Performance of a Solar Thermoelectric Power ‐ Harvesting Device Based on an All ‐ Glass Solar Heat Transfer Pipe and Gravity ‐ Assisted Heat Pipe with Recycling Air Cooling and Water Cooling Circuits

: For the purpose of collecting solar radiation for energy conversion and utilization and improving the output performance of thermoelectric power ‐ generation components, a new solar thermoelectric conversion device based on an all ‐ glass solar heat transfer pipe and gravity ‐ assisted heat pipe with recycling air cooling and water cooling circuits is designed. The uniqueness of the device lies in the combination of gravity ‐ assisted heat pipes with excellent thermal conductivity and a direct air ‐ cooled mode, a fin ‐ cooled mode, and two solar ‐ driven water ‐ cooling modes with different flow rates. Based on the structure, the device can realize four separate output modes and multiple composite output modes and has practical significance for meeting different load power requirements, such as wireless sensors and electronics. Under a state of regular illumination from 3.14 × 10 4 lx to 10.04 × 10 4 lx, with one thermoelectric power generator (TEG) in one mode, the peak output voltage and power values of the device in single ‐ output mode range from 183.1 mV to 370.7 mV and 33.5 mW to 137.2 mW, respectively, proving the feasibility of the proposed device. The energy supply of the above structure is completely obtained from the natural environment, and this aspect provides a high reference value for the cross ‐ research of natural environment energy utilization and thermoelectric energy ‐ conversion technology. 114.2 mW, 73.0 mW, and 33.5 mW, respectively. The results show that large ‐ channel water cooling exhibits a 20.14% increase in output power and a 9.62% increase in output voltage compared with small ‐ channel water cooling under the same flow of the water pump. Aluminium radiator cooling exhibits a 117.91% increase in output power and a 47.57% increase in output voltage compared with air cooling under the same air flow. These results provide evidence of specific output performance levels and a combination basis for multiple composite output modes to meet different load power requirements, such as wireless sensors, electronics, and other loads. All parameters are continuously measured in outdoor circumstances without man ‐ made power supported by urban electricity, and this aspect contributes to the development and utilization of green clean energy. The cost of the system is approximately $200, indicating the system’s cost ‐ effectiveness and high availability when it is applied in a stable process. Furthermore, the output energy of the system can be collected, stored, and then output or directly applied to a load to provide an energy supply through a boost and voltage stabilization circuit such as a DC1582 from Linear Technology. The energy supply of the above structure is completely obtained from the natural environment, and this aspect provides a high reference value for the cross ‐ research of natural environment energy utilization and thermoelectric energy ‐ conversion


Introduction
Thermoelectric technology has become a popular means of energy conversion in recent years because of the rapid development of thermoelectric materials [1,2]. Thermoelectric materials provide a reliable source of heat transfer between two or more electromagnets, and thermoelectric power generators are a research hotspot in thermodynamics. Benefitting from light weight, high reliability, low cost, lack of noise, and environmental friendliness, an increasing number of thermoelectric power generators have been investigated, analysed and widely used to solve power supply limitation issues.
Due to the low energy efficiency of thermoelectric materials, the output power of thermoelectric power devices is limited, which greatly hinders the promotion and utilization of thermoelectric technology. To obtain a higher output power, more researchers have begun to combine thermoelectric power with solar energy. As a result, solar thermoelectric power generation and photovoltaic and thermoelectric power generation (PV/TEG) systems have attracted the attention of researchers. Zhang Z et al. presented a thermoelectric power-generation system that absorbed solar power and supplied power for low-power loads [3]. Later, a solar thermoelectric power-generation system was developed by Zhang Z et al. and achieved a larger output with the application of heat transfer pipes [4]. Demir ME et al. designed a solar thermoelectric power-generation system that is beneficial for fresh water production [5]. Karthick K et al. achieved 24 h of continuous work by a solar thermoelectric power generator through an energy storage method [6]. Kumar A et al. studied the temperatures of various areas of a solar pond to improve the output of thermoelectric power generation [7]. Sathiyanathan M et al. discussed the output parameters of a solar thermoelectric power energy converter [8]. The excellent behaviour of a solar thermoelectric generator was demonstrated by Zhang XF et al. [9]. Zhu W et al. presented a thin-film solar thermoelectric generator that is suitable for sensor applications [10]. Furthermore, Kwan TH et al. demonstrated the advantages of a PV/TEG system over conventional thermoelectric power generation [11]. A hybrid PV/TEG system with a cavity designed by Marandi OF et al. achieved three times the amount of power generated by ordinary PV/TEG systems [12]. Singh S et al. evaluated a concentrated PV-TEG system to provide a reference for related studies [13]. Lekbir A et al. discussed the viability and advantages of a PV-TEG system when applied in energy-harvesting fields [14]. Zhu W et al. realized a better output with a PV-TEG system than with ordinary PV units through the optimization of thermal structures [15].
