Rhombohedral/Cubic In2O3 Phase Junction Hybridized with Polymeric Carbon Nitride for Photodegradation of Organic Pollutants

In recent studies, phase junctions constructed as photocatalysts have been found to possess great prospects for organic degradation with visible light. In this study, we designed an elaborate rhombohedral corundum/cubic In2O3 phase junction (named MIO) combined with polymeric carbon nitride (PCN) via an in situ calcination method. The performance of the MIO/PCN composites was measured by photodegradation of Rhodamine B under LED light (λ = 420 nm) irradiation. The excellent performance of MIO/PCN could be attributed to the intimate interface contact between MIO and PCN, which provides a reliable charge transmission channel, thereby improving the separation efficiency of charge carriers. Photocatalytic degradation experiments with different quenchers were also executed. The results suggest that the superoxide anion radicals (O2−) and hydroxyl radicals (·OH) played the main roles in the reaction, as opposed to the other scavengers. Moreover, the stability of the MIO/PCN composites was particularly good in the four cycling photocatalytic reactions. This work illustrates that MOF-modified materials have great potential for solving environmental pollution without creating secondary pollution.


Introduction
Organic dye pollutants in wastewater have constantly been a concern with the development of society [1][2][3]. Their toxicity and carcinogenicity always threaten ecological balance and biological health. The processing methods of organic dyes generally include adsorption, physical/chemical precipitation, biological methods, and photodegradation. Among them, solar-driven degradation by semiconductor photocatalysts has great potential in resolving organic dye pollution due to its convenience, eco-friendliness, and low cost [4,5]. It is well known that the most important part of photocatalysis is the catalysts because they accelerate the reaction process and improve the degradation efficiency in organic dye degradation reactions [6,7]. Therefore, photocatalysts working under visible light irradiation with outstanding photodegradation efficiency still need further exploration.
As an organic representative, polymeric carbon nitride (PCN) is a star material in photocatalysis owing to its suitable energy band position, excellent stability, and simple synthetic applications [8][9][10][11]. The extended π-conjugated systems consisting by sp 2 -hybridized C and N atoms have been widely used for studies on energy and the environment [12]. The suitable bandgap of PCN (2.7 eV) enables it to harvest visible light and surmount the endothermic character of water-splitting reactions (theoretically, 1.23 eV) [13]. However, as a non-metal photocatalyst, the insufficient capacity of charge carrier transfer results in the unsatisfactory photocatalytic ability of PCN [12,14]. Many strategies have been used to Int. J. Mol. Sci. 2022, 23, x FOR PEER REVIEW 3 of 14 radation reaction mechanism of MIO/PCN is discussed. This present strategy may promote new ideas for exploring the application field of the phase junction oxides and other related materials.

Results and Discussion
The crystal structure of x wt% MIO/PCN composites was confirmed by X-ray diffraction (XRD) analysis. As observed from the XRD pattern in Figure 1a, the crystal structure of the MIL-68(In)-NH2 precursor and MIO were in accordance with the previous report and no other characteristic peak was detected, respectively [31]. MIO calcined at 500 °C is composed of the mixed phase of rh-In2O3 (PDF No. 22-0336) and c-In2O3 (PDF No. 06-0416) [28]. And no other peaks appeared, indicating good purity of the In2O3 phase-junction. In Figure 1b, there were two characteristic diffraction peaks of the pure PCN sample located at 2θ = 12.8° and 27.3°, which corresponded to the (100) and (002) planes, respectively (JCPDS card No. 87-1526). The former was assigned to the packing motif of heptazine units in plane and the latter originated from the stacking of the conjugated aromatic system in the interlayer [18]. In the XRD patterns of MIO/PCN composites, the peak intensity of MIO became more muscular while the content of MIO increased. It was identified that MIO and PCN existed in the MIO/PCN composites. In addition, the peaks of the pure PCN sample located at 2θ = 27.3° moved to high degree, indicating that the spacing d was reduced according to the Bragg equation. That is because of the interaction between PCN and MIO and is beneficial to charge transfer [8].

