Enhancement of Diversity in Production and Applications Utilizing Electrolytically Polymerized Rubber Sensors with MCF: The Second Report on Various Engineering Applications

We investigated the proposed hybrid skin (H-Skin) for the requirement of haptic sensibility in rubber using our proposed consummate fabrication process together with a multi-layered magnetic compound fluid (MCF) rubber and stocking-like porous rubber permeated by liquids, which was demonstrated in our previous report. The objective was to assess its applicability to sensing normal force and temperature, as well as fields dominated by shear force. For normal force, we investigated the piezo-electricity and electric current induced voltage, as well as the piezo-resistivity of the MCF rubber sensor under pressure. Additionally, we clarified the viability of measuring the softness and texture of materials using the MCF rubber sensor. For the shear motion, we clarified the characteristics of the friction coefficient using the MCF rubber sensor. The MCF rubber sensor can capture the reactions of paper, cloth, convex- and concave-shaped objects such as plant leaves and metal, and the skin of the human finger. Therefore, it is useful to investigate its texture and biological surfaces. Our obtained outstanding results indicated the feasibility of sensing the surface texture for any material in fields such as paper, fashion, apparel manufacturing, and cosmetic industries, which was impossible until now.


Introduction
In our first report, we investigated the viability of the electrolytic polymerization technique for the solidification of diverse rubbers using a combination of various surfactants and water-insoluble magnetic fluids (MFs) via the consummate fabrication of a magnetic compound fluid (MCF) rubber sensor [1]. MCF has nm-ordered magnetite (Fe 3 O 4 ) due to MFs and µm-ordered metal particles [2]. MCF rubber is the rubber that incorporates MCF. By the application of a magnetic field, magnetic clusters of Fe 3 O 4 and metal particles are created in the rubber under solidification from rubber latex [1]. The solidification was presented with several combinations of various rubbers and MFs using various emulsifiers. Rubber can be categorized into diene and non-diene rubbers, or natural and synthetic rubbers. We demonstrated the feasibility of silicone rubber (Q) and urethane rubber (U) as non-diene rubbers, in addition to natural rubber (NR) and chloroprene rubber (CR) as diene rubbers. In general, diene rubber is water-soluble and non-diene is water-insoluble. Some MFs are water-soluble and others are water-insoluble. The various arrangements of water-soluble or water-insoluble rubbers 16.5 mm × 24 mm in size and 4.5 mm thick, and the inner Q rubber was 16 mm × 21.5 mm and 4 mm thick. First, we investigated the electrical properties of the MCF rubber sensor produced using the consummate fabrication process under normal or shear forces.

Compression
From the aspect of piezo-elements, the electric characteristics are predominantly categorized into piezo-electricity and piezo-resistivity [17]. The former is evaluated as built-in electricity (i.e., built-in voltage and current), which is caused by the ionized molecules and particles of the rubber latex, oleic acid-coated around the Fe 3 O 4 of the MF, water, and PVA. They functionalize an acceptor-like p-type semiconductor (corresponding to A − ) and a donor-like n-type semiconductor (corresponding to D + ) [18,19]. However, the latter requires the application of voltage through a power supply so that resistivity changes, whose mechanism can be explained by typical tunnel theory [18].
We used a previously proposed normal force experiment (NFE) apparatus [20] and it is shown in Figure A1, in Appendix A. We measured the electrical properties of the MCF rubber sensor under compression. In the NFE, the upper electrode was moved to be in contact with the MCF rubber sensor, which was sandwiched between the electrodes, onto the lower electrode using an actuator at a pressing speed of 10 mm/min. The pressing normal force was measured using a load cell installed in the actuator. The actuator used a commercial, small tensile testing machine (SL-6002, IMADA-SS Co. Ltd., Toyohashi, Japan). The paired electrodes used had the same 7 mm × 7 mm square form. For piezo-electricity, we measured the induced voltage from the electric wires of the MCF rubber sensor. For piezo-resistivity, by the application of a voltage to the MCF rubber, we measured the electrical current passing through the MCF rubber sensor at compression. This was accomplished using an electric power supply of 10 V and electric resistance of 1.8 kΩ in the electric circuit for piezo-resistivity.
The MCF rubber sensor was produced using the proposed consummate fabrication process [1]. "Adhesive MCF rubber 2" consisted of 0.5 g of Na 2 WO 4 ·2H 2 O, 3 g of water, 0.75 g of MF (W40, Ichinen-Chemicals Co., Ltd., Shibaura, Japan), 3 g of KE1300T (Shin-Etsu Chemical Co. Ltd., Tokyo, Japan), 3 g of PVA, 3 g of NR-latex (Ulacol, Rejitex Co. Ltd., Atsugi, Japan), 3 g of CR-latex (671A, Showa Denko Co. Ltd., Tokyo, Japan), 3 g of TiO 2 (Anatase type, Fujifilm Wako Pure Chemical Co., Ltd., Osaka, Japan), and 3 g of Ni. "Porous MCF rubber 1" consisted of 0.5 g of Na 2 WO 4 ·2H 2 O, 3 g of water, 0.75 g of MF, 3 g of KE1300T, 3 g of NR-latex (Ulacol), 3 g of CR-latex (671A), 3 g of TiO 2 , and 3 g of Ni. It was permeated with glycerin. "MCF rubber 3" consisted of 0.75 g of MF, 3 g of NR-latex (Ulacol), 3 g of CR-latex (671A), 3 g of TiO2, and 3 g of Ni. Here, we used KE1300T instead of the KF96 in the figure of the proposed consummate fabrication process shown in [1]. The MCF rubber liquid was electrolytically polymerized, whereby a static magnetic field of 312 mT was applied to a pair of two stainless electrodes with a 1-mm gap using permanent magnets as paired opposites via the application of a constant electric field at 2.7 A. The Ni powder had particles in the order of microns and bumps on the surface (No. 123 by Yamaishi Co. Ltd., Noda, Japan). The MF used was 40 wt% Fe 3 O 4 . The MCF rubber sensor produced in this study was the same as that in the previous one [1]. Figure 1a shows the induced voltage as piezo-electricity in response to the repeating pressure and Figure 1b the electric current as piezo-resistivity in response to a pressure. For the former, as the pressure increased, the induced voltage increased and subsequently decreased to zero. This tendency can be explained by the fact that, as the counter negative and active ions become closer, the induced voltage increases. As the pressure increases, the counter ions come into contact and this phenomenon has previously been clarified [17]. In contrast, for the latter, because the outer Q rubber acted as a buffer to the applied pressure, the electric current reacted slightly later than the pressure, which was a peculiar property. Regardless of the Q rubber buffer, the MCF rubber sensor is attractive to the normal force.

