A Study of Hot Climate Low-Cost Low-Energy Eco-Friendly Building Envelope with Embedded Phase Change Material

: The generation and use of energy are signiﬁcant contributors to CO 2 emissions. Globally, approximately 30% to 40% of all energy consumption can be directly or indirectly linked to buildings. Nearly half of energy usage in buildings is linked to maintaining the thermal comfort of the inhabitants. Therefore, ﬁnding solutions that are not only technically but also economically feasible is of utmost importance. Though much research has been conducted to address this issue, most solutions are still costly for developing countries to implement practically. This study endeavors to ﬁnd a less expensive yet straightforward methodology to achieve thermal comfort while conserving energy. This study takes a broader view of multiple habitat-related CO 2 emission issues in developing regions and describes a hybrid solution to address them. New technologies and innovative concepts are being globally examined to beneﬁt from the considerable potential of PCMs and their role in thermal energy storage (TES) applications for buildings. The current study numerically investigates the thermal response of a hybrid building envelope consisting of PCM and local organic waste materials for low-cost low-energy buildings. The local organic waste materials used are those whose disposal is usually done by burning, resulting in an immense amount of greenhouse gases. In the ﬁrst phase, different waste materials are characterized to determine their thermophysical properties. In the second phase, a low-cost, commonly available PCM calcium chloride hexahydrate, CaCl 2 · 6H 2 O, is integrated with a brick and corn husk wall to enhance the thermal storage in the building envelope to minimize energy consumption. Temperature distribution plots are primarily used for analysis. The results show a marked improvement in thermal comfort by maintaining a maximum indoor temperature of 27 ◦ C when construction is performed with a 6% corn husk composite material embedded with the PCM, while under similar conditions, the standard brick construction maintained a 31 ◦ C indoor temperature. It is concluded that the integration of the PCM layer with the corn husk wall provides an adequate solution for low-cost and low-energy buildings.


Introduction
The buildings and construction sectors utilize one-third of global energy consumption and are the primary source of carbon emissions globally [1]. Forty-three percent of residential building energy is utilized in heating, cooling, and lighting, while for commercial buildings, these applications account for 39% of total energy consumption [2]. PCMs have Figure 1. Emission outlook of different greenhouse gas production sectors of Pakistan [20].
As a result of the increase in energy consumption, the CO2 emissions have also risen sharply, as depicted in Figure 2. Pakistan CO2 emissions from fossil fuel burning and cement production for the last 70 years [22].
The latest available data on CO2 emissions in Pakistan are shown in Figure 2, and the annual variation in emissions is seen in Figure 3.  As a result of the increase in energy consumption, the CO 2 emissions have also risen sharply, as depicted in Figure 2. production to 40,000 MW in the current year. This is likely to cause a further increase in GHG emissions in Pakistan unless immediate measures are not taken to control the emissions of pollutants. In comparison to global carbon emissions, Pakistan's per capita carbon footprint has been small in the past, but it has started to increase rapidly [20] in the last few years due to a healthy growth rate of the economy.