With the help of energy-conversion technology, thermoelectric material advancement and photovoltaic science, thermoelectric power generators have been widely applied in environmental energy-harvesting fields, especially in supplying power to various loads. However, several limitations remain to be solved. As a limitation of thermoelectric materials, the thermoelectric power conversion efficiency is far from satisfactory. Furthermore, the temperature difference between the hot side and cold side of thermoelectric power generators is still not large and stable, and this limitation deserves further study. On this point, studies of the heating or cooling methods of thermoelectric power generators have become significant. In fact, studies of the heating methods of thermoelectric power generators have become a focus of recent thermoelectric research, and various heating methods, such as the concentration of solar energy, choice of high-temperature streams and use of other fuels as heating sources, have been discussed. According to the Seebeck effect, the temperature of the cold side of a thermocouple is closely related to the cooling effect of the cold end. Therefore, studying the cooling effect of the cold end of a thermocouple is significant for the development of cooling research. Karimov KS et al. presented a two-stage solar thermoelectric power generator cooled by outdoor air with a glass lens [16]. Rodrigo PM et al. established a model of a PV-TEG system, choosing air cooling as its cooling method [17]. Maolikul S et al. studied the behaviour of the battery of a thermoelectric power generator whose cooling method was outdoor air cooling [18]. Chen WH et al. chose an indoor water-cooling method to demonstrate the benefits of improving the output performance of a thermoelectric power generation system [19]. Ding LC et al. compared the performance of an outdoor pump-powered water-cooled thermoelectric system with that of solar ponds [20]. Ma M et al. analysed the cooling parameters of a thermoelectric power generator equipped with an indoor water-cooling structure [21]. Date A et al. discussed the performance of a system including a solar heating structure and TEG, whose cooling method was indoor water cooling [22].
In this article, for the purpose of improving the output performance of a thermoelectric powergeneration process, a new solar thermoelectric conversion device based on an all-glass solar heat transfer pipe and gravity-assisted heat pipe with recycling air cooling and water cooling circuits is designed. The distinguishing feature of the device is the combination of gravity-assisted heat pipes with excellent thermal conductivity and a direct air-cooled mode, a fin-cooled cooling mode, and two solar-driven water-cooling modes with different flow rates. The output performance of four different cooling modes located on the cold sides of the thermocouples of the thermoelectric power-generation device is continuously tested and measured in natural outdoor circumstances. Two series of experiments are designed to test the output parameters of the system. The first series of experiments studied the performance of the output current, output voltage of the load resistance, output power and thermoelectric efficiency of the thermoelectric module with a large-channel water cooling radiator in the case of a gradual increase in load resistance when the temperatures of the hot and cold sides of the thermoelectric module vary within relatively stable small ranges. The second series of experiments concentrated on the continuous working status of thermoelectric modules with four different cooling modes, where the output parameters of the four different cooling modes are discussed and analysed to provide a reference for related continuous working cooling research. The results clearly show the cooling effects of four cooling structures located on the cold side of the thermocouples of the thermoelectric power-generation device. With different cooling media, including water, aluminium and air, the device provides data support for a single application or combinations of cooling modes in different cooling circumstances. Based on the structure mentioned above, the device is capable of matching the complex requirements of wireless sensors, electronic modules, and other similar loads. More importantly, the energy supply of the above structure is completely obtained from the natural environment, and this aspect provides a high reference value for the cross-research of natural environment energy utilization and thermoelectric energyconversion technology.