Shear Motion
We used a previously used same shear force experiment (SFE) apparatus [20] to measure the electric property of the MCF rubber sensor under shear motion, as shown in Figure A2 in the Appendix B. The power supply was 10 V and the electric resistance 1.8 kΩ in the electric circuit for piezo-resistivity. By applying a voltage, we measured the electric current in the MCF rubber sensor, which was the same as that in NFE. The MCF rubber sensor 4 was placed under an acrylic resin body 2 on which two electrodes of the stainless plate were attached. As Figure 2 shows, the MCF rubber sensor 4 came into contact with a rubbed object 7 and was moved parallel to the object by adjusting a constant height interval by adjustment device 1 along the object surface using actuator 6 at a sweeping distance of 50 mm. Our used range of sweeping velocity was less than 4 mm/s. The pressing normal force was measured using a load cell that is embedded inner the base on which the rubbed object 7 is settled. Our used range of initial normal force means the normal force before the sensor's movement was less than 5 N. The sweeping distance was measured using laser displacement 5. A hard, non-electric body with φ 0.5 mm was interposed between the MCF rubber sensor 4 and the acrylic resin body 2 so that the MCF rubber sensor could be contacted correctly [20]. This contact method was previously used [20] to be more effective when the contact area was smaller than the MCF rubber as a whole, and the MCF rubber is very slightly bent owing to the bending effect of the MCF rubber. The shear force was measured using a load cell 3 attached to the actuator 6.

