Synthesis of Co3O4 Nanoparticles-Decorated Bi12O17Cl2 Hierarchical Microspheres for Enhanced Photocatalytic Degradation of RhB and BPA

Three-dimensional (3D) hierarchical microspheres of Bi12O17Cl2 (BOC) were prepared via a facile solvothermal method using a binary solvent for the photocatalytic degradation of Rhodamine-B (RhB) and Bisphenol-A (BPA). Co3O4 nanoparticles (NPs)-decorated BOC (Co3O4/BOC) heterostructures were synthesized to further enhance their photocatalytic performance. The microstructural, morphological, and compositional characterization showed that the BOC microspheres are composed of thin (~20 nm thick) nanosheets with a 3D hierarchical morphology and a high surface area. Compared to the pure BOC photocatalyst, the 20-Co3O4/BOC heterostructure showed enhanced degradation efficiency of RhB (97.4%) and BPA (88.4%). The radical trapping experiments confirmed that superoxide (•O2−) radicals played a primary role in the photocatalytic degradation of RhB and BPA. The enhanced photocatalytic performances of the hierarchical Co3O4/BOC heterostructure are attributable to the synergetic effects of the highly specific surface area, the extension of light absorption to the more visible light region, and the suppression of photoexcited electron-hole recombination. Our developed nanocomposites are beneficial for the construction of other bismuth-based compounds and their heterostructure for use in high-performance photocatalytic applications.


Introduction
Rapid industrialization and population growth has led to a tremendous increase in environmental pollutions. These pollutants mostly consist of hazardous Azo dyes and phenolic compounds. Rhodamine-B (RhB) cationic Azo dye is an anthraquinone derivative. It is highly stable and non-biodegradable in nature and is classified as a carcinogenic and neurotoxic substance [1]. Aside from dyes, the other frequently used compound is the colorless Bisphenol-A. It is a diphenylmethane derivative and a raw material that is widely used in the fabrication of numerous polymeric materials [2]. Long-term exposure of BPA causes endocrine, neurological, and reproductive developmental disorders [3]. Therefore, it is crucial to eradicate RhB and BPA before waste is discharged into water reservoirs and landfills. Pollution-free environmental remediation technologies to degrade these organic pollutants have attracted substantial attention [4]. Among them, visiblelight-driven photocatalytic technology has emerged as the most promising approach for wastewater cleaning and pollutant removal [5].
Recently, bismuth-based nanomaterials, such as BiPO 4 [6], Bi 2 O 2 CO 3 [7][8][9], Bi 4 Ti 3 O 12 [10], Bi 2 MoO 6 [11], Bi 2 WO 6 [12], Bi 2 O 3 [13], and BiOX (X = Cl, Br, I) [14,15], have attracted substantial attention for their use in photocatalytic applications, because O 2p and Bi 6s valence band hybridization not only narrows the bandgap but also enhances the mobility of photo-generated holes in the valence band. Similarly, a bismuth and oxygen-enriched bismuth-oxyhalide (Bi 12 O 17 Cl 2 (BOC)) is a typical tetragonal phase compound composed after 140 min and 175 min of visible light irradiation, respectively, compared to pure BOC and other composite samples. The improved photocatalytic degradation performance could be ascribed to the synergetic effects of the larger active area of hierarchical microsphere, the extended light absorption to visible light range with Co 3 O 4 NPs, and the suppression of e − -h + recombination caused by the p-n junction formation of Co 3 O 4 /BOC.