Figure 1.
Emission outlook of different greenhouse gas production sectors of Pakistan [20].
As a result of the increase in energy consumption, the CO2 emissions have also risen sharply, as depicted in Figure 2. Pakistan CO2 emissions from fossil fuel burning and cement production for the last 70 years [22].
The latest available data on CO2 emissions in Pakistan are shown in Figure 2, and the annual variation in emissions is seen in Figure 3. Figure 2 clearly shows a sharp rise in CO2 emissions for the last decade compared to a slow increase from 1950-2010. Figure 3 shows a step change from 2010 to 2019 while analyzing historical emissions data of Pakistan. The latest available data on CO 2 emissions in Pakistan are shown in Figure 2, and the annual variation in emissions is seen in Figure 3. Figure 2 clearly shows a sharp rise in CO 2 emissions for the last decade compared to a slow increase from 1950-2010. Figure 3 shows a step change from 2010 to 2019 while analyzing historical emissions data of Pakistan.  As seen from the above data, emissions from the built environment are the highest and increasing alarmingly. Several efforts have been made to achieve energy efficiency and reduce the carbon footprint of different buildings in the past decade [23][24][25][26]. It has also been observed that thermal comfort is lacking in most academic buildings available to school-going children in developing countries, even where a significant cost is being incurred on heating and cooling of academic buildings [27]. Thus, improving thermal comfort using efficient temperature control techniques and designing buildings with inbuilt thermal comfort using thermal energy storage materials [27][28][29], providing natural ventilation, and using optimum building orientation are also priorities in developed countries.
Similarly, several studies have been performed on composite materials having clay, cement, or gypsum plaster. Khabbazi et al. [30] have investigated an insulating material based on a mixture of cement mortar and cork. Cherki et al. [31][32][33] and Mounir et al. [34] have worked on materials based on granular cork mixed with different binders to achieve better thermal properties. Mounir et al. [35] have also shown improved thermal properties of clay by mixing it with wool. Date palm wood and fibers have also been suggested as an ingredient to make composite reinforced building materials by several studies. Kriker et al. studied date palm fiber-reinforced concrete properties as a function of water curing [36]. Tlijani et al. used the periodic method to determine thermal conductivity and thermal diffusivity of the wood-scale of palm trees [37]. Agoudgil et al. report thermophysical properties of different varieties of date palm wood [38]. Mekhermeche et al. studied the thermal properties of date palm fiber reinforced clay bricks [39]. Benmansour et al. examined the thermophysical and mechanical properties of date palm fibers [40]. The experimental work shows that date palm wood and fibers mixed with binders result in good thermal properties for use in the built environment. Laaroussi et al. [41,42] use a hot plate and flash method to measure the thermal properties of different mixtures of clay bricks. Mahamat et al. study the thermophysical properties of cow dung mixed with clay and their effect on energy consumption of buildings [43]. Lamrani et al. [44] and Bhutto [45] have worked on new ecological building materials based on peanut shells and wheat straw mixed with plaster. As seen from the above data, emissions from the built environment are the highest and increasing alarmingly. Several efforts have been made to achieve energy efficiency and reduce the carbon footprint of different buildings in the past decade [23][24][25][26]. It has also been observed that thermal comfort is lacking in most academic buildings available to schoolgoing children in developing countries, even where a significant cost is being incurred on heating and cooling of academic buildings [27]. Thus, improving thermal comfort using efficient temperature control techniques and designing buildings with inbuilt thermal comfort using thermal energy storage materials [27][28][29], providing natural ventilation, and using optimum building orientation are also priorities in developed countries.
Similarly, several studies have been performed on composite materials having clay, cement, or gypsum plaster. Khabbazi et al. [30] have investigated an insulating material based on a mixture of cement mortar and cork. Cherki et al. [31][32][33] and Mounir et al. [34] have worked on materials based on granular cork mixed with different binders to achieve better thermal properties. Mounir et al. [35] have also shown improved thermal properties of clay by mixing it with wool. Date palm wood and fibers have also been suggested as an ingredient to make composite reinforced building materials by several studies. Kriker et al. studied date palm fiber-reinforced concrete properties as a function of water curing [36]. Tlijani et al. used the periodic method to determine thermal conductivity and thermal diffusivity of the wood-scale of palm trees [37]. Agoudgil et al. report thermophysical properties of different varieties of date palm wood [38]. Mekhermeche et al. studied the thermal properties of date palm fiber reinforced clay bricks [39]. Benmansour et al. examined the thermophysical and mechanical properties of date palm fibers [40]. The experimental work shows that date palm wood and fibers mixed with binders result in good thermal properties for use in the built environment. Laaroussi et al. [41,42] use a hot plate and flash method to measure the thermal properties of different mixtures of clay bricks. Mahamat et al. study the thermophysical properties of cow dung mixed with clay and their effect on energy consumption of buildings [43]. Lamrani et al. [44] and Bhutto [45] have worked on new ecological building materials based on peanut shells and wheat straw mixed with plaster. In the current research effort, authors concentrate on a novel hybrid building envelope consisting of PCM and local organic waste materials for low-cost low-energy buildings. The locally available sustainable materials are mixed with clay, sand, cement, and their thermal properties. These materials are then simulated to form the building envelope. Numerical simulation is conducted to investigate their effect on the annual energy consumption for heating and cooling loads. The results are then compared with the energy consumption of buildings made from standard construction materials. TRNSYS software is initially used for simulations under local annual weather conditions. So far, the potential for use of PCMs in these buildings has remained limited due to associated cost and accessibility in the local market [46,47]. To overcome the economic barrier, this study proposes a reduction in the existing construction cost by using the proposed composite material compressed bricks. These compressed bricks are used to replace the existing brick and concrete blocks as the primary construction material. There are many abundantly and locally available waste materials that can be used in this sustainable construction process. This work studies the integration of low-cost PCM and local raw materials to find whether this approach provides a better solution that is viable to be commercialized at a large scale. Currently, fired bricks are used as the primary construction material. The manufacturing of these bricks results in a considerable amount of greenhouse gases (GHG). The fired brick has been replaced in this study by locally developed compressed bricks. After experimental testing of several materials, a mixture of clay-cement-sand was selected as the base material. To further enhance the base material's thermal energy storage (TES) capability, several waste materials were added to form a composite construction material. The mixture of the said materials was formed into a block shape using compressive forces. This study examines the TES capability of the materials mentioned above. It also studies the possibility of introducing a PCM layer with the best performing block replacing the bricks. CaCl 2 ·6H 2 O is selected for this study based on the melting temperature of 28-29 • C. For Islamabad, Pakistan, about eight months of hot weather and cooling load are a substantial part of annual energy consumption. CFD simulations have been performed on a typical 9 inches thick masonry brick wall and corn husk wall with and without PCM. The authors have conducted a comprehensive effort to study the effects of this hybrid building envelope in detail earlier, not mentioned in the literature. Experimental and numerical analysis using TRNSYS and CFD tools are used to study various aspects of the proposed building envelope. The authors also consider some pressing emissions issues of the region, like burning paddy fields and other organic waste. The study shows that a significant reduction in energy consumption and greenhouse gas emissions is possible using the proposed comprehensive approach while curtailing the construction cost. Section 2 presents the material and methods used for this study; Section 3 presents the base material testing; Section 4 discusses the details of the composite material used. Computational analysis is discussed in Section 5, followed by Section 6, which provides a detailed comparison of all the scenarios. Recommendations are made as per the finding of the current study in the conclusions section.