Materials and Methods
During the energy-collection process of the concentrated solar thermoelectric power-generation device, solar energy is absorbed and transferred to the conductive copper block through an all-glass solar heat transfer pipe and a gravity-assisted heat pipe. The energy that reaches the conductive copper block can be expressed as follows: where absorb Q is the entire amount of solar energy absorbed by the solar thermoelectric powergeneration device; are the average surface emissivity of the all-glass solar heat-transfer pipe, the Stefan-Boltzmann constant, the air temperature in the inner part of the all-glass solar heat transfer pipe device surface, and the temperature of the environment surrounding the outer part of the all-glass solar heat-transfer pipe device surface, respectively. The energy that reaches the conductive copper block can be conducted as the energy source of the hot sides of the four thermoelectric modules attached tightly to the surface of the conductive copper block, and these modules are equipped with four different cooling structures. Here, where bwh Q , swh Q , alh Q and airh Q are the energy that reaches the hot side of the thermoelectric module with a large-channel water cooling radiator, a small-channel water cooling radiator, an aluminium air cooling radiator and direct air cooling, respectively. The energy that reaches the hot side of the thermoelectric module is converted into electric power or transferred by the cooling structure. Then, where bwc Q , swc Q , alc Q , and ac Q are the energy acquired at the cold side of the thermoelectric module with a large-channel water cooling radiator, a small-channel water cooling radiator, an aluminium air cooling radiator and a direct air cooling structure, respectively; teg  and teg S are the Seebeck coefficient and the area of the thermoelectric power generator, respectively; u N is the are the temperature of the cold side, the temperature of the air flow, and the temperature difference between the hot and cold sides of the thermoelectric module with an aluminium air-cooling radiator and a direct air cooling structure, respectively.
The whole output power of the concentrated solar thermoelectric power generation system can be calculated as follows: which can be written as: where BW P , SW P , AL P , and AIR P are the output power of the thermoelectric module with a largechannel water-cooling radiator, a small-channel water cooling radiator, an aluminium air-cooling radiator and a direct air-cooling structure, respectively, and TE R is the electrical resistance of the thermoelectric module. As shown in Figure 1A,B, Figure 2A,B, the solar thermoelectric power generator in this paper includes thermoelectric cooling structures (containing three different cooling radiators and a direct air cooling structure), a solar heat transfer pipe, four thermoelectric power generators, a set of water pumps with transparent hoses, solar panels, a water tank, a set of gravity-assisted heat pipes, a thermally conductive copper block, and silica insulation material (placed inside the black surfaces shown in Figure 2B. The different cooling radiators are a large-channel water-cooling radiator with a channel diameter of 10 mm and external size of 40 × 40 × 12 mm, which is shown in Figure 2A and (b) and (e) in Figure 2B; a small-channel water-cooling radiator with a channel diameter of 2 mm and external size of 40 × 40 × 2.5 mm, which is shown in Figure 2A and (c) and (f) in Figure 2B; and an aluminium air-cooling radiator, which is shown in Figure 2A and (d) in Figure 2B and has an external size of 40 × 40 × 15 mm. These three cooling radiators are tightly placed close to the cold side of the thermoelectric power generator (shown in Figure 2A,B, and this placement contributes to the improvement in the cooling effects of the solar thermoelectric power generator. Both the large-and small-channel water-cooling radiators are connected to water pumps placed in the water tank by different types of transparent hoses, which are shown in (e) and (f) in Figure 2B. The water pumps in the water tank are driven by solar panels, which harvest energy from the outside sunshine as a power source and then provide an output power of 3 W. When the solar panels are exposed to sunlight, the energy begins to be collected and stored, and this energy is then transferred to the water pumps to operate the pumps. When the water pumps operate in stable conditions, the cooling water starts its journey from the water tank shown in Figure 1A to the channels of the large-and small-channel water-cooling radiators. As a result, the cooling water in the channels removes heat from the cold side of the thermoelectric power generator, and this process further improves the output characteristics of the solar thermoelectric power generator.
The length, outer diameter and inside diameter of the solar heat transfer pipe are 1800 mm, 58 mm and 48 mm, respectively, and the internal space of this pipe is embedded in a gravity-assisted heat pipe. The top of the gravity-assisted heat pipe is inserted into a thermally conductive copper block, whose four outside surfaces fit closely with the hot sides of the four thermoelectric modules. Each thermoelectric module is a commercial GM-200-127-14-16 from European Thermodynamics.