Results and Discussion
2.1. Structural, Morphological, and Elemental Analyses Figure 1 shows the morphology of the BOC fabricated with different volume ratios of ethylene glycol (EG) and ethyl alcohol (EtOH). BOC-1 (Figure 1a) synthesized in EG only and BOC-3 ( Figure 1c) prepared in mixtures of EG and EtOH both have uniform 3D architectures, whereas BOC-2 ( Figure 1b) prepared in pure EtOH solution shows a nanoparticle-like morphology with almost no agglomeration. Compared to BOC-1, the morphology of BOC-3 was more regular with a flower-like shape, and the size of the microflower was about 4 µm (Figure 1c). In addition, BOC-3 was also prepared with different solvothermal reaction times to understand the microspherical morphology growth and optimize the reaction time (discussed in Appendix A). BOC-3 synthesized following 6 h of solvothermal treatment was composed of many ultrathin nanosheets (inset of Figure 1), which is beneficial for photocatalytic degradation due to the increased specific surface area. Figure 1d shows the N 2 adsorption-desorption isotherms of BOC-1 (dark), BOC-2 (red), and BOC-3 (blue). The isotherm plots showed type-IV isotherm and hysteresis loop curves [32]. The S BET values of BOC-1, BOC-2, and BOC-3 were 8.914, 8.160, and 15.720 m 2 /g, respectively, indicating that BOC-3 had the largest specific surface area.  Figure 2a shows a FESEM image of the 20-Co3O4/BOC synthesized with 20 mg of Co3O4 NPs and BOC-3. Its hierarchical morphology was almost identical to that of BOC-3, and it was not affected by the incorporation of Co3O4 NPs during the synthesis process. To investigate the existence of the nanosized Co3O4 in the BOC hierarchical morphology,   O 4 NPs and BOC-3. Its hierarchical morphology was almost identical to that of BOC-3, and it was not affected by the incorporation of Co 3 O 4 NPs during the synthesis process. To investigate the existence of the nanosized Co 3 O 4 in the BOC hierarchical morphology, HRTEM measurements of 20-Co 3 O 4 /BOC were performed, as shown in Figure 2b. The results confirmed that the Co 3 O 4 NPs, which had an approximate diameter of 10 nm, were decorated on the surface of BOC. In the HRTEM, the fringe spacing of 0.23 nm belonged to the (222) crystal plane of Co 3 O 4 . By contrast, the fringe spacings of 0.272 nm and 0.31 nm, which respectively refer to the (200) and (117) crystal planes of BOC, have also been observed. Further, a high-angle annular dark-field (HAADF) image of 20-Co 3 O 4 /BOC was obtained (Figure 2c), in which the tiny black spots identified across the BOC surface indicated Co 3 O 4 NPs; this finding was further confirmed by EDX analysis in Figure 2d,e. These results confirmed the 0D/3D morphology of the prepared photocatalyst might be conducive to the photocatalytic performance of the Co 3 O 4 /BOC heterostructure. Moreover, the obtained EDS mapping spectrum ( Figure A2 in Appendix B) confirmed the presence of bismuth (Bi), oxygen (O), chlorine (Cl), and cobalt (Co) elements in the 20-Co 3 O 4 /BOC sample. The at.% and wt.% of the elements are also shown (inset table in Figure A2). Figure 2f presents the N 2 adsorption-desorption isotherm plots for 20-Co 3 O 4 /BOC. The estimated S BET using N 2 isotherms was found to be 14.873 m 2 /g, which was close to the S BET value of BOC-3. This result shows that the surface area of 20-Co 3 Figure 2h. All characteristic peaks of BOC have been observed in the Raman spectrum of pure BOC-3 [33]. The observed peak at 165.80 cm −1 belonged to the A 1g internal stretching of the Bi-Cl bond [33,34]. Because of the oxygen-rich nature of BOC-3, the observed peaks in the range from 200 cm −1 to 500 cm −1 belong to the vibrational modes of Bi and O bonding. Among them, The peak at 470.51 cm −1 is the characteristic vibrational mode of BOC-3, which belongs to O-Bi-O bending modes. Further, the peak at 598.80 cm −1 represents Cl-Cl stretching modes [35]. Regarding Co 3 O 4 NPs, all the characteristic peaks of Co 3 O 4 appeared in the Raman spectra, indicating the successful formation of Co 3 O 4 NPs, along with an extra peak at 481.15 cm −1 from the glass substrate. These observed peaks belonged to the F 2g and E g modes of the combined vibrations of the tetrahedral site and octahedral oxygen vibrations [36,37]  To analyze the chemical composition and chemical state of the elements, we performed X-ray photoelectron spectroscopy (XPS) of the 20-Co3O4/BOC heterostructure photocatalyst (Appendix C). The XPS survey spectrum clearly demonstrated that all peaks were attributable to Bi, O, Cl, and Co elements, revealing that the heterostructure consisted of Bi, O, Cl, and Co elements, as shown in Figure A3 (See Appendix C). The high-resolution XPS spectra of Bi 4f, C 1s, O 1s, and Co 2p for the heterostructure are respectively shown in Figure A3b-e. The two strong peaks at 159.63 and 164.93 eV were assigned to Bi 4f7/2 and Bi 4f5/2, respectively, which are the features of Bi 3+ in BOC ( Figure  A3b). As depicted in Figure A3c, the O 1s profile could be deconvoluted into three peaks, thus indicating the existence of three different kinds of O species in the sample. The peaks observed at 529.674 and 530.568 eV were assigned to the lattice oxygen metal bonds and hydroxyl ( • OH) functional groups in 20-Co3O4/BOC, respectively [39]; the peak at 531.592 eV corresponded to oxygen vacancies in Co3O4 in the 20-Co3O4/BOC composite sample [40]. Figure A3d shows the spectrum of Cl 2p, which contained diverse peaks at 198.58 To analyze the chemical composition and chemical state of the elements, we performed X-ray photoelectron spectroscopy (XPS) of the 20-Co 3 O 4 /BOC heterostructure photocatalyst (Appendix C). The XPS survey spectrum clearly demonstrated that all peaks were attributable to Bi, O, Cl, and Co elements, revealing that the heterostructure consisted of Bi, O, Cl, and Co elements, as shown in Figure A3 (See Appendix C). The high-resolution XPS spectra of Bi 4f, C 1s, O 1s, and Co 2p for the heterostructure are respectively shown in Figure A3b-e. The two strong peaks at 159.63 and 164.93 eV were assigned to Bi 4f 7/2 and Bi 4f 5/2 , respectively, which are the features of Bi 3+ in BOC ( Figure A3b). As depicted in Figure A3c, the O 1s profile could be deconvoluted into three peaks, thus indicating the existence of three different kinds of O species in the sample. The peaks observed at 529.674 and 530.568 eV were assigned to the lattice oxygen metal bonds and hydroxyl ( • OH) functional groups in 20-Co 3 O 4 /BOC, respectively [39]; the peak at 531.592 eV corresponded to oxygen vacancies in Co 3 O 4 in the 20-Co 3 O 4 /BOC composite sample [40]. Figure A3d shows the spectrum of Cl 2p, which contained diverse peaks at 198.58 and 200.139 eV, respectively. These can be attributed to Cl 2p 3/2 and Cl 2p 1/2 of the Cl − ions in the corresponding 20-Co 3 O 4 /BOC sample [41]. In Figure A3e, the Co 2p peak of 20-Co 3 O 4 /BOC showed Co 2p 3/2 and Co 2p 1/2 spin-orbit doublets. The peaks at 782.25 and 793.50 eV in 20-Co 3 O 4 /BOC corresponded to Co 2+ ions, whereas the peaks observed at 779.50 and 792.50 eV were assigned to Co 3+ ions, therefore indicating the coexistence of Co 2+ and Co 3+ in both samples [42].