Materials and Methods
For this study, a school building located in Islamabad, Pakistan, was selected. The selected school was built in 2004. The school's building is a double-story structure with 44 classrooms and a floor area of 2240 m 2 . The school has an enrolment of 1020 students on average. A detailed analysis of the school building energy consumption was performed earlier to show energy-saving opportunities and the possibility of cost savings and reduction in carbon emission [48]. Considering the data obtained [48], the current study investigates the advantages of using composite materials and phase change materials (PCMs) in the building envelope to increase the building thermal mass to improve indoor thermal comfort.
The simplest and most cost-effective method for thermal energy storage is sensible heat storage. Further, the amount of heat stored in a material depends on the density ρ, volume v, temperature variation T, and specific heat capacity C p and thermal conductivity k of the storage materials. The sensible heat storage capacity of a material is calculated using Equation (3). The temperature difference T across the storage material has inverse dependence on the thermal conductivity k of the material.
By replacing mass in Equation (1), it becomes:

Thermal Conductivity
To find out the thermal conductivity of various eco-friendly materials used in this study, an experimental setup is designed, as shown in Figure 4. volume , temperature variation △ , and specific heat capacity and thermal conductivity of the storage materials. The sensible heat storage capacity of a material is calculated using Equation (3). The temperature difference △ across the storage material has inverse dependence on the thermal conductivity of the material.
By replacing mass in Equation (1), it becomes:

Thermal Conductivity
To find out the thermal conductivity of various eco-friendly materials used in this study, an experimental setup is designed, as shown in Figure 4. This experimental setup is known as the hot-plate steady-state method for finding the thermal conductivity of materials [32,35,42,44].
A screwed rod is used to slightly press all the materials together to ensure gap-less contact between different materials to avoid a rise in thermal conductivity due to air gaps and any heat loss. To measure the temperatures of the testing material, heating element, and polystyrene foam, temperature sensors are placed as shown in Figure 5. These temperature sensors have a temperature sensitivity of 0.125 °C.  This experimental setup is known as the hot-plate steady-state method for finding the thermal conductivity of materials [32,35,42,44].
A screwed rod is used to slightly press all the materials together to ensure gap-less contact between different materials to avoid a rise in thermal conductivity due to air gaps and any heat loss. To measure the temperatures of the testing material, heating element, and polystyrene foam, temperature sensors are placed as shown in Figure 5. These temperature sensors have a temperature sensitivity of 0.125 • C.
Energies 2021, 14, x FOR PEER REVIEW 6 of 23 volume , temperature variation △ , and specific heat capacity and thermal conductivity of the storage materials. The sensible heat storage capacity of a material is calculated using Equation (3). The temperature difference △ across the storage material has inverse dependence on the thermal conductivity of the material.
By replacing mass in Equation (1), it becomes:

Thermal Conductivity
To find out the thermal conductivity of various eco-friendly materials used in this study, an experimental setup is designed, as shown in Figure 4. This experimental setup is known as the hot-plate steady-state method for finding the thermal conductivity of materials [32,35,42,44].
A screwed rod is used to slightly press all the materials together to ensure gap-less contact between different materials to avoid a rise in thermal conductivity due to air gaps and any heat loss. To measure the temperatures of the testing material, heating element, and polystyrene foam, temperature sensors are placed as shown in Figure 5. These temperature sensors have a temperature sensitivity of 0.125 °C.  A microcontroller (Arduino) is used to record the temperature values received from the temperature sensors, and Tera Term© open-source software by PARSEC Group, Arvada, CO, USA [51] is used for the graphical display of temperature values.
The temperature difference across test material (T 2 − T 1 ) and temperature difference across polystyrene (T 2 − T 3 ) are calculated to find the thermal conductivity of test material by using Equation (4).

Specific Heat Capacity
The calorimetry method as described by Cengel [52] is used to measure the heat capacity of various materials being investigated. The changes in temperature of the water and the sample are measured and specific heat capacity is calculated using Equation (7).

Validation
The experimental setup is validated by calculating the thermal conductivity of the known materials using this setup and comparing the measured results with the standard data of polystyrene [35,42,44,52], clay [41,53], brick [42,54], and concrete [49,54], respectively.
After getting the temperature difference, the thermal conductivity of the samples is calculated by using Equation (4). Fourier's law of heat conduction for one-dimensional heat conduction is given in Equation (8) [52].
where . Q cond = rate of heat transfer; k = thermal conductivity; S = surface area.
dT dx = temperature gradient. The rate of heat transfer and the area of the material is constant. Thus, dT dx is constant, which means that the temperature through the test material varies linearly with e (thickness of the material in the direction of heat flow), and the temperature distribution in the material kS dT (9) .
where U = applied voltage and R = resistance of the heating element.
As the heating element provides equal heat on both sides, so Equation (12), in this case, will become.
Equation (15) is used in this study to calculate the thermal conductivity of test materials, as given in Table 1 below. Polystyrene is taken as the reference material with known thermal conductivity k 2 .

Specific Heat Capacity
The calorimetry method [52,53] is used to measure the heat capacity of the various materials. The changes in temperature of the water and the sample and specific heat capacity are calculated by using Equation (7).

Base Material Testing
One of the aims of this study was to compare different waste organic materials to formulate a new eco-friendly construction material that can reduce energy consumption and GHG emissions. For that purpose, different sustainable materials were selected for the study. First, a base material was taken, which is locally available and itself environmentally friendly. Clay was selected as the base material, as it is abundantly available in nature, low-cost, and environmentally friendly. Fired clay bricks are most commonly used in Pakistan as a building construction material. A large amount of waste rubber and coal is burned during the brick manufacturing process. According to the EIA report, this is not an eco-friendly manufacturing process; one pound of coal produces 2.86 pounds of carbon dioxide [54]. Therefore, in this study, 20 kN compression force is used to produce clay bricks for thermal properties testing, using the ©G.U.N.T. Hamburg, Germany, Gerätebau GmbH compression equipment. To improve the structural strength of brick and improve its binding properties, sand and cement were added in different samples [55]. After preparing the samples, they were sundried for a week to allow mechanical stabilization. Then thermal conductivity and specific heat of the clay samples were calculated using the experimental setups described earlier. The thermal conductivity and the specific heat results are shown in Table 2. Table 2. Specific heat capacity, density, thermal conductivity, and thermal diffusivity of the samples.

