The Exploitation of Low-Temperature Hot Water Boiler Sources with High-Temperature Heat Pump Integration

: The article presents an original and innovative technical solution for the exploitation of low-temperature excess heat from hot water boilers that use gas or liquid fuel for the needs of high-temperature heating in buildings or in industry. The primary fuel e ﬃ ciency used for hot water boilers can be signiﬁcantly increased by utilizing the excess low-temperature heat of ﬂue gases that are discharged into the environment and thus also reduce CO 2 emissions. Hot water systems usually operate at higher temperatures of the heating water, which is transported to the heat consumer via supply pipe, and the cooled heating water is returned to the hot water boiler via the return pipe. For the excess low-temperature heat exploitation of the ﬂue gases from hot water boiler, it is necessary to install a condenser in the ﬂue gas discharge pipe, where condensation of water vapour present in the ﬂue gas heats water or a mixture of water and glycol. The heating water, which is cooled and returned from the heat consumer via the return pipe, is led to the condenser of the high-temperature heat pump, where it is preheated and then led to the hot water boiler, where it is heated to the ﬁnal temperature. A computer simulation with the Aspen plus software package for the series or parallel connection of high-temperature heat pump to a hot water heating system and the economic analysis of the excess heat exploitation from the ﬂue gases are also performed.


Introduction
In the last few decades, much effort has been invested in the European Union (EU) and the rest of the world into achieving cleaner air and consequently, reducing greenhouse gas (GHG) emissions. The use of fossil fuels has brought great pressure on the environment itself, therefore scientists all around the world are investigating new environmentally friendly technologies that would be suitable for high penetration of renewable energies in the energy system [1], because renewable energies have shown huge potential in the reduction of GHG emissions. Several strategies, agreements, protocols, and directives on environmental issues, such as the Paris Agreement [2], European Green Deal [3], or European Energy Efficiency Directive [4] have been signed to navigate all European and other world countries when switching the fossil-fuel-based systems to renewable energy sources, such as solar, wind, bioenergy, or geothermal energy [5].
Moreover, increasing the efficiency of new or existing heat-generation plants is one of the priorities in line with the EU's commitments to reduce GHG emissions and achieve several environmental goals [6]. There are several heat pumps suitable for waste heat exploitation.