Photocatalytic Performance
The photocatalytic performance of BOC-1, BOC-3, 10- where k, C 0 , and C represent the reaction rate constant, initial concentration, and remaining concentration at time t, respectively. Figure Figure 3c,d. The BPA degradation results showed that 20-Co 3 O 4 /BOC efficiently decomposed BPA aqueous pollutant solution in 170 min. Moreover, the degradation of BPA in the presence of each photocatalyst followed the 1st-order reaction kinetic model. Figure 3d shows the reaction rate and degradation efficiency after 110 min for all the photocatalysts used for BPA degradation. 20-Co 3 O 4 /BOC had the highest degradation rate of 1.66 × 10 −2 /min and an efficiency of 88.4%, followed by BOC-3, BOC-1, and BOC-2.
We further conducted a reusability test for the 20-Co 3 O 4 /BOC in the presence of RhB and BPA pollutants, as shown in Figure A4 (in Appendix D). During RhB and BPA degradation, a consistent decrease in the degradation of RhB and BPA occurred after the 3rd cycle of degradation, and its degradation performance was slightly reduced. This slight reduction in photocatalytic degradation may be attributable to the adsorption of RhB and BPA molecules on the surface of the 20-Co 3 O 4 /BOC sample.

Analysis of Enhanced Photocatalytic Activity of Co3O4/BOC
Photocatalytic activity is mainly attributed to light absorption capacity and the separation and transfer efficiency of photoinduced charge carriers. Firstly, photoluminescence (PL) measurements were conducted to investigate the recombination rate of photo-induced e − -h + pairs in BOC-3 and 20-Co3O4/BOC photocatalysts, as shown in Figure 4a. The PL emission intensity of 20-Co3O4/BOC was lower than that of BOC-3, thus indicating reduced recombination of e − -h + pairs in the 20-Co3O4/BOC photocatalyst. The transient photocurrent response was also measured to provide further support to the efficient separation of photo-generated charges, as shown in Figure 4b. The 20-Co3O4/BOC had a higher photocurrent response than BOC-3. The higher photocurrent response of 20-Co3O4/BOC was attributed to the higher separation efficiency of the excitons and its longer lifetime. Moreover, the EIS Nyquist plot was obtained to examine the electrode/electrolyte interfacial charge transfer resistance, as shown in Figure 4c. 20-Co3O4/BOC showed a smaller arc radius than BOC-3. The inset in Figure 4c shows the circuit of the samplesolution in the EIS measurements. According to the model of the circuit, Rs is related to uncompensated solution resistance, Rp is related to the porosity of the electrode, and Rct represents the charge transfer resistance at the interface [43]. The Rct values for BOC and 20-Co3O4/BOC are 1.58 × 10 −4 Ω and 82.93 × 10 −4 Ω, respectively. The smaller Rct value of 20-Co3O4/BOC represents its lower charge transfer resistance, which is beneficial for high redox reactions during photocatalysis.