Sample
Cp

Base Material Selection
The clay-cement-sand sample was considered to possess better thermal properties than other samples. It displayed better strength, much smaller thermal conductivity, greater density, and thermal diffusivity equal to clay. Hence, clay-cement-sand brick was selected as the base material for the formation of composite eco-friendly sustainable materials.

Wheat Straw
Wheat is the main agricultural crop in Pakistan; around nine million hectares of area are used for the growth of wheat, which is almost 40% of the country's total cultivated land. In the 2016/2017 season, the total wheat production was around 25.6 million metric tons in Pakistan [56]. After harvesting the wheat crop, a considerable amount of wheat residue is produced, which is used for various purposes. However, many farmers are unable to use it fully and burn a significant portion. This crop residue burning produces a considerable amount of harmful emissions, causing breathing difficulties and atmospheric pollution. Wheat straw, being abundantly available, was selected in this study as the first composite material. Wheat straw is a natural material and environmentally friendly, and its use in building materials can avoid the pollution created due to its burning. Samples of the first sustainable building material were prepared by adding 2%, 4%, and 6% wheat straw by weight in the base material while reducing the same amount of clay.

Corn Husk
Corn is the second-largest agricultural crop in Pakistan after wheat; around 1.350 million hectares of area are used to grow corn. In the 2017/2018 season, the total corn production was around 5.8 million tons [56]. After harvesting the corn crop, a considerable amount of corn residue is left over as waste material. Thus, corn husk is selected as the second composite material for mixing in the base material. The exact mixing ratio, as in the case of wheat straw, is used.

Rice Husk
Rice is the third-largest crop in Pakistan after wheat and cotton in terms of area sown. The total production of rice in Pakistan is 10.351 million metric tons [56]. For every 1 ton of rice, about 1.5 tons of waste crop residue are produced [57]. The burning of this crop residue produces a vast amount of GHG emissions, estimated at 0.9 kg CO 2 /kg-rice husk [57]. This crop burning practice has a harmful impact not only on humans but also on animals and birds. Due to residue burning, a very lightweight particulate matter is generated, which causes massive smog, as it can stay in the air for a long time and travels along with the wind for hundreds of kilometers [58]. In October 2017, crop fires in and across the border in Indian provinces produced a considerable amount of smoke. This smoke mixed with fog with cooler weather in November and resulted in dangerous amounts of pollution. The smoke particles and fog, industrial pollution, and dust formed a particularly thick haze for several days in November 2017. On 7 November 2017, the Moderate Resolution Imaging Spectroradiometer (MODIS) on NASA's Aqua satellite captured a natural-color image of haze and fog blanketing the region, as shown in Figures 6 and 7 below.      As shown in Figures 6 and 7, the immense pollution caused by carbon emissions is a real danger to achieving the global warming and emission control goals. This disaster in the past became a primary reason for selecting wheat straw, rice husk, and corn husk as waste for the composite construction material. The burning of organic waste materials is a common practice [60] that is followed in the region. The literature presents the work related to these composites. Saman et al. determined the fired clay brick composite thermophysical properties with rice husk, corn cob, and waste tea [61]. Phonphuak et al. experimentally determined the physical and mechanical properties of fired clay brick samples with different percentages of rice husk [62]. Using these materials in construction will help mitigate the emissions. If these waste materials become a sellable commodity for construction, it will provide the farmers with an incentive to avoid burning. This work, therefore, studies the disposal of the said organic waste materials by using them in construction to achieve the following two significant advantages.

•
First, the improvement in thermal comfort of the buildings with reduced energy usage. • Second, a significant reduction in greenhouse gas emissions volume resulted from burning these waste materials.
These aims align with the targets set by the IEA-COP26 Net Zero Summit of realizing net zero emissions by 2050 [63].    Brick samples using 2%, 4%, and 6% of these three organic waste material ratios by weight were produced. The waste residues of wheat straw, corn husk, and rice husk used in this study are shown in Figure 8, while the compressed brick samples produced are depicted in Figure 9 below. As shown in Figures 6 and 7, the immense pollution caused by carbon emissions is a real danger to achieving the global warming and emission control goals. This disaster in the past became a primary reason for selecting wheat straw, rice husk, and corn husk as waste for the composite construction material. The burning of organic waste materials is a common practice [60] that is followed in the region. The literature presents the work related to these composites. Saman et al. determined the fired clay brick composite thermophysical properties with rice husk, corn cob, and waste tea [61]. Phonphuak et al. experimentally determined the physical and mechanical properties of fired clay brick samples with different percentages of rice husk [62]. Using these materials in construction will help mitigate the emissions. If these waste materials become a sellable commodity for construction, it will provide the farmers with an incentive to avoid burning. This work, therefore, studies the disposal of the said organic waste materials by using them in construction to achieve the following two significant advantages.


