Decarbonization of the Iron and Steel Industry with Direct Reduction of Iron Ore with Green Hydrogen

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Introduction
Anthropogenic climate change is one of society's greatest challenges.Decarbonization of all sectors of the energy system is essential to mitigate climate change.Although the industrial sector consumes one-third of the primary energy resources and releases one-quarter of the energy-related greenhouse gas emissions, it has not received as much attention from researchers and policy-makers as other demand sectors like electricity generation, buildings and transport etc.The non-homogeneity of industrial plants and the use of fossil fuels as feedstock makes it difficult to find effective strategies to decarbonize industries.Iron and steel, chemicals, cement, non-ferrous metals, paper, and pulp etc. are referred to as energy-intensive industries (EII) because they use energy resources as primary raw material.Energy efficiency has played a major role in reducing the industrial sector's energy intensity and emissions.Nonetheless, incremental changes in current industrial production technologies would not reach the emission reduction goals needed to avoid catastrophic effects of anthropogenic climate change [1,2].
Steel is the backbone of modern civilization.It is used in buildings, transport, packaging, shipping and infrastructure etc.Approximately 1.73 billion tons of crude steel was produced in 2017 [3].The apparent steel use per capita (finished steel products) was 216.3 kg in 2017.Industrialized countries like Germany have a high apparent steel use per capita of approximately 500 kg.India, a developing country, on the other hand, has a per capita steel consumption of 66.3 kg.As the standard of living in developing countries increases, demand for steel will grow further.The demand for steel will increase until 2050 [4].Steel could be produced by reducing iron ore or by recycling steel scrap in an electric arc furnace (EAF).Iron and steel sector releases seven percent of the total CO 2 emission and 16% of the total industrial emission of CO 2 globally [5,6].Limited availability of scrap and demand for special grades of steel, which can not be produced from steel recycling, would lead to an increased demand for ore based steel production in the future.More than 80% [3] of the ore based steel is produced through the BF-BOF route.The BF-BOF route uses approximately 18 GJ/t of energy supplied from coal [7], and has an emission intensity of approximately 1870 kgCO 2 /tls [4,8] (considering pellet making, steel rolling and finishing steps).Majority of the emissions is released from the blast furnace (61%) and coke making plant (27%) [9].Some of the alternative processes with significantly reduced carbon footprint are BF-BOF with carbon capture and storage (CCS), direct reduction of iron ore (DRI) with CCS, electrowining (electrolysis of iron ore) [10] and green hydrogen-based DRI production.Integration of CCS in steelmaking processes is being explored under the ultra-Low carbon dioxide(CO 2 ) steelmaking (ULCOS) [11,12] project.However, concerns over the safe transport and storage of captured makes CCS options less attractive.Electrowining or molten electrolysis of iron ore is a relatively new technology and is quite far from reaching commercial feasibility.Hydrogen direct reduction of iron ore (HDRI)-EAF based steel production is the most viable alternative to BF-BOF based steel production, as the production of hydrogen with intermittent renewable energy generators has an additional benefit of providing flexibility to the electricity grid [7].Hydrogen, as an energy carrier, has applications in other sectors of the energy system, like chemical production, heavy transport, aviation, shipping etc.Large scale production, storage and transport of hydrogen to cater to the demands of the steel industry will reduce the price of hydrogen for other industries like chemical production, transportation, buildings and district heating etc. [13][14][15].The use of green hydrogen in the iron and steel sector, has the potential to reduce emissions by 2.3 gigatonnes of carbon dioxide per year (GtCO 2 /y) [16] globally.
The first HDRI based steel production unit was commissioned in the year 1999 in Trinidad.Production was based on fluidized bed reactors [17].The plant produced steel with 95% metallization rate, at a production capacity of 65 tonnes of liquid steel per hour (tls/hr) [18].Energiron, which is a commercial supplier of natural gas-based DRI shaft furnaces, tested direct reduction of iron ore with more than 90% hydrogen in its test facility at Hysla, Monterrey [19].The pilot plant had a capacity of 36 tls/day of hot and cold DRI production.A high metallization rate of 94-96% was achieved.The company claims that their shaft furnace reactors could be easily optimized to use 100% hydrogen for the reduction of iron ore.It is supplying shaft furnace reactors to many European demonstration projects for hydrogen-based steel production.The higher cost of hydrogen compared to fossil fuel resources is a roadblock for further development of the technology.There is a renewed interest in the hydrogen economy among researchers, policy-makers and industries, on the back of declining prices of renewable electricity generators and demand for more flexibility in the electricity grid to integrate intermittent renewable energy generators [16].Techno-economic modeling of hydrogen and ammonia production using water electrolysis was carried out by [20].They found that the cost of green hydrogen could reduce to 2 USD/Kg, which is comparable to hydrogen produced from fossil fuel sources.Researchers at the Technical University of Munich and Stanford University found that the cost of hydrogen produced from renewable electricity has decreased to e3.23 kg −1 and will further decrease to e2.50 kg −1 in Germany and Texas [21] within the next decade.The cost of producing hydrogen from renewable electricity could fall 30% by 2030 as a result of declining costs of renewable energy and the scaling up of hydrogen production [22].In the HYBRIT project [23], hydrogen-based steel production would be demonstrated by Luossavaara-Kiirunavaara Aktiebolag (LKAB), Svenskt Stål AB (SSAB), Vattenfall along with Swedish energy agency.Voestalpine is testing a six-megawatt proton exchange membrane electrolyzer (PEM) developed by Siemens for hydrogen production [24].Under the Salcos [25] project along with GrInHy2 [26] and Windh2 [27], the feasibility of integrating 30 MW of wind electricity generators with solid oxide electrolyzers for hydrogen production at a steel production facility in Germany is being explored.Tata steel Europe, Nouryon and the port of Amsterdam have partnered to develop the largest green hydrogen cluster in Europe [28].Arcelormittal is building a demonstration HDRI unit, with a production capacity of 100,000 t/year [29].The plant will use grey hydrogen produced from natural gas until green hydrogen becomes cost-competitive.Midrex technologies will supply the shaft furnace reactor for the plant [30].Thyssenkrupp has begun testing of hydrogen-based steel production at its production facility in Duisburg, Germany.Coke has been replaced with hydrogen in one of the nine blast furnaces.If the results from the pilot study are favorable, hydrogen could replace coke in all blast furnaces [31].
There have been many discussions about the use of 100% hydrogen as reducing agent DRI based steel production [7,9,[32][33][34][35] in the scientific literature.However, energy consumption and emissions values reported in the literature vary significantly.There is a lack of clarity about system configuration and boundaries.In this work, system boundary has been clearly defined, making it easier to compare the energy and emission intensity of BF-BOF and HDRI-EAF based steelmaking process.More details about the process parameters are included in this model than other comparable models available in the literature.The model codes are written in an open-source software and are available to the scrutiny of other researchers [36].Theoretical concepts and the chemical reactions, along with discussions on the reaction kinetics are presented in Section 2. The HDRI-EAF model, along with mass and energy flows through the different components are discussed in Section 3. Modelling results are presented in the Section 4, followed by the conclusions in Section 5 and discussions on future work in Section 6.

