Sensitivity Analysis and Optimization of Operating Parameters of an Oxyfuel Combustion Power Generation System Based on Single-Factor and Orthogonal Design Methods

: The main purpose of this paper is to quantitatively analyze the sensitivity of operating parameters of the system to the thermodynamic performance of an oxyfuel combustion (OC) power generation system. Therefore, the thermodynamic model of a 600 MW subcritical OC power generation system with semi-dry flue gas recirculation was established. Two energy consumption indexes of the system were selected, process simulation was adopted, and orthogonal design, range analysis, and variance analysis were used for the first time on the basis of single-factor analysis to conduct a comprehensive sensitivity analysis and optimization research on the changes of four operating parameters. The results show that with increasing oxygen purity, the net standard coal consumption rate first decreases and then increases. With decreasing oxygen concentration, the recirculation rate of dry flue gas in boiler flue gas ( (cid:2031) (cid:2869) ) and an increasing excess oxygen coefficient, the net standard coal consumption rate increases. The net electrical efficiency was just the opposite. The sensitivity order of two factors for four indexes is obtained: the excess oxygen coefficient was the main factor that affects the net standard coal consumption rate and the net electrical efficiency. The influence of oxygen concentration and oxygen purity was lower than that of excess oxygen coefficient, and (cid:2031) (cid:2869) has almost no effect. flue direct contact dehydration,