Analysis of Enhanced Photocatalytic Activity of Co 3 O 4 /BOC
Photocatalytic activity is mainly attributed to light absorption capacity and the separation and transfer efficiency of photoinduced charge carriers. Firstly, photoluminescence (PL) measurements were conducted to investigate the recombination rate of photo-induced e − -h + pairs in BOC-3 and 20-Co 3 O 4 /BOC photocatalysts, as shown in Figure 4a. The PL emission intensity of 20-Co 3 O 4 /BOC was lower than that of BOC-3, thus indicating reduced recombination of e − -h + pairs in the 20-Co 3 O 4 /BOC photocatalyst. The transient photocurrent response was also measured to provide further support to the efficient separation of photo-generated charges, as shown in Figure 4b. The 20-Co 3 O 4 /BOC had a higher photocurrent response than BOC-3. The higher photocurrent response of 20-Co 3 O 4 /BOC was attributed to the higher separation efficiency of the excitons and its longer lifetime. Moreover, the EIS Nyquist plot was obtained to examine the electrode/electrolyte interfacial charge transfer resistance, as shown in Figure 4c. 20-Co 3 O 4 /BOC showed a smaller arc radius than BOC-3. The inset in Figure 4c shows the circuit of the sample-solution in the EIS measurements. According to the model of the circuit, R s is related to uncompensated solution resistance, R p is related to the porosity of the electrode, and R ct represents the charge transfer resistance at the interface [43]. Further, the UV-vis DRS of Co3O4, BOC-3, and 20-Co3O4/BOC were measured to investigate the optical absorption ability, as shown in Figure 4d. Co3O4 showed absorption throughout the whole UV and visible range. The absorption edges for BOC-3 were located around 520 nm. In comparison, 20-Co3O4/BOC showed enhanced absorption in the visible range after loading Co3O4 NPs on BOC. The high absorption of 20-Co3O4/BOC was attributed to the strong contribution of Co3O4 in 20-Co3O4/BOC to the absorption of visible light. Ultimately, these results suggest that the formation of the heterojunction in 20-Co3O4/BOC heterostructure could effectively suppress the recombination of the photoexcited charge carriers and enhance the visible light absorption ability. Therefore, the photocatalytic performance could effectively be improved by the 20-Co3O4/BOC heterostructure.

Interfacial Charge Transfer Behavior and Photocatalytic Reaction Mechanism
The electronic structures of Co3O4, BOC, and Co3O4/BOC were analyzed by UV-Vis diffuse reflectance spectra (DRS), the Mott-Schottky (MS) plot, and valence band (VB) XPS measurements to elucidate the photocatalytic mechanism of the 20-Co3O4/BOC heterostructure during the photodegradation of RhB and BPA, as shown in Figure 5. First, the optical bandgap energies of BOC-3 and Co3O4 could be obtained through curve fitting of the Tauc plot of (αhν) n/2 versus hν (Figure 5a), where n = 4 for the Co3O4 direct band gap semiconductor and n = 1 for the indirect band gap semiconductor [44,45]. The obtained bandgap energies were 2.34 and 2.25 eV for BOC-3 and Co3O4, respectively.
Secondly, the Fermi energy (Ef) levels of the prepared Co3O4 and BOC-3 were obtained using MS analysis, as shown in Figure 5b,c, respectively. The MS plots of Co3O4 and BOC-3 showed negative and positive slopes, thus indicating p-type and n-type