Concept
Direct reduction of iron ore refers to the conversion of solid iron ore to metallic iron without conversion to the liquid phase [37].Majority of the direct reduced iron (DRI) [38] is produced by reacting iron oxide with hydrocarbon-based reducing gases produced from reforming natural gas or coal gasification [39][40][41][42].DRI technology has been deployed commercially and five percent of the total global steel is produced through the DRI route [43].Lower capital investment, space requirements, and simpler design and operation make it easier to build and operate a DRI plant [33].With the declining price of shale gas, there has been an upsurge in the installation of DRI plants in the US [44].Shaft furnaces, rotary kilns, rotary hearth furnaces and fluidized bed reactors are used for direct reduction of iron ore.Most of the DRI plants use shaft furnace reactors developed by MIDREX [43] and HYL-Energiron [45] technologies.Shaft furnaces are moving bed counter-current reactors.Rotary hearth furnaces are used, when coal is used as the source for production of reducing gases [33].Kinetic studies have revealed that the reduction of hematite occurs in stages, it is first converted to magnetite and at temperatures above 570 °C, wustite is formed [46].At temperatures below 570 °C, magnetite is converted to iron directly [35] as wustite is not stable below 570 °C.Reduction reactions occurring inside the shaft furnace, with syngas as the reducing gas are depicted in Equations ( 1) and (2).Exothermic reduction of Hematite by CO [42,47]: Endothermic reduction of Hematite by H 2 : Natural gas is converted to a mixture of CO and H 2 using steam methane reforming (SMR).The reaction is endothermic and has a reaction enthalpy of 206 kJmol −1 [48], as shown in Equation (3).
Countries with large reserves of natural gas such as Saudi Arabia, Qatar, USA(shale gas) and Iran have deployed the technology for steel production [43].The DRI produced from the shaft furnace can either be fed to an EAF as hot DRI or cooled and briquetted for transport.Addition of DRI in the EAF reduces the dependence on scrap and improves the quality of the steel produced [49][50][51].