Introduction
Increasing greenhouse gas emissions are one of the main reasons for the frequent occurrence of global extreme weather.CO2 comprises approximately 80% of those emissions [1]; therefore; reducing CO2 emissions to cope with global climate change is one of the greatest challenges facing mankind in energy production today. A promising technology for power generation that reduces CO2 emissions is oxyfuel combustion (OC) with carbon capture. In this type of power plant; the fuel is burned in an O2/CO2 atmosphere; producing flue gas consisting mainly of CO2 and H2O [2].
As a near-zero-emission clean coal power generation technology that can directly capture CO2, OC technology is a commercially feasible technology for large-scale CO2 capture [3]. However, large-scale carbon capture coal-fired generating units using OC technology need to use an air separation unit and CO2 purification and compression unit. The high energy consumption incurred by these additional types of equipment leads to a decrease in the overall generating efficiency of the units and an increase in operating costs, which are the main obstacles to their large-scale use [4]. Therefore, it is necessary to conduct a comprehensive and in-depth analysis of the relevant operational factors that affect those obstacles. These analyses are important for reducing unit energy consumption, promoting large-scale use of OC technology, and reducing CO2 capture cost.
Extensive work has been done on operation energy consumption and techno-economic analysis of OC and CO2 capture units. Han [5] and Jin [6] used an exergy analysis method to analyze the thermodynamic performance of an air-separation oxygen system and a CO2 capture system. They also proposed ways to reduce the operating energy consumption of the systems. Tola [7] and Oboirien [8] did a techno-economic analysis on the operating energy consumption, equipment investment, power generation cost, and CO2 emission reduction cost of coal-fired generating sets that used OC and a CO2 capture system. They concluded that the CO2 emission rate was reduced by 10 times after the power plant was modified with oxyfuel technology, and 27% to 29% of the energy was used to capture CO2. The energy loss was related to the nature of coal. Fu [9] proposed applying process heat to the Rankine cycle of regenerative steam to increase the power generation of the steam turbine in an OC power plant. Yan [10] did a comprehensive sensitivity analysis on a 600MW supercritical steam oxyfuel combustion power generation system using dry, semidry, and wet flue gas recycling modes. After evaluating the changes in eight main operating parameters, he concluded that air leakage had the greatest influence on the output energy of the system and that the most practical flue gas recirculation mode was the semidry type. Gładysz [11] and Koiwanit [12] adopted the method of total life cycle cost of coal-fired units before and after the modification of OC equipment investment, power generation cost, and CO2 emission reduction cost, and put forward a different method of life cycle assessment. Jin [13], Kong [14], and Han [15], through modeling and process simulation, analyzed and evaluated OC and CO2 capture generator sets from the perspective of thermal dynamics and thermal economics. They then proposed the best value of oxygen concentration and an optimization scheme for reducing system energy consumption. Escudero [16] proposed technology for an oxyfuel coal-fired power plant that uses a high-concentration oxidizer of over 40% and integrates waste heat into the new steam cycle to minimize energy consumption. The net efficiency of their power plant was significantly higher than that of a benchmark oxyfuel plant, and the energy penalty could be reduced from 10.5% to 7.3%. Gładysz [17] and Ziębik [18] used cumulative exergy loss, local exergy loss, and a thermodynamic system to devise a perfect degree of cumulative exergy efficiency. They analyzed three techno-economic indexes such as the OC, the CO2 capture generating set, and the thermodynamic performance of the system. Lei [19] proposed a new OC process. Its capital investment and the operation costs of the air separation unit and the circulating fan were lower. The variation of flue gas composition in the flue gas combustion furnace was small, and when the ratio of air to oxygen was 2 or 3, the economy of the OC was better. Gao [20] used a Peng-Robinson (PR) equation of state model on the basis of the actual gas state equation to establish a method using a bias function and a CO2 compressed air separation unit to calculate the operation energy consumption of a purification unit.
Previous studies have mostly analyzed the influence of one or several single operating factors on the energy efficiency indicators of an OC power generation system. For example, Jin [13] analyzed the influence of oxygen concentration on the net efficiency. Kong [14] and Han [15] analyzed the influence of oxygen purity on net efficiency. Yan [10] undertook a comparative analysis and evaluation on the influence of such parameters as flue gas recirculation rate, air leakage rate, pressure rise of fans, flue gas condensation temperature, oxygen concentration, and flue gas circulation model on the net efficiency. However, in a uniform experiment or simulation platform, the main operation parameters, such as the oxygen purity in the air separation unit, the oxygen concentration and excess oxygen coefficient in power generation unit, and the recirculation rate of dry flue gas in boiler flue gas for quantitative analysis of the operating energy indexes of in-depth research has yet to carry out in-depth research. These operating economic indexes include the net standard coal consumption rate and the net electrical efficiency, among which the net standard coal consumption rate can comprehensively reflect the overall operating energy consumption level of a power generation system.
Moreover, due to a large number of influencing parameters in the study of thermodynamic characteristics of an OC power generation system, each parameter has a certain range of variation. How to consider the interaction between parameters requires a comprehensive analysis of each parameter's collocation, so the calculation will be very large. Therefore, the single factor analysis method with fixed other parameters was mostly used in previous studies. However, this method cannot determine the optimization order of each factor and the influence of the interaction between each factor on the system performance.
An orthogonal design method is a design method to study multi-factors and multi-levels. This method selects representative points from the overall test according to the orthogonality for the test, which can solve the coupling effect of multi-factors and reduce the number of tests [21,22].
At present, the orthogonal design method is often used in the design and parameter optimization of different power generation systems and cycles. For example, Wang [23] and Liu [24] established the thermodynamic model of the organic Rankine circulation system, and through the analysis of the orthogonal design results, the optimal level composition of system parameters to improve the thermal and economic performance of the system was given. Xi [25] analyzed the experimental system of a new organic Rankine cycle based on the range analysis method of orthogonal design and obtained the optimal and the worst constitutions of six indexes. Chiu [26] conducted an experimental study on the reaction conditions of methanol steam reforming, obtained the influence of each reaction condition on the MSR process, and obtained the optimal combination of each control factor. Chen [27] and Terzioğlu [28], respectively, analyzed the performance of the thermoelectric generator by the orthogonal design method and obtained the influence relationship of material and geometric parameters on system performance. However, the application of an orthogonal design method to the optimization of operating parameters in an OC power generation system has not been carried out yet.
The purpose of this study is to take the net standard coal consumption and the net electrical efficiency of the system as specific energy efficiency indicators, study the sensitivity characteristics of various single factors under a unified platform, and obtain the results of comprehensive sensitivity analysis of operating parameters to improve the thermal performance and economic performance of the OC power generation system through orthogonal design method, range analysis, and variance analysis for the first time. This study will provide theoretical guidance for the engineering design and optimization of an OC power generation system.

Model of the Oxyfuel Combustion System
We used Aspen Plus (Aspen Technology, Inc., USA) [29] and EBSILON Professional (STEAG Gmbh, Germany) [30] software to model an OC power generation system based on the conventional subcritical coal-fired units currently in operation. Four operating parameters, including oxygen purity, oxygen concentration, the recirculation rate of dry flue gas in boiler flue gas ( ), and the excess oxygen coefficient, were selected as factors. The power station modeled in this study included three units: OC power generation unit, air separation unit (ASU), and flue gas compression and purification unit (CPU). Figures 1-3 showed the details of each unit.