Shear Motion
We used a previously used same shear force experiment (SFE) apparatus [20] to measure the electric property of the MCF rubber sensor under shear motion, as shown in Figure A2 in the Appendix B. The power supply was 10 V and the electric resistance 1.8 kΩ in the electric circuit for piezo-resistivity. By applying a voltage, we measured the electric current in the MCF rubber sensor, which was the same as that in NFE. The MCF rubber sensor 4 was placed under an acrylic resin body 2 on which two electrodes of the stainless plate were attached. As Figure 2 shows, the MCF rubber sensor 4 came into contact with a rubbed object 7 and was moved parallel to the object by adjusting a constant height interval by adjustment device 1 along the object surface using actuator 6 at a sweeping distance of 50 mm. Our used range of sweeping velocity was less than 4 mm/s. The pressing normal force was measured using a load cell that is embedded inner the base on which the rubbed object 7 is settled. Our used range of initial normal force means the normal force before the sensor's movement was less than 5 N. The sweeping distance was measured using laser displacement 5. A hard, non-electric body with ϕ 0.5 mm was interposed between the MCF rubber sensor 4 and the acrylic resin body 2 so that the MCF rubber sensor could be contacted correctly [20]. This contact method was previously used [20] to be more effective when the contact area was smaller than the MCF rubber as a whole, and the MCF rubber is very slightly bent owing to the bending effect of the MCF rubber. The shear force was measured using a load cell 3 attached to the actuator 6. Initially, the rubbed object was sandpaper that was attached to a flat plate with a rough surface. The sandpaper was prepared with various values of surface roughness and was optimal for investigating the effect of surface roughness on the MCF rubber sensor. The electric current of the MCF rubber sensor is shown in Figure 3. The MCF rubber sensor moved from a positive location to a negative one (from right to left). Using a surface roughness measuring device (SJ-400, Mitutoyo, Co.  Initially, the rubbed object was sandpaper that was attached to a flat plate with a rough surface. The sandpaper was prepared with various values of surface roughness and was optimal for investigating the effect of surface roughness on the MCF rubber sensor. The electric current of the MCF rubber sensor is shown in Figure 3. The MCF rubber sensor moved from a positive location to a negative one (from right to left). Using a surface roughness measuring device (SJ-400, Mitutoyo, Co. Ltd., Kawasaki, Japan), we observed that #40 sandpaper had 56.2 µm Ra, 216.7 µm Ry, and 68.2 µm Rq; #180 sandpaper had 14.1 µm Ra, 74.4 µm Ry, and 17.2 µm Rq; #280 sandpaper had 9.75 µm Ra, 55.8 µm Ry, and 12.6 µm Rq; and #1000 sandpaper had 3.32 µm Ra, 21.6 µm Ry, and 4.1 µm Rq. When the roughness curve represents z(x), the arithmetic average height Ra and root mean square height (Rq) are shown in Equation (1) at a reference length (L). Ry is the maximum height.
Sensors 2020, 20, x 6 of 24 Figure 3. Electrical properties of MCF rubber sensor rubbing over sandpaper in the SFE: the force is presented as the initial normal force just before sweeping. The sweeping velocity is also presented.
(a) (b) Figure 3. Electrical properties of MCF rubber sensor rubbing over sandpaper in the SFE: the force is presented as the initial normal force just before sweeping. The sweeping velocity is also presented.
The electric current changes by three parameters: the surface roughness of the rubbed object, sweeping velocity, and normal force. Even with an outer shell of a Q rubber coating around the MCF rubber sensor [1], the MCF rubber sensor was sensitive to both shear and normal forces.
To ensure that the obtained lines in Figure 3 correctly represented shear force, we adopted #180 sandpaper with a 2.1-mm/s sweeping velocity and 3.7-N normal force, and then compared the electric current with the shear force measured using a load cell (Figure 4a). By considering that the electric pole of the electric current was reversed to that of the shear force, a quantitative changing tendency was coincident to both of them. Therefore, the electric current characteristics on the shear force were reactions to the convex and concave shapes of the object. Subsequently, the friction coefficient calculated by dividing the measured shear by the normal forces characterized the surface roughness of the object (Figure 4b). The change in the friction coefficient was non-linear overall, although a constant existed depending on the experimental conditions, such as in for #40, #280, and #1000 sandpapers. The non-linearity was due to the repeated deformation and restoration of the multi-layered MCF rubber sensor by the force created between the layers under shear motion (Figure 4c). . Electrical properties of MCF rubber sensor rubbing over sandpaper in the SFE: the force is presented as the initial normal force just before sweeping. The sweeping velocity is also presented.   In the following paragraphs, we investigate the electric current affected by three parameters: the surface roughness of the rubbed object, sweeping velocity, and normal force. From the observation that the electric current corresponds to the shear force ( Figure 4), the electric current can be evaluated using the same ordinary arithmetic values on the roughness curve measured using ordinary surface-roughness-measuring devices such as SJ-400: Ra, Rq, and Ry. Therefore, with respect to the electric current, Ra ,E , Rq ,E , and R y,E , which corresponds to Ra, Rq, and Ry, are calculated. These are affected by the surface roughness of the object (RMI_Ra, RMI_Rq, and RMI_Ry), sweeping velocity (v), initial normal force (N o ) (which is the normal force before sweeping), as well as by Ra ,N , Rq ,N , and Ry ,N , which are evaluated on the normal force and correspond to Ra, Rq, and Ry, and by Ra ,S , Rq ,S , and Ry ,S , which are evaluated on the shear force and correspond to Ra, Rq, and Ry.
The relationships among these parameters are shown in Figures 5-10. To investigate the effect of the parameters on the electric current of the MCF rubber sensor, we adopt the coefficient of determination (R 2 ), which can exhibit linear regression and is also shown in the figures. We adopt the linear regression because of the convenience that if these parameters have a linear formula, when one of these parameters is known beforehand, all of the other parameters can become clear. The arrangement of the linear relationship is significant in the engineering development by using our sensor. In general, we can conclude that the correlation is strong when R 2 is more than 0.7 and is weak when R 2 is less than 0.4 and greater than 0.2. When R 2 is small, the formula might be arranged nonlinear relationship. As Figure 5 shows, the electric current has a strong correlation with the surface roughness and their correlations on Ra and Rq are stronger than on Ry. As Figures 6 and 7 show, the electric current has a moderate correlation with the normal force and a stronger correlation with Sensors 2020, 20, 4674 7 of 23 the normal force than N o . As Figures 7 and 8 show, the electric current has a stronger correlation with the normal force than with the shear force and has stronger correlations with normal and shear forces on Ra than on Rq and Ry. As Figure 9 shows, the electric current has a weak correlation with v. However, Figure 10 shows that the shear force has a strong correlation with the sweeping velocity, which means that the dynamic frictional force is a function of the sweeping velocity that changes non-linearly. This nonlinearity is indicated in Figure 4c.
As a result, the MCF rubber sensor is sensitive to both normal and shear forces, regardless of the Q rubber buffer coated around the fabricated MCF rubber. Therefore, we expect that it can be used for the haptic sensing of diverse objects by either normal or shear motions. The feasibility of this method is discussed in the following section.
Incidentally, the cross sensitivity is also significant because it is relevant to the sensor's accuracy. As for the present MCF rubber sensor, the data involving the cross sensitivity are obtained by measurement. The cause is that the particles and molecules of the MCF rubber are mixed and that the electric property generates inner the hybrid particles and molecules notwithstanding the existence of magnetic clusters aligned along the single direction, such as a needle in which electricity transmits. Therefore, the cross sensitivity cannot be divided from the obtained data.
are evaluated on the normal force and correspond to Ra, Rq, and Ry, and by Ra,S, Rq,S, and Ry,S, which are evaluated on the shear force and correspond to Ra, Rq, and Ry.
The relationships among these parameters are shown in Figures 5-10. To investigate the effect of the parameters on the electric current of the MCF rubber sensor, we adopt the coefficient of determination (R 2 ), which can exhibit linear regression and is also shown in the figures. We adopt the linear regression because of the convenience that if these parameters have a linear formula, when one of these parameters is known beforehand, all of the other parameters can become clear. The arrangement of the linear relationship is significant in the engineering development by using our sensor. In general, we can conclude that the correlation is strong when R 2 is more than 0.7 and is weak when R 2 is less than 0.4 and greater than 0.2. When R 2 is small, the formula might be arranged nonlinear relationship. As Figure 5 shows, the electric current has a strong correlation with the surface roughness and their correlations on Ra and Rq are stronger than on Ry. As Figures 6 and 7 show, the electric current has a moderate correlation with the normal force and a stronger correlation with the normal force than No. As Figures 7 and 8 show, the electric current has a stronger correlation with the normal force than with the shear force and has stronger correlations with normal and shear forces on Ra than on Rq and Ry. As Figure 9 shows, the electric current has a weak correlation with v. However, Figure 10 shows that the shear force has a strong correlation with the sweeping velocity, which means that the dynamic frictional force is a function of the sweeping velocity that changes non-linearly. This nonlinearity is indicated in Figure 4c.
As a result, the MCF rubber sensor is sensitive to both normal and shear forces, regardless of the Q rubber buffer coated around the fabricated MCF rubber. Therefore, we expect that it can be used for the haptic sensing of diverse objects by either normal or shear motions. The feasibility of this method is discussed in the following section.      Incidentally, the cross sensitivity is also significant because it is relevant to the sensor's accuracy. As for the present MCF rubber sensor, the data involving the cross sensitivity are obtained by measurement. The cause is that the particles and molecules of the MCF rubber are mixed and that the electric property generates inner the hybrid particles and molecules notwithstanding the existence of magnetic clusters aligned along the single direction, such as a needle in which electricity transmits. Therefore, the cross sensitivity cannot be divided from the obtained data.