Hydrogen Direct Reduction of Iron Ore
In the HDRI-EAF system, hydrogen is used as the reducing gas in a moving bed shaft furnace.The DRI is fed to an EAF for steel production.The reduction reactions are depicted in Equations ( 4)-( 6) [52].The reduction reaction is endothermic and energy in the form of heat needs to be supplied to carry the reaction forward [37].The reaction propagation and the different processes involved in the reaction are depicted in Figure 1. ) ) As depicted in Figure 1, the chemical reaction occurs by adsorption of hydrogen gas on the iron oxide interface.At high temperatures, the rate of chemical reaction is higher than the transport rate or mass transfer rate of reactants and products.This observation is in accordance with the Arrhenius equation [37].In a solid-gas reaction at high temperatures, diffusion of reactants and products is often the rate-limiting step.The porosity of the pellets is an important factor, as higher porosity of the raw material leads to higher permeability and diffusivity of the reactants and products.The size and geometry of the pellets and temperature of the inlet gas have a strong influence on the reaction rate.The reaction rate varies inversely with the size of the pellets [53].The reaction rate is faster with hematite ore than magnetite ore as the porosity of intermediate reaction products formed by hematite is higher [54].Addition of biomass in the iron ore pellets could increase the porosity of the pellets and reduce the apparent activation energy required for the reduction reaction [55].Water vapor formed during the reduction of iron oxide has a lower adsorption and desorption rate than hydrogen.At lower temperatures, this could affect the rate of reaction.Experimental studies have shown that the rate of iron ore reduction reaction is higher with pure hydrogen than with traditionally used syngas (mixture of CO and H 2 ) [56] between 700-900 °C.Higher reduction rates could lead to a more compact design of the shaft furnace for the same DRI output, which could reduce capital costs and lower the heat losses from the shaft furnace, owing to a smaller surface area available for heat transfer.The addition of small amounts of CO in the reducing gas mixture can slow down the reduction reaction significantly, as CO reduces the diffusivity of the reducing gases [57].By conducting experiments on hematite reduction with hydrogen at different temperatures, it was found that at temperatures higher than 900 °C, the reaction rate decreases because of sintering and formation of a dense outer layer on the iron ore pellets [46].The values for apparent activation energy for the reduction reaction varies from 11 kJ mol −1 to 246 kJ mol −1 .The large variation in the values of apparent activation energies is due to its dependence on multiple factors.Thermo-physical properties of the input material, reducing gas composition, reduction temperature, particle size and the experimental set-up are some of the variables listed by [37].There is a need for a more thorough investigation to evaluate the apparent activation energy required for iron ore reduction reaction with pure hydrogen.
Mass transfer of hydrogen from the gaseous stream through the laminar layer of the iron oxide to the interface Diffusion of hydrogen from the surface to the oxide interface Adsorption of reactant gas (hydrogen) at the oxide interface Removal of Oxygen with formation of water and iron ions.
Desorption of products formed from the reductio -n reaction.
Solid-state diffusion of solid reaction products, nucleation and growth of nuclei.

Diffusion of gaseous reaction products back to the laminar layer.
Mass transfer of the gaseous products through the laminar layer back to gas stream.
(a) (  [37].The location of the process steps is represented from numbers 1 to 5 (1b), which are also depicted in the shrinking core model (1a).

Methodology
The objective of this analysis is to improve the understanding of the impact of different process parameters on the energy and emission intensity of the steel production system.A new system configuration was modeled and analyzed in this work.The system configuration is shown in Figure 2. Other configurations with different technologies for hydrogen production, pellet pre-heating, adsorption of hydrogen from the waste gas stream etc. are also possible and should be explored.Energy consumption and emissions related to iron ore mining, pellet making and downstream steel finishing steps have not been considered in this model.Modeling assumptions are presented in Appendix A. The model has been developed using Python, which is open-source software.The codes were written in the Jupyter notebook [58] environment.NumPy [47] and Pandas [59] libraries have been used for calculations and data visualization.The graphs and bar charts have been plotted using matplotlib [60] library.All these libraries could be used with the standard anaconda [61] distribution.Python codes for the model in the form of a Jupyter notebook are available for download [36].In the following section, mass and energy flows through the different components of HDRI-EAF system will be described.