OC Power Generation Unit
Currently, 600 MW OC power generation units have not been put into operation. Thus, we selected a 600 MW subcritical generating unit as the reference unit in this study. The unit had a rated power of 600 MW and a maximum continuous output of 641.6 MW. The boiler model was SG-2023/17.5-M914, and the design fuel was shenhua wanlichuan bituminous coal. An analysis of the coal is shown in Table 1. The turbine model was N600-16.67/538/538. The regenerative system consisted of a three-stage high-pressure heater, a four-stage low-pressure heater, and a deaerator. The specific process is shown in Figure 1. The flow of the modeled OC power generation system was basically the same as that of a reference conventional combustion generation system. The difference was that the combustion gas in the OC power generation system was a proportional mixture of circulating flue gas and oxygen, not air. The OC power generation system could be divided into two types, dry cycle and wet cycle, according to the temperature and water content of the circulating flue gas. The dry cycle dusted and cooled the flue gas to remove part of its moisture in the furnace and oxygen to participate in the combustion. The wet cycle pumped part of the hot flue gas directly into the furnace from behind the economizer. In this model, semi-dry flue gas recirculation was used. That is, the dry cycle was used for the primary gas flow, and the wet cycle was used for the secondary gas flow [10,11].
For the OC boiler with primary air as dry flue gas and secondary air as wet flue gas recirculation, after entering the stable operation stage, , in the flue gas circulation process should satisfy: where is the oxygen flow rate output by ASU, Nm 3 /h; is the oxygen purity, %. The oxygen purity is defined as the molar proportion of pure oxygen contained in the oxygen fed into the OC generating unit from the air separation unit; is the recirculating wet flue gas flow rate, Nm 3 /h; w rf O is the oxygen volume content in the recirculating wet flue gas without dehydration and drying by the dehydration device, %; is the oxygen concentration in all combustion-supporting gases, %. The oxygen concentration is defined as the molar proportion of oxygen in the auxiliary gas fed into the OC power generation unit; is the actual volume of combustion supporting gas required for the combustion process of the OC pot, Nm 3 /h; is the total circulating flue gas flow rate, Nm 3 /h. Two important definitions of a flue gas cycle rate are d rf is the recirculation rate of dry flue gas in the total flue gas, is the recirculation rate of dry flue gas in the boiler flue gas. The dry flue gas mentioned here refers to the flue gas after desulfurization and direct contact dehydration unit.
is the total flue gas of the boiler, Nm 3 /h; is the boiler flue gas flow rate, Nm 3 /h; is the total flue gas volume after gas heat transfer, desulfurization, and direct contact dehydration, Nm 3 /h, is the volume flow of flue gas into the CPU.
We used EBSILON Professional software to establish models for a conventional power plant and the OC power generation system. In the single-factor analysis of OC conditions, the simulation parameters were set as follows: • The coal used was the same as that of conventional coal-fired units.
• The combustion process of the boiler was under 0.097 MPa of pressure.
• The oxygen temperature after preheating was 351 °C: the same as the air temperature of the conventional combustion power generation system after preheating. • The inlet oxygen temperature of the gas-gas heat exchanger was set at 45 °C. • The pulverized coal burnout rate was 98%.
• To ensure the coal burnout rate, the excess oxygen coefficient was 1.10.
• The air leakage coefficient of the system was 3%.
• The oxygen purity ( ) was set at 96%; the nitrogen content was 0.8%, the argon content was 3.2%.
The proportion of primary and secondary gas mixture, the oxygen concentration, and the oxygen supply (the difference between the total oxygen demand and the oxygen in the circulating flue gas) were all set and calculated by the controller in EBSILON. The simulation results and design values of the conventional unit and the oxyfuel unit are shown in Table 2. Table 2 shows that the difference between the design value of the conventional unit and the simulation value of the conventional unit was very small, thus verifying the accuracy of the model.
Cryogenic oxygen production is the only commercial large-scale oxygen production method, which can be divided into external compression and internal compression. According to the applied pressure level, oxygen production level, and technical perfection, this study selected five sets of air separation units with a single machine capable of 6 × 10 4 Nm 3 /h for external compression flow. After simplifying the process, Aspen Plus software was applied to establish the air separation unit model of the OC generator set based on the PR state equation of real gas.
In the process of oxygen production, the air separation unit separates the compressed air into oxygen with purity and nitrogen with purity through the rectification device. The actual separation work required in the separation process is as follows:  (6) where is actual separation work required in the separation process, J; the is the environment temperature, K; is the gas constant, J/(mol·K); n is the amount of nitrogen with the purity of obta ined after the separation of one mole of air. Before entering the rectification system for separation, the air needs to be compressed by the multistage compressor to improve the exergy value, so as to achieve the actual separation work required by the separation process. Therefore, at the outlet of the multistage compressor, the flow pressure p required by the air is: where 0 p is inlet air pressure of the multistage compressor, MPa.