Electrical Properties of Diverse Object
The condition of rubbing an object creates several opportunities for haptic sensing. We investigated the feasibility of the MCF rubber sensor on diverse objects under normal or shear motions.

Soft Object
The softness of the rubbed object was adjusted using silicone gel. We first investigated its softness by using the MCF rubber sensor through compression and then investigated its characteristics under shear motion.
For compression, we attached the MCF rubber sensor 3 under a rigid acrylic resin body 1 in contact with the silicone gel 4 which is settled on the base 2 ( Figure 11). The silicone gel 4 was created from KE1300T and a mixing thinner at various weight-ratios of the thinner to KE1300T: 0.5, 1.5, 2.0, 2.5, 3.5, 4.0, and 5.0. By comparing the softness of the silicone gel, we also used a rigid body of iron.

Electrical Properties of Diverse Object
The condition of rubbing an object creates several opportunities for haptic sensing. We investigated the feasibility of the MCF rubber sensor on diverse objects under normal or shear motions.

Soft Object
The softness of the rubbed object was adjusted using silicone gel. We first investigated its softness by using the MCF rubber sensor through compression and then investigated its characteristics under shear motion.
For compression, we attached the MCF rubber sensor 3 under a rigid acrylic resin body 1 in contact with the silicone gel 4 which is settled on the base 2 ( Figure 11). The silicone gel 4 was created from KE1300T and a mixing thinner at various weight-ratios of the thinner to KE1300T: 0.5, 1.5, 2.0, 2.5, 3.5, 4.0, and 5.0. By comparing the softness of the silicone gel, we also used a rigid body of iron. Using the NFE described previously, a rigid acrylic resin body was installed on the actuator. By applying pressure, the electric current in the MCF rubber sensor 3, as piezo-resistivity, was measured ( Figure 12a). Because of the elasticity of the silicone gel, the electric current fluctuated slightly. Therefore, we investigated the elasticity of the silicone gel based on the relationship between pressure and compressive shear rate (Figure 12b). The results of the iron body corresponded to those in Figure 1b. As the enhancement of the amount of thinner increased, the elasticity weakened. From Figure 12b, we can posit that the relationship of the pressure to the shear rate has an approximate quadratic function. The coefficient of the secondary term of the approximated quadratic function is dominant such that it might represent the stiffness of the silicone gel, which is indicated by the parameter a in this paper. The electric current, Ra ,E , Rq ,E , and Ry ,E , as in the previous section, are shown with the parameter a in Figure 12c. "Max" in the figure is the maximum value of the electric current at compression. Ra ,E , Rq ,E , Ry ,E , and Max are linear to a, which means that the electric current can be presented by the stiffness of the silicone gel.
we can posit that the relationship of the pressure to the shear rate has an approximate quadratic function. The coefficient of the secondary term of the approximated quadratic function is dominant such that it might represent the stiffness of the silicone gel, which is indicated by the parameter a in this paper. The electric current, Ra,E, Rq,E, and Ry,E, as in the previous section, are shown with the parameter a in Figure 12c. "Max" in the figure is the maximum value of the electric current at compression. Ra,E, Rq,E, Ry,E, and Max are linear to a, which means that the electric current can be presented by the stiffness of the silicone gel. such that it might represent the stiffness of the silicone gel, which is indicated by the parameter a in this paper. The electric current, Ra,E, Rq,E, and Ry,E, as in the previous section, are shown with the parameter a in Figure 12c. "Max" in the figure is the maximum value of the electric current at compression. Ra,E, Rq,E, Ry,E, and Max are linear to a, which means that the electric current can be presented by the stiffness of the silicone gel. For shear motion, the MCF rubber sensor was rubbed along the surface of the silicone gel using the SFE instrument and measuring method described in the previous section. No conventional instrument for measuring shear force or friction coefficient without destroying the gel exists. The MCF rubber sensor did not break the gel. The electric current of the MCF rubber sensor as piezo-resistivity is shown in Figure 13 under shear motion. The MCF rubber sensor moved from a positive location to a negative one (from right to left). The electric current included the effect of normal force and sweeping velocity, as discussed in the previous section. However, in this study, both the initial normal force and sweeping velocity were maintained at a constant. The deforming motion of the silicone gel is illustrated in Figure 14a. At the beginning of the rubbing, the MCF rubber sensor slid smoothly on the silicone gel, and then the silicone gel gathered in billows (a and b in Figure 14a). Subsequently, the silicone gel returned to its original flat shape, and the gathered silicone gel passed under the MCF rubber sensor (c and d in Figure 14a). This deformation was repeatable. Therefore, the friction coefficient had several peaks or fluctuations (Figure 14b). The electric current can be used to demonstrate the friction coefficient.
In contrast, when the softness of a soft object such as the silicone gel is measured, it is pushed and its elasticity measured, as discussed in the previous section using the NFE. In general, the For shear motion, the MCF rubber sensor was rubbed along the surface of the silicone gel using the SFE instrument and measuring method described in the previous section. No conventional instrument for measuring shear force or friction coefficient without destroying the gel exists. The MCF rubber sensor did not break the gel. The electric current of the MCF rubber sensor as piezo-resistivity is shown in Figure 13 under shear motion. The MCF rubber sensor moved from a positive location to a negative one (from right to left). The electric current included the effect of normal force and sweeping velocity, as discussed in the previous section. However, in this study, both the initial normal force and sweeping velocity were maintained at a constant. The deforming motion of the silicone gel is illustrated  Figure 14a. At the beginning of the rubbing, the MCF rubber sensor slid smoothly on the silicone gel, and then the silicone gel gathered in billows (a and b in Figure 14a). Subsequently, the silicone gel returned to its original flat shape, and the gathered silicone gel passed under the MCF rubber sensor (c and d in Figure 14a). This deformation was repeatable. Therefore, the friction coefficient had several peaks or fluctuations (Figure 14b). The electric current can be used to demonstrate the friction coefficient.   In contrast, when the softness of a soft object such as the silicone gel is measured, it is pushed and its elasticity measured, as discussed in the previous section using the NFE. In general, the relationship between normal and shear motions has not been conducted on a soft object before. Therefore, we investigated the relationship between the elasticity and the friction coefficient of the silicone gel. The former is denoted by the parameter a and the latter by the electric current of the MCF rubber sensor. Ra ,E , Rq ,E , and Ry ,E denote the friction coefficients and thus the elasticity and friction coefficient are related (Figure 14c). The indexes a, b, c, and d in Figure 14c correspond to a, b, c, and d in Figure 14a respectively. Ra ,E , Rq ,E , and Ry ,E exhibit two predominant peaks, which correspond to b and d in Figure 14a.
Therefore, the normal and shear motion of the MCF rubber sensor on the soft body can be used for the haptic sensing of any soft body.