Interfacial Charge Transfer Behavior and Photocatalytic Reaction Mechanism
The electronic structures of Co 3 O 4 , BOC, and Co 3 O 4 /BOC were analyzed by UV-Vis diffuse reflectance spectra (DRS), the Mott-Schottky (MS) plot, and valence band (VB) XPS measurements to elucidate the photocatalytic mechanism of the 20-Co 3 O 4 /BOC heterostructure during the photodegradation of RhB and BPA, as shown in Figure 5. First, the optical bandgap energies of BOC-3 and Co 3 O 4 could be obtained through curve fitting of the Tauc plot of (αhν) n/2 versus hν (Figure 5a), where n = 4 for the Co 3 O 4 direct band gap semiconductor and n = 1 for the indirect band gap semiconductor [44,45]. The obtained bandgap energies were 2.34 and 2.25 eV for BOC-3 and Co 3 O 4 , respectively.
Secondly, the Fermi energy (E f ) levels of the prepared Co 3 O 4 and BOC-3 were obtained using MS analysis, as shown in Figure 5b,c, respectively. The MS plots of Co 3 O 4 and BOC-3 showed negative and positive slopes, thus indicating p-type and n-type semiconducting behaviors, respectively [46,47]. Further, by extrapolating MS plots, the flatband potentials of Co 3 O 4 and BOC-3 were found to be +0.037 and −0.51 V, respectively, vs. the standard calomel electrode (SCE). Note that the flatband potential (E fb ) of the n-type and p-type semiconductors represents the E f level. The E f level vs. the normal hydrogen electrode (NHE) scale could be calculated using Equation (2). The resultant E f of Co 3 O 4 and BOC-3 were +0.277 and −0.266 eV vs. NHE, respectively E fb (vs. NHE) = E fb (vs. SCE) + 0.244 (eV), Valence band (VB) XPS measurement was conducted to determine the VB potentials of Co 3 O 4 and BOC-3, as shown in Figure 5d. The VB XPS spectra revealed the VB maxima of 0.86 and 1.69 eV for Co 3 O 4 and BOC-3, respectively. Thus, the VB potentials with respect to the E f level were calculated to be 1.137 and 1.424 eV vs. NHE, respectively (Figure 6a). The CB minima of Co 3 O 4 and BOC-3 were determined using the following Equation (3).
where E CB , E VB , and E g denote the sample's CB potential, VB potential, and bandgap, respectively. As a result, the calculated CB potentials for Co 3 O 4 and BOC-3 were −1.113 and −0.916 eV vs. NHE, respectively.
semiconducting behaviors, respectively [46,47]. Further, by extrapolating MS plots, the flatband potentials of Co3O4 and BOC-3 were found to be +0.037 and −0.51 V, respectively, vs. the standard calomel electrode (SCE). Note that the flatband potential (Efb) of the ntype and p-type semiconductors represents the Ef level. The Ef level vs. the normal hydrogen electrode (NHE) scale could be calculated using Equation (2) Valence band (VB) XPS measurement was conducted to determine the VB potentials of Co3O4 and BOC-3, as shown in Figure 5d. The VB XPS spectra revealed the VB maxima of 0.86 and 1.69 eV for Co3O4 and BOC-3, respectively. Thus, the VB potentials with respect to the Ef level were calculated to be 1.137 and 1.424 eV vs. NHE, respectively (Figure 6a). The CB minima of Co3O4 and BOC-3 were determined using the following Equation (3).
where ECB, EVB, and Eg denote the sample's CB potential, VB potential, and bandgap, respectively. As a result, the calculated CB potentials for Co3O4 and BOC-3 were −1.113 and −0.916 eV vs. NHE, respectively. Therefore, based on the above analysis, we can obtain the band structures of Co3O4 and BOC in NHE scale before contact, as shown in Figure 6. When Co3O4 and BOC form the Co3O4/BOC heterojunction after they come into contact, the electrons will spontaneously migrate from BOC to Co3O4 through the Co3O4/BOC interface to align with the Fermi level because BOC has a higher Ef level than Co3O4. The migration of these electrons results in the band bending upward for BOC and downward for Co3O4, near the Therefore, based on the above analysis, we can obtain the band structures of Co 3 O 4 and BOC in NHE scale before contact, as shown in Figure 6. When Co 3 O 4 and BOC form the Co 3 O 4 /BOC heterojunction after they come into contact, the electrons will spontaneously migrate from BOC to Co 3 O 4 through the Co 3 O 4 /BOC interface to align with the Fermi level because BOC has a higher E f level than Co 3 O 4 . The migration of these electrons results in the band bending upward for BOC and downward for Co 3 O 4 , near the interface of BOC and Co 3 O 4 , respectively, as shown in Figure 6b. These band bendings lead to a depletion region at the Co 3 O 4 and BOC-3 interface, thus resulting in the generation of an internal electric field (IEF) from BOC toward Co 3 O 4 at the interface. After light is irradiated on the photocatalyst, the charge carriers simultaneously excite from VB to the CB in Co 3 O 4 and BOC-3 to produce photo-generated e − and h + pairs. Then, the photoexcited electrons in the CB of Co 3 O 4 will quickly migrate to the CB of BOC-3, whereas the remaining holes in the VB of BOC-3 will migrate to the VB of Co 3 O 4 because of the IEF directed from BOC to Co 3 O 4 in the 20-Co 3 O 4 /BOC, which is a typical charge transport of a type-II heterostructure. As a result, the e − -h + recombination is suppressed in the heterostructure system. Moreover, the unique 0D/3D morphology of 20-Co 3 O 4 /BOC will provide more active catalytic reaction centers and increase the active sites. Thus, the developed heterostructure could be suggested to be beneficial in photocatalytic degradation.
interface of BOC and Co3O4, respectively, as shown in Figure 6b. These band bendings lead to a depletion region at the Co3O4 and BOC-3 interface, thus resulting in the generation of an internal electric field (IEF) from BOC toward Co3O4 at the interface. After light is irradiated on the photocatalyst, the charge carriers simultaneously excite from VB to the CB in Co3O4 and BOC-3 to produce photo-generated e − and h + pairs. Then, the photoexcited electrons in the CB of Co3O4 will quickly migrate to the CB of BOC-3, whereas the remaining holes in the VB of BOC-3 will migrate to the VB of Co3O4 because of the IEF directed from BOC to Co3O4 in the 20-Co3O4/BOC, which is a typical charge transport of a type-II heterostructure. As a result, the e − -h + recombination is suppressed in the heterostructure system. Moreover, the unique 0D/3D morphology of 20-Co3O4/BOC will provide more active catalytic reaction centers and increase the active sites. Thus, the developed heterostructure could be suggested to be beneficial in photocatalytic degradation. Finally, photocatalytic active radical detection experiments were conducted to investigate the photocatalytic reaction mechanism and validate our proposed heterojunction formation, as depicted in Figure 7. Here, BQ, IPA, and KI were used as scavengers of • O2 − radicals, • OH radicals, and hole (h + ), respectively, which are produced during the photocatalytic degradation of RhB [48]. Since 20-Co3O4/BOC composite decomposed the RhB dye efficiently compared to the other photocatalysts (shown in Figure 3a), a 20-Co3O4/BOC photocatalyst sample was chosen for active radical detection. As shown in Figure 7, in the presence of BQ and IPA, the degradation efficiency of RhB was significantly reduced from 98% (no scavenger) to 68.5% and 86.2%, respectively. However, no effect on the degradation efficiency was observed when using KI as an h + scavenger. Therefore, • O2 − and • OH radicals were found to be the reactive species with increased generation of • O2 − during the photodegradation of RhB.
Based on the radical scavenger experiments, the possible reaction mechanism was proposed as shown in reaction (4)-(10); the excited electrons on BOC reduced the oxygen molecule (O2) into • O2 − radicals, and then the • O2 − radicals reacted with e-and hydrogen ions (H + ), ultimately resulting in the generation of hydrogen peroxide (H2O2) radical, which was further reduced to • OH and hydroxyl ion (OH − ). Then, the • O2 − , • OH, and OH − finally decomposed RhB and BPA into small chain molecules.
Co3O4 + hν  Co3O4 * (e − +h + ) (4) Finally, photocatalytic active radical detection experiments were conducted to investigate the photocatalytic reaction mechanism and validate our proposed heterojunction formation, as depicted in Figure 7. Here, BQ, IPA, and KI were used as scavengers of • O 2 − radicals, • OH radicals, and hole (h + ), respectively, which are produced during the photocatalytic degradation of RhB [48]. Since 20-Co 3 O 4 /BOC composite decomposed the RhB dye efficiently compared to the other photocatalysts (shown in Figure 3a), a 20-Co 3 O 4 /BOC photocatalyst sample was chosen for active radical detection. As shown in Figure 7, in the presence of BQ and IPA, the degradation efficiency of RhB was significantly reduced from 98% (no scavenger) to 68.5% and 86.2%, respectively. However, no effect on the degradation efficiency was observed when using KI as an h + scavenger. Therefore, • O 2 − and • OH radicals were found to be the reactive species with increased generation of • O 2 − during the photodegradation of RhB.