The output parameters are effectively measured using a series of K-type thermocouples (Thermometers TT-K-30  When sunlight irradiates the solar heat transfer pipe, its interior and exterior surface temperatures rise rapidly, and the heat is collected and transferred to the gravity-assisted heat pipe. The gravity-assisted heat pipe transfers heat to the thermally conductive copper block, which then transfers heat to the hot sides of the thermoelectric modules, making the hot-side temperatures rise sharply. The heat from the hot end is transferred to the cold end through a thermoelectric power generator. As the heat accumulates at the cold side, the temperature of the radiator rises. With the normal work of the efficient cooling structure, the temperatures of the cold sides of the thermoelectric modules are far lower than the temperature of the radiator, resulting in heat convection due to the large temperature differences. Cooling water flows rapidly in the channels of the large-and smallchannel water cooling radiators, sharply reducing their temperatures. Additionally, air blows on the aluminium radiator, rapidly decreasing the temperature of the radiator as well as that of the cold end. To better show the cooling effects of the cooling modes, a thermoelectric module tightly placed at the outside surface of the thermally conductive copper block is exposed directly to air without other cooling structures, representing a matched group and the simplest cooling mode. Selectively, an external energy conversion module, such as a DC1582 from Linear Technology, can be chosen to improve the voltage when the thermoelectric voltage reaches the start voltage of the electrical energy collection module, and this module provides a convenient means for collecting and supplying power for low-power loads such as wireless sensors in environmental conditions.

Results
The experiments on the concentrated solar thermoelectric power generation system mainly include two parts, which are output parameter tests for the thermoelectric module with a largechannel water cooling radiator under various load resistances shown in Figure 3 to Figure 7 and continuous output tests for the thermoelectric modules with four different cooling modes shown in Figure 8 to Figure 11 under a state of regular illumination from 3.14 × 10 4 lx to 10.04 × 10 4 lx, with one TEG module in one mode. The first experiment studies the change trends of the output current, output voltage of the load resistance, output power and thermoelectric efficiency of the thermoelectric module with a large-channel water cooling radiator in the case of a gradual increase in load resistance when the temperatures of the hot and cold sides of the thermoelectric module vary within relatively stable small ranges. The second experiment concentrates on the continuous working status of the thermoelectric modules with the four cooling modes, where the output parameters of the four cooling modes are discussed and analysed to provide a reference for a single application or combinations of cooling modes in different cooling circumstances to match the complex requirements of wireless sensors, electronic modules, and other similar loads. As shown in Figure 3, when the load resistance changes from 1 ohm to 110 ohm, the temperatures of the cold sides of the thermoelectric modules (shown in Figure 3 as cd T ) vary from 291.2 K to 299.2 K, the temperatures of the hot sides of the thermoelectric modules (shown in Figure   3 as hot T ) vary from 325.2 K to 329.2 K, and the average temperatures between the hot and cold sides of the thermoelectric modules (shown in Figure 3 as avg T ) vary from 308.2 K to 314.2 K. Considering that the electrical resistance of a thermoelectric module is 4 ohm, the temperature data are centrally tested when the load resistance changes from 1 ohm to 10 ohm. As the load resistance increases, the energy collected by the concentrated solar thermoelectric power-generation system accumulates, making the heat exchange between the thermoelectric module and the outside environment gradually become stable. When the load resistance is larger than 60 ohm, the temperature changes on the hot and cold sides of the thermoelectric module are no longer obvious, indicating that heat exchange stability has been reached.