First, the improvement in thermal comfort of the buildings with reduced energy usage.  Second, a significant reduction in greenhouse gas emissions volume resulted from burning these waste materials.
These aims align with the targets set by the IEA-COP26 Net Zero Summit of realizing net zero emissions by 2050 [63].
Brick samples using 2%, 4%, and 6% of these three organic waste material ratios by weight were produced. The waste residues of wheat straw, corn husk, and rice husk used in this study are shown in Figure 8, while the compressed brick samples produced are depicted in Figure 9 below.  The method described earlier was used to calculate the thermal properties of these brick samples and the results are shown in Table 3. As shown in Figures 6 and 7, the immense pollution caused by carbon emissions is a real danger to achieving the global warming and emission control goals. This disaster in the past became a primary reason for selecting wheat straw, rice husk, and corn husk as waste for the composite construction material. The burning of organic waste materials is a common practice [60] that is followed in the region. The literature presents the work related to these composites. Saman et al. determined the fired clay brick composite thermophysical properties with rice husk, corn cob, and waste tea [61]. Phonphuak et al. experimentally determined the physical and mechanical properties of fired clay brick samples with different percentages of rice husk [62]. Using these materials in construction will help mitigate the emissions. If these waste materials become a sellable commodity for construction, it will provide the farmers with an incentive to avoid burning. This work, therefore, studies the disposal of the said organic waste materials by using them in construction to achieve the following two significant advantages.


First, the improvement in thermal comfort of the buildings with reduced energy usage.  Second, a significant reduction in greenhouse gas emissions volume resulted from burning these waste materials.
These aims align with the targets set by the IEA-COP26 Net Zero Summit of realizing net zero emissions by 2050 [63].
Brick samples using 2%, 4%, and 6% of these three organic waste material ratios by weight were produced. The waste residues of wheat straw, corn husk, and rice husk used in this study are shown in Figure 8, while the compressed brick samples produced are depicted in Figure 9 below.  The method described earlier was used to calculate the thermal properties of these brick samples and the results are shown in Table 3. The method described earlier was used to calculate the thermal properties of these brick samples and the results are shown in Table 3. Table 3. Comparison of specific heat capacity, density, thermal conductivity, and thermal diffusivity of clay, clay-cement, and clay-cement-sand samples.

Sample
Cp (

Computational Analysis
The thermal properties established during the above detailed experimental study were used for computational analysis to calculate the heating and cooling loads for a selected building. The computational analysis also established how much energy use and GHG emissions due to energy saving can be reduced. The computational analysis was performed using TRNSYS simulation software [64]. The local weather conditions were used to calculate the annual heating and cooling loads for a two-story building of an academic institute located in Islamabad. To conduct the simulations, the building was designed using TRNSYS plugin TRNSYS3D in Google SketchUp. The modeled building design is shown in Figure 10.  Table 3. Comparison of specific heat capacity, density, thermal conductivity, and thermal diffusivity of clay, clay-cement, and clay-cement-sand samples.

Computational Analysis
The thermal properties established during the above detailed experimental study were used for computational analysis to calculate the heating and cooling loads for a selected building. The computational analysis also established how much energy use and GHG emissions due to energy saving can be reduced. The computational analysis was performed using TRNSYS simulation software [64]. The local weather conditions were used to calculate the annual heating and cooling loads for a two-story building of an academic institute located in Islamabad. To conduct the simulations, the building was designed using TRNSYS plugin TRNSYS3D in Google SketchUp. The modeled building design is shown in Figure 10. The selected building envelope building properties with the selected materials are defined in TRNSYS using the TRNBuild tool. The heating and cooling loads using each of the selected envelope materials are obtained for the entire year. The simulation results are compared to show the thermal efficiency of the designed materials. The thermal behavior of the building is simulated using building envelope properties for a nine-inch-thick brick wall of experimentally studied materials, with half-inch plaster on both sides. Properties of plaster used are thermal conductivity 0.5 W/m-K, heat capacity 1.00 kJ/kg-K, and density 1300 kg/m 3 [23]. The ground floor ceilings are designed as four-inch concrete slabs with half-inch plaster on both sides. The thermal properties of concrete used are thermal conductivity of 1.30 W/m-K, the specific heat capacity of 1.13 kJ/kg-K, and a concrete density of 2240 kg/m 3 [29]. Properties of plaster are the same as those used in the case of the wall. The selected building envelope building properties with the selected materials are defined in TRNSYS using the TRNBuild tool. The heating and cooling loads using each of the selected envelope materials are obtained for the entire year. The simulation results are compared to show the thermal efficiency of the designed materials. The thermal behavior of the building is simulated using building envelope properties for a nine-inch-thick brick wall of experimentally studied materials, with half-inch plaster on both sides. Properties of plaster used are thermal conductivity 0.5 W/m-K, heat capacity 1.00 kJ/kg-K, and density 1300 kg/m 3 [23]. The ground floor ceilings are designed as four-inch concrete slabs with half-inch plaster on both sides. The thermal properties of concrete used are thermal conductivity of 1.30 W/m-K, the specific heat capacity of 1.13 kJ/kg-K, and a concrete density of 2240 kg/m 3 [29]. Properties of plaster are the same as those used in the case of the wall.
Properties of the external roof of the building are defined as a four-inch concrete slab whose properties are with half-inch plaster covered with one inch of granite having thermal conductivity 1.87 W/m-K, specific heat capacity 0.71 kJ/kg-K, and density of 2200 kg/m 3 [23].
For the winter months, the required 20 • C temperature is set to calculate the heating load. During the summer months, 26 • C temperature is set as the requirement to calculate the cooling load. The reference building is an academic institute building, so heating and cooling loads are calculated according to the institute work timing of 08:00 AM to 06:00 PM for working days, while Saturday and Sunday are considered the closed weekend. The heating load is calculated for January, February, March, October, November, and December, while the cooling load is calculated for March, April, May, June, July, August, September, and October.

