Nickel(II) Coordination Polymers Supported by Bis-pyridyl-bis-amide and Angular Dicarboxylate Ligands: Role of Ligand Flexibility in Iodine Adsorption

Reactions of N‚N’-bis(3-pyridylmethyl)oxalamide (L1), N‚N’-bis(4-pyridylmethyl)oxalamide (L2), or N,N’-bis(3-pyridylmethyl)adipoamide) (L3) with angular dicarboxylic acids and Ni(II) salts under hydro(solvo)thermal conditions afforded a series of coordination polymers: {[Ni(L1)(OBA)(H2O)]·H2O}n (H2OBA = 4,4-oxydibenzoic acid), 1, {[Ni(L1)(SDA)(H2O)2]·H2O·CH3OH}n (H2SDA = 4,4-sulfonyldibenzoic acid), 2, {[Ni(L2)(OBA)]·C2H5OH}n, 3, {[Ni(L2)(OBA)]·CH3OH}n, 4, {[Ni2(L2)(SDA)2(H2O)3]·5H2O}n, 5, {[Ni2(L2)(SDA)2(H2O)3]·H2O·2C2H5OH}n, 6, {[Ni(L3)(OBA)(H2O)2]·2H2O}n, 7, {[Ni(L3)(SDA)(H2O)2]·2H2O}n, 8, and {[Ni(L3)0.5(SDA)(H2O)2]·0.5C2H5OH}n, 9, which have been structurally characterized by using single-crystal X-ray crystallography. Complex 1 exhibits an interdigitated 2D layer with the 2,4L2 topology and 2 is a 2D layer with the sql topology, while 3 and 4 are 3D frameworks resulting from polycatenated 2D nets with the sql topology and 5 and 6 are 2-fold interpenetrated 3D frameworks with the dia topology. Complexes 7 and 8 are 1D looped chains and 9 is a 2D layer with the 3,4L13 topology. The various structural types in 1–9 indicate that the structural diversity is subject to the flexibility and donor atom position of the neutral spacer ligands and the identity of the angular dicarboxylate ligands, while the role of the solvent is uncertain. The iodine adsorption of 1–9 was also investigated, demonstrating that that the flexibility of the spacer L1–L3 ligands can be an important factor that governs the feasibility of the iodine adsorption. Moreover, complex 9 shows a better iodine adsorption and encapsulates 166.55 mg g−1 iodine in the vapor phase at 60 °C, which corresponded to 0.38 molecules of iodine per formula unit.


Introduction
Coordination polymers (CPs) have rapidly developed into an active area of chemical research, not only for their interesting structures and distinctive topologies, but also potential applications in diverse areas such as gas storage, drug delivery, catalysis, luminescence sensing, and ionic conductivity [1][2][3][4]. The coordinate covalent bonds that link the metal ions and the spacer ligands result in multi-dimensional networks, which are also subject to the nature of hydrogen bonding and other weak interactions. Entanglement is a widely known phenomenon in the crystal engineering of CPs, because the self-assembled structures usually try to fill the space as much as possible to increase the stability of the structure. Three main entanglements involving interpenetration, polycatenation, and selfcatenation [5] have been shown, while interdigitation represents that part of an adjacent identical structure is interlaced into the space of the other without interlock. Although many CPs with interesting structures and properties have been reported, the control of their dimensionality and structural type is still a challenge and a great effort is necessary for the ongoing investigation.
Radioactive iodine such as 129 I represents one of the most critical fission products in nuclear waste disposal, which has a long radioactive half-life and is harmful to human health. Therefore, these iodine species have to be captured and disposed of effectively [6][7][8]. However, limited adsorption ability, high cost, and environmental issues with the materials under investigation has created demand for developing alternative materials. On the other hand, CPs showing tailorable structures and possessing pores may facilitate iodine adsorption through noncovalent interactions involving iodine and various sorption sites such as amino functionalities [6][7][8].
We have been committed to the synthesis and structural characterization of bispyridyl-bis-amide (bpba) ligands containing pyridyl nitrogen atoms and amide groups linked by different-(CH2)n-backbones [9][10][11][12]. Modification of ligand flexibility has been found important in changing the structural diversity. In this report, the L 1 -L 3 ligands with different flexibility (Figure 1) were reacted with the metal salts, together with the angular dicarboxylic acid, to explore the structural diversity of nine Ni(II) CPs in mixed-ligand systems. The effect of flexibility and the donor atom position of the spacer ligands on the structural diversity and iodine adsorption were also investigated.