Preparation of Co3O4 Nanoparticles
The Co3O4 NPs were prepared by the solvothermal method [29]. In a typical synthesis, 80 mg of Co(CH3COO)2.4H2O was dissolved in 60 mL of EtOH using a magnetic stirrer. The prepared solution was then transferred to a 100 mL Teflon-lined autoclave and heated at 150 °C for 4 h in a thermal oven to initiate the solvothermal reaction. After completion of the reaction, the autoclave was allowed to cool down to room temperature, at which point the raw Co3O4 was washed with EtOH and centrifuged at 15,000 rpm for 30 min. Following centrifugation, the collected sample was dried at 60 °C overnight to obtain the Co3O4 NPs.

Preparation of Co 3 O 4 Nanoparticles
The Co 3 O 4 NPs were prepared by the solvothermal method [29]. In a typical synthesis, 80 mg of Co(CH 3 COO) 2 .4H 2 O was dissolved in 60 mL of EtOH using a magnetic stirrer. The prepared solution was then transferred to a 100 mL Teflon-lined autoclave and heated at 150 • C for 4 h in a thermal oven to initiate the solvothermal reaction. After completion of the reaction, the autoclave was allowed to cool down to room temperature, at which point the raw Co 3 O 4 was washed with EtOH and centrifuged at 15,000 rpm for 30 min. Following centrifugation, the collected sample was dried at 60 • C overnight to obtain the Co 3 O 4 NPs.

Preparation of BOC and Co 3 O 4 /BOC
BOC was prepared by a solvothermal method, as shown in Scheme 1a. In a typical synthesis method, 2.186 g (4.5 mmol) of Bi(NO 3 ) 3 .5H 2 O was dissolved in 17.5 mL of ethanol by ultrasonication, followed by stirring. The resulting solution was referred to as solution-A. At the same time, 1.5 mmol of KCl was dissolved in 17.5 mL of EG by ultrasonication, followed by stirring for 30 min. The resulting solution was referred to as solution-B. Next, solution-B was added dropwise to solution-A and then constantly stirred for 30 min. Then, the resulting combined solution was transferred to a 50 mL Teflon autoclave and heated for 6 h at 160 • C. The product obtained in this way was washed and dried overnight at 60 • C. Afterward, the gray powder was collected and calcinated in a muffle furnace at 450 • C for 1 h to obtain the targeted BOC hierarchical microspheres. The Co 3 O 4 /BOC samples were prepared using the identical synthesis procedure with the addition of Co 3 O 4 NPs (10, 20, and 40 mg) into the combined solution (see Scheme 1b). Moreover, the BOC sample was prepared in pure EG and EtOH solutions to investigate the roles of EG, EtOH, and EG-EtOH mixed solvents during BOC synthesis. The samples prepared in EG, EtOH, and EG-ETOH mixed solvents were labeled as BOC-1, BOC-2, and BOC-3, and the sample prepared with the addition of 10, 20, and 40 mg of