Heating Load
The heating load of the schedule mentioned above is simulated in TRNSYS simulation software. As an example, the heating load of the last week of January using rice husk composite bricks in the building envelope is shown in Figure 11. The school is in session from Monday to Friday and hence the heating load on weekends is negligible. It is clear in Figure 11 that heating load decreases with the increase of composite material mixing ratio. Higher room temperature is kept on both floors when composite bricks with a 6% husk composition are used for construction. The above results show that the rice husk mixing increases the heat storage capacity of the building envelope. The detailed results for the heating load calculated are given in Table 4.

2021, 14, x FOR PEER REVIEW 13 of 23
Properties of the external roof of the building are defined as a four-inch concrete slab whose properties are with half-inch plaster covered with one inch of granite having thermal conductivity 1.87 W/m-K, specific heat capacity 0.71 kJ/kg-K, and density of 2200 kg/m 3 [23].
For the winter months, the required 20 °C temperature is set to calculate the heating load. During the summer months, 26 °C temperature is set as the requirement to calculate the cooling load. The reference building is an academic institute building, so heating and cooling loads are calculated according to the institute work timing of 08:00 AM to 06:00 PM for working days, while Saturday and Sunday are considered the closed weekend. The heating load is calculated for January, February, March, October, November, and December, while the cooling load is calculated for March, April, May, June, July, August, September, and October.

Heating Load
The heating load of the schedule mentioned above is simulated in TRNSYS simulation software. As an example, the heating load of the last week of January using rice husk composite bricks in the building envelope is shown in Figure 11. The school is in session from Monday to Friday and hence the heating load on weekends is negligible. It is clear in Figure 11 that heating load decreases with the increase of composite material mixing ratio. Higher room temperature is kept on both floors when composite bricks with a 6% husk composition are used for construction. The above results show that the rice husk mixing increases the heat storage capacity of the building envelope. The detailed results for the heating load calculated are given in Table 4.   Trends of energy consumption for rice husk, wheat straw, and corn husk with different mixing ratios are shown in Figure 12. These results indicate that increasing the mixing density of all three composite materials causes an appreciable decrease in the energy required to heat the building. Among the three materials selected for this study, it is found that the mixing of corn husk provides the best results, and the energy needed to maintain thermal comfort level is decreased substantially by approximately 15.6% when compared with the standard brick construction. Trends of energy consumption for rice husk, wheat straw, and corn husk with different mixing ratios are shown in Figure 12. These results indicate that increasing the mixing density of all three composite materials causes an appreciable decrease in the energy required to heat the building. Among the three materials selected for this study, it is found that the mixing of corn husk provides the best results, and the energy needed to maintain thermal comfort level is decreased substantially by approximately 15.6% when compared with the standard brick construction.

Cooling Load
The cooling load for the building ground and the first floor of the days mentioned above and the schedule are simulated in TRNSYS simulation software. For example, the cooling load of the first week of July using rice husk composite bricks in the building envelope is shown in Figures 13 and 14. The results show that cooling load decreases with the increase of composite material mixing ratio. Lower room temperature is kept on both floors when composite bricks with a 6% husk composition are used for construction. This shows that the rice husk mixing increases the building envelope's heat storage capacity, thus allowing lesser heat to be transmitted from the surroundings to inside the building. The results for cooling load are calculated for different density ratios of three selected waste materials and are given in Table 5.

Cooling Load
The cooling load for the building ground and the first floor of the days mentioned above and the schedule are simulated in TRNSYS simulation software. For example, the cooling load of the first week of July using rice husk composite bricks in the building envelope is shown in Figures 13 and 14. The results show that cooling load decreases with the increase of composite material mixing ratio. Lower room temperature is kept on both floors when composite bricks with a 6% husk composition are used for construction. This shows that the rice husk mixing increases the building envelope's heat storage capacity, thus allowing lesser heat to be transmitted from the surroundings to inside the building. The results for cooling load are calculated for different density ratios of three selected waste materials and are given in Table 5.  As seen in the graph, cooling load is decreasing with the increase of the composite material mixing ratio. The detailed results for the cooling load calculated are given in Table 5. Trends of energy consumption for rice husk, wheat straw, and corn husk with different mixing ratios are shown in Figure 15 below. These results indicate that increasing the mixing density of all three composite materials causes a decrease in the energy needed to cool the  As seen in the graph, cooling load is decreasing with the increase of the composite material mixing ratio. The detailed results for the cooling load calculated are given in Table 5. Trends of energy consumption for rice husk, wheat straw, and corn husk with different mixing ratios are shown in Figure 15 below. These results indicate that increasing the mixing density of all three composite materials causes a decrease in the energy needed to cool the  As seen in the graph, cooling load is decreasing with the increase of the composite material mixing ratio. The detailed results for the cooling load calculated are given in Table 5.
Trends of energy consumption for rice husk, wheat straw, and corn husk with different mixing ratios are shown in Figure 15 below. These results indicate that increasing the mixing density of all three composite materials causes a decrease in the energy needed to cool the building. Among the three materials selected for this study, it is found that the mixing of corn husk provides the best results, and the energy needed to keep thermal comfort level is decreased and a saving of 36 GJ is achieved by using 6% corn husk bricks for the building envelope when compared with the standard brick construction. building. Among the three materials selected for this study, it is found that the mixing of corn husk provides the best results, and the energy needed to keep thermal comfort level is decreased and a saving of 36 GJ is achieved by using 6% corn husk bricks for the building envelope when compared with the standard brick construction.

Figure 15.
Cooling load comparison using different composite materials and mixing ratios.