Air Separation Unit
The operating energy consumption of the air separation unit can be calculated by the electrical power required to produce oxygen with the purity of and a flow rate of .
where , g l ϕ is the volume fraction of l gas contained in the air, %; n is the multistage compressor series; is the theoretical compression work required for the adiabatic compression of l gas in the air by the first stage of the multistage compressor, kJ/mol; com η is the efficiency of the multistage compressor. The specific model and process are shown in Figure 2. The setting of simulation parameters: • The air volume composition is nitrogen 78.12%, oxygen 20.95%, and argon 0.93% (atmospheric condition is 101.325 kPa, 0 °C). • The efficiency of the air compressor is set at 85%.
• Molecular sieve switching loss and instrument loss are calculated at 1% according to Linde's experience. • The oxygen content of the product is 98% O2 and 2% N2.
• The recycled gas of molecular sieve is 20% of the processed air, the heating temperature is 120 °C and the regeneration time is a quarter of the switching period [14]. • Two-stage air compression and two-stage intercooler are used in the air separation unit. The above simulation parameters were selected according to the parameters of the air separation unit in [14]. The comparison between the simulated values obtained and those in the literature [14] is shown in Table 3. Table 3 shows that the error between the simulated value in this study and the simulated value in the literature is small, and the energy consumption per unit of oxygen production is approximately 0.36 (kW• h) / m 3 , which is basically consistent with the actual production result. Thus, verifying the accuracy of the model. Meanwhile, it can be seen that the compression energy consumption of the air separation unit accounts for approximately 97% of the total energy consumption of the entire air separation unit, the energy consumption of the air separation unit mainly comes from air compression.

Compressed and Purification Unit of Gas
Flue gas compression and purification is a process that condenses, purifies, and compresses flue gas until it contains a higher purity of CO2 to meet the requirements of large-scale CO2 transportation. The specific process is that first the CO2 in the flue gas is dehydrated and separated after multistage compression and multistage condensation. Then the flue gas enters the triethylene glycol (TEG) dehydration process for deep dehydration, and finally enters the purification system to separate the entire compressed flue gas flash. After purification, the flue gas is pressurized and heated by a centrifugal pump and heater and transported by a pipe after conforming with the typical conditions of large-scale CO2 transportation. Typical parameters of pipeline transportation are a temperature of 20 °C; a pressure of 11.0 MPa, a volume fraction (ψ) of CO2 of greater than 95%, ψ (O2, Ar, N2) of less than 4%, and ψ (H2O) of less than 50 ppm. A flow diagram of the gas compression and purification unit is shown in Figure 3 [14].  The operating energy consumption of the flue gas compression and purification unit can be calculated by the electrical power required to compress the flue gas with a flow rate of and the highly pure CO2 in the flue gas.
According to the calculation model of compression work 0 W of the actual gas theory, the calculation model of operation energy consumption of CO2 compression and purification unit can be obtained as: where y e ϕ − is the portion of e gas contained in the flue gas; is the CO2 flow into the booster pump, m 3 /s; p η is the efficiency of booster pump.

Calculation Model of Energy Consumption of the Oxyfuel System
A calculation model of the net standard coal consumption rate of the OC power generation system is where is the power consumption of the plant, kW; is the power generation, kW; is the auxiliary power ratio, %; is the coal consumption, kg/h; is the standard coal consumption, kg/h; is the gross coal consumption rate, g/kWh; and is the net standard coal consumption rate, g/kWh. is the net electrical efficiency; EP is the energy penalty due to carbon capture in an OC power generation system, %; Q is the low heating value of coal, kJ/kg; is the net electrical efficiency of the OC power generation system; is the net electrical efficiencies of the reference plant.