Preparation of BOC and Co3O4/BOC
BOC was prepared by a solvothermal method, as shown in Scheme 1a. In a typical synthesis method, 2.186 g (4.5 mmol) of Bi(NO3)3.5H2O was dissolved in 17.5 mL of ethanol by ultrasonication, followed by stirring. The resulting solution was referred to as solution-A. At the same time, 1.5 mmol of KCl was dissolved in 17.5 mL of EG by ultrasonication, followed by stirring for 30 min. The resulting solution was referred to as solution-B. Next, solution-B was added dropwise to solution-A and then constantly stirred for 30 min. Then, the resulting combined solution was transferred to a 50 mL Teflon autoclave and heated for 6 h at 160 °C. The product obtained in this way was washed and dried overnight at 60 °C. Afterward, the gray powder was collected and calcinated in a muffle furnace at 450 °C for 1 h to obtain the targeted BOC hierarchical microspheres. The Co3O4/BOC samples were prepared using the identical synthesis procedure with the addition of Co3O4 NPs (10, 20, and 40 mg) into the combined solution (see Scheme 1b). Moreover, the BOC sample was prepared in pure EG and EtOH solutions to investigate the roles of EG, EtOH, and EG-EtOH mixed solvents during BOC synthesis. The samples prepared in EG, EtOH, and EG-ETOH mixed solvents were labeled as BOC-1, BOC-2, and BOC-3, and the sample prepared with the addition of 10, 20, and 40 mg of Co3O4 NPs were labeled as 10-Co3O4/BOC, 20-Co3O4/BOC, and 40-Co3O4/BOC, respectively. Scheme 1. Synthesis of (a) nanoflower-like BOC, and (b) 0D/3D Co3O4/BOC hierarchical micro flower.

Characterization of Samples
The crystal structure and phase purity were characterized by powder X-ray diffraction (XRD) in the 2θ range from 10~80° (2° min −1 ) using an X-ray diffractometer (Rigaku D/MAX-2500) with a Cu Kα irradiation source (λ = 1.54178 Å) and X-ray power of 40 kV/30 mA. Micro-Raman spectroscopy (XperRAM100, Nanobase Inc., Seoul, Korea) equipped with a monochromatic laser source (wavelength of 532 nm and power of 6 mW) was used to characterize the crystalline phase. The morphologies were examined using a field emission scanning electron microscope (SEM) (JSM-6700F, Jeol Ltd., Tokyo, Japan) and a transmission electron microscope (TEM) ("NEOARM "/JEM-ARM200F, Jeol Ltd.) equipped with an energy dispersive spectroscope (EDX). X-ray photoemission spectroscopy (XPS) (Veresprobe II, ULVAC-PHI Inc., Kanagawa, Japan) with a Monochromatic Al Kα X-ray source was used to examine the chemical compositions of

Characterization of Samples
The crystal structure and phase purity were characterized by powder X-ray diffraction (XRD) in the 2θ range from 10~80 • (2 • min −1 ) using an X-ray diffractometer (Rigaku D/MAX-2500) with a Cu Kα irradiation source (λ = 1.54178 Å) and X-ray power of 40 kV/30 mA. Micro-Raman spectroscopy (XperRAM100, Nanobase Inc., Seoul, Korea) equipped with a monochromatic laser source (wavelength of 532 nm and power of 6 mW) was used to characterize the crystalline phase. The morphologies were examined using a field emission scanning electron microscope (SEM) (JSM-6700F, Jeol Ltd., Tokyo, Japan) and a transmission electron microscope (TEM) ("NEOARM "/JEM-ARM200F, Jeol Ltd.) equipped with an energy dispersive spectroscope (EDX). X-ray photoemission spectroscopy (XPS) (Veresprobe II, ULVAC-PHI Inc., Kanagawa, Japan) with a Monochromatic Al Kα X-ray source was used to examine the chemical compositions of the samples. The specific surface area was volumetrically assessed by measuring the nitrogen adsorption/desorption isotherms at 77 K using Microtrac, BELsorp-mini II. UV-vis diffuse reflectance spectra (DRS) were obtained using a spectrometer (V-750, Jasco Inc., Tokyo, Japan) equipped with a 60 mm integrating sphere while using BaSO 4 as a reference. Photoluminescence spectra (PL) were collected using a spectrophotometer (FS5 fluorescence, Edinburg, United Kingdom) with an excitation wavelength of 375 nm. Electrochemical impedance spectroscopy (EIS) was performed using a three-electrode workstation (VSP Potentiostat, Biologic, Seyssinet-Pariset, France). A pt square plate (1 × 2 cm 2 ) and a standard calomel were used as counter and reference electrodes, respectively. A clean fluorine-doped tin oxide (FTO) glass with an active surface area of 0.8 cm 2 was used as a substrate for the working electrode, whereas an aqueous solution of 0.5 M Na 2 SO 4 (80 mL) was used as the electrolyte. In the preparation of the working electrode, 0.1 mg of photocatalyst was added to 1 mL of DMF solution and sonicated for 1 h. Then, 50 µL of the dispersed solution was drop-casted on FTO and annealed at 160 • C for 1 h, which was further used in the electrochemical investigation.