Paper
The parameters of sensing a soft body are softness and texture. The former can be measured by applying a normal force and elucidated from the results obtained in the previous section. In contrast, the latter is measured by applying shear force and has not been clarified yet except using silicone gel in the previous section. First, because paper is a typical texture of a soft body, it is discussed here. The MCF rubber sensor was rubbed along the surface of a paper using the SFE instrument and measured using a method described in the previous section. Figure 15 shows images of various forms of paper, labeled A-D. The electric current of the MCF rubber sensor with respect to piezo-resistivity is shown in Figure 16a. The MCF rubber sensor was rubbed along the surface of the paper using the same SFE instrument and measuring method described in the previous section. For comparison, the measurement of the acrylic resin is also shown. The Ra ,E , Rq ,E , and Ry ,E obtained from the electric current of Figure 16a, and the RMI_Ra, RMI_Rq, and RMI_Ry of the paper measured using the ordinary surface-roughness-measuring device are shown in Figure 16b. In contrast to the RMI_Ra, RMI_Rq, and RMI_Ry of acrylic resin, which were sufficiently low to be smooth, Ra ,E , Rq ,E , and Ry ,E were larger because of the peak or fluctuation created by the surface roughness owing to the layered fabrication of the MCF rubber sensor (Figures 4 and 14). In contrast, the surface of A was coarser than B, C, and D; therefore, its RMI_Ry was larger. However, for B, C, and D, Ra ,E , Rq ,E , and Ry ,E were larger than RMI_Ra, RMI_Rq, and RMI_Ry. In particular, the Ry ,E of B was the largest because the fiber of the newspaper was coarse. These results can be guessed from the images by scanning electron microscope (SEM) that fibers of A and B are large. They indicate that the fineness of the paper cannot be subtly measured by sweeping the diamond needle of an ordinary surface-roughness-measurement device such as SJ-400. B, C, and D; therefore, its RMI_Ry was larger. However, for B, C, and D, Ra,E, Rq,E, and Ry,E were larger than RMI_Ra, RMI_Rq, and RMI_Ry. In particular, the Ry,E of B was the largest because the fiber of the newspaper was coarse. These results can be guessed from the images by scanning electron microscope (SEM) that fibers of A and B are large. They indicate that the fineness of the paper cannot be subtly measured by sweeping the diamond needle of an ordinary surface-roughness-measurement device such as SJ-400.

Cloth
Cloth is a typical fine and soft material. Figure 17 shows images of various cloths, labeled A-H. The electric current of the MCF rubber sensor as piezo-resistivity is shown in Figure 18a. The MCF rubber sensor was rubbed along the surface of the cloth using the same SFE instrument and measuring method described in the previous section. Figure 2 corresponds to Figure 17b. Figure 18b shows the comparison between Ra,E, Rq,E, and Ry,E obtained from the electric current in Figure 18a and RMI_Ra, RMI_Rq, and RMI_Ry of paper measured using ordinary surface-roughness measurement. RMI_Ra, RMI_Rq, and RMI_Ry were observed to be inaccurate values that the surface roughness of the cloths cannot be measured by sweeping the diamond needle of ordinary surface-roughness-measurement devices such as SJ-400. Therefore, the cloths were torn by SJ-400, particularly the large fibers of cloth B (Figure 17f). However, the MCF rubber sensor can measure the surface roughness without breaking the surface, and the Ra,E, Rq,E, and Ry,E of the different cloths could be obtained. In particular, the surface roughness of cloth B, fabricated using many large and soft fibers, could be obtained. Regarding the denseness and alignment of fibers, the more neatly the

Cloth
Cloth is a typical fine and soft material. Figure 17 shows images of various cloths, labeled A-H. The electric current of the MCF rubber sensor as piezo-resistivity is shown in Figure 18a. The MCF rubber sensor was rubbed along the surface of the cloth using the same SFE instrument and measuring method described in the previous section. Figure 2 corresponds to Figure 17b. Figure 18b shows the comparison between Ra ,E , Rq ,E , and Ry ,E obtained from the electric current in Figure 18a and RMI_Ra, RMI_Rq, and RMI_Ry of paper measured using ordinary surface-roughness measurement. RMI_Ra, RMI_Rq, and RMI_Ry were observed to be inaccurate values that the surface roughness of the cloths cannot be measured by sweeping the diamond needle of ordinary surface-roughness-measurement devices such as SJ-400. Therefore, the cloths were torn by SJ-400, particularly the large fibers of cloth B (Figure 17f). However, the MCF rubber sensor can measure the surface roughness without breaking the surface, and the Ra ,E , Rq ,E , and Ry ,E of the different cloths could be obtained. In particular, the surface roughness of cloth B, fabricated using many large and soft fibers, could be obtained. Regarding the denseness and alignment of fibers, the more neatly the fibers align, such as for H, the larger Ry ,E becomes. However, even if the fibers form neat lines, Ry ,E changes significantly or slightly depending on whether the cloth is soft or hard, such as cloths E and F. Therefore, we investigated from the perspective of the material fibers, A and B had fibers made of cotton. The fiber's shape is slightly twisted or wrung one as shown in Figure 17i,j. C, D, and G had both chemical fibers made of polyester and wool. The fiber's shape is smooth one without twisting as shown in Figure 17k,l,w. E, F, and H had fibers made of wool. The fiber has small jagged cuticles as shown in Figure 17u,v,x. The Ry ,E of the cloths made of cotton, such as A and B, and those of wool such as E and H, tended to be small. The Ry ,E of F was larger than that of E and H because the lump of fibers of F was larger than that of E and H. At the cloth including chemical fibers such as C and D, Ry ,E tended to become larger. The Ry ,E of G was smaller than that of C and D because its fibers were smaller than that of C and D.