Crystal Structure of 1
The single-crystal X-ray diffraction analysis showed that 1 crystallizes in the triclinic space group Pī. The asymmetric unit comprises one Ni(II) cation, one L 1 ligand, one OBA 2− ligand, and one coordinated and one co-crystallized water molecule. Figure 2a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from two L 1 ligands [Ni-N = 2.064(2) − 2.090(2) Å], three oxygen atoms from two OBA 2− ligands [Ni-O = 2.039(16) − 2.195 (16) Å], and one oxygen atom from the coordination water [Ni-O = 2.100(17) Å]. The Ni(II) cations are linked by the OBA 2− and L 1 ligands to form a 2D layer. If the Ni(II) units are defined as 4-connected nodes and the OBA 2− as 2-connected nodes, the structure can be simplified as a 2,4-connected net with the 2,4L2 topology (Figure 2b), determined using ToposPro [13]. Figure 2c shows the interdigitation.

Crystal Structure of 1
The single-crystal X-ray diffraction analysis showed that 1 crystallizes in the triclinic space group Pī. The asymmetric unit comprises one Ni(II) cation, one L 1 ligand, one OBA 2− ligand, and one coordinated and one co-crystallized water molecule. Figure 2a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from two L 1 ligands [Ni-N = 2.064 (2)

Structure of 2
The crystal structure of 2 was solved in the triclinic space group Pī, revealing that each asymmetric unit consists of one Ni(II) cation, one L 1 ligand, one SDA 2− ligand, two coordinated and one co-crystallized water molecule, and one MeOH molecule. Figure 3a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from L 1 ligands [Ni-N = 2.104 (19)

Structure of 2
The crystal structure of 2 was solved in the triclinic space group Pī, revealing that each asymmetric unit consists of one Ni(II) cation, one L 1 ligand, one SDA 2− ligand, two coordinated and one co-crystallized water molecule, and one MeOH molecule. Figure 3a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from L 1 ligands [Ni-N = 2.104 (19)

Structure of 2
The crystal structure of 2 was solved in the triclinic space group Pī, revealing that each asymmetric unit consists of one Ni(II) cation, one L 1 ligand, one SDA 2− ligand, two coordinated and one co-crystallized water molecule, and one MeOH molecule. Figure 3a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from L 1 ligands [Ni-N = 2.104 (19)

Structures of 3 and 4
Structures of 3 and 4 are similar but different in the co-crystallized solvents. Crystals of 3 and 4 conform to the monoclinic space group P21/c and each asymmetric unit contains one Ni(II) cation, one L 2 ligand, one OBA 2− ligand, and one co-crystallized solvent molecule (EtOH, 3; MeOH, 4). Figure 4a displays a representative coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from two L 2 ligands [Ni-N = 2.057(2) and 2.064(2) Å, 3; 2.050 (16)

Structures of 3 and 4
Structures of 3 and 4 are similar but different in the co-crystallized solvents. Crystals of 3 and 4 conform to the monoclinic space group P21/c and each asymmetric unit contains one Ni(II) cation, one L 2 ligand, one OBA 2− ligand, and one co-crystallized solvent molecule (EtOH, 3; MeOH, 4).

Structure of 5 and 6
The structures of complexes 5 and 6 are similar but different in the co-crystallized solvents. Single-crystal X-ray diffraction analysis showed that 5 and 6 crystallize in the triclinic space group Pī. Each asymmetric unit consists of two Ni(II) cations, one L 2 ligand, one SDA 2− ligand, and three coordinated water molecules (two terminal and one bridging), together with five co-crystallized water molecules in 5 and one co-crystallized water molecule and two EtOH molecules in 6, respectively. Figure 5a shows a representative coordination environment of the two Ni(II) metal centers. While the Ni(1) atom is sixcoordinated by two nitrogen atoms from two L 2 ligands [Ni-N = 2.087(2) and 2.120(2) Å,

