in the afternoon and the average illuminance at other measurement locations is below 250 Lux. The uniformity of illuminance level on the entire floor was rather poor.

Retrofitting Scenario: Building Envelope
In order to reduce the heat gain of the building envelope and the electricity consumption of the air conditioning system in this case study, we reduced the window area by 35%, changed the glass from clear tempered glass to green tempered glass and installed a dry cladding system on the existing external wall with the aerogel porous board. After retrofitting this building, the SHGC of the glass was reduced from 0.83 to 0.60 and the visi-

Retrofitting Scenario: Building Envelope
In order to reduce the heat gain of the building envelope and the electricity consumption of the air conditioning system in this case study, we reduced the window area by 35%, changed the glass from clear tempered glass to green tempered glass and installed a dry cladding system on the existing external wall with the aerogel porous board. After retrofitting this building, the SHGC of the glass was reduced from 0.83 to 0.60 and the visible light transmission of the glass was changed from 0.88 to 0.74. Recladding significantly reduced the overall U value of the wall from 3.495 to 1.394 W/m 2 /K because of its fabric construction change.

Evaluation on the Energy Efficiency Improvement
In this study, the building energy simulation and analysis platform (BESTAI) was adopted to conduct simulations of energy consumption. It is the integrated graphical interface software program developed for the purpose of conducting an EnergyPlus building energy consumption analysis as a dynamic engine. BESTAI provides users with the modeling and design of an on-line real-time building simulation analysis to obtain optimal energy analysis data in Taiwan. In addition, it offers users a customized analysis with various reporting functions, such as: ROI (return on investment) assessment, the annual energy consumption analysis and various types of electricity price estimates from the Taiwan Power company and other analytical services. BESTAI integrates ESCO, BEMS, the construction materials and equipment industry to provide customized recommendations for different conditions and applications through functional modules. It received a 2017 R&D 100 Award [48].
For computer simulation and modeling, the physical parameters include the window, the external wall structure and the window-to-wall ratio. The numbers of occupants, the heat gain of appliances and lighting for each floor are listed in Table 5. In general, the lighting equipment, computer and appliances on the first floor have identical operating periods corresponding to the staff's work shifts from 7:30 am to 8:30 pm. A load of operating lighting, computers and appliances, according to the period, on the other floors, are set according to the survey by Lin et al. [47]. The installed air conditioning system at this building is a multisplit type air conditioning system. The total cooling capacity of the air conditioning system installed on the first floor was 33 kW and on the other feet was 6 kW and the specified coefficient of performance (COP) was 2.7. The start and stop of the air conditioners on the first floor were scheduled according to the different seasons. In the summertime, the shop on the first floor had a significant cooling demand from June to September, as shown in Table 6. Conversely, the cooling load was low in winter, so the operating hours of air conditioner were shortened on regular working days. On other floors, the occupants' air conditioning hours were from 8 pm to 2 am on weekdays and from 1 pm to 2 am on Sunday and holidays.
The weather data was taken from the latest typical meteorological years (TMY3) for the building energy simulation of Taiwan proffered by the Architecture and Building Research Institute (ABRI) [49]. Basically, it sampled 15 standard years from 1998 to 2012 as standard weather data. The weather data can be generated to analyze the power consumption of an air conditioning system once the user selects the location of the building.  Figure 10 shows the breakdown of electricity consumption by equipment type in this building. Before the renovation, about 41% electricity consumption was associated with the air conditioning system. Lighting system and appliance accounted for 26.5% and 32.0% of the total electricity consumption, respectively. With our proposed renovation concept the total and air conditioning system's electricity consumption shown in Figure 11 would be reduced by 29% and 70%, respectively, resulting in the air conditioning system accounting for 16.69% of the total electricity consumption. Figure 12 shows the comparison between the simulations and the real monthly electricity consumption of this building. The monthly simulation result gave a power consumption that was significantly higher than real electricity consumption in the first half of the year. The simulated results came out with 9.5% and 4.0% more electricity consumption than the metered data before and after renovation. This discrepancy could have occurred because the weather data file used in BESTAI was for the years between 1998 and 2012, while the actual data gathered in this building was for the years 2019-2020. This case study result implies that the proper use of the aerogel porous board in buildings not only reduces the energy usage but also downsizes the HVAC system during the design. The weather data was taken from the latest typical meteorological years (TMY3) for the building energy simulation of Taiwan proffered by the Architecture and Building Research Institute (ABRI) [49]. Basically, it sampled 15 standard years from 1998 to 2012 as standard weather data. The weather data can be generated to analyze the power consumption of an air conditioning system once the user selects the location of the building. Figure 10 shows the breakdown of electricity consumption by equipment type in this building. Before the renovation, about 41% electricity consumption was associated with the air conditioning system. Lighting system and appliance accounted for 26.5% and 32.0% of the total electricity consumption, respectively. With our proposed renovation concept the total and air conditioning system's electricity consumption shown in Figure  11 would be reduced by 29% and 70%, respectively, resulting in the air conditioning system accounting for 16.69% of the total electricity consumption. Figure 12 shows the comparison between the simulations and the real monthly electricity consumption of this building. The monthly simulation result gave a power consumption that was significantly higher than real electricity consumption in the first half of the year. The simulated results came out with 9.5% and 4.0% more electricity consumption than the metered data before and after renovation. This discrepancy could have occurred because the weather data file used in BESTAI was for the years between 1998 and 2012, while the actual data gathered in this building was for the years 2019-2020. This case study result implies that the proper use of the aerogel porous board in buildings not only reduces the energy usage but also downsizes the HVAC system during the design.
(a) (b) Figure 10. Comparison of annual electricity use breakdown for a residential building case study before (a) and after (b) renovation.  Figure 10. Comparison of annual electricity use breakdown for a residential building case study before (a) and after (b) renovation.