Plants
Subsequently, we investigated a comparatively rough-surface, convexo-concave body. We attempted the test on the back surfaces of hydrangea and cherry leaves ( Figure 19). The MCF rubber sensor was rubbed along the surface of the leaf using the same SFE instrument and measuring method described in the previous section. By crossing the leaf veins as shown in Figure 19b,d, the MCF rubber sensor captures their convexo-concave shapes using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 19a,c).

Plants
Subsequently, we investigated a comparatively rough-surface, convexo-concave body. We attempted the test on the back surfaces of hydrangea and cherry leaves ( Figure 19). The MCF rubber sensor was rubbed along the surface of the leaf using the same SFE instrument and measuring method described in the previous section. By crossing the leaf veins as shown in Figure 19b,d, the MCF rubber sensor captures their convexo-concave shapes using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 19a,c).

Plants
Subsequently, we investigated a comparatively rough-surface, convexo-concave body. We attempted the test on the back surfaces of hydrangea and cherry leaves ( Figure 19). The MCF rubber sensor was rubbed along the surface of the leaf using the same SFE instrument and measuring method described in the previous section. By crossing the leaf veins as shown in Figure 19b,d, the MCF rubber sensor captures their convexo-concave shapes using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 19a,c).

Large Convexo-Oconcave Body
Additionally, we investigated the surface roughness of a large convexo-concave body, which was a metal body fabricated from brass ( Figure 20). The height of the convexo-concave body in Figure 20a was significantly larger than those of Figure 19b,d. The MCF rubber sensor was rubbed along the surface of the body using the same SFE instrument and measuring method described in the previous section. By crossing the body, the MCF rubber sensor captured its convexo-concave shape using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 20b).

Large Convexo-Oconcave Body
Additionally, we investigated the surface roughness of a large convexo-concave body, which was a metal body fabricated from brass ( Figure 20). The height of the convexo-concave body in Figure 20a was significantly larger than those of Figure 19b,d. The MCF rubber sensor was rubbed along the surface of the body using the same SFE instrument and measuring method described in the previous section. By crossing the body, the MCF rubber sensor captured its convexo-concave shape using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 20b).

Large Convexo-Oconcave Body
Additionally, we investigated the surface roughness of a large convexo-concave body, which was a metal body fabricated from brass ( Figure 20). The height of the convexo-concave body in Figure 20a was significantly larger than those of Figure 19b,d. The MCF rubber sensor was rubbed along the surface of the body using the same SFE instrument and measuring method described in the previous section. By crossing the body, the MCF rubber sensor captured its convexo-concave shape using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 20b).

Cosmetic
Finally, we examined the surface roughness of human skin as shown in Figure 21a. The MCF rubber sensor was rubbed along the surface of the little finger using the same SFE instrument and measuring method described in the previous section. By crossing the little finger, the MCF rubber captured its convexo-concave shape using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 21b). A large electric current occurred at the first and second joints and the base of the nail.
(a) image of the body; (b) surface roughness of the body.

Cosmetic
Finally, we examined the surface roughness of human skin as shown in Figure 21a. The MCF rubber sensor was rubbed along the surface of the little finger using the same SFE instrument and measuring method described in the previous section. By crossing the little finger, the MCF rubber captured its convexo-concave shape using the electric current of the MCF rubber sensor as piezo-resistivity (Figure 21b). A large electric current occurred at the first and second joints and the base of the nail.
In contrast, the surface roughness of the human skin coated with cosmetic cream was smoother than that without one. Therefore, if we apply the MCF rubber sensor to the human body, we can measure and evaluate the degree to which the skin is covered by cosmetics or the quality of hair with cuticles.

Temperature Sensing
The MCF rubber can be used for diverse sensing including the force sensing of temperature and a wide range of electromagnetic waves involving photovoltaics, irradiation, and infrared rays [4]. In this study, we investigated temperature sensing. We will present the investigations on photovoltaics and irradiation in subsequent reports [21].
As Figure 22a shows, we measured the electric current as the piezo-resistivity of the MCF rubber sensor immersed in water into which hot water was poured. The MCF rubber sensor and measurement method were the same as described in the previous section. We simultaneously measured the temperature adjacent to the MCF rubber sensor using a thermocouple. Figure 22b shows the change in the electric current as a function of water temperature. At the initiative period of less than approximately 2 s, the electric current was independent of the increase in water temperature because of the buffer of the outer shell of the Q rubber coat around the MCF rubber sensor. Subsequently, the electric current changed according to the increase in water temperature, which indicated a good agreement. In contrast, the surface roughness of the human skin coated with cosmetic cream was smoother than that without one. Therefore, if we apply the MCF rubber sensor to the human body, we can measure and evaluate the degree to which the skin is covered by cosmetics or the quality of hair with cuticles.