Results and Discussion
The crystal structure of x wt% MIO/PCN composites was confirmed by X-ray diffraction (XRD) analysis. As observed from the XRD pattern in Figure 1a, the crystal structure of the MIL-68(In)-NH 2 precursor and MIO were in accordance with the previous report and no other characteristic peak was detected, respectively [31]. MIO calcined at 500 • C is composed of the mixed phase of rh-In 2 O 3 (PDF No. 22-0336) and c-In 2 O 3 (PDF No. 06-0416) [28]. And no other peaks appeared, indicating good purity of the In 2 O 3 phase-junction. In Figure 1b, there were two characteristic diffraction peaks of the pure PCN sample located at 2θ = 12.8 • and 27.3 • , which corresponded to the (100) and (002) planes, respectively (JCPDS card No. 87-1526). The former was assigned to the packing motif of heptazine units in plane and the latter originated from the stacking of the conjugated aromatic system in the interlayer [18]. In the XRD patterns of MIO/PCN composites, the peak intensity of MIO became more muscular while the content of MIO increased. It was identified that MIO and PCN existed in the MIO/PCN composites. In addition, the peaks of the pure PCN sample located at 2θ = 27.3 • moved to high degree, indicating that the spacing d was reduced according to the Bragg equation. That is because of the interaction between PCN and MIO and is beneficial to charge transfer [8].
radation reaction mechanism of MIO/PCN is discussed. This present strategy may promote new ideas for exploring the application field of the phase junction oxides and other related materials.