Results and Discussion
The net standard coal consumption rate and the net electrical efficiency of an OC power generation system were the important energy consumption indicators in its operation. In this study, flow models of the entire conventional and OC power generation systems were made. On the basis of the literature [10,14,15,19], as influencing factors, we selected four key operating parameters: oxygen purity ( ), oxygen concentration ( ), recirculation rate of dry flue gas in boiler flue gas ( ), and the excess oxygen coefficient ( ). The single-factor and multifactor orthogonal influences of the above four operating parameters on the net standard coal consumption rate and the net electrical efficiency were analyzed. Other factors in the process of analysis, whether variable or immutable, were taken as input to known conditions.

Operating Factors Influencing Energy Consumption of an Oxyfuel Combustion System
3.1.1. Oxygen purity ( ) Figure 4 shows that with the increased oxygen purity ( ), the oxygen flow rate into the boiler for combustion and the flue gas volume into the CPU all decreased. Energy consumption per unit of oxygen production and the air separation system increased.
It can be explained as follows: With the increase of , the actual separation work s W required by the air separation process and the flow pressure required by the compressed air will both increase, resulting in the corresponding increase in the oxygen mono consumption; other things being equal, the oxygen flow rate (Figure 1) decreases as the oxygen purity increases. Although the oxygen flow decreased somewhat, it was not enough to offset the effects of increased energy consumption per unit of oxygen production, so the energy consumption of ASU increased with the increase of oxygen purity. As the oxygen purity increases, the oxygen flows into the boiler for combustion to decrease. Under the premise of constant oxygen concentration, the amount of circulating flue gas (V rf , see Equation (3)) increases correspondingly to supplement the influence brought by the decrease of oxygen quantity, which leads to the increase of power consumption of the circulating fan. At the same time, the total amount of flue gas (V fg , see Figure 1) increases due to the increase of circulating flue gas flow (V rf , see Equation (3)). The increase of V fg leads to the decrease of flue gas temperature difference under the condition of the same heat transfer, which leads to the rise of flue gas temperature. However, due to the rising of the flue gas temperature, the heat loss of the flue gas was increased, resulting in the decrease of boiler efficiency and the increase of boiler coal consumption, but the range is not large. Due to the increase of V rf , although V fg increases, it will still lead to a decrease in flue gas flow (V y , see Figure 1). As V y decreases, the amount of flue gas entering the CPU unit decreases. According to Equation (9), Vy decreases and decreases, so the energy consumption of the flue gas compression unit decreases. Figure 5 shows that the energy consumption of the ASU increases with the increase of oxygen purity, and the increased range becomes larger when the purity is higher than 96%. The energy consumption of CPU decreases with the increase of oxygen purity, but the decrease is small. The power consumption of the circulating fan also increases correspondingly. The superposition of the above effects causes the total energy consumption of the system to decrease first and then increase with the increase of oxygen purity, which was the minimum when the oxygen purity was 96%. Figure 6 shows that with the increase of oxygen purity, the system's power supply and the net electrical efficiency first increased and then decreased, and reached the maximum when the oxygen purity was 96%. The net standard coal consumption rate and the energy penalty due to carbon capture in an OC power generation system (EP) decrease first and then increase, and were minimized when the purity was 96%. System standard coal consumption (t/h) Figure 5. Energy consumption of the air separation, the flue gas compression and purification , and the total system, coal consumption for various .   The net standard coal consumption rate (g/kWh) Figure 6. System power supply, the net electrical efficiency, the energy penalty due to carbon capture in an OC power generation system (EP), and the net standard coal consumption rate of the system for various . Figure 7 shows that the temperature of high-temperature flue gas entering the flue gas preheater decreased with the increase in oxygen concentration, and the temperature of primary flue gas requiring preheating was 351 °C. When the oxygen concentration reached 33.4%, the flue gas temperature was equal to that of the required preheating primary flue gas. Therefore, we selected the range of oxygen concentrations like 21% to 33%. It can be explained as follows: with the increase of oxygen concentration, the decrease of flue gas volume (V rf , see Equation (3)) leads to the increase of flue gas temperature difference when the heat transfer in the furnace is constant, so the flue gas temperature decreases.

