The Study of HEMs Based on the Mechanically Activated Intermetallic Al12Mg17 Powder

In this work, Al–Mg intermetallic powders were characterized and obtained by melting, casting into a steel chill and subsequent mechanical activation in a planetary mill. The method for producing Al12Mg17 intermetallic powder is presented. The dispersity, morphology, chemical composition, and phase composition of the obtained powder materials were investigated. Certain thermodynamic properties of high-energy materials containing the Al-Mg powder after mechanical activation of various durations were investigated. The addition of the Al-Mg powders to the high-energy composition (synthetic rubber SKDM-80 + ammonium perchlorate AP + boron B) can significantly increase the burning rate by approximately 47% and the combustion heat by approximately 23% compared with the high-energy compositions without the Al-Mg powder. The addition of the Al12Mg17 powder obtained after 6 h of mechanical activation provides an increase in the burning rate by 8% (2.5 ± 0.1 mm/s for the mechanically activated Al12Mg17 powder and 2.3 ± 0.1 mm/s for the commercially available powder) and an increase in the combustion heat by 3% (7.4 ± 0.2 MJ/kg for the mechanically activated Al-Mg powder and 7.1 ± 0.2 MJ/kg for the commercially available powder). The possibility of using the Al-Mg intermetallic powders as the main component of pyrotechnic and special compositions is shown.


Introduction
Improving the energy characteristics of high-energy materials (HEMs), improving traditional components, and searching for new components is a relevant objective for many fields of science and technology. High-energy metal powders began to be intensively studied as fuels for burning systems when Russian scientists Kondratyuk and Tsander suggested using high-energy metals (Al, Be, B, Mg, Zr, Ti, etc.) as energy additives for propellants [1]. Metal powders with a high enthalpy of combustion are of great interest as reactive materials in the compositions of propellants, explosives, pyrotechnics, etc [2]. Fine metal powders that are part of high-energy systems are mainly used as components to control the burning rate and reduce ignition delays [3][4][5].
Aluminum powder is the most affordable, widely studied, and effective additive in various high-energy compositions [4,6,7]. Despite the extensive use of aluminum as a metal fuel, there are certain disadvantages. The major disadvantage is the formation of an oxide film on the surface of aluminum particles, which prevents the rapid flow of chemical reactions and forms agglomerates before ignition [8]. To reduce agglomeration, aluminum particles must be optimized for rapid ignition. There are various methods to solve this problem: the use of nanosized aluminum powder [9]; the use of metallic and polymer coatings [10,11]; the use of other additives [12,13]; and the replacement of pure aluminum powder with powders of intermetallic alloys [14][15][16][17]. Despite the attractive properties of

Preparation of Al-Mg Material
First, 99% pure Al-Mg alloy was obtained from commercial-purity aluminum ingot (99 wt % Al, 0.9 wt % Si, 0.04 wt % Mg and other impurities) and commercial-purity magnesium ingot (99.95 wt % Mg, 0.01 wt % Al, 0.01 wt % Mn, and other impurities). The alloy was fabricated by casting in a clay-graphite crucible. The fusion of aluminum and magnesium was carried out in argon. Aluminum ingot was loaded into the crucible and placed in a furnace. When the temperature reached 730 • C, Al melt was removed from the furnace, and magnesium ingot was added into the aluminum melt in small parts in a mass ratio of Al:Mg-1:1. The magnesium ingots were shaped cubes and parallelepipeds, and the approximate mass of individual fragments was 100-150 g. For homogeneous distribution of the components in the melt, mixing was carried out using the device with a rotation speed of 1500 rpm [29]. Mechanical mixing was carried out until the magnesium ingot was completely dissolved in the aluminum melt. The resulting alloy was poured into a steel chill at a temperature of 670 • C.

Mechanical Activation
The obtain alloy was crushed using a jaw crusher. The obtain Al-Mg flakes were mechanically milled in a planetary mill (Figure 1), the main element of which is the ball mill container. The lid of the container has two taps. One of them is used to evacuate the working space, and the second is used to pump inert gas (argon). Steel balls with a diameter of 8.7 mm were used as grinding bodies. The mass ratio of grinding bodies to powder mixture was 2:1. The mechanical activation was conducted for 6 h in an argon atmosphere with a rotation frequency of 12 rpm.