Pellet Heating
It has been assumed that an electrical heating unit is used to heat iron ore pellets to 800 °C.Mass and energy flow through the electrical heating unit is depicted in Figure 3.The amount of iron ore required for producing one ton of steel was calculated using Equation (7).Equations ( 8) and ( 9) describe the mass and energy flow through the pellet electrical heating system.

Pellet electrical Heater Electricity
Mass balance Energy balance

Direct Reduction Shaft Furnace
The DRI shaft furnace is a counter-current solid-gas reactor, where pre-heated iron ore pellets at 800 °C are fed from the top to react with hydrogen stream entering from the bottom of the reactor.The reduction reaction is endothermic with a reaction enthalpy of 99.5 kJmol −1 .Iron ore particles need to be completely submerged in hydrogen for the optimal reaction rate.The ratio of actual flow rate of hydrogen to the stoichiometric flow rate of hydrogen required for the reduction reaction is represented by lambda λ [34].The stoichiometric flow rate of hydrogen per ton of liquid steel is calculated by Equation (10).Actual mass flow of hydrogen in the reactor is the product of λ and stoichiometric quantity of hydrogen required to reduce 1 ton of hematite ore, as depicted in Equation (11).The mass and energy flow through the reactor are shown in Figure 4.
Fe molecular weight (10) Metalization rate (α), is defined as the percentage of metallic iron (Fe) leaving the shaft furnace in the iron stream.DRI contains metallic iron along with FeO (wustite), which needs to be reduced inside the EAF.Metalization rate of 94% has been assumed for the base case.The amount of Fe, and FeO (Wustite) in the stream exiting the shaft furnace is calculated by using Equations ( 12) and ( 13).The mass balance of the shaft furnace is represented by Equation ( 16).
It is assumed that the waste gas stream is a mixture of unreacted hydrogen and water/steam produced from the reduction reaction as shown in Equation (15).The amount of water produced depends on the metallization rate.For ease of calculations, it is assumed that metallization is complete.The amount of unused hydrogen in the waste stream depends on the amount of hydrogen entering the shaft furnace.A thorough understanding of the kinetics of the reaction and design of the shaft furnace is required to calculate the exact composition and temperature of the waste gas stream.Typically, the exhaust gases in a DRI shaft furnace exit the furnace at a temperature of 275 °C to 400 °C [42].An exhaust gas temperature of 250 °C has been considered in the model to account for the endothermic reaction between hydrogen and iron ore.
More energy is required for 100% hydrogen-based DRI production compared to reduction with syngas, as hydrogen reduction of iron ore is an endothermic reaction, whereas, reduction of iron ore with CO is an exothermic reaction.Energy in the form of heat is lost to the environment due to heat transfer from the shaft furnace walls.The energy flows through the reactor represented by Equation (17).Mass balance Energy balance

Electric Arc Furnace
It is assumed that DRI with a metallic content of 94% enters the EAF at a temperature of 700 °C.The EAF is operated with 100% hot DRI.EAF temperature is assumed to be 1650 °C to ensure complete melting of metallic iron.The efficiency of the electric arc furnace, β el , is assumed to be 0.6 to account for losses in the transformer, rectifier, electrodes and other sub-systems [51].Carbon is added in the EAF for CO production.Oxygen, produced in the water electrolyzer could be added in the EAF for the production of CO to reduce the FeO in the EAF.It is assumed that 70% of the FeO entering the EAF is reduced and the rest is removed as slag.The dissolution of carbon in molten metal is an endothermic reaction and 3.59 KWh/kg of energy is used in the process.Exhaust gas stream from the EAF is assumed to be a mixture of CO and CO 2 .Additional elements are added in the molten iron to improve its thermo-physical properties.They have not been considered in this analysis.Mass and energy flow through the EAF are shown in Figure 5.The mass and energy flow through the EAF are shown in Equations ( 18) and (19).
Mass balance Energy balance

Electrolyzer
Alkaline or PEM electrolyzers could be used in the system configuration presented in the model for hydrogen production.An alkaline electrolyzer has been considered in the present model owing to the lower capital cost of alkaline electrolysers [62] and their use in HYBRIT project [63] for a pilot project on hydrogen-based direct reduction of iron ore in Sweden.Technical specifications of the electrolyzer have been taken from 20 MW electric alkaline electrolyzer module produced by Thyssenkrupp industries [64].Excess hydrogen produced during off-peak hours could be fed into the pressurized hydrogen storage tank.Dynamic operation of the electrolyzer has not been considered in the model.Electricity from the grid or from a dedicated renewable energy generation system could be utilized in the electrolyzer [65].Mass and energy flow through the electrolyzer is presented in Figure 6.