Temperature Sensing
The MCF rubber can be used for diverse sensing including the force sensing of temperature and a wide range of electromagnetic waves involving photovoltaics, irradiation, and infrared rays [4]. In this study, we investigated temperature sensing. We will present the investigations on photovoltaics and irradiation in subsequent reports [21].
As Figure 22a shows, we measured the electric current as the piezo-resistivity of the MCF rubber sensor immersed in water into which hot water was poured. The MCF rubber sensor and measurement method were the same as described in the previous section. We simultaneously measured the temperature adjacent to the MCF rubber sensor using a thermocouple. Figure 22b shows the change in the electric current as a function of water temperature. At the initiative period of less than approximately 2 s, the electric current was independent of the increase in water temperature because of the buffer of the outer shell of the Q rubber coat around the MCF rubber sensor. Subsequently, the electric current changed according to the increase in water temperature, which indicated a good agreement. Sensors 2020, 20,

Conclusions
An MCF rubber sensor produced using the consummate fabrication process presented in the last report is sensitive to both normal and shear forces. Therefore, it can be used for haptic sensing of diverse objects using either normal or shear motions. In addition, the MCF rubber sensor is sensitive to softness and temperature. The unclear inclination of the texture of the surfaces of paper, cloth, skin applied with cosmetics, etc., can be clarified using the MCF rubber sensor. The novelty of the present report is the feasibility of sensing the shear force and the softness of the object by stretchable and elastic rubber made of a single material. Our proposed sensing technique could contribute to the enterprising development of their production.
Using shear motion, the electric current of the MCF rubber sensor reacts to the convex and concave shapes of the object. Subsequently, the friction coefficient can be measured using the MCF rubber sensor and it is non-linear because of the repeated deformation and restoration of the multilayered MCF rubber sensor by the force created between the layers under shear motion. The electric current can be evaluated by the same ordinary arithmetic values such as Ra,E, Rq,E, and Ry,E on its roughness curve measured using an ordinary surface-roughness-measuring device: Ra, Rq, and Ry. Ra,E, Rq,E, and Ry,E are affected by the surface roughness of the object, sweeping velocity, and normal and shear forces. Because the outer dimensions of the MCF rubber sensor are reasonable (16.5 mm × 24 mm × 4.5 mm), the MCF rubber sensor can be installed on a fingerstall, is portable, and is useful in measuring the surface roughness of any automobile, airplane, and large ship that cannot be broken for measurement using ordinary surface-roughness-measuring devices. The MCF rubber sensor is a novel surface-roughness-measuring device.
For engineering applications using the MCF rubber sensor, we investigated the feasibility of the MCF rubber sensor for the haptic sensing of diverse surfaces under normal or shear motions.
First, for a soft body, using silicone gel, the electric current of the MCF rubber sensor can represent the softness or elasticity of the silicone gel under compression. Moreover, the electric current of the MCF rubber sensor under shear motion can indicate the friction coefficient of the silicone gel. The friction coefficient and elasticity are related; the friction coefficient to the elasticity has two peaks. In general, the relationship between normal and shear motions has not yet been investigated for soft objects. However, we can investigate the relationship between the elasticity and the friction coefficient of a soft object.
Second, the fineness of paper texture can be measured using the MCF rubber sensor under shear motion. Additionally, the sensor can be used to measure the surface roughness of a cloth as a typical fine and soft object, which an ordinary surface-roughness-measurement device cannot do. Thus, the MCF rubber sensor is applicable to the fields of paper and fashion or apparel manufacturing

Conclusions
An MCF rubber sensor produced using the consummate fabrication process presented in the last report is sensitive to both normal and shear forces. Therefore, it can be used for haptic sensing of diverse objects using either normal or shear motions. In addition, the MCF rubber sensor is sensitive to softness and temperature. The unclear inclination of the texture of the surfaces of paper, cloth, skin applied with cosmetics, etc., can be clarified using the MCF rubber sensor. The novelty of the present report is the feasibility of sensing the shear force and the softness of the object by stretchable and elastic rubber made of a single material. Our proposed sensing technique could contribute to the enterprising development of their production.
Using shear motion, the electric current of the MCF rubber sensor reacts to the convex and concave shapes of the object. Subsequently, the friction coefficient can be measured using the MCF rubber sensor and it is non-linear because of the repeated deformation and restoration of the multi-layered MCF rubber sensor by the force created between the layers under shear motion. The electric current can be evaluated by the same ordinary arithmetic values such as Ra ,E , Rq ,E , and Ry ,E on its roughness curve measured using an ordinary surface-roughness-measuring device: Ra, Rq, and Ry. Ra ,E , Rq ,E , and Ry ,E are affected by the surface roughness of the object, sweeping velocity, and normal and shear forces. Because the outer dimensions of the MCF rubber sensor are reasonable (16.5 mm × 24 mm × 4.5 mm), the MCF rubber sensor can be installed on a fingerstall, is portable, and is useful in measuring the surface roughness of any automobile, airplane, and large ship that cannot be broken for measurement using ordinary surface-roughness-measuring devices. The MCF rubber sensor is a novel surface-roughness-measuring device.
For engineering applications using the MCF rubber sensor, we investigated the feasibility of the MCF rubber sensor for the haptic sensing of diverse surfaces under normal or shear motions.
First, for a soft body, using silicone gel, the electric current of the MCF rubber sensor can represent the softness or elasticity of the silicone gel under compression. Moreover, the electric current of the MCF rubber sensor under shear motion can indicate the friction coefficient of the silicone gel. The friction coefficient and elasticity are related; the friction coefficient to the elasticity has two peaks. In general, the relationship between normal and shear motions has not yet been investigated for soft objects. However, we can investigate the relationship between the elasticity and the friction coefficient of a soft object.
Second, the fineness of paper texture can be measured using the MCF rubber sensor under shear motion. Additionally, the sensor can be used to measure the surface roughness of a cloth as a typical fine and soft object, which an ordinary surface-roughness-measurement device cannot do. Thus, the MCF rubber sensor is applicable to the fields of paper and fashion or apparel manufacturing industries. Until now, we determined the texture of paper and cloths by touching them with hands, through which the texture cannot be evaluated numerically. However, by using the MCF rubber sensor, their texture can be evaluated quantitatively by Ra ,E , Rq ,E , and Ry ,E .
Third, the MCF rubber sensor can capture the shapes of convexo-concave bodies, such as the surface of plant leaves and convexo-concave metal. Significantly small surface roughness, such as for a plant leaf, can be evaluated using Ra ,E , Rq ,E , and Ry ,E . However, large surface roughness, such as that of large convexo-concave metal bodies, can be measured directly.
Finally, the MCF rubber sensor can capture the convexo-concave shape of the human body and the surface roughness of skin to which cosmetics are applied. Therefore, if we apply the MCF rubber sensor to the human body, we can measure and evaluate the degree to which the skin is covered by cosmetics or the quality of hair with cuticles. Thus, the MCF rubber sensor is applicable to the cosmetics industry.
The MCF rubber sensor was observed to be effective in diverse haptic and temperature sensing. We expect that the MCF rubber applies to the force and temperature sensing for a wide range of electromagnetic waves involving photovoltaics, irradiation, and infrared rays. These investigations will be presented in subsequent reports. Thus, the MCF rubber sensor can be applied to a wide range of engineering fields. Furthermore, we can develop our proposing MCF rubber sensor with using the Artificial Intelligent (AI) model. The possibility that the sensing gets closer to the virtual sensing of the human skin might be facilitated. The technique would be expectable enough to be useful in the field of virtual sensing of skin installed in human being and robot.
Author Contributions: For this research article, K.S. conceived, designed, and performed the experiments, analyzed the data, and wrote the paper; R.I., H.K. and H.T. contributed reagents, materials, and analysis tools, as well as analyzed the data. All authors have read and agreed to the published version of the manuscript.
Funding: This work was supported in parts by JSPS KAKENHI Grant Number JP 18K04040 and by the Fukushima Innovation Coast Framework project "Namie Town Creation with Revitalizics using Risk Communication Engineering: for Realization of Innovation Coast Framework" in Japan.