Mechanical Activation
The obtain alloy was crushed using a jaw crusher. The obtain Al-Mg flakes were mechanically milled in a planetary mill (Figure 1), the main element of which is the ball mill container. The lid of the container has two taps. One of them is used to evacuate the working space, and the second is used to pump inert gas (argon). Steel balls with a diameter of 8.7 mm were used as grinding bodies. The mass ratio of grinding bodies to powder mixture was 2:1. The mechanical activation was conducted for 6 h in an argon atmosphere with a rotation frequency of 12 rpm.

Particle Size, Chemical Analysis, Morphology, and Phase Composition
The average particle size of the mechanically activated powder mixtures was measured using an ANALYSETTE 22 MicroTec plus apparatus (Fritsch GmbH, Dresden, Germany) based on the laser diffraction method in the range 0.08-2000 µm and the Fraunhofer theory. The dispersion was carried out in a liquid medium (distilled water). The chemical analysis of the intermetallic Al-Mg powders was performed using an XRF-1800 wavelength-dispersive spectrometer. When calibrating the XRF-1800, a curve was constructed showing the relationship between the element content in the standard sample and its measured intensity (calibration curve); then, the element content in the studied sample was found. The microstructure of the powders was determined using a Vega3 Tescan (TESCAN ORSAY HOLDING, Brno, Czech Republic). To determine the amount of oxygen in the powder, a LECO ONH (LECO Corporation, Michigan, USA) analyzer was used. X-ray diffraction analysis of the powders was performed using a Shimadzu XRD 6000 diffractometer with CuKα radiation. The phase composition was determined using the POWDER CELL 2.4 program and PDF 4+ (Powder Diffraction File) database.

Calorimetric Studies
Calorimetric studies of the mechanically activated powder mixtures were performed using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) on a Mettler Toledo thermal analyzer with a TGA/SDTA 851 module (Mettler-Toledo, LLC, Columbus, OH, USA) in Al2O3 crucible in the temperature range of 25-1200 °C (heat rate 10 K/min) in an O2/Ar atmosphere.

Particle Size, Chemical Analysis, Morphology, and Phase Composition
The average particle size of the mechanically activated powder mixtures was measured using an ANALYSETTE 22 MicroTec plus apparatus (Fritsch GmbH, Dresden, Germany) based on the laser diffraction method in the range 0.08-2000 µm and the Fraunhofer theory. The dispersion was carried out in a liquid medium (distilled water). The chemical analysis of the intermetallic Al-Mg powders was performed using an XRF-1800 wavelength-dispersive spectrometer. When calibrating the XRF-1800, a curve was constructed showing the relationship between the element content in the standard sample and its measured intensity (calibration curve); then, the element content in the studied sample was found. The microstructure of the powders was determined using a Vega3 Tescan (TESCAN ORSAY HOLDING, Brno, Czech Republic). To determine the amount of oxygen in the powder, a LECO ONH (LECO Corporation, St. Joseph, MI, USA) analyzer was used. X-ray diffraction analysis of the powders was performed using a Shimadzu XRD 6000 diffractometer with CuKα radiation. The phase composition was determined using the POWDER CELL 2.4 program and PDF 4+ (Powder Diffraction File) database.

Calorimetric Studies
Calorimetric studies of the mechanically activated powder mixtures were performed using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) on a Mettler Toledo thermal analyzer with a TGA/SDTA 851 module (Mettler-Toledo, LLC, Columbus, OH, USA) in Al 2 O 3 crucible in the temperature range of 25-1200 • C (heat rate 10 K/min) in an O 2 /Ar atmosphere.

Process to Obtain Samples of HEMs
The basic composition of the samples contained the following: bidispersed ammonium perchlorate (AP) with a dispersion of 160-315 µm and less than 50 µm in a ratio of 60/40 as an oxidizing agent; Molecules 2020, 25, 3561 4 of 14 divinyl rubber based on butadiene rubber, which was plasticized with transformer oil in a ratio of 20/80 (SKDM-80) as a combustible binder; and amorphous black boron powder (B-99) as an energy additive. The amorphous boron was selected due to its high combustion heat (Q boron = 58 KJ/g). In traditional high-energy materials, aluminum powder is used as an energy additive with a lower combustion heat (Q Al = 31 KJ/g). The Al 12 Mg 17 powder additive was selected to increase the combustion completeness of boron. Aluminum powder has a high combustion temperature, and magnesium is a highly flammable component. The content of components in the studied samples (Table 1)   From the obtained mixtures, the samples with a diameter of 10 mm and a height of 30-40 mm were pressed. The obtaining of the studied samples consisted of sequential mixing of the components (ammonium perchlorate, Al-Mg powders, and processing aids) with a polymer combustible binder. To obtain high-quality samples, the oxidizer charge was divided into several parts. For homogeneous distribution of the components, each charge was mixed for 10-15 min.
In this work, the Al-Mg powder, because of its high exothermicity, was used as a catalytic additive that is capable of increasing the energy parameters of boron in the high-energy compositions and also significantly increasing their burning rate. Experimental studies to determine the combustion heat and burning rate, as well as the calculation of the combustion heat, were carried out according to the approved methods presented in [30,31].