Oxygen Concentrations ( )
2 0 % 2 1 % 2 2 % 2 3 % 2 4% 2 5% 2 6% 2 7% 2 8% 2 9% 3 0% 3 1% 3 2% 3 3% 3 4% Ente ring fl ue ga s pre hea te r high tem pe rature flue gas tempe ra ture(? ) P ri mary cyc le flue ga s tempe rature(? ) Figure 7. The relation between the temperature of flue gas in the primary cycle and the temperature of flue gas entering the gas-gas heat exchanger for various . Figure 8 shows that energy consumption of ASU, energy consumption of CPU, the total energy consumption of the system, and the system standard coal consumption all decrease with the increase of oxygen concentration.
It can be explained as follows: with the increase of oxygen concentration, the coal burnout rate increases, resulting in the reduction of oxygen required for combustion ( , see Figure 1), resulting in the reduction of energy consumption of the ASU; after the oxygen concentration rises, the amount of other gases into the air decreases, thus reducing the amount of circulating flue gas (V rf , see Equation (3)) and the power consumption of the circulating fan. At the same time, the flue gas volume of the system (V y , see Figure 1) is also reduced, thus reducing the energy consumption of the CPU. Above all, the total energy consumption of the system decreases, and the power supply of the system increases. However, due to the constant total heat release, the decrease of flue gas volume (V fg , see Figure 1) leads to the increase of flue gas temperature difference, so the flue gas temperature decreases. The flue gas volume (V fg1 , see Figure 1) and the flue gas temperature of the system was reduced, so the heat loss of the system flue is reduced, the thermal efficiency of the boiler is increased, and the coal consumption of the system is reduced.
2 0% 21 % 22% 23% 24% 25% 26% 2 7% 28% 29% 30% 31% 32% 3 3% 34 % System standard coal consumption (t/h) Figure 8. Energy consumption of air separation, compression and purification of flue gas, system total energy consumption, and the system standard coal consumption for various . Figure 9 shows that with the increase of oxygen concentration, the system power supply and the net electrical efficiency of the system increase, the net standard coal consumption rate and the energy penalty due to carbon capture in an OC power generation system (EP) reduce. It can be explained as follows: the external power supply of the system remains unchanged, while the power consumption of the plant decreases, so the external power output increases; At the same time, as the coal consumption decreases, the net standard coal consumption rate decreases, the net electrical efficiency increases, and the EP decreases.   The net standard coal consumption rate (g/kWh) Figure 9. System power supply, the net electrical efficiency, the energy penalty due to carbon capture in an OC power generation system (EP), and the net standard coal consumption rate of the system for various .

The recirculation Rate of Dry Flue Gas in Boiler Flue Gas ( )
is the recirculation rate of dry flue gas in the boiler flue gas. Figure 10 shows that with the increase in , the total amount of flue gas discharged decreased. However, as the CO2 content in the flue gas increased, the total CO2 in the flue gas increased. Therefore, if the capture rate remained unchanged, the amount of CO2 that must be collected and compressed increased.  The mass of captured CO 2 (kg/h) Figure 10. Trend chart of flue gas quality, CO2 content in flue gas, total CO2 mass in flue gas, and CO2 capture mass for various . Figure 11 shows that with the increase of , the energy consumption of the ASU, the energy consumption of the CPU and the total energy consumption of the system decrease, while the standard coal consumption of the system increases.
It can be explained as follows: with the increase of , the higher oxygen content of the primary flue gas after dehydration reduces the amount of oxygen supplied ( , see Figure 1). The energy consumption of the ASU was also reduced as the amount of oxygen supplied reduced. However, due to the increase in , the amount of secondary flue gas circulation ( w rf V , see Figure 1) decreases, and because the oxygen content of primary flue gas ( d rf V , see Figure 1) after dehydration is higher, when the oxygen concentration remains unchanged, the amount of secondary flue gas reduction will be higher than the amount of primary flue gas increment, so the total flue gas circulation rate will be reduced, and the power consumption of circulating fan will be correspondingly reduced. However, due to the increase of the primary flue gas circulation, the flue gas output (V fg2 , see Figure 1) of the system increases. With the increase of V fg2 , when the discharge heat of flue gas was unchanged, the temperature difference of flue gas decreased, so the flue gas temperature rises. As a result, the heat loss of flue gas increased, the boiler efficiency decreased, and the boiler coal consumption increased. At the same time, the energy consumption of gas compression and purification was reduced due to the increase of primary gas circulation and the decrease of (V fg4 , see Figure 1). The above effects added up to reduce the total energy consumption of the system. Figure 12 shows that with the increase in , the power supply of the OC power generation system and the net electrical efficiency showed an increasing trend, whereas the net coal consumption of the system and the energy penalty due to carbon capture in an OC power generation system (EP) showed a decreasing trend.
It can be explained as follows: with the increase of , the energy consumption of the ASU and the energy consumption of the CPU all reduced. The boiler coal consumption increased with the increase of , but the increased range was small. These effects added up to the above results. Energy consumption of air separation (MW) Figure 11. System standard coal consumption, the energy consumption of air separation, compression and purification of flue gas, and system total energy consumption for various ( ).