Conclusions
In the study, a new aerogel porous board for application in Taiwan was investigated. It can be used in the near future for reducing energy consumption and enhancing fire safety performance in buildings due to its low thermal conductivity and good fire resistance. The results of the experiment are summarized as follows: (1) A well-designed method including emulsification condensation gelation and controlled ambient drying at 150 °C for 24 h was developed to fabricate an aerogel porous board with a uniform skeleton. One of advantages is that it was fabricated under ambient pressure drying without tedious surface modification and the solvent ex-

Conclusions
In the study, a new aerogel porous board for application in Taiwan was investigated. It can be used in the near future for reducing energy consumption and enhancing fire safety performance in buildings due to its low thermal conductivity and good fire resistance. The results of the experiment are summarized as follows: (1) A well-designed method including emulsification condensation gelation and controlled ambient drying at 150 °C for 24 h was developed to fabricate an aerogel porous board with a uniform skeleton. One of advantages is that it was fabricated under ambient pressure drying without tedious surface modification and the solvent ex-

Conclusions
In the study, a new aerogel porous board for application in Taiwan was investigated. It can be used in the near future for reducing energy consumption and enhancing fire safety performance in buildings due to its low thermal conductivity and good fire resistance. The results of the experiment are summarized as follows: (1) A well-designed method including emulsification condensation gelation and controlled ambient drying at 150 • C for 24 h was developed to fabricate an aerogel porous board with a uniform skeleton. One of advantages is that it was fabricated under am-bient pressure drying without tedious surface modification and the solvent exchange process. The reproducibility of the aerogel porous board was also good, especially with respect to mesopore size distributions. This suggests a low fabrication cost is technically viable. (2) For the microstructural properties, it was possible to verify high values of porosity, low density and superhydrophobicity for the aerogel porous board, similar to that of the benchmarked aerogel particle.
(3) For the thermal insulation property, adding 1 wt % of glass fiber to the aerogel porous board could increase its mechanical strength but lead to the thermal conductivity of the aerogel porous board being higher than that of the commercially available aerogel particle. Compared with the other typical foam boards, the thermal conductivity of the aerogel porous board was slightly higher than that of other ones, but the U values of the EWI system with the aerogel porous board should be similar to that with other foam boards. (4) For the fire resistance property, the PU and PS foam boards were flammable, even when the flame-retardants were added to these foam boards. Therefore, reducing the flammability of traditional EWI materials by using the flame retardant is hard to achieve. The proposed aerogel porous board can dramatically inhibit the combustion intensity and restrict the heat release during combustion without using additives. It could reach non-flammable class 1 in accordance with CNS 14705-1-2013. (5) Concerning the hygric performance, the water absorption of the aerogel porous board was low (0.186 g/100 cm 2 ) and the surface was hydrophobic, so it is suitable to use under the typical Taiwan climate, i.e., high temperature and humidity climate. The aerogel porous board will not absorb too much water vapor and cause a decrease in thermal insulation performance. (6) From the energetic point of view, the pilot study in this paper suggests that the aerogel porous board could be applied feasibly in regions with hot and humid climates in general and particularly in Taiwan. The evaluation result of the case study reported in this paper indicated that the utilization of dry construction with stone cladding on the external wall with an additional aerogel porous board unit could reduce 26.1% electricity consumption of a four-story building.

Institutional Review Board Statement: Not applicable.
Informed Consent Statement: Not applicable.

Data Availability Statement:
The data that support the findings of this study are available from the corresponding author, upon reasonable request.