Mass balance
Energy balance Energy consumption of the electrolyzer (EL s pec) is assumed to be 45 KWh/kgH 2 .In practice, efficiency of the electrolyzer varies with current density and hydrogen output.For a more detailed analysis of the operations and energy balance of the electrolsyer, readers could refer to [65][66][67].

Waste Gas Separation Unit
Unreacted hydrogen is separated from the waste gas stream using a pressure swing adsorber [68,69].Mass and energy flows through the pressure swing adsorber are shown in Figure 7. Pressure swing adsorbers have been used for industrial production of hydrogen in ammonia plants [70,71].The temperature of the incoming waste gas stream was assumed to be 250 °C.Water separated from the waste stream is fed back to the electrolyzer.The energy required to run the pressure swing adsorber has not been considered in this model.It has been assumed that the water and hydrogen stream are free of impurities.

Electric Heater for Hydrogen Stream
Electrical heater, with an efficiency of 0.6 has been considered for heating the hydrogen gas stream entering the shaft furnace to a temperature of 500 °C.Hydrogen gas stream entering the electrical heater is a mixture of hydrogen coming from the electrolyser at 90 °C and hydrogen separated in the pressure swing adsorbers at 250 °C.The mass and energy flow of the electrical heating unit is shown in Figure 8.

Results and Discussions
The modeling results are presented in this section.It has been assumed that the ore contains five percent impurities and the metallization rate of 0.94 is achieved in the DRI shaft furnace in the base case [34].Modeling results have been compared with the energy consumption and emission values reported in the literature for the HDRI-EAF system.

Mass and Energy Flow
Mass and energy flow through the different components of the HDRI-EAF system are presented in Table 1.Hydrogen entering the shaft furnace was considered to be 1.5 times the stoichiometric value (λ = 1.5).Exhaust stream from the EAF, M 8 , comprising of CO 2 and CO was not calculated as the composition and temperature are dependent on the operation of the EAF.Carbon, M 10 , was added to the system at a fixed rate of 10 kg/tls.It was assumed that 50 kg/tls of Lime and MgO, M 11 , is added to the EAF.Oxygen, M 9 , was added in the EAF for production of CO.Hydrogen flow from the storage, M 15 and M 16 , was not considered in the model.

Electricity Consumption
Variation of electricity consumption with a change in the mass flow of hydrogen is shown in Figure 9.Total energy consumption varied from 3.4 to 5.91 MWh/tls, as λ is varied from one to five.Specific energy consumption (SEC) of the HDRI-EAF system at 3.72 MWh/tls (λ = 1.5) system was higher than the BF-BOF based steel production, which has an SEC of 3.48 MWh.All the energy in the HDRI-EAF system was consumed in the form of electricity.Electricity is required for pellet heating, hydrogen production, heating the hydrogen stream entering the shaft furnace and melting of iron in the electric arc furnace.Switching from BF-BOF to HDRI-EAF based steel production would lead to an additional electricity demand of 375 TWh in the EU.It was observed that increasing the mass flow of hydrogen in the DRI shaft furnace, increases energy consumption in the electrolyzer and in the electric heater for hydrogen heating.
Approximately, 436 KWh/tls of electricity was used for heating the iron ore pellets to the reaction temperature of 800 °C.Waste gases exiting the DRI shaft furnace could be used for pre-heating the iron ore pellets.Endothermic reduction reaction of iron oxide with hydrogen requires 334 KWh of energy.Pre-heating the hydrogen stream entering the shaft furnace requires 160 KWh of electricity.
The electrolyzer consumed 2680 KWh of electricity, which was approximately 70% of the total energy consumed in the HDRI-EAF system.The performance of electrolyzer and mass flow of hydrogen has a significant impact on the overall energy consumption of the system.As stated in Section 2, the type of raw material, temperature of the reduction reaction and design of the reactor have an impact on the mass flow of hydrogen for optimal reaction rate.In order to reduce the energy consumption, design of the reactor and the operating conditions could be optimized for a lowering the λ value.EAF consumes 445 KWh/tls of electrical energy.EAF energy consumption increases at lower metallization rates.If the amount of impurities in the iron ore pellet increased, a similar trend in energy consumption of the EAF could be observed.The value of EAF energy consumption decreases at higher DRI temperatures.