.   , the output voltage and the output current of the thermoelectric module with a large-channel water cooling radiator under various load resistances. Here, Rall means the whole resistance of the device, comprising the load resistance and inner resistance of the thermoelectric power generator. With an increase in the load resistance, the values of / load all TR R  sharply increase, leading to a substantial growth in the output voltage. The reason for this increase is that the ratio of the load resistance to the total resistance gradually increases when the load resistance changes from 1 ohm to 110 ohm, but the electrical resistance of the thermoelectric module remains at 4 ohm. Moreover, it is clear that as the load resistance increasingly approaches the total resistance of the system, the growth rate of / load all TR R  gradually decreases, resulting in a decreasing growth rate of the output voltage. According to Ohmʹs law, it is clear that the change trend of the output current is inversely proportional to that of the total resistance, and this effect is obviously observed in Figure 5. The maximum output voltage is 1213.2 mV when the load resistance is 110 ohm, which suggests that the impact of the ratio of the load resistance on the output voltage is significant. ohm, which is equal to the value of the electrical resistance of the thermoelectric module. The reason for this is that the largest output power occurs when the load resistance is the same as the inner resistance of the system, which is the electrical resistance of the thermoelectric module in this experiment. This result provides an efficient solution to obtain the largest output power when the concentrated solar thermoelectric power-generation system is used to power various loads. However, this solution is hard to realize because of the minor load resistances of low-power loads that are no more than one ohm. As a result, the values of The continuous working test experiment of the thermoelectric modules with the four cooling modes was carried out in outdoor conditions in Beijing. The value of the load resistance was chosen to be one ohm to test the output performance of the concentrated solar thermoelectric powergeneration system under low-power load conditions. The output parameters were acquired and are shown in Figure 8 to Figure 11, which present the continuous change trends of the temperatures of the cold sides of the thermoelectric modules (shown in Figure 8 as bwc T , swc T , alc T , and ac T , which are the temperatures of the cold sides of the thermoelectric modules in large-channel water-cooling mode, small-channel water cooling mode, aluminium radiator cooling mode and air cooling mode, respectively), the temperature differences between the hot and cold sides of the thermoelectric modules, the output voltage and the output power. The peak values of the temperature difference between the hot and cold sides of the thermoelectric modules, the output voltage and the output power are 43.6 K, 370.4 mV and 137.2 mW, respectively, which were obtained when the experiment had been carried out for three hours and 40 minutes.

Discussion
The output power shown in Figure 6 is closely related to the output current of the thermoelectric module with a large-channel water-cooling radiator under various load resistances, as shown in Figure 5. As shown in Equations (7), (11) and (17), the output current of the thermoelectric module with a large-channel water-cooling radiator has a significant impact on the energy reaching the hot side of the thermoelectric module with a large-channel water-cooling radiator, the energy acquired at the cold side of the thermoelectric module with a large-channel water-cooling radiator and the output power of the thermoelectric module with a large-channel water-cooling radiator. On the one hand, as the output current of the thermoelectric module with a large-channel water-cooling radiator increases, the values of αtegIbwTbwh and αtegIbwTbwc increase, which contributes to increases in the energy reaching the hot and cold sides of the thermoelectric module with a large-channel water-cooling radiator and the output power. On the other hand, as the aforementioned output current increases, the value of −0.5RteIbw 2 increases, which reduces the amount of energy reaching the hot and cold sides of the thermoelectric module with a large-channel water-cooling radiator and the output power. The change trend of the output power shown in Figure 6 is the result of the combined effect of the above two change trends. When the output current of the thermoelectric module with a large-channel water-cooling radiator shown in Figure 5 is less than 150 mA, the output power shown in Figure 6 continues to increase. During this time, the changes in αtegIbwTbwh and αtegIbwTbwc have a significant effect on the final output power. The decrease in the output power shown in Figure 6 starts when the output current shown in Figure 5 is greater than 150 mA, as the change in −0.5RteIbw 2 has a more important effect on the final output power.
The thermoelectric efficiency of the thermoelectric module ηTE shown in Figure 7 changes from 0.40% to 0.65% when the load resistance varies from 0 to 180 ohm. According to thermoelectric conversion theory and calculations of thermoelectric efficiency in previous literature [3,4], the thermoelectric efficiency is closely related to the temperatures of the hot and cold sides of the thermoelectric module (shown in Figure 3   As shown in Figures 10 and 11, the exact values of BW V , SW V , AL V , and AIR V and those of BW P , SW P , AL P , and AIR P are obtained, respectively. As a whole, it is obvious that the values of the first four parameters ordered from large to small are BW V , SW V , AL V , and AIR V , which means that the cooling performance of the four parameters ranging from strong to weak follows the order BW V , SW V , AL V , and AIR V . The reason for this result is similar to the reason discussed for the exact temperature data. As shown in Figure 10, the largest values of BW V , SW V , AL V , and AIR V are 370.4, 337.9, 270.2 and 183.1 mV, respectively. These values are acquired when the load resistance of the solar thermoelectric power generation system is 1 ohm, which is close to the exact value of low-power loads such as wireless sensors. As the inner resistance of the thermoelectric power generator is 4 ohm, it is easy to increase the value of the output voltage when a larger load resistance is chosen.