Structure of 5 and 6
The structures of complexes 5 and 6 are similar but different in the co-crystallized solvents. Single-crystal X-ray diffraction analysis showed that 5 and 6 crystallize in the triclinic space group Pī. Each asymmetric unit consists of two Ni(II) cations, one L 2 ligand, one SDA 2− ligand, and three coordinated water molecules (two terminal and one bridging), together with five co-crystallized water molecules in 5 and one co-crystallized water molecule and two EtOH molecules in 6, respectively. Figure 5a shows a representative coordination environment of the two Ni(II) metal centers. While the Ni(1) atom is six-coordinated by two nitrogen atoms from two L 2 ligands [Ni-N = 2.087(2) and 2.120 (2)

Structure of 5 and 6
The structures of complexes 5 and 6 are similar but different in the co-crystallized solvents. Single-crystal X-ray diffraction analysis showed that 5 and 6 crystallize in the triclinic space group Pī. Each asymmetric unit consists of two Ni(II) cations, one L 2 ligand, one SDA 2− ligand, and three coordinated water molecules (two terminal and one bridging), together with five co-crystallized water molecules in 5 and one co-crystallized water molecule and two EtOH molecules in 6, respectively. Figure 5a shows a representative coordination environment of the two Ni(II) metal centers. While the Ni(1) atom is sixcoordinated by two nitrogen atoms from two L 2 ligands [Ni-N = 2.087(2) and 2.120 (2)

Structure of 7
The single-crystal X-ray diffraction analysis showed that 7 crystallizes in the monoclinic space group C2/c, with each asymmetric unit consisting of one Ni(II) cation, one L 3 ligand, one OBA 2− ligand, and one coordinated and two co-crystallized water molecules. Figure 6a shows the coordination environment of the Ni(II) metal center, which is sixcoordinated by two nitrogen atoms from two L 3 showing the 2-fold interpenetration.

Structure of 7
The single-crystal X-ray diffraction analysis showed that 7 crystallizes in the monoclinic space group C2/c, with each asymmetric unit consisting of one Ni(II) cation, one L 3 ligand, one OBA 2− ligand, and one coordinated and two co-crystallized water molecules. Figure 6a shows the coordination environment of the Ni(II) metal center, which is sixcoordinated by two nitrogen atoms from two L 3

Structure of 7
The single-crystal X-ray diffraction analysis showed that 7 crystallizes in the monoclinic space group C2/c, with each asymmetric unit consisting of one Ni(II) cation, one L 3 ligand, one OBA 2− ligand, and one coordinated and two co-crystallized water molecules. Figure 6a shows the coordination environment of the Ni(II) metal center, which is sixcoordinated by two nitrogen atoms from two L 3  2.6. Structure of 8 Crystals of 8 conform to the monoclinic space group C2/c, with each asymmetric unit consisting of one Ni(II) cation, one L 3 ligand, one SDA 2− ligand, and two coordinated and

Structure of 8
Crystals of 8 conform to the monoclinic space group C2/c, with each asymmetric unit consisting of one Ni(II) cation, one L 3 ligand, one SDA 2− ligand, and two coordinated and two co-crystallized water molecules. Figure 7a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from two L 3 ligands

Structure of 8
Crystals of 8 conform to the monoclinic space group C2/c, with each asymmetric unit consisting of one Ni(II) cation, one L 3 ligand, one SDA 2− ligand, and two coordinated and two co-crystallized water molecules. Figure 7a shows the coordination environment of the Ni(II) metal center, which is six-coordinated by two nitrogen atoms from two L 3

Structure of 9
The single-crystal X-ray diffraction analysis showed that 9 crystallizes in the triclinic space group Pī. The asymmetric unit consists of one Ni(II) cation, a half L 3 ligand, one SDA 2− ligand, two coordinated water molecules, and a half co-crystallized EtOH molecule. Figure 8a shows the coordination environment of the Ni(II) metal center, which is sixcoordinated by one nitrogen atom from one L 3 ligand [Ni-N = 2.098 (2)

Structure of 9
The single-crystal X-ray diffraction analysis showed that 9 crystallizes in the triclinic space group Pī. The asymmetric unit consists of one Ni(II) cation, a half L 3 ligand, one SDA 2− ligand, two coordinated water molecules, and a half co-crystallized EtOH molecule. Figure 8a shows the coordination environment of the Ni(II) metal center, which is sixcoordinated by one nitrogen atom from one L 3 ligand [Ni-N = 2.098 (2)