Waste Gas Enthalpy
The enthalpy of waste gas exiting the shaft furnace varies with temperature and flow rate of incoming hydrogen stream, as shown in Figure 10.Although majority of the outgoing energy could be captured by mixing the incoming hydrogen stream with the waste gas hydrogen stream, an optimal design of the shaft furnace and operating conditions would ensure lower losses through the waste stream.

Emissions from the HDRI-EAF System
Emissions are directly related to the amount of electricity used in the HDRI-EAF system.A small amount of emission is also produced in the EAF, as a result of the reduction of wustite with carbon and from the oxidation of carbon to CO and to CO 2 subsequently.These emissions were not considered.The emission intensity of the system varies with the grid emission factor of the countries, as shown in Figure 11.Emission intensity of BF-BOF process is 1688 kgCO 2 /tls in the EU [72], which is much higher than the HDRI-EAF's emission intensity of 1101 kgCO 2 /tls (at EU's grid emission factor of 295 kgC 2 /MWh).Modeling results show that the emissions from the production of steel in the HDRI-EAF system would be lower in most EU countries at present grid emission levels, except Poland.The grid emission factor of Poland is 773 gCO 2 /KWh, which is more than twice the EU average of 295 gCO 2 /KWh.The emission intensity of HDRI-EAF based steel production could be reduced to 415 kgCO 2 /tls in countries with low grid emission factors like Sweden.If electricity is provided from renewable energy sources then it would result in a reduction of 170.26 MtCO 2 annually.The use of HDRI-EAF based steel production could increase the emissions from steel production in countries with a grid emission factor higher than 456 gCO 2 /KWh.

Comparison with Literature Values
Specific energy consumption (SEC) and emission for production of 1 ton of liquid steel have been compared with the results available in the literature, shown in Figure 12.The grid emission factor of the German electricity grid has been considered for emission calculations, which is 440.9 gCO 2 /KWh.Emission values were not reported by Vogl et al. [34] and Fischedick et al. [7], emissions associated with the use of electricity from the German electric grid have been considered for comparison.The mass flow rate of hydrogen was not specified by Otto et al. [32] and Fischedick et al. [7], the λ value of 1.5 was assumed as specified by Vogl et al. [34].SEC of 3.72 MWh, corresponding to λ value of 1.5 has been considered for the comparison.The difference in the SEC and emission intensity could stem from the different system configurations considered.Otto et al. [32] have considered the Circored process, which uses a fluidized bed reactor instead of a shaft furnace.The use of natural gas for pellet heating and other process steps increases the energy and emission intensity in the circored process.Electric energy has been considered for pre-heating the pellets and incoming hydrogen stream, instead of a waste heat utilization unit as described by Vogl et al. [34].It has been assumed that 80% of the hydrogen gas available in the waste stream will be adsorbed, and the remaining 20% will be generated in the electrolyzer.

Energy Consumption and Emissions in EU Countries
The impact of transitioning to HDRI-EAF based primary steel production on energy demand and emissions in different EU countries has been evaluated in this section.Steel production data has been taken from the integrated database of the European energy sector(IDEES) [72].The reference year for the steel production data is 2015.Additional energy consumption and emissions arising from pellet making, sintering, and steel finishing processes have also been considered in this analysis.The results are presented in Figure 13.The energy requirement for steel production could increase from 493 TWh to 517 TWh for EU-28 by switching to HDRI-EAF based steel production.At the same time, emissions from steel production could be reduced from 193 million tonnes of CO 2 /year to approximately 134 million tonnes of CO 2 /year.Considering the price of carbon to be 30 e/ton of CO 2 in the EU, it is estimated that HDRI-EAF based steel production could lead to a saving of 18 e/ton of steel, at present grid emission levels in the EU.The savings could be much higher in the future with increasing CO 2 prices and a reduction in the grid emission factor.