As shown in Figure 11, the largest values of BW P , SW P , AL P , and AIR P are 137.2, 114.2, 73.0 and 33.5 mW, respectively. Under the same constant pumping power condition, the cooling output power performance of the large-channel water cooling is better than that of the small-channel water cooling because of its larger channel diameter, which results in a larger heat exchange area and improves the heat exchange efficiency between the cold side of the thermoelectric module and the cooling structures. However, as the pump power is constant, the volume of water sprayed by the pump is a fixed value, which means that the larger the heat exchange area, the slower the fluid shifting speed will be. At this point, choosing an appropriate heat exchange area and fluid shifting speed is critical for achieving satisfactory cooling performance. Taking the values of the output voltage and output power as a reference, large-channel water cooling exhibits better performance than small-channel water cooling in the cooling process of the solar thermoelectric power generator, showing a 20.14% increase in output power and a 9.62% increase in output voltage. For the cooling output power performance of aluminium radiator cooling and air cooling, the heat exchange mode is natural convection heat transfer of air for both, and the key parameter of cooling is the heat exchange area. It is clear that aluminium radiator cooling has a larger heat exchange area than air cooling and, as a result, when the sizes of the air flow rates between the cold side of the thermoelectric module and the cooling structures are similar, the larger the heat exchange area, the better the cooling performance that will be achieved. Taking the values of the output voltage and output power as a reference, aluminium radiator cooling exhibits better performance than air cooling in the cooling process of the solar thermoelectric power generator, showing a 117.91% increase in output power and a 47.57% increase in output voltage, and these results are clearly and intuitively reflected in Figures 10 and 11.

Conclusions
In this work, a new solar thermoelectric conversion device based on an all-glass solar heat transfer pipe and gravity-assisted heat pipe with recycling air cooling and water cooling circuits is designed. With different cooling modes, such as large-channel water cooling, small-channel water cooling, aluminium radiator cooling and air cooling, the device can realize four separate output modes and multiple composite output modes. This device has practical significance for meeting different load power requirements, such as wireless sensors, electronics, and other loads. When the system is installed with only a large-channel water cooling radiator, the maximum output voltage is 1213.2 mV when the load resistance is 110 ohm, and the peak value of the thermoelectric efficiency of the thermoelectric module Under a state of regular illumination from 3.14 × 10 4 lx to 10.04 × 10 4 lx, with one GM-200-127-14-16 TEG module from European Thermodynamics in one mode and 1 ohm load resistance, the peak output voltage and power values of the device with large-channel water cooling, small-channel water cooling, aluminium radiator-cooling and air-cooling modes are 370.7 mV, 337.9 mV, 270.2 mV, and 183.1 mV and 137.2 mW, 114.2 mW, 73.0 mW, and 33.5 mW, respectively. The results show that largechannel water cooling exhibits a 20.14% increase in output power and a 9.62% increase in output voltage compared with small-channel water cooling under the same flow of the water pump. Aluminium radiator cooling exhibits a 117.91% increase in output power and a 47.57% increase in output voltage compared with air cooling under the same air flow. These results provide evidence of specific output performance levels and a combination basis for multiple composite output modes to meet different load power requirements, such as wireless sensors, electronics, and other loads. All parameters are continuously measured in outdoor circumstances without man-made power supported by urban electricity, and this aspect contributes to the development and utilization of green clean energy. The cost of the system is approximately $200, indicating the system's costeffectiveness and high availability when it is applied in a stable process. Furthermore, the output energy of the system can be collected, stored, and then output or directly applied to a load to provide an energy supply through a boost and voltage stabilization circuit such as a DC1582 from Linear Technology. The energy supply of the above structure is completely obtained from the natural environment, and this aspect provides a high reference value for the cross-research of natural environment energy utilization and thermoelectric energy-conversion technology.
Author Contributions: All authors contributed to the paper. W.L., provided guidance, supervision, and revised the paper; Z.Z., designed the research, conceived the idea of the study, and wrote the paper; Z.Z. and Y.W., performed the experiment and discussed experimental results; Z.Z. and D.X., discussed the experimental results and revised the paper. All authors read and approved the final manuscript.

Conflicts of Interest:
The authors declare no conflict of interest.