Ligand Conformations and Coordination Modes
By calculating the torsion angles of the long carbon chain and evaluating the orientations of the pyridyl rings and carbonyl group, the conformations of the bpba ligands can be expressed as follows [14]: When the torsion angle is 0 ≤ θ ≤ 90°, it is defined as gauche (G), and 90 < θ ≤ 180° as anti (A). Additionally, cis and trans conformations can also be shown if the two C=O groups are in the same and the opposite direction, respectively. Due to the different orientations adopted by the pyridyl nitrogen atoms and the amide oxygen atoms, three more conformations, syn-syn, syn-anti, and anti-anti, can also be found for bpba. Table 1 lists the ligand conformations and coordination modes of the organic ligands in complexes 1-9. Noticeably, the L 1 , L 2 , and L 3 ligands in 1-8 bridge two metal ions through two pyridyl nitrogen atoms, while the L 3 ligand of 9 bridges four metal ions through two pyridyl nitrogen atoms and two amide oxygen atoms. The bpba ligands that bridge four metal ions are rare and can be found for the bis(N-pyrid-3-ylmethyl)suberoamide (L) in {[Cd(L)(1,4-NDC)]·2H2O}n (1,4-H2NDC = naphthalene-1,4-dicarboxylic acid) and {[Cd2(L)(1,4-NDC)2]·3H2O}n [15].
The OBA 2− and SDA 2− ligands show variable coordination modes. In 1, the OBA 2− ligand bridges two Ni(II) ions with one chelation mode, while the dicarboxylate ligands in 2 and 7-9 bridge two Ni(II) ions, and each of the two carboxylate groups coordinates one Ni(II) ion through one oxygen atom. In 3 and 4, the OBA 2− ligands bridge two Ni(II) ions with two chelation modes, while in 5 and 6, the SDA 2− ligands bridge three Ni(II) ions, leaving one of the carboxylate oxygen atoms uncoordinated. Structural comparisons show that for the complexes with L 1 (1 and 2) or L 2 (3)(4)(5)(6) ligands, the structural diversity is subject to the change of the angular dicarboxylate ligand, while the solvent is not influential. However, the structural diversity of those containing L 3 (7-9) is subject to the changes of both the angular dicarboxylate ligand and solvent. The different structural

Ligand Conformations and Coordination Modes
By calculating the torsion angles of the long carbon chain and evaluating the orientations of the pyridyl rings and carbonyl group, the conformations of the bpba ligands can be expressed as follows [14]: When the torsion angle is 0 ≤ θ ≤ 90 • , it is defined as gauche (G), and 90 < θ ≤ 180 • as anti (A). Additionally, cis and trans conformations can also be shown if the two C=O groups are in the same and the opposite direction, respectively. Due to the different orientations adopted by the pyridyl nitrogen atoms and the amide oxygen atoms, three more conformations, syn-syn, syn-anti, and anti-anti, can also be found for bpba. Table 1 lists the ligand conformations and coordination modes of the organic ligands in complexes 1-9. Noticeably, the L 1 , L 2 , and L 3 ligands in 1-8 bridge two metal ions through two pyridyl nitrogen atoms, while the L 3 ligand of 9 bridges four metal ions through two pyridyl nitrogen atoms and two amide oxygen atoms. The bpba ligands that bridge four metal ions are rare and can be found for the bis(N-pyrid-3-ylmethyl)suberoamide (L) in {[Cd(L)(1,4-NDC)]·2H 2 O} n (1,4-H 2 NDC = naphthalene-1,4-dicarboxylic acid) and {[Cd 2 (L)(1,4-NDC) 2 ]·3H 2 O} n [15].
The OBA 2− and SDA 2− ligands show variable coordination modes. In 1, the OBA 2− ligand bridges two Ni(II) ions with one chelation mode, while the dicarboxylate ligands in 2 and 7-9 bridge two Ni(II) ions, and each of the two carboxylate groups coordinates one Ni(II) ion through one oxygen atom. In 3 and 4, the OBA 2− ligands bridge two Ni(II) ions with two chelation modes, while in 5 and 6, the SDA 2− ligands bridge three Ni(II) ions, leaving one of the carboxylate oxygen atoms uncoordinated. Structural comparisons show that for the complexes with L 1 (1 and 2) or L 2 (3-6) ligands, the structural diversity is subject to the change of the angular dicarboxylate ligand, while the solvent is not influential. However, the structural diversity of those containing L 3 (7-9) is subject to the changes of both the angular dicarboxylate ligand and solvent. The different structural types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-trans-syn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. GAG-trans-syn-anti μ2-κO:κO' trans types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. GAG-trans-syn-anti μ2-κO:κO' trans types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. AAA-trans-syn-syn types between 8 and 9 demonstrate that the ligand conformation of the flexible L 3 is subject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively. ject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively.