Results and Discussion
The crystal structure of x wt% MIO/PCN composites was confirmed by X-ray diffraction (XRD) analysis. As observed from the XRD pattern in Figure 1a, the crystal structure of the MIL-68(In)-NH2 precursor and MIO were in accordance with the previous report and no other characteristic peak was detected, respectively [31]. MIO calcined at 500 °C is composed of the mixed phase of rh-In2O3 (PDF No. 22-0336) and c-In2O3 (PDF No. 06-0416) [28]. And no other peaks appeared, indicating good purity of the In2O3 phase-junction. In Figure 1b, there were two characteristic diffraction peaks of the pure PCN sample located at 2θ = 12.8° and 27.3°, which corresponded to the (100) and (002) planes, respectively (JCPDS card No. 87-1526). The former was assigned to the packing motif of heptazine units in plane and the latter originated from the stacking of the conjugated aromatic system in the interlayer [18]. In the XRD patterns of MIO/PCN composites, the peak intensity of MIO became more muscular while the content of MIO increased. It was identified that MIO and PCN existed in the MIO/PCN composites. In addition, the peaks of the pure PCN sample located at 2θ = 27.3° moved to high degree, indicating that the spacing d was reduced according to the Bragg equation. That is because of the interaction between PCN and MIO and is beneficial to charge transfer [8].  The FT-IR spectra of PCN, MIO, and MIO/PCN are shown in Figure 2 to illustrate the information pertaining to functional groups. In the FT-IR spectra of PCN, the broad peaks located at 3000-3600 cm −1 indicate the stretching vibration of O-H, N-H, and hydrogenbonding interactions [38,39]. The characteristic peaks at 1200-1600 cm −1 correspond to the C-N skeleton of PCN. The breathing mode of the triazine units appeared at 800 cm −1 , meaning the presence of -NH and -NH 2 groups [39]. In that of MIO, the characteristic peaks at 570 cm −1 were determined to be In-O asymmetric stretching, and the peaks at 3000-3400 cm −1 correspond to the stretching vibration of the -OH hydrogen bond [11,34]. As shown in the FT-IR spectra of MIO/PCN, all the characteristic peaks of PCN appeared, indicating the main structure of PCN was not changed. Although the In-O peak was not observed, possibly because of the small amount of MIO in composites and the weak peak intensity, the characteristic peaks of PCN and MIO appeared simultaneously at 3000-3600 cm −1 . The FT-IR spectra further confirmed the formation of MIO/PCN. The FT-IR spectra of PCN, MIO, and MIO/PCN are shown in Figure 2 to illustrate the information pertaining to functional groups. In the FT-IR spectra of PCN, the broad peaks located at 3000-3600 cm −1 indicate the stretching vibration of O-H, N-H, and hydrogenbonding interactions [38,39]. The characteristic peaks at 1200-1600 cm −1 correspond to the C-N skeleton of PCN. The breathing mode of the triazine units appeared at 800 cm −1 , meaning the presence of -NH and -NH2 groups [39]. In that of MIO, the characteristic peaks at 570 cm −1 were determined to be In-O asymmetric stretching, and the peaks at 3000-3400 cm −1 correspond to the stretching vibration of the -OH hydrogen bond [11,34]. As shown in the FT-IR spectra of MIO/PCN, all the characteristic peaks of PCN appeared, indicating the main structure of PCN was not changed. Although the In-O peak was not observed, possibly because of the small amount of MIO in composites and the weak peak intensity, the characteristic peaks of PCN and MIO appeared simultaneously at 3000-3600 cm −1 . The FT-IR spectra further confirmed the formation of MIO/PCN. SEM and TEM images shown in Figures 3 and S1 are to illustrate the morphology of the composites. In Figure S1, the shape of MIL-68(In)-NH2 is a rod with a smooth surface and that of PCN is a nanosheet, which was in accordance with the previous reports. After in situ calcination loading, the morphology of MIO/PCN had no noticeable change compared with pure PCN, whereas MIO could not be observed. In the TEM images of MIO/PCN (Figure 3a-c), the rod-like MIO was surrounded by nanosheets of carbon nitride. This was mainly due to the in situ method, which mixed the two precursors of carbon nitride and indium oxide first, which were then calcined together. Moreover, that is why only PCN could be observed in the SEM images of MIO/PCN. In Figure 3d, the HRTEM image of MIO/PCN, two lattice fringes could be observed in MIO/PCN with layer distances of 0.274 nm and 0.292 nm, corresponding to (110) rh-In2O3 crystal planes and (222) c-In2O3 crystal planes, respectively. In addition, amorphous PCN nanosheets were observed. The EDX mapping in Figure 3e showed that C, N, In, and O were mainly distributed across the whole nanocomposites. This phenomenon may be caused by the in situ method. The analysis of XRD, FT-IR spectra, SEM, and TEM images confirmed the formation of MIO/PCN composites. SEM and TEM images shown in Figures 3 and S1 are to illustrate the morphology of the composites. In Figure S1, the shape of MIL-68(In)-NH 2 is a rod with a smooth surface and that of PCN is a nanosheet, which was in accordance with the previous reports. After in situ calcination loading, the morphology of MIO/PCN had no noticeable change compared with pure PCN, whereas MIO could not be observed. In the TEM images of MIO/PCN (Figure 3a-c), the rod-like MIO was surrounded by nanosheets of carbon nitride. This was mainly due to the in situ method, which mixed the two precursors of carbon nitride and indium oxide first, which were then calcined together. Moreover, that is why only PCN could be observed in the SEM images of MIO/PCN. In Figure 3d, the HRTEM image of MIO/PCN, two lattice fringes could be observed in MIO/PCN with layer distances of 0.274 nm and 0.292 nm, corresponding to (110) rh-In 2 O 3 crystal planes and (222) c-In 2 O 3 crystal planes, respectively. In addition, amorphous PCN nanosheets were observed. The EDX mapping in Figure 3e showed that C, N, In, and O were mainly distributed across the whole nanocomposites. This phenomenon may be caused by the in situ method. The analysis of XRD, FT-IR spectra, SEM, and TEM images confirmed the formation of MIO/PCN composites.