Low-Temperature Water Exploitation with High-Temperature Heat Pump Integration
The proposed system of exploiting low-temperature heat sources of hot water boilers with high-temperature heat pumps [16] responds to the needs of the economy. It is an innovative and economically profitable process that stands out for technical excellence. A high-temperature heat pump [17] is used to upgrade low-temperature heat from hot water boiler systems. The excess heat is a source to the higher temperature heat pump, and the produced heat can be used by a heat consumer for space or process heating, preferably in the scope of district heating. According to the study, it is important that the high-temperature heat pumps are used to heat up and raise the temperature of a heat transfer medium in a return line of a heat distribution network.
For example, exploiting low-temperature sources of hot water boiler with one or more single-stage high-temperature heat pumps would be carried out on the hot water boiler, which will be installed in Energies 2020, 13, 6311 3 of 12 the boiler room of the district heating system. The exploiting the low-temperature heat sources of the hot water boiler makes it possible to increase the production of heat up to 17%, without the additional consumption of natural gas.
The principle of exploiting low-temperature sources of the hot water boiler plant with the high-temperature heat pump [18] is shown in Figure 1, where a hot water boiler with an incorporated high-temperature heat pump in a heat distribution network is schematically presented.
Energies 2020, 13, x FOR PEER REVIEW 3 of 13 sources of the hot water boiler makes it possible to increase the production of heat up to 17%, without the additional consumption of natural gas. The principle of exploiting low-temperature sources of the hot water boiler plant with the hightemperature heat pump [18] is shown in Figure 1, where a hot water boiler with an incorporated high-temperature heat pump in a heat distribution network is schematically presented. Figure 1. Schematic presentation of a hot water boiler with incorporated high temperature heat pump in a heat distribution network [18]. Figure 1 shows a schematic representation of a hot water plant preferential embodiment with incorporated water source high-temperature heat pump (HP) having a condenser unit, an evaporator unit, and a compressor with adopted lubrication oil cooling system (CS) for high-temperature heat pump principle utilization, where the following items are further shown and marked: hot water Figure 1. Schematic presentation of a hot water boiler with incorporated high temperature heat pump in a heat distribution network [18]. Figure 1 shows a schematic representation of a hot water plant preferential embodiment with incorporated water source high-temperature heat pump (HP) having a condenser unit, an evaporator unit, and a compressor with adopted lubrication oil cooling system (CS) for high-temperature heat pump principle utilization, where the following items are further shown and marked: hot water boiler (HWB) heat distribution circuit and exhaust system comprising a network of pipes (P1-P13), Energies 2020, 13, 6311 4 of 12 valve (V2) and pumps (PU1-PU4) which interconnects the heat consumer (HC) with stated heat sources, heat exchanger (HE), hatch (H1), fan (F1) and ambient (O).
Referring to the preferential embodiment of the power plant with incorporated water source high-temperature heat pump, the system comprises a furnace with incorporated boiler in the scope of the first heat releasing unit of the hot water boiler, which preferably runs on a gas fuel, such as natural gas, liquefied petroleum gas, fuel oil, landfill gas, wood gas, biogas or coal, for example. While the hot water boiler first heat releasing unit is used for heat generation when powered, a significant amount of heat is released by the flue gas, wherein the heat is either used by a heat consumer rather than discharged and dissipated to the ambient through the exhaust pipe (P12) (i.e., chimney). It is important to notice that the first heat source for a heat consumer is preferably represented by the boiler in the scope of the hot water boiler, having an inlet and outlet aperture, whereby a plurality of excess heat sources arise in the scope of the hot water boiler and incorporated high-temperature heat pump, at least when the hot water boiler and high-temperature heat pump are turned on and powered, preferably at optimal efficiency or full load regime.
According to the preferential embodiment depicted, as represented in Figure 1, the hot water boiler inflow (i.e., inlet port) and outflow (i.e., outlet port) apertures are operable coupled to the closed-loop heating circuit comprising a network of pipes (P1-P11) that operable interconnects the heat consumer and heat sources in the scope of the hot water boiler with incorporated water source high-temperature heat pump. The heat distribution network further comprises a primary heat transfer medium and automated regulation means comprising a control unit (i.e., control electronics), valve (V2), and pumps (PU1-PU4) for primary heat transfer medium streamflow regulation, wherein the heat of heat sources is preferably transferred to the heat consumer by the principle of primary heat transfer medium circulation in the closed-loop heating circuit.
Excess low-temperature heat from the hot water boiler system is not used and is released into the environment through 140 • C hot flue gas heat. In order to utilise the exhaust gas heat with a temperature of 140 • C, a heat exchanger must be installed in the exhaust gas system of the hot water boiler system, in which the exhaust gases are cooled down to a temperature of 25 • C by cooling and condensation of the flue gases.

Low-Temperature Heat Source
The low-temperature heat source of the HTHP is the hot water boiler flue gases, and operating data are given in Table 1  Referring to the preferential embodiment of the power plant with incorporated water source high-temperature heat pump, the system comprises a furnace with incorporated boiler in the scope of the first heat releasing unit of the hot water boiler, which preferably runs on a gas fuel, such as natural gas, liquefied petroleum gas, fuel oil, landfill gas, wood gas, biogas or coal, for example. While the hot water boiler first heat releasing unit is used for heat generation when powered, a significant amount of heat is released by the flue gas, wherein the heat is either used by a heat consumer rather than discharged and dissipated to the ambient through the exhaust pipe (P12) (i.e., chimney). It is important to notice that the first heat source for a heat consumer is preferably represented by the boiler in the scope of the hot water boiler, having an inlet and outlet aperture, whereby a plurality of excess heat sources arise in the scope of the hot water boiler and incorporated high-temperature heat pump, at least when the hot water boiler and high-temperature heat pump are turned on and powered, preferably at optimal efficiency or full load regime.
According to the preferential embodiment depicted, as represented in Figure 1, the hot water boiler inflow (i.e., inlet port) and outflow (i.e., outlet port) apertures are operable coupled to the closed-loop heating circuit comprising a network of pipes (P1-P11) that operable interconnects the heat consumer and heat sources in the scope of the hot water boiler with incorporated water source high-temperature heat pump. The heat distribution network further comprises a primary heat transfer medium and automated regulation means comprising a control unit (i.e., control electronics), valve (V2), and pumps (PU1-PU4) for primary heat transfer medium streamflow regulation, wherein the heat of heat sources is preferably transferred to the heat consumer by the principle of primary heat transfer medium circulation in the closed-loop heating circuit.
Excess low-temperature heat from the hot water boiler system is not used and is released into the environment through 140 °C hot flue gas heat. In order to utilise the exhaust gas heat with a temperature of 140 °C, a heat exchanger must be installed in the exhaust gas system of the hot water boiler system, in which the exhaust gases are cooled down to a temperature of 25 °C by cooling and condensation of the flue gases.