Sensitivity Analysis
Local sensitivity analysis [73] was carried out by varying the input parameters by ±5 %, ±10 %, ±15 %, ±20 % one-at-a-time and keeping other parameters fixed.The parameters considered for the sensitivity analysis are hydrogen mass flow rate (λ), electrolyzer efficiency, hydrogen input temperature(T3), EAF input temperature (T4), adsorber efficiency and the grid emission factor.The results of the sensitivity analysis are presented in Figure 14.Sensitivity analysis revealed that electrolyzer output affects the electricity consumption of the EAF-DRI system.Electrolyzer output is an indicator of the electrolyzer efficiency in terms of the amount of electricity required for the production of one kg of hydrogen (KWh/kgH 2 ).Another important parameter affecting the electricity consumption is λ, which is a ratio of the actual hydrogen required for production of one ton of liquid steel to the stoichiometric requirement of hydrogen.The value of λ is related to the design of the shaft furnace reactor and operating conditions.Electricity requirement of the system decreases as the adsorption efficiency increases in the pressure swing adsorption system.Emissions from the system are strongly correlated with the grid emission factor.Electrolyzer output, lambda and the adsorption factor are important factors, which decide the overall emissions from the system, as they are directly related to the electricity consumption of the HDRI-EAF system.Hydrogen input temperature (T3) and the EAF input temperature (T4) do not have a major impact on the energy requirement and emissions from the HDRI-EAF system.

Conclusions
HDRI-EAF based steel production is a viable alternative to BF-BOF based steel production, but adoption of the technology would depend on the future cost of electrolyzers and electricity.Sensitivity analysis revealed that electrolyzer efficiency is the most important factor affecting the system energy consumption, while the grid emission factor is strongly correlated with the overall system emissions.Recent improvements in the performance of electrolyzers could reduce the energy consumption and emissions from the HDRI-EAF based steel production.The iron and steel industry could play a major role in the transition to the hydrogen economy by creating a demand for large quantities of hydrogen, which could lead to the development of infrastructure for generation, storage, and safe transport of hydrogen.The use of hydrogen in steel making coupled with hydrogen storage could provide flexibility to the electricity grid to integrate intermittent renewable energy sources and open new opportunities for revenue generation for steel companies by participating in the power reserve markets.Other strategies for flexible operation of the HDRI-EAF system could be explored by storing the DRI and operating the EAF according to electricity prices.Dynamic modeling of the HDRI-EAF system could quantify the potential of the steel industry to participate in the demand response market.

Future Work
In the future works, the techno-economical performance of DRI-EAF based system coupled with different hydrogen production technologies will be compared under different scenarios.The price of electricity and carbon costs would be varied to see their impact on the cost of steel production.The impact of using grid electricity on the costs and performance of the system would be compared with using dedicated renewable energy generators.Different hydrogen production technologies with varying system configurations like solid oxide electrolysis, methane pyrolysis and steam methane reforming with CCS would be considered for the production of hydrogen.Large scale generation and storage of hydrogen for steel production could have a substantial impact on other sectors of the energy system like energy generation, transport, buildings etc.The integration of HDRI-EAF based steel production in an energy system model could highlight these interactions, which could assist policy-makers to make more informed decisions.Appendix A Some of the important assumptions made for the model are listed below: 1.
All calculations are done for the production of 1 ton of liquid steel from the system.2.
Energy consumption and emissions related to iron ore mining, pellet making, and downstream steel finishing steps were not considered in this analysis.