To analyze the chemical components and chemical states in 2.5 wt% MIO/PCN, XPS research was then conducted. Consistent with the EDX results, In, O, C, and N elements were all detected in the XPS survey spectra ( Figure S2), which further proves the co-existence of MIO and PCN in the composites. High-resolution XPS spectrum of the elements in MIO/PCN was also carried out. In Figure 4a, there were three peaks of C 1s at the binding energy of 288.2, 286.4, and 284.8 eV. The first peak was vested in N-C=N of the triazine ring, the second peak was attributed to C-O=C bond, while the last ones were vested in the C=C group of PCN [17,38]. In Figure 4b, the peaks of N 1s were divided into three characteristic peaks. The characteristic peak at 401.0 eV was caused by uncondensed C-N-H groups on the surface of PCN [9,10]. The last two forms of N 1s, located at 400.1 and 398.6 eV, belonged to the tertiary N-(C) 3 groups and sp 2 -hybridized nitrogen (C=N-C) in aromatic triazine rings, respectively [39]. Both of them and sp 2 -C constituted the heptazine C 6 N 7 units of PCN [40]. In Figure 4c, the two XPS peaks located at 444.8 and 452.5 eV corresponded to the spin-orbit coupling of In 3d 5/2 and In 3d 3/2 of MIO [41]. The peak in Figure 4d at 532.0 eV belongs to O C orbitals fitted to chemisorbed oxygen species. The XPS analysis indicated the co-existence of MIO and PCN in the composites. To analyze the chemical components and chemical states in 2.5 wt% MIO/PCN, XPS research was then conducted. Consistent with the EDX results, In, O, C, and N elements were all detected in the XPS survey spectra (Figure S2), which further proves the co-existence of MIO and PCN in the composites. High-resolution XPS spectrum of the elements in MIO/PCN was also carried out. In Figure 4a, there were three peaks of C 1s at the bind- corresponded to the spin-orbit coupling of In 3d5/2 and In 3d3/2 of MIO [41]. The peak in Figure 4d at 532.0 eV belongs to OC orbitals fitted to chemisorbed oxygen species. The XPS analysis indicated the co-existence of MIO and PCN in the composites. The performance of the MIO/PCN composites was measured by photodegradation RhB under LED light irradiation (λ = 420 nm). It can be seen in Figure 5a that the adsorption of RhB on pure PCN, MIO, or x wt% MIO/PCN was faint. In the absence of a catalyst, the photodegradation of RhB hardly occurred. This further illustrated the crucial importance of a catalyst in photodegradation of RhB. However, the photocatalytic activity of the pure MIO sample showed poor degradation capacity (17%) for RhB while that of PCN was 90% in 60 min. Experimental results indicated that controlling the ratio of MIO in the MIO/PCN sample was of great importance in achieving optimal photocatalytic degradation [42]. The 2.5 wt% MIO/PCN sample exhibited the best activity, reaching almost 100% degradation within 50 min under LED light irradiation (λ = 420 nm). The photodegradation efficiency of MIO/PCN samples was obviously enhanced compared to that of pure MIO. The photocatalytic stability of the 2.5 wt% MIO/PCN sample was tested by cycle degradation of RhB (Figure 5b). After four runs of continuous reaction, the 2.5 wt% MIO/PCN sample still exhibited stable photodegradation efficiency. The experimental results indicate that the MIO/PCN sample had good stability and the enhanced photodegradation activity of RhB was due to the introduction of MIO in the composites.
Photodegradation of RhB occurred because of the active species produced in MIO/PCN during the reaction. Therefore, the main active species were tested under the same photocatalytic degradation condition except for adding different scavengers. The The performance of the MIO/PCN composites was measured by photodegradation RhB under LED light irradiation (λ = 420 nm). It can be seen in Figure 5a that the adsorption of RhB on pure PCN, MIO, or x wt% MIO/PCN was faint. In the absence of a catalyst, the photodegradation of RhB hardly occurred. This further illustrated the crucial importance of a catalyst in photodegradation of RhB. However, the photocatalytic activity of the pure MIO sample showed poor degradation capacity (17%) for RhB while that of PCN was 90% in 60 min. Experimental results indicated that controlling the ratio of MIO in the MIO/PCN sample was of great importance in achieving optimal photocatalytic degradation [42]. The 2.5 wt% MIO/PCN sample exhibited the best activity, reaching almost 100% degradation within 50 min under LED light irradiation (λ = 420 nm). The photodegradation efficiency of MIO/PCN samples was obviously enhanced compared to that of pure MIO. The photocatalytic stability of the 2.5 wt% MIO/PCN sample was tested by cycle degradation of RhB (Figure 5b). After four runs of continuous reaction, the 2.5 wt% MIO/PCN sample still exhibited stable photodegradation efficiency. The experimental results indicate that the MIO/PCN sample had good stability and the enhanced photodegradation activity of RhB was due to the introduction of MIO in the composites. cohol (IPA), which capture superoxide radicals (·O2 − ), holes (h + ), and hydroxyl radicals (·OH), respectively [43]. Figure 5c,d shows that significantly decreased efficiency of the photodegradation occurred when BQ and IPA were added to the system. Additionally, there was no obvious change after the addition of MeOH in photocatalytic degradation. The photocatalytic experiment with scavengers suggested that ·O2 − and OH were the major active species in the photodegradation reaction of RhB [44].  Photodegradation of RhB occurred because of the active species produced in MIO/PCN during the reaction. Therefore, the main active species were tested under the same photocatalytic degradation condition except for adding different scavengers. The scavengers included 1, 4-benzoquinone (BQ), methyl alcohol (MeOH), and isopropyl alcohol (IPA), which capture superoxide radicals (·O 2 − ), holes (h + ), and hydroxyl radicals (·OH), respectively [43]. Figure 5c,d shows that significantly decreased efficiency of the photodegradation occurred when BQ and IPA were added to the system. Additionally, there was no obvious change after the addition of MeOH in photocatalytic degradation. The photocatalytic experiment with scavengers suggested that ·O 2 − and OH were the major active species in the photodegradation reaction of RhB [44].