Conflicts of Interest:
The founding sponsors had no role in the design of the study. The authors declare no conflict of interest. Figure A shows the experimental apparatus used to measure the electric current, voltage, or electric resistance between the opposing electrodes at the application of a normal force to the MCF rubber; the experiment is called NFE [20]. This was accomplished using an electric power supply of 10 V and electric resistance of 1.8 kΩ. The vulcanized MCF rubber was placed between the two electrodes, which were 7-mm stainless steel squares. The upper electrode was moved to be in contact with the lower electrode by an actuator at a pressing speed of 10 mm/min. industries. Until now, we determined the texture of paper and cloths by touching them with hands, through which the texture cannot be evaluated numerically. However, by using the MCF rubber sensor, their texture can be evaluated quantitatively by Ra,E, Rq,E, and Ry,E. Third, the MCF rubber sensor can capture the shapes of convexo-concave bodies, such as the surface of plant leaves and convexo-concave metal. Significantly small surface roughness, such as for a plant leaf, can be evaluated using Ra,E, Rq,E, and Ry,E. However, large surface roughness, such as that of large convexo-concave metal bodies, can be measured directly.

Appendix A
Finally, the MCF rubber sensor can capture the convexo-concave shape of the human body and the surface roughness of skin to which cosmetics are applied. Therefore, if we apply the MCF rubber sensor to the human body, we can measure and evaluate the degree to which the skin is covered by cosmetics or the quality of hair with cuticles. Thus, the MCF rubber sensor is applicable to the cosmetics industry.
The MCF rubber sensor was observed to be effective in diverse haptic and temperature sensing. We expect that the MCF rubber applies to the force and temperature sensing for a wide range of electromagnetic waves involving photovoltaics, irradiation, and infrared rays. These investigations will be presented in subsequent reports. Thus, the MCF rubber sensor can be applied to a wide range of engineering fields. Furthermore, we can develop our proposing MCF rubber sensor with using the Artificial Intelligent (AI) model. The possibility that the sensing gets closer to the virtual sensing of the human skin might be facilitated. The technique would be expectable enough to be useful in the field of virtual sensing of skin installed in human being and robot.
Author Contributions: For this research article, K.S. conceived, designed, and performed the experiments, analyzed the data, and wrote the paper; R.I., H.K. and H.T. contributed reagents, materials, and analysis tools, as well as analyzed the data. All authors have read and agreed to the published version of the manuscript.
Funding: This work was supported in parts by JSPS KAKENHI Grant Number JP 18K04040 and by the Fukushima Innovation Coast Framework project "Namie Town Creation with Revitalizics using Risk Communication Engineering: for Realization of Innovation Coast Framework" in Japan.

Conflicts of Interest:
The founding sponsors had no role in the design of the study. The authors declare no conflict of interest. Figure A shows the experimental apparatus used to measure the electric current, voltage, or electric resistance between the opposing electrodes at the application of a normal force to the MCF rubber; the experiment is called NFE [20]. This was accomplished using an electric power supply of 10 V and electric resistance of 1.8 kΩ. The vulcanized MCF rubber was placed between the two electrodes, which were 7-mm stainless steel squares. The upper electrode was moved to be in contact with the lower electrode by an actuator at a pressing speed of 10 mm/min. Figure A1. Schematic of the experimental apparatus used to investigate the electric characteristics in the NFE [20]. Figure B shows the experimental apparatus used to measure the electric current, voltage, or electric resistance between the opposing electrodes at the application of a shear force to the MCF rubber; this experiment is called SFE [20]. This was accomplished using an electric power supply of 10 V and an electric resistance of 1.8 kΩ. The MCF rubber sensor was placed under an acrylic resin body on which two electrodes of the stainless plate were attached. The MCF rubber sensor contacted a rubbing object and was moved parallel to the object surface by an actuator at a speed and a sweeping distance of 50 mm.

Appendix B
Sensors 2020, 20, x 23 of 24 Figure A1. Schematic of the experimental apparatus used to investigate the electric characteristics in the NFE [20]. Figure B shows the experimental apparatus used to measure the electric current, voltage, or electric resistance between the opposing electrodes at the application of a shear force to the MCF rubber; this experiment is called SFE [20]. This was accomplished using an electric power supply of 10 V and an electric resistance of 1.8 kΩ. The MCF rubber sensor was placed under an acrylic resin body on which two electrodes of the stainless plate were attached. The MCF rubber sensor contacted a rubbing object and was moved parallel to the object surface by an actuator at a speed and a sweeping distance of 50 mm. Figure A2. Schematic of the experimental apparatus used to investigate the electric characteristics in the SFE [20]. Figure A2. Schematic of the experimental apparatus used to investigate the electric characteristics in the SFE [20].