3.
5% impurities are present in the raw materials.The assumption is consistent with the plant data available in the literature.The primary components of the impurities are silica and alumina.4.
The iron ore pellets are heated from ambient temperature to 800 °C, through an electrical heater of efficiency, η thermal = 0.85. 5.
Output from the shaft furnace would be metallic Fe and FeO.The remaining FeO will be reduced to pure iron in the electric arc furnace.Although, in practice, some amount of FeO does not get reduced and becomes a part of the EAF slag.6.
The flow rate of hydrogen is considered to be higher than the stoichiometric requirements.7.
Apparent activation energy of 35 kJ/mole has been considered in this model.8.
Hydrogen produced from electrolyzers is heated in an electrical heater with an efficiency of η thermal = 0.6.9.
DRI stream exiting the shaft furnace is considered to be at a temperature of 800 °C.10.
The exhaust gas stream is assumed to be composed of hydrogen and water.The waste stream enthalpy varies with exhaust gas temperature and λ h2 .11.
Energy required to separate hydrogen and water from the waste stream is not considered in the present calculations.12.
100% DRI is fed into the furnace without any scrap.The quality of scrap has a significant effect on energy consumption in a DRI. 13.
Hot DRI is fed into the DRI at 700 °C as it saves a considerable amount of electrical energy in the EAF.14.
Natural gas is not used for heating the material as its the general practice to use natural gas with scrap for initial heating.15.
As DRI is reduced only with Hydrogen, it is assumed that it does not contain any ferric carbide.Carbon required for reduction of remaining FeO in the EAF is supplied externally as coal or coke.16.
Temperature of the DRI being fed into the EAF is not taken into account into empirical energy models [74].Thermodynamic modeling of the EAF has been done to get the specific energy consumption of the EAF with 100% DRI. 17.
Iron ore pellets generally contain elements such as silicon, manganese, chromium, aluminium, sulphur, phosphorus, molybdenum etc.They get oxidized inside the electric arc furnace, releasing heat and assist in the melting of the iron ore.As iron ore pellets containing only alumina and silica have been considered in this model, additional energy supplied from the oxidation of these elements has not been considered, but a provision for their inclusion in future work has been made in the code.18.
Carbon is added into the EAF to reduce the remaining FeO in the mix and also to generate CO for froth formation, which is essential for the operation of the EAF and to extend the life of the graphite electrodes and the refractory.19.
CaO and MgO are added in the EAF as slag formers to maintain the basicity of the EAF.The weights of CaO and MgO used are according to data published in the literature [51].20.
Efficiency parameters used in the EAF model for electrical and chemical energy are according to the reference [51].

FeOFe 3 O 4 Fe 5 Figure 1 .
Figure 1.(a) Shrinking core model depicting the evolution of iron ore reduction reaction with hydrogen [56].(b) Process steps in the reduction of iron ore pellets with hydrogen[37].The location of the process steps is represented from numbers 1 to 5 (1b), which are also depicted in the shrinking core model (1a).

Figure 2 .
Figure 2. Schematic of the Hydrogen direct reduction shaft furnace coupled with an electric arc furnace.An electrolyzer is considered for hydrogen production.

M 2 ,T 2 M 1 ,T 1 Figure 3 .
Figure 3. Mass and energy flows through the pellet heating unit.

Figure 4 .
Figure 4. Mass and energy flow through the DRI shaft furnace.

8 Figure 5 .
Figure 5. Mass and energy flow through the electric arc furnace.

Figure 6 .
Figure 6.Mass and energy flow through the electrolyzer.

Figure 7 .
Figure 7. Mass and energy flow through the waste gas separation unit.

2 Figure 8 .
Figure 8. Mass and energy balance through the electrical heating unit for hydrogen stream.

Figure 9 .
Figure 9. Variation of electricity demand (in KWh) in DRI-EAF system with varying mass flow rate of hydrogen in the DRI shaft furnace.

Figure 10 .
Figure 10.Waste gas enthalpy variation with temperature and mass flow rate of input hydrogen.

Figure 12 .
Figure 12.(a) Comparison of energy demand for hydrogen direct reduction of iron ore with literature values.(b) Comparison of CO 2 emission from hydrogen direct reduction of iron ore with literature values.

Figure 13 .
Figure 13.(a) Comparison of present energy demand from primary steel production in EU countries and projected energy demand for conversion to hydrogen direct reduction of iron ore (HDRI)-EAF based steel production.(b) Comparison of present emissions from primary steel production in EU countries and projected emissions for complete conversion to HDRI-EAF based steel production.

Figure 14 .
Figure 14.(a) Sensitivity analysis to identify the parameters affecting the electricity requirements of the HDRI-EAF system.(b) Sensitivity analysis to identify the most important parameters affecting the CO 2 emission from the HDRI-EAF system.

Table 1 .
Mass and energy flow through the DRI-EAF system.N.A refers to not available or not calculated.
Mass of iron ore at heater inlet for production of 1 ton of liquid steel in kg/tlsM 2Mass of iron ore at heater outlet for production of 1 ton of liquid steel in kg/tlsFe 2 O 3 purePercentage of pure iron ore in the iron ore stream (assumed to be 0.95) Mass of hydrogen produced in the electrolyzer and supplied to the DRI shaft furnace in kgh 13H 2Enthalpy of hydrogen produced in the electrolyzer and supplied to the DRI shaft furnace in kgM 15H 2Mass of hydrogen produced in the electrolyzer and supplied to the hydrogen storage in kg