CO2 Emissions
CO2 emissions during the production of the materials and building life cycle (assumed to be 40 years) are shown in Table 6. CO2 emission during the production of 1000 bricks is 427.985 kg [60]. The total wall area of the building is 2043 m 2 (excluding windows area; the total number of bricks for that area is calculated by taking the brick size of 9 × 4.5 × 3 inches, and the size of the in-between plaster layer of 0.12 inch (3 mm). The total number of bricks used during the construction of the building comes out to be 258,427 and the total CO2 emission during the production of a standard brick used in the building is calculated to be 0.12 MtCO2e, while the emission during the production of proposed samples is almost zero because manual compression is used for their preparation.

CO 2 Emissions
CO 2 emissions during the production of the materials and building life cycle (assumed to be 40 years) are shown in Table 6. CO 2 emission during the production of 1000 bricks is 427.985 kg [60]. The total wall area of the building is 2043 m 2 (excluding windows area; the total number of bricks for that area is calculated by taking the brick size of 9 × 4.5 × 3 inches, and the size of the in-between plaster layer of 0.12 inch (3 mm). The total number of bricks used during the construction of the building comes out to be 258,427 and the total CO 2 emission during the production of a standard brick used in the building is calculated to be 0.12 MtCO 2 e, while the emission during the production of proposed samples is almost zero because manual compression is used for their preparation.

Introducing PCM Layer
The above analysis showed the advantage of using composite building blocks; by finding a significant reduction in energy consumption and GHG emissions and to further consolidate this advantage and avoid the use of cooling altogether while providing better thermal comfort for the dwellers in low-cost housings, the use of PCMs was considered. BenZaid et al. experimentally determined the thermal advantage of using PCMs in clay-straw walls in Morocco [65]. Usually, as already mentioned, the cost of PCMs is high [66]. Paraffin is one choice available to be used as a PCM in the human thermal comfort range. However, paraffin is considered a fire hazard and still expensive for use in low-cost housing. Hydrated salts are not a fire hazard coupled with higher volumetric storage abilities and are among the least expensive PCMs available [67]. Considering this, calcium chloride hexahydrate CaCl 2 ·6H 2 O was selected for this study. The thermophysical properties of CaCl 2 ·6H 2 O are given in Table 7. As thermophysical properties given in Table 7 of selected PCM include both solid and liquid phases of material along with the melting temperature around 29 • C, it shows that when the temperature reached this threshold, the PCM would change its phase from solid to liquid by using heat to change its phase at a constant temperature. To prove the relative advantage of incorporating PCMs and composite material blocks in the construction of low-cost housing, a wall was modeled in ANSYS software. Simulation of heat transfer through the wall was conducted for the full-fired brick wall, entire composite 6% corn husk block wall, fired brick wall with embedded PCM, and composite 6% corn husk block wall with embedded PCM.
Simulations were conducted for weather conditions of the first ten days of June. In simulations, the time-dependent energy equation is solved for fired brick and 6% corn husk composite block case, while for PCM, the enthalpy porosity-based energy equation is used. SIMPLE (semi-implicit method) pressure velocity coupling and second-order upwind formulation for energy are used. A time step size of 60 s is selected.

Wall Geometry
The wall geometries for all four wall configurations are given in Figure 16. A 10 mm layer of PCM is embedded at the horizontal center of the 220 mm wall thickness used in this study. Configurations for fired brick and 6% corn husk composite block are considered. Comparison for indoor temperature is obtained for all configurations for the climatic conditions of the first ten days of June of Islamabad, Pakistan. It is characterized as humid subtropical weather with all four seasons, including a hot summer typically from May to August. The latitude and longitude of Islamabad are 33.6844 • N and 73.0479 • E, respectively.
The outdoor transient temperature profile is input in all the cases, and free convection with a heat transfer coefficient of 5 W/m 2 at the outlet boundary is used to simulate the typical wall loading of a hot climate. The top and bottom sides are set as adiabatic for 1-dimensional heat transfer. s 2021, 14, x FOR PEER REVIEW 18 of 23 Figure 16. Model of fired brick and 6% corn husk composite block walls (a-d) with and without PCM.

Simulation Results for PCM Wall
The outdoor boundary condition and the indoor temperatures for the first ten days of June and the simulation results depicting indoor temperature variation with outdoor ambient conditions are shown in Figure 17. It can be seen from these results that standard fired brick wall performs quite poorly, and much higher temperatures are experienced indoors, at times reaching as high as 31 °C, which is considered beyond the human thermal comfort range. The fired brick wall without PCM integration shows a high sensitivity to the outdoor temperature, showing that it does not protect the inhabitants from the varying weather conditions. Even with a PCM layer, the fired brick wall does not perform too well, and the performance of the 6% Corn Husk composite block wall even without any PCM layer is better than a brick wall. In comparison, the 6% Corn Husk composite block wall with the PCM layer is very stable and can keep an indoor temperature of 27 °C throughout the day, even on scorching days when the outdoor ambient temperatures are reaching close to 38 °C. For the first three days, the indoor temperature for PCM-based fired brick wall fluctuates between 27-28 °C, showing temperature fluctuating within the 1 °C range, whereas the fired brick shows temperature fluctuation of 4 °C. The trend is continued for fired brick with and without PCM for days 4-7. For days 8-10, both simple fired brick and embedded PCM exhibit more significant temperature variation, as the outdoor temperature peaks lower than preceding days.