GAG-trans-syn-anti μ2-κO:κO'
AAA-trans-syn-syn ject to the change of the solvent identity, resulting in AAA-trans-syn-syn and GAG-transsyn-anti and leading to the formation of a 1D looped chain and 2D layer, respectively.

PXRD Patterns and Thermal Analysis
The experimental PXRD patterns of complexes 1-9 ( Supplementary Figures S1-S9) match well with their corresponding simulated ones, which demonstrates that the purities of the bulk samples are good enough for further use. On the other hand, thermal gravimetric analysis (TGA) was carried out to examine the thermal decomposition of complexes 1-9. The TGA curves are shown in Supplementary Figures S10-S18, and Table 2 lists the decomposition temperatures, showing two-step decomposition and indicating that the decomposition temperatures for organic ligands of the frameworks of 3 and 4 with the polycatenated frameworks are much higher among 1-9.

Iodine Adsorption
Complexes 7-9 provide a unique opportunity to investigate the degree of iodine adsorption of bpba-based Ni(II) CPs, which have been executed at 25 and 60 • C and with time intervals of 30, 60, 120, 180, and 360 min, respectively. For each experiment, 0.05 mmol of the complex was placed in a 5 mL sample bottle inside a 50 mL one containing 100 mg of iodine, which was sealed, kept in the oven, and heated. The I 2 -adsorbed complex was then weighted and the amount of adsorbed I 2 was calculated. Each experiment was repeated three times and the results were averaged (Supplementary Tables S1-S6). At 25 • C, the color of complex 7 changed from blue to green, while the color changed from blue to yellow at 60 • C (Supplementary Figure S19). Complex 8 showed no color change at 25 and 60 • C (Supplementary Figure S20), while the color of complex 9 changed from green to dark brown at these two temperatures (Supplementary Figure S21). Figures 9-11 display the average weight changes per gram of 7-9 upon iodine adsorption at different time intervals and at 25 and 60 • C, respectively, while Table 3 summarizes the results, showing that the adsorption capacities of 7 and 8 are much poorer than 9. With the increase of temperature from 25 to 60 • C, the absorption rate of iodine also showed a good increase for each complex. The different iodine adsorption capacities can be ascribed to their different diversity, which are 1D chains for 7 and 8 and a 2D layer for 9, respectively, showing a maximum adsorption factor of 166.55 mg g −1 for complex 9 at 60 • C for 360 min, corresponding to 0.38 iodine molecules per unit cell. Powder X-ray diffraction (PXRD) patterns of the I 2 -adsorbed complexes 7-9 have been measured to confirm their stability. As shown in Supplementary Figures S22-S24, most of the experimental patterns are consistent with the theoretical ones, indicating that these iodine-adsorbed complexes remain stable. Only the PXRD patterns of 8 at 60 • C showed some changes after 180 min. diffraction (PXRD) patterns of the I2-adsorbed complexes 7-9 have been measured to confirm their stability. As shown in Supplementary Figures S22-S24, most of the experimental patterns are consistent with the theoretical ones, indicating that these iodine-adsorbed complexes remain stable. Only the PXRD patterns of 8 at 60 °C showed some changes after 180 min.   diffraction (PXRD) patterns of the I2-adsorbed complexes 7-9 have been measured to confirm their stability. As shown in Supplementary Figures S22-S24, most of the experimental patterns are consistent with the theoretical ones, indicating that these iodine-adsorbed complexes remain stable. Only the PXRD patterns of 8 at 60 °C showed some changes after 180 min.   diffraction (PXRD) patterns of the I2-adsorbed complexes 7-9 have been measured to con firm their stability. As shown in Supplementary Figures S22-S24, most of the experimenta patterns are consistent with the theoretical ones, indicating that these iodine-adsorbed complexes remain stable. Only the PXRD patterns of 8 at 60 °C showed some changes afte 180 min.    Energy dispersive X-ray (EDX) analysis of complexes 7-9 was performed after iodine adsorption (Supplementary Figures S25-S27), confirming the iodine uptake of 7-9. The iodine-adsorbed samples of 7-9 can be regarded as the mixtures of iodine and their corresponding complexes. As expected, the amounts of iodine elements were different at three different spots of the samples selected for measurement, indicating the inhomogeneous distribution of iodine in the iodine-adsorbed samples. Table 4 shows the average weights and atomic percentages of the selected elements for the iodine-adsorbed 7-9, confirming that 9 displays the best iodine adsorption capacity. In addition, experiments have also been performed for complexes 1-6 to evaluate their iodine adsorption capacities. As shown in Supplementary Figures S28-S33, the colors of 1-6 remained unchanged at both 25 and 60 • C, indicating minor or no iodine absorption, supported by their EDX data that showed no detectable iodine element (Supplementary Figures S34-S39). The ability of the CPs to accommodate iodine molecules in the interchain/interlayer space perhaps governs the iodine adsorption capacity [16][17][18]. The solvent accessible volumes calculated by using the PLATON program [19] for 7-9 were 6.9, 9.3 and 13.7%, respectively, of the unit cell volume, indicating that the 2D 9 may accommodate more iodine than the 1D 7 and 8. However, as shown in Supplementary Table S7, the solvent accessible volumes of complexes 1-6 were comparable to those of 7-9, but these CPs revealed no iodine adsorption capacity, demonstrating the important role of the flexibility of the neutral spacer ligands, L 1 , L 2 , and L 3 , in determining the iodine adsorption capacities of 1-9. The more flexible L 3 ligand that resulted in the 2D layer 9 with the 3,4L13 topology may be more susceptible to the changes of the ligand conformation upon the attack of the iodine molecules and thus better to accommodate the iodine molecules. On the other hand, the entangled complexes 1-6 comprising the rigid L 1 and L 2 ligands are not vulnerable to the changes of the frameworks upon the iodine attack, allowing undetectable iodine adsorption.