Low-Temperature Heat Source
The low-temperature heat source of the HTHP is the hot water boiler flue gases, and operating data are given in Table 1    To be able to use the low-temperature heat of the flue gas with a temperature of 140 °C, it is necessary to install the condenser heat exchanger in the flue gas system of hot water boilers where the flue gasses are to be cooled to a temperature of 25 °C.

High-Temperature Heat Pump
High-temperature heat pumps are devices that make a remarkable contribution to reducing energy consumption, as their use is possible in all industries where low-temperature fluid heat fluxes are generated. They provide an economically and environmentally efficient way of harnessing lowtemperature sources to improve specific energy use in processes, increase efficiency and, reduce CO2 emissions due to lower fossil fuel consumption for heat production.
Commercially available high-temperature heat pumps with rated outputs of 500 kW, 1.4 MW, 4.5 MW, and 9.8 MW [19] and can be used for the excess heat recovery with high-temperature heat pumps of small or more parallel installed large hot water boiler of total power 50 MW or more. The coolant of high-temperature heat pumps is ammonia (R717). The operational data of a 500 kW hightemperature heat pump are given in Table 2.

Process Simulation with AspenPlus
To utilize the heat excess of the hot water boiler, a computer simulation of four series-connected high-temperature heat pumps with a nominal power of 500 kW was performed using the Aspen Plus software package [15]. The operating data of a 500 kW high-temperature heat pump at a compressor rotation speed of 1450 min −1 are given in [15]. Heat production using the aforementioned hightemperature heat pump can be controlled by a frequency-controlled electric motor drive where a maximum permissible speed of a reciprocating compressor is 1600 min −1 .
Schematics of four high-temperature heat pumps with some computer simulation results are presented in Figure 4. In the system, all high-temperature heat pumps are connected in series and they consist of four compressors (COMP1, COMP2, COMP3, COMP4), four refrigerant evaporators (EVAP1, EVAP2, EVAP3, EVAP4), four condensers (COND1, COND2, COND3, COND3), and four expansion valves (VALVE1, VALVE2, VALVE3, VALVE4). It must be mentioned that the lowtemperature heat source of those high-temperature heat pumps is water or a mixture of water and glycol, which is heated in the condenser (HE) shown in Figure 1 when using the heat excess of the flue gas of the hot water boiler.
Water or a mixture of water and glycol, which is firstly heated to approximately 50 °C during the utilization of heat excess from the flue gases of a hot water boiler, is passed successively through all four drains (EVAP1, EVAP2, EVAP3, EVAP4) via pipeline P7 shown in Figures 1 and 4. Later it is cooled down to about 25 °C and returned to the condenser (HE) via pipeline P6. In each of the four  To be able to use the low-temperature heat of the flue gas with a temperature of 140 • C, it is necessary to install the condenser heat exchanger in the flue gas system of hot water boilers where the flue gasses are to be cooled to a temperature of 25 • C.

High-Temperature Heat Pump
High-temperature heat pumps are devices that make a remarkable contribution to reducing energy consumption, as their use is possible in all industries where low-temperature fluid heat fluxes are generated. They provide an economically and environmentally efficient way of harnessing low-temperature sources to improve specific energy use in processes, increase efficiency and, reduce CO 2 emissions due to lower fossil fuel consumption for heat production. Commercially available high-temperature heat pumps with rated outputs of 500 kW, 1.4 MW, 4.5 MW, and 9.8 MW [19] and can be used for the excess heat recovery with high-temperature heat pumps of small or more parallel installed large hot water boiler of total power 50 MW or more. The coolant of high-temperature heat pumps is ammonia (R717). The operational data of a 500 kW high-temperature heat pump are given in Table 2.