Photocatalytic Activity Measurements
The photocatalytic characteristics of the samples were examined using a visible light source with a 300 W Xenon lamp (1000 W/m 2 ) (CEL-HXF300, CEAULIGHT Co., Beijing, China) equipped with a UV-IR cutoff filter (420 nm > λ > 780 nm). A double wall jacket beaker with a surface area of 80 cm 2 connected to a water chiller was used to perform the photocatalytic degradation measurement of the photocatalysts. The height from the surface of the pollutant solution to the light source was kept at 30 cm. In this study, RhB dye and BPA colorless pollutants were used to evaluate the degradation efficiency of the synthesized photocatalysts. Briefly, 20 and 40 mg of photocatalyst was used to degrade 40 mL of RhB dye (20 ppm) and BPA colorless pollutant (10 ppm), respectively. Before initiating the photocatalytic experiment, the RhB and BPA aqueous solutions were stirred for 60 min and 30 min, respectively, in dark conditions to attain an adsorption-desorption equilibrium of the photocatalysts. To investigate the photocatalytic degradation rate, 2 mL solution was taken from the RhB or BPA solution after a specific interval, and this solution was then centrifuged for 3 min at 5000 rpm to separate the photocatalyst, after which the absorbance spectrum of the supernatant using UV-visible spectrophotometer was measured. Further, radical trapping experiments were conducted to determine the dominant radical species involved in the photocatalytic decomposition of RhB and BPA. IPA, BQ, and KI of 2 mmol were used as trapping reagents to explore the active species, such as, • O 2 − , • OH radicals, and h +, respectively.

Conclusions
In this work, we successfully developed a 3D hierarchical BOC microsphere and a 0D/3D-Co 3 O 4 /BOC heterojunction photocatalyst composed of BOC decorated with Co 3 O 4 NPs using a simple solvothermal synthesis method. The developed heterostructure showed a conventional type II charge transport phenomenon across Co 3 O 4 and BOC-3 by forming a p-n heterojunction. The 0D/3D hierarchical morphology of the Co 3 O 4 /BOC could increase active sites because of its high surface area, suppressing e − -h + recombination, and improving visible light absorption. The results of mechanistic studies have proven that the generation of an IEF from BOC-3 to Co 3 O 4 led to a p-n junction and the formation of a type II heterojunction. Thus, benefiting from the above properties, the Co 3 O 4 /BOC sample demonstrated a higher reaction rate and a higher degradation efficiency than bare Co 3 O 4 and BOC during RhB and BPA degradation. Conclusively, our developed photocatalyst should be considered a good candidate for pollutant degradation.

Conflicts of Interest:
The authors declare no conflict of interest.

Appendix A
We also prepared BOC-3 in different solvothermal reaction times to explore the formation mechanism of the BOC microspherical morphology. Figure A1 represents the SEM images of the BOC samples prepared with solvothermal reaction times of 3, 6, 9, 12, and 18 h. The formation of a sphere-like morphology composed of ultrathin nanosheets could be observed after 3 h of solvothermal reaction ( Figure A1a). When the solvothermal reaction time increased to 6 h, the nanosheets grew further, thus increasing the diameter of the microspheres with clear visibility of ultrathin nanosheets ( Figure A1b). When the reaction time was increased to 9 h, the microspheres were covered with external BOC nanosheets, and the nanosheets did not grow further ( Figure A1c). The BOC nanosheets were covered with BOC nanosheets after increasing the hydrothermal reaction time to 12 h and 18 h, respectively ( Figure A1d,e). These results indicate that the formation of BOC microspheres quickly underwent nucleation, growth, and self-assembly.
Based on the above results, the formation of the BOC samples in the different solvent ratios proceeded as illustrated in Scheme 1. It could be concluded that Bi(NO 3 ) 3 ·5H 2 O will be hydrolyzed into [Bi 2 O 2 ] 2+ after dissolution in EtOH. Secondly, Cl − ions generated from KCl in EG solution could react with [Bi 2 O 2 ] 2+ to form Cl-Bi-O-Bi-Cl nuclei through the coulomb force during the solvothermal reaction [49], thus resulting in homogenous nucleation. As the reaction proceeded in the first 3 h of the solvothermal reaction time at 160 • C, the BOC nanosheets formed. These nanosheets formations could potentially have occurred due to the bonding of the OH functional group to Bi 3+ ions in Cl-Bi-O-Bi-Cl complex, which grew vertically along the c axis due to its intrinsic crystal structure. Since BOC has a known silane-type structure with a space group of P4/nmm and lattice constants of a = 5.4 Å and c = 35.20 Å, which are related to √ 2a s × √ 2b s × c s supercell, its layered structure was constructed through the combination of the 6-fold metal-oxygen (Bi-O) layer separated by the Cl layer [50]. Therefore, the formation of the nanosheets and their regulation with the OH functional group were considered to be favorable [51]. Thirdly, as the reaction progressed, the obtained nanosheets were assembled into microspheres, which could decrease the surface energy and achieve a stable structure. Finally, the hierarchical microspheres grew further and the size of the samples gradually increased.  Appendix B Figure A2. EDX spectrum of 20-Co3O4/BOC, and its elemental and atomic wt.% in the inset table. Figure A2. EDX spectrum of 20-Co 3 O 4 /BOC, and its elemental and atomic wt.% in the inset table.