Simulation Results for PCM Wall
The outdoor boundary condition and the indoor temperatures for the first ten days of June and the simulation results depicting indoor temperature variation with outdoor ambient conditions are shown in Figure 17. It can be seen from these results that standard fired brick wall performs quite poorly, and much higher temperatures are experienced indoors, at times reaching as high as 31 • C, which is considered beyond the human thermal comfort range. The fired brick wall without PCM integration shows a high sensitivity to the outdoor temperature, showing that it does not protect the inhabitants from the varying weather conditions. Even with a PCM layer, the fired brick wall does not perform too well, and the performance of the 6% Corn Husk composite block wall even without any PCM layer is better than a brick wall. In comparison, the 6% Corn Husk composite block wall with the PCM layer is very stable and can keep an indoor temperature of 27 • C throughout the day, even on scorching days when the outdoor ambient temperatures are reaching close to 38 • C. For the first three days, the indoor temperature for PCM-based fired brick wall fluctuates between 27-28 • C, showing temperature fluctuating within the 1 • C range, whereas the fired brick shows temperature fluctuation of 4 • C. The trend is continued for fired brick with and without PCM for days 4-7. For days 8-10, both simple fired brick and embedded PCM exhibit more significant temperature variation, as the outdoor temperature peaks lower than preceding days.
shows PCM's latent heat thermal energy storage capability, which makes them a potential candidate for energy storage in buildings at a constant temperature. Moreover, this implies integrating PCMs with alternative sustainable materials solutions for construction to give a better trade-off with energy consumption and construction cost. It can thus be concluded that the 6% Corn Husk composite block with integrated PCM can provide reasonable thermal comfort and is a good choice as a construction material for low-cost housing projects. Figure 17. Simulation results depicting indoor temperature variation with outdoor ambient conditions.

Conclusions
Sustainable and organic waste materials like corn husk, rice husk, and wheat straw are abundantly available in Pakistan. Experimental and simulation studies show how they can help save energy when used in construction materials. Thermo-physical properties and thermal energy storage of base materials are improved by mixing the suggested organic waste materials in different weight ratios. The overall result shows that mixing of corn husk in base material improves its thermo-physical properties and thermal energy storage better than rice husk and wheat straw, but rice husk and wheat straw can also help reduce the consumption of energy in building sectors. The use of waste agri-materials to create the suggested building material can save energy consumption of buildings by up to 3.5% and reduce carbon dioxide during production and usage. Standard fired bricks used for the construction of the buildings are baked using coal or other harmful fuels. CO2 emission to produce 1000 bricks is 120 MtCO2e, while in the production of sustainable material bricks using manual compression, no emission of CO2 occurs during the production. Similarly, a considerable amount of CO2 emissions is also saved by preventing the burning of waste agri-materials and using them as building materials.
PCMs using their thermal characteristics can store and use heat to change their phase at a constant temperature, which provides a better opportunity for building design primarily from a thermal comfort point of view. However, a low-cost PCM should be Furthermore, the 6% Corn Husk configuration without PCM maintains a lower temperature than the PCM-based fired brick configuration but fluctuates throughout ten days, while PCM based configuration keeps a constant temperature for days 1-8. This shows PCM's latent heat thermal energy storage capability, which makes them a potential candidate for energy storage in buildings at a constant temperature. Moreover, this implies integrating PCMs with alternative sustainable materials solutions for construction to give a better trade-off with energy consumption and construction cost. It can thus be concluded that the 6% Corn Husk composite block with integrated PCM can provide reasonable thermal comfort and is a good choice as a construction material for low-cost housing projects.

Conclusions
Sustainable and organic waste materials like corn husk, rice husk, and wheat straw are abundantly available in Pakistan. Experimental and simulation studies show how they can help save energy when used in construction materials. Thermo-physical properties and thermal energy storage of base materials are improved by mixing the suggested organic waste materials in different weight ratios. The overall result shows that mixing of corn husk in base material improves its thermo-physical properties and thermal energy storage better than rice husk and wheat straw, but rice husk and wheat straw can also help reduce the consumption of energy in building sectors. The use of waste agri-materials to create the suggested building material can save energy consumption of buildings by up to 3.5% and reduce carbon dioxide during production and usage. Standard fired bricks used for the construction of the buildings are baked using coal or other harmful fuels. CO 2 emission to produce 1000 bricks is 120 MtCO 2 e, while in the production of sustainable material bricks using manual compression, no emission of CO 2 occurs during the production. Similarly, a considerable amount of CO 2 emissions is also saved by preventing the burning of waste agri-materials and using them as building materials.
PCMs using their thermal characteristics can store and use heat to change their phase at a constant temperature, which provides a better opportunity for building design primarily from a thermal comfort point of view. However, a low-cost PCM should be integrated with new and innovative construction materials such as those derived from agriculture waste Energies 2021, 14, 3544 20 of 23 materials to be possible. This unique combination not only reduces energy consumption and cost but also has an impact on GHG emission reduction. It is further concluded that integrating PCM within the Corn Husk composite block wall stabilizes the indoor temperature and provides reasonable thermal comfort for humans. This combination can keep a constant 27 • C temperature indoors without cooling even when the outdoor temperatures are very high. Therefore, the corn husk composite blocks with integrated PCM are recommended as good construction material for low-cost low-energy buildings. In future work, it is envisaged that a detailed error analysis of experiments may be performed. Furthermore, samples of these agriculture waste-compressed composite bricks need to be characterized for structural and mechanical properties. Experimental testing of a building with a PCM-integrated composite wall may be conducted to find the heat transfer characteristics of the building envelope and the level of thermal comfort achieved. A detailed economic analysis including life-cycle costing and emissions of construction using the compressed composite bricks in comparison to energy savings when compared to fired brick structures may be conducted. Acknowledgments: The support of the Air University Mechatronics Engineering Department and lab staff was crucial in the completion of work.

Conflicts of Interest:
The authors declare no conflict of interest.