Process Simulation with AspenPlus
To utilize the heat excess of the hot water boiler, a computer simulation of four series-connected high-temperature heat pumps with a nominal power of 500 kW was performed using the Aspen Plus software package [15]. The operating data of a 500 kW high-temperature heat pump at a compressor rotation speed of 1450 min −1 are given in [15]. Heat production using the aforementioned high-temperature heat pump can be controlled by a frequency-controlled electric motor drive where a maximum permissible speed of a reciprocating compressor is 1600 min −1 .
Schematics of four high-temperature heat pumps with some computer simulation results are presented in Figure 4. In the system, all high-temperature heat pumps are connected in series and they consist of four compressors (COMP1, COMP2, COMP3, COMP4), four refrigerant evaporators (EVAP1, EVAP2, EVAP3, EVAP4), four condensers (COND1, COND2, COND3, COND3), and four expansion valves (VALVE1, VALVE2, VALVE3, VALVE4). It must be mentioned that the low-temperature heat source of those high-temperature heat pumps is water or a mixture of water and glycol, which is heated in the condenser (HE) shown in Figure 1 when using the heat excess of the flue gas of the hot water boiler.
Water or a mixture of water and glycol, which is firstly heated to approximately 50 • C during the utilization of heat excess from the flue gases of a hot water boiler, is passed successively through all four drains (EVAP1, EVAP2, EVAP3, EVAP4) via pipeline P7 shown in Figures 1 and 4. Later it is cooled down to about 25 • C and returned to the condenser (HE) via pipeline P6. In each of the four evaporators of high-temperature heat pumps, the evaporation pressure of the coolant (ammonia) is different because it depends on the availability of heat flows obtained by cooling the water in each evaporator. Vapours of refrigerants leaving the evaporators are compressed by compressors (COMP1, COMP2, COMP3, COMP4) to the pressure required to condense the refrigerants in a series-connected condensers (COND1, COND2, COND3, COND4) when heating the heating water. The heating water, as a return of the hot water system, is fed to the first condenser through the pipeline P3 as shown in Figures 1 and 4, and is consequently fed sequentially to each individual condenser of the high-temperature heat pumps. In each condenser, the heating water is heated slightly until the desired temperature is reached in the last condenser. The water of the heating system is then fed to pipeline P4 to a hot water boiler, in which it is heated to the final temperature of the hot water system.
To compare the operating characteristics, a computer simulation of the utilization of heat excess of a hot water boiler with four-series connection high-temperature heat pumps is also made. For a simpler presentation, only one heat pump is used in the computer simulation, and the compressor has the same operating characteristics as four high-temperature heat pump compressors connected in series. The scheme of one high-temperature heat pump shown in Figure 5 consists of a single compressor (COMP), a refrigerant evaporator (EVAP), a condenser (COND), and an expansion valve (VALVE). The low-temperature heat source of a high-temperature heat pump is again water or a mixture of water and glycol, which is heated in the condenser (HE) shown in Figure 1. Water or a mixture of water and glycol is heated to approximately 50 • C and passed to the high-temperature heat pump (EVAP) via pipeline P7 shown in Figures 1 and 4. When the source is cooled down to 25 • C, it is returned to the condenser (HE) via pipeline P6.
The refrigerant vapours leaving the evaporator (EVAP) are compressed by a compressor (COMP) to the pressure required to condense the refrigerant in the condenser (COND) when heating the return water of the hot water heating system. The return water of the hot water heating system is supplied to the condenser via pipeline P3 shown in Figures 1 and 4. In the condenser, the return water of the hot water heating system is heated to the desired temperature and then returned to the hot water boiler via pipeline P4, where it is heated to the final temperature.
Effective recovery of excess heat is critical to provide good total utilization of fuel energy, thus, the first and the most important excess heat source is represented by the stream of low temperature flue gas in the exhaust system, which is a product of the combustion process within the hot water boiler. Secondly, there is at least one additional excess heat source represented by high-temperature heat pump compressor lubrication oil cooling systems (CS), which under certain circumstances are still important for good total excess heat source utilization.
Electricity for compressors in high-temperature heat pumps is needed, which can be supplied from the grid, or generated by on a CHP unit if it is located near a boiler room [20][21][22].     Comparison of natural gas efficiencies and the production of a hot water boiler and hot water boiler by utilizing the excess heat with high-temperature heat pumps that use electric power from the grid fora drive of compressors are given in Table 1. Comparison of natural gas efficiencies and the production of a hot water boiler and hot water boiler by utilizing the excess heat with high-temperature heat pumps that use electric power from the grid fora drive of compressors are given in Table 1.
With the cascading installation of four single-stage high-temperature heat pump with a rated output heat of 500 kW th , can be increased by 1730 kW th , that is, from 7435 kW th to 9165 kW th and the total primary energy consumption of natural gas by 17.6%, that is from 90.6% (7435 kW th ) to 108.2% (8860 kW th ).