The generation of the main active species on the MIO/PCN composite under visiblelight irradiation was also probed by a 5,5-dimethyl-1-pyrroline N-oxide (DMPO) spintrapping electron paramagnetic resonance (EPR) technique. In Figure 5e, when the light was off, no EPR signal appeared. When the light was on, a strong EPR signal of DMPO-·O 2 − appeared. Additionally, when the light was kept on for another five minutes, the signals were measurably enhanced. As shown in Figure 5f, the characteristic signals of the DMPO-·OH radical emerged after visible light irradiation. It can be concluded that both ·O 2 − and ·OH are the major reactive species in photodegradation of RhB by 2.5 wt% MIO/PCN photocatalyst. The EPR spectra is in accordance with the results of the capture experiments of active species [45]. By the above experimental studies, the possible mechanism was speculated as follows [46,47]: The optical and photoelectrical properties of MIO/PCN were investigated to explore the mechanism of enhanced photoactivity. In Figure 6a, there was a red shift of the DRS curve with increasing content of MIO in MIO/PCN. Broadened visible light absorption is vitally essential for increasing photocatalytic activity [48,49]. PL and TRPL spectra were used to explore the charge-carrier separation and migration behavior. It can be observed from Figure 6b that the fluorescence intensity of 2.5 wt% MIO/PCN was apparently quenched after being modified by MIO, indicating that the charge recombination was efficiently suppressed [17]. The average lifetime of PCN and 2.5 wt% MIO/PCN composite in Figure 6c was 2.54 ns and 1.32 ns. The rapid charge-carrier transfer from MIO to PCN resulted in a shorter PL lifetime [14,46]. Furthermore, the charge separation was further explored by the electrochemical impedance spectra (EIS). The evidently decreased Nyquist radius in Figure 6d illustrates that the resistance of 2.5 wt% MIO/PCN was much smaller than that of PCN [50,51]. The reduced resistance was conducive to the rapid migration of charge carriers. These results convincingly prove that the construction of MIO/PCN could promote charge separation and transfer.
In order to exclude the influence of structural change of the photocatalyst, XRD analysis was conducted. As shown in Figure 7a, the structure of the MIO/PCN did not change before or after photodegradation of RhB. This indicates that the impact of structural changes of photocatalysts on their enhanced photoactivity can be excluded. In Figure 7b, the BET surface areas of PCN and MIO were determined as 72 and 45 m 2 g −1 , respectively, while that of the MIO/PCN sample was 65 m 2 g −1 . Compared with pure PCN, the slightly decreased specific surface areas of MIO/PCN was due to the addition of MIL-68(In)-NH 2 by the in situ calcination [7,32]. The combination of the two block substances resulted in the decrease of BET-specific surface area. Therefore, the MIO/PCN composites performed well in photodegradation of RhB because of boosting solar absorption, fasting charge transfer, and being suppressed charge recombination. Based on the above discussion, a possible mechanism of charge transfer route in the MIO/PCN composites was proposed, as shown in Scheme 2. Irradiated by visible light, the electrons (e − ) excited by light in the valence band (VB) of PCN transferred to the conduction band (CB) of PCN, and then flowed to the CB of MIO. Certainly, part of the electrons and holes recombined before the reaction. In addition, the electrons that migrated to the surface of photocatalysts reacted with O 2 to form ·O 2 − . The holes in the CB reacted with H 2 O/OH − to generate ·OH. The two active species, ·O 2 − /OH, attacked the RhB pollutants and generated harmless products, even including water and carbon dioxide. In order to exclude the influence of structural change of the photocatalyst, XRD analysis was conducted. As shown in Figure 7a, the structure of the MIO/PCN did not change before or after photodegradation of RhB. This indicates that the impact of structural changes of photocatalysts on their enhanced photoactivity can be excluded. In Figure 7b, the BET surface areas of PCN and MIO were determined as 72 and 45 m 2 g −1 , respectively, while that of the MIO/PCN sample was 65 m 2 g −1 . Compared with pure PCN, the slightly decreased specific surface areas of MIO/PCN was due to the addition of MIL-68(In)-NH2 by the in situ calcination [7,32]. The combination of the two block substances resulted in the decrease of BET-specific surface area. Therefore, the MIO/PCN composites performed well in photodegradation of RhB because of boosting solar absorption, fasting charge transfer, and being suppressed charge recombination. Based on the above discussion, a possible mechanism of charge transfer route in the MIO/PCN composites was proposed, as shown in Scheme 2. Irradiated by visible light, the electrons (e − ) excited by light in the valence band (VB) of PCN transferred to the conduction band (CB) of PCN, and then flowed to the CB of MIO. Certainly, part of the electrons and holes recombined before the reaction. In addition, the electrons that migrated to the surface of photocatalysts reacted with O2 to form ·O2 − . The holes in the CB reacted with H2O/OH − to generate ·OH. The two active species, ·O2 − /OH, attacked the RhB pollutants and generated harmless products, even including water and carbon dioxide.