Excess Oxygen Coefficient ( 2
O α ) Figure 13 shows that with the increase of , energy consumption of the air separation system, gas compression system, total energy consumption, and standard coal consumption of the system increase.
It can be explained as follows: with the increase of excess oxygen coefficient, the amount of oxygen supplied ( , see Figure 1) increases, and when the single consumption of oxygen production remains unchanged, the energy consumption of the air separation system increases. Moreover, due to the increase of oxygen supply, the amount of flue gas (V fg , see Figure 1) increases, so the amount of circulating flue gas (V rf , see Equation (3)) and the amount of flue gas (V y , see Figure 1) also increase correspondingly. The increase of V rf leads to the increase of power consumption of the circulating fan, and the increase of V y leads to an increase of CPU energy consumption. When V fg increased, the temperature difference of flue gas decreased when the heat transfer of flue gas was constant, so the flue gas temperature increased. Above all, the total energy consumption of the system increased. At the same time, the increase of flue gas volume led to an increase in, heat loss and coal consumption. The net standard coal consumption rate (g/kWh) Figure 12. The net standard coal consumption rate, the net electrical efficiency, the energy penalty due to carbon capture in an OC power generation system (EP), and the power supply of the system for various .  Figure 14 shows that with the increase of the excess oxygen coefficient, the system power supply, and the net electrical efficiency decreased, and the net standard coal consumption rate and the energy penalty due to carbon capture in an OC power generation system (EP) increased. The power generation of the system remained unchanged, while the total energy consumption of the system increased, so the external output power decreased; at the same time, due to the increase of coal consumption, the net standard coal consumption rate increased, the net electrical efficiency decreased, and the net electrical efficiency drop increased.
Based on the above results, it can be seen that when the oxygen purity ( ) increased, the oxygen concentration ( ) decreased, the recirculation rate of dry flue gas in boiler flue gas ( ) decreased and the excess oxygen coefficient ( ) increased, the power supply standard coal consumption of the OC power generation system increased and the net power efficiency of the system decreased. When oxygen purity, oxygen concentration, the recirculation rate of dry flue gas in boiler flue gas, and excess oxygen coefficient were 96%, 33%, 55%, and 1.05, respectively, the net standard coal consumption rate of system was minimum, and the net electrical efficiency of the system was maximum. The net st andard coal consumption rate (g/kWh) Figure 14. The net standard coal consumption rate, system power supply, the net electrical efficiency, and the energy penalty due to carbon capture in an OC power generation system (EP) for

Orthogonal Analysis of the Influence of Operating Factors on Energy Consumption of the Oxyfuel Combustion System
The orthogonal analysis test method can consider the individual effect of each key parameter on system performance. It can also consider the influence of the interaction between factors on system performance.

Orthogonal Experimental Design
On the basis of the results of the single-factor study above, we selected four parameters as factors: oxygen purity ( ), oxygen concentration ( ), the recirculation rate of dry flue gas in boiler flue gas ( ), and the excess oxygen coefficient ( ). We then used five levels of each factor to design the orthogonal test. The L25 (5 6 ) orthogonal table was used, with four factors accounting for one column each. The remaining two columns were left blank for error analysis. See Table 4 for the specific experimental design.

Orthogonal Test Scheme and Experimental Results
The orthogonal test scheme and results are shown in Table 5.