Results and Discussion
The low-temperature heat source of high-temperature heat pumps are the flue gases of the hot water boiler, which are cooled in the HP condenser shown in Figure 1. The results of the computer simulation of flue gas cooling are given in the form of diagrams in Figures 2 and 3.
It can be seen from the diagrams in Figures 2 and 3 that the flue gases of the hot water boiler are first cooled from a temperature of 140 • C to a temperature of 48 • C, obtaining approximately 500 kW of heat. However, the further cooling of the flue gases causes condensation of water vapor, which is present in the flue gases. Most of the heat, about 920 kW, is obtained by cooling the flue gases from 48 • C to 25 • C, producing about 0.315 kg/s of condensate. By further cooling the hot water flue gas to about 5 • C, an additional 800 kW of heat could be obtained, thereby further increasing the primary fuel efficiency of the hot water boiler to about 117% relative to the LHV (low heating value) of the natural gas. The temperature to which the flue gases would be cooled depends on the economics of operation of the cascade-connected high-temperature heat pumps, as this would significantly reduce the average COP of the heat pumps.
In case you want to use an additional 800 kW of heat, you would have to add three more high-temperature heat pumps to the existing four high-temperature heat pumps in Figure 2. By lowering the evaporation temperature of the refrigerant in the evaporator of the high-temperature heat pump, the pressure ratio of the compressor increases, and therefore more power is required for the electric motor drive of the compressor, which results in a lower COP.
To better present an innovative technical solution for exploiting low-temperature sources of a hot water boiler, a computer simulation of four high-temperature heat pumps connected in series is performed in Figure 3 and a computer simulation of one high-temperature heat pump is shown in Figure 4. as if they had four high-temperature heat pumps connected in parallel, which were used in the process simulation in Figure 3. The operating characteristic of one heat pump in Figure 4 is the same as if four high-temperature heat pumps were used in parallel, Figure 3.
A summary of the computer simulation results of the series-connected heat pumps shown in Figure 3 is given in Table 2, and a summary of the results of the computer simulation of one heat pump Energies 2020, 13, 6311 9 of 12 shown in Figure 4 is given in Table 3. The data in Table 2 show that the average COP (coefficient of performance) of all four high temperature heat pumps is 5.51. By lowering the temperature of the low-temperature heat source, the COP of the high-temperature heat pumps also decreases. The calculation was made by heating the return heating water from a temperature of 50 • C to a temperature of 70 • C in series-connected condensers of high-temperature heat pumps.
From the results of computer simulation of one heat pump given in Figure 4, a summary is made, which is given in Table 3. The data in Table 3 show that the COP is 3.82, which is much less than series-connected heat pumps. The reason is that it is necessary to overcome the larger temperature difference ((T = 50 • C) between the low-temperature heat source and the desired heating water return temperature with a high-temperature heat pump. This also requires more electrical power to drive the electric motor of the high-pressure compressor, because it is necessary to create a higher pressure ratio between the pressure at the evaporation temperature and the pressure at the condensing temperature of the refrigerant with the compressor.