Preparation of MIL-68(In)-NH 2
The precursor MIL-68(In)-NH 2 was prepared using a hydrothermal method [26]. Typically, a certain amount of 2-aminoterephthalic acid and In(NO 3 ) 3 ·xH 2 O were dissolved in DMF and the hydrothermal reaction occurred in an oven. After the reaction ended, the obtained products were washed with methanol and dried overnight at 80 • C.

Preparation of MIO/PCN and PCN
MIO/PCN samples were obtained using an in situ method [8]. Different amounts of MIL-68(In)-NH 2 mixed with urea and calcined at 500 • C for 2 h in a muffle furnace. The products were collected and named x wt% MIO/PCN, where x means the calculated conversion rate of MIO.
Pure PCN was synthesized under the same conditions without the addition of MIL-68(In)-NH 2 .

Characterization
XRD patterns were measured on an X-ray diffractometer (D/MAX-2200, Rigaku Company) to examine the crystal structure of samples. FT-IR spectra was used to analyze the functional groups of samples by using an ALPHA-P spectrometer. The morphology and elemental mapping images of samples were characterized by field-emission scanning electron microscopy (SEM, JSM-6700F) and transmission electron microscopy (TEM, JEOL JEM 2100F). The chemical valence of the elements in the samples was obtained using X-ray photoelectron spectroscopy (XPS, Thermo ESCALAB 250XI, standard peak is the C 1s peak at 284.8 eV). Nitrogen adsorption-desorption isotherms and the Brunauer-Emmett-Teller (BET) surface areas were collected at 77 K using Micromeritics ASAP2010 equipment. The visible-light absorption of samples was measured by UV-visible diffuse reflectance spectra (UV-DRS, Cary 500 Scan Spectrophotometer, Varian, Palo Alto, CA, USA). PL was performed on Varian Cary Eclipse (Agilent, Santa Clara, CA, USA) to research the recombination of charge carriers of samples. Electrochemical impedance spectroscopy (EIS) of samples was measured on an electrochemical workstation (Shanghai chenhua) in a standard three-electrode system in which the working electrode was the FTO glass with synthesized samples (10 mg catalyst in 1 mL 1% ethanol and 0.5 mL Nafion with an active area of 1 cm 2 ); the reference electrode was the Ag/AgCl electrode; and the counter electrode was Pt wire. The electrolyte was 0.4 M Na 2 SO 4 aqueous solution.

Photocatalytic Rhodamine b Degradation
The photocatalytic performance test was conducted under LED lamp (λ = 420 nm) irradiation. In the reaction, 10 mg samples were put into 50 mL 20 ppm rhodamine B (RhB) solution and stirred for 30 min under dark condition. Then the mixture was illuminated under a LED lamp (λ = 420 nm) for 1h. The original solution concentration was labeled C 0 . During the irradiation, the suspension (2-3 mL) was taken from the dispersion every 10 min, and the clarified reaction solution (concentration C) could be obtained by filtering with a needle filter. The absorbance of the solution at 664 nm was determined using a Shimazu UV-2600 UV-Vis spectrophotometer. The degradation efficiency of the RhB solution was calculated according to the formula D = ln (C/C 0 ) × 100%. The absorption method replaced C 0 and C according to the Lambert-Beer law.

Conclusions
In conclusion, the MIO/PCN composites were synthesized by a facile in situ method that tightly combined PCN and MIO. The successful construction of MIO/PCN was determined by XRD, TEM, and XPS analysis. The best-performing sample was determined to be the 2.5 wt% MIO/PCN composite, which could degrade RhB almost 100% within 50 min under LED light irradiation. The reason for the excellent degradation capability of MIO/PCN was revealed by DRS, PL/TRPL, and EIS analysis. Experimental data showed the phase junction MIO provided a reliable electronic transmission channel for charge transfer and improved the separation efficiency of electron and hole. The active species were identified as ·O 2 − and ·OH by photodegradation reaction containing scavenger and EPR. Additionally, the durability and stability of the MIO/PCN were upheld to an excellent degree after four cycle tests. Our work provides an avenue for the application of phase junction materials in photocatalysis.

Conflicts of Interest:
The authors declare no conflict of interest.