Orthogonal Test Range Analysis
On the basis of the test designed by the orthogonal table, we calculated the index value of each test and judged the sensitivity of each factor to the index according to the test result: where Kij is the sum of the test results with the horizontal sign i on the column j , ij k is the factor in the j column and the mean value of orthogonal test results at horizontal i , and S is the number of occurrences of horizontal i on the j column.
The evaluation criterion for the factor sensitivity of the range analysis method is Rj. Rj is the difference between the ij k maximum and minimum values of the statistical parameters calculated at each level of the factor. The formula is as follows: The range reflects the relative influence of each factor on the test index. The influence degree of factors can be directly judged from R. The greater the range R, the greater the influence of the factor level on the net standard coal consumption rate of the OC power generation system. Tables 6 and 7, and Figure 15 show that in the orthogonal test analysis of the net standard coal consumption rate of OC power generation system, the factors with the largest and smallest range differences are D ( ) and C ( ), respectively. The influence of each operating factor on the net standard coal consumption rate and the net electrical efficiency of the OC power generation system is as follows: D ( ) > B ( ) ≈ A ( ) > C ( ).

Analysis of Variance by Orthogonal Test
According to the calculation results of orthogonal design, the specific calculation equations of variance analysis [21,31] are: where r is the level number of factors, N is the number of simulation calculations, Kij is the simulation result of factor j at the i level, i y is the ith simulation result, y is the average of n calculated results, ij K is the average value of calculated results at the i level of factor j, Sj is the sum of deviation squares of any case, fj is the degrees of freedom, and j S is the mean square sum.
The variance analysis of the orthogonal experiment separates the variance that belongs to the category of experimental error from the sum of square variances caused by experimental factors. We used the sum of the squares of deviation and error of each factor to construct the test statistics and conducted an F-test to judge whether the effect of each factor was significant or not. The analysis of variance (ANOVA) can make up for the shortcomings of range analysis, determine whether each factor is significant to the test index and the magnitude of significance, and evaluate the error [21,22,31]. According to the calculation results of orthogonal design, the specific calculation equation of variance analysis is as follows: The sum of the squares of deviations caused by the jth factor column is where t is the test number of the j factor at the i level. The sum of the squares of the deviations of all the empty columns in the interactive orthogonal table is called the sum of the squares of the random errors of the experiment, denoted as Se. The deviation means square and Vj of each factor, the random error mean square, and Ve is: where fj is the degree of freedom, fj = r−1, and fe is the sum of the degrees of freedom of each blank column. Therefore, the corresponding statistic j F of each factor is: The symbol"  " indicates that Fj is compared with ( ) , j e F f f . The significance level of the F-test was 0.10, 0.05, and 0.01 [22,31]. Tables 8 and 9 show that the excess oxygen coefficient has a particularly significant influence on the net standard coal consumption rate and the net electrical efficiency for the OC power generation system (confidence P = 99%). The oxygen concentration and oxygen purity have a significant influence (confidence P = 95%). The recirculation rate of dry flue gas in boiler flue gas does not have a significant influence (confidence P = 90%). It is generally believed that when F is greater than F0.01, the influence of factors is particularly significant, denoted as "★★★." When F0.01 ≥ F > F0.05, the influence of factors is significant, denoted as "★★." When F0.05 ≥ F > F0. 10, the factors have a certain influence, denoted as "★." When F0.10 > F, the influence of factors is not significant and is denoted as "☆." trend. With the increase of the excess oxygen coefficient, the combustion oxygen flow rate and the flue gas volume of the boiler increase, leading to an increase in energy consumption of ASU and CPU. The result is that with the increase of excess oxygen coefficient, the net standard coal consumption rate increases and the net electrical efficiency decreases. 2. When oxygen purity, oxygen concentration, recirculation rate of dry flue gas in boiler flue gas, and excess oxygen coefficient are 96%, 33%, 55%, and 1.05, respectively, the net standard coal consumption rate of system reaches the lowest, and the net electrical efficiency of the system reaches the highest. 3. The orders of the four factors' sensitivity to the two indices are also obtained. The influence of each operating factor on the net standard coal consumption rate and the net electrical efficiency of the OC unit was as follows: excess oxygen coefficient > oxygen concentration ≈ oxygen purity > recirculation rate of dry flue gas in boiler flue gas Among the operating factors, the excess oxygen coefficient had a particularly significant influence on the net electrical efficiency and the net standard coal consumption rate of the power supply for OC power generation system. The influence of oxygen concentration and oxygen purity was significant. The influences of the recirculation rate of dry flue gas in boiler flue gas were not significant.