Gas Adsorption
Low-pressure N 2 adsorption and desorption measurements were performed at 77 K for complexes 7-9, and their isotherms are shown in Supplementary Figures S40-S42, showing a Brunauer-Emmet-Teller (BET) surface area and Langmuir surface of 10.00 and 15.22 m 2 /g for 7, 9.04 and 14.47 m 2 /g for 8, and 10.00 and 15.88 m 2 /g for 9, respectively, indicating similar BET surface areas and Langmuir surfaces. match well with the corresponding simulated ones, indicating that the bulk samples are pure enough.
Single-crystal X-ray diffraction data for complexes 1-9 were collected on a Bruker AXS SMART APEX II CCD diffractometer with a graphite-monochromated MoKα (λ α = 0.71073 Å) radiation at 296 K [20]. Data reduction and absorption correction were performed by using standard methods with well-established computational procedures [21]. Some of the heavier atoms were located by the direct or Patterson method and the remaining atoms were found in a series of different Fourier maps and least-square refinements, while the hydrogen atoms were added by using the HADD command in SHELXTL. Basic information pertaining to crystal parameters and structure refinement is listed in Table 5.

Conclusions
Nine Ni(II) coordination polymers containing angular dicarboxylate ligands and bpba ligands with different flexibility and donor atom positions have been synthesized under hydro(solvo)thermal conditions. The various structural types in 1-9 showed that the structural diversity of these Ni(II) CPs is subject to the flexibility and donor atom position of the bpba ligands and the identity of the angular dicarboxylate ligands. The L 3 ligand of 9 adopted a rare coordination mode that bridges four metal ions through two pyridyl nitrogen atoms and two amide oxygen atoms. Complex 9 showed an iodine adsorption factor of 166.55 mg g −1 at 60 • C for 360 min, while that of 7 and 8 was low and 1-6 showed undetectable iodine adsorption, demonstrating that the flexibility of the bpba ligands is important in governing the iodine adsorption of the bpba-CPs supported by the angular dicarboxylate ligands.