Economics
The economic efficiency of using low-temperature heat sources from a selected hot water boiler system with the HTHP was calculated in MS Excel. Some companies produce heat with a CHP plant, therefore the economic efficiency for the example is calculated as if the electricity is produced by CHP. Electricity prices vary from country to country. Two calculations have been made: -with electricity from the grid (92.2 €/MWh); and with electricity from the CHP unit (39.62 €/MWh).
The data are given in Table 4. The heat price has been defined as the production price of heat produced from natural gas with hot water boilers. The economic calculation using electricity from a cogeneration plant (39.62 €/MWh) is shown in Figure 6.

Economic data
Investment 650,000 EUR Discount rate 2.0 % The economic calculation using electricity from a cogeneration plant (39.62 €/MWh) is shown in Figure 6.  Figure 6 shows the internal rate of return (IRR) = 39.3% and payback of the investment exploiting excess heat from hot water boiler with four series-connected high-temperature heat pumps is less than 3 years.
The economic calculation with the electricity taken from the grid (92.2 €/MWh) is shown in Figure 7.  Figure 6 shows the internal rate of return (IRR) = 39.3% and payback of the investment exploiting excess heat from hot water boiler with four series-connected high-temperature heat pumps is less than 3 years.
The economic calculation with the electricity taken from the grid (92.2 €/MWh) is shown in Figure 7. The diagram in Figure 7 shows the IRR = 28.8% and payback of the investment exploiting excess heat from a hot water boiler with four series-connected high-temperature heat pumps is less than 4 years.

Conclusions
The article presents an innovative technical solution to increase the efficiency of primary fuel and thus reduce CO2 emissions by upgrading existing or new hot water boilers with hightemperature heat pumps that use excess heat from flue gases. The system is suitable for each process in which a hot water boiler is installed to raise the energy efficiency of the entire process and consequently reduce the primary fuel consumption and reduce operation costs.
The technology described in the article is new and should be included in national energy efficiency directives and establishing best available techniques (BAT) to increase the primary fuel efficiency of hot water boilers.
In order to exploit the excess heat of the flue gases of the hot water boiler, it is necessary to install The diagram in Figure 7 shows the IRR = 28.8% and payback of the investment exploiting excess heat from a hot water boiler with four series-connected high-temperature heat pumps is less than 4 years.

Conclusions
The article presents an innovative technical solution to increase the efficiency of primary fuel and thus reduce CO 2 emissions by upgrading existing or new hot water boilers with high-temperature heat pumps that use excess heat from flue gases. The system is suitable for each process in which a hot water boiler is installed to raise the energy efficiency of the entire process and consequently reduce the primary fuel consumption and reduce operation costs.
The technology described in the article is new and should be included in national energy efficiency directives and establishing best available techniques (BAT) to increase the primary fuel efficiency of hot water boilers.
In order to exploit the excess heat of the flue gases of the hot water boiler, it is necessary to install a heat exchanger in the flue gas exhaust system, where the water present in the flue gases is additionally cooled by cooling and condensing. The heat produced in this way has temperature too low to be used directly for the needs of high-temperature heating, but it can also be used by using high-temperature heat pumps.
A computer simulation of four series-connected high-temperature heat pumps was undertaken to clearly demonstrate the operation of innovative technology for the exploitation of low-temperature sources of hot water boilers. With an innovative system of sequential connection of high-temperature heat pumps, by utilizing low-temperature heat sources of the hot water boiler, the total primary energy efficiency of natural gas can be increased by 17.6% (from 90.6% to 108.2% compared to LHV of natural gas). This 17.6% increase in the primary energy efficiency of natural gas is obtained if the flue gases of the hot water boiler are cooled to a temperature of 25 • C.
The energy efficiency of the primary fuel of a hot water boiler can be increased significantly by additional cooling of flue gases (up to approximately 5 • C) with the presented technology of serial connection of high-temperature heat pumps.
The presented innovative technical solution is also very economical with a very short return of investment. If the hot water boiler does not reach a sufficiently large number of operating hours, it is necessary to install two heat accumulators in the heating system, where the first accumulates low-temperature heat produced by exploiting excess heat from flue gases, and the second heat accumulator stores heat produced by high-temperature pumps. In this case, the installed power of the heat pumps can also be correspondingly lower, because it will be possible to operate them even when the hot water boiler is not operating.
The operating parameters (hot water boiler and HTHP) of the real system were taken into account in the presented computer simulation.