Study of the Combustion Heat and Burning Rate of HEMs
The combustion heat was measured using a calorimetric apparatus, the main part of which is a bomb calorimeter. To obtain results with high accuracy, important requirements are imposed on the bomb calorimeter described in [32]. Critical requirements are that it is gastight and has mechanical strength under high pressure. The container of the calorimetric apparatus was filled with 3 L of distilled water, and a bomb calorimeter was immersed in it. For a uniform and quick distribution of water temperature throughout the calorimetric apparatus, a propeller was placed next to the bomb calorimeter. The propeller provided rotation at a speed of 400-500 rpm. The water temperature was measured using a Beckman metastatic thermometer, which allows high-precision measurements. After performing all the above steps, the samples of HEMs were ignited, and the temperature of water in the container of the calorimetric apparatus was measured. Three experiments were performed for each composition.
The burning rate of the studied samples was measured in the air atmosphere under a pressure of 0.1 MPa. The initial temperature of the samples is the ambient temperature (22 • C). The samples with a diameter of 10 mm and a height of 30 mm were armored with a linoleum solution in acetone. The samples were ignited by the local heating of the upper surface with a molybdenum spiral. Burning time was fixed by a stopwatch. The process was observed visually and also with a NIKON D600 camera and a Yukon thermal imager, UX 70P (Yukon Advanced Optics Worldwide, UAB, Lithuania).

Particle Size, Chemical Analysis, Morphology, and Phase Composition
The particle size distribution for the Al-Mg powder after mechanical activation in the planetary mill is shown in Figure 2. The particle size distribution substantially depends on the duration of mechanical activation. With an increase in the duration of mechanical activation, the particle size of the Al-Mg powder decreases. The obtained Al-Mg powder (after 6 h of mechanical activation) was compared with commercially available Al-Mg powder. It was found that the average particle size is 49 µm for the obtained Al-Mg powder and 50 µm for the commercially available Al-Mg powder, respectively (Figure 3), where D m,1 and D m,2 -modal particle diameter.

Particle Size, Chemical Analysis, Morphology, and Phase Composition
The particle size distribution for the Al-Mg powder after mechanical activation in the planetary mill is shown in Figure 2. The particle size distribution substantially depends on the duration of mechanical activation. With an increase in the duration of mechanical activation, the particle size of the Al-Mg powder decreases. The obtained Al-Mg powder (after 6 h of mechanical activation) was compared with commercially available Al-Mg powder. It was found that the average particle size is 49 µm for the obtained Al-Mg powder and 50 µm for the commercially available Al-Mg powder, respectively (Figure 3), where Dm,1 and Dm,2-modal particle diameter.

Particle Size, Chemical Analysis, Morphology, and Phase Composition
The particle size distribution for the Al-Mg powder after mechanical activation in the planetary mill is shown in Figure 2. The particle size distribution substantially depends on the duration of mechanical activation. With an increase in the duration of mechanical activation, the particle size of the Al-Mg powder decreases. The obtained Al-Mg powder (after 6 h of mechanical activation) was compared with commercially available Al-Mg powder. It was found that the average particle size is 49 µm for the obtained Al-Mg powder and 50 µm for the commercially available Al-Mg powder, respectively (Figure 3), where Dm,1 and Dm,2-modal particle diameter.   The dependence of the average particle size <d> of the Al-Mg powder on the duration of mechanical activation in the planetary mill is shown in Figure 4. After 2 h of mechanical activation, the average particle size of the Al-Mg powder decreases significantly from 196 µm (2 h) to 64 µm (3 h).
Molecules 2020, 25, x FOR PEER REVIEW 6 of 15 The dependence of the average particle size <d> of the Al-Mg powder on the duration of mechanical activation in the planetary mill is shown in Figure 4. After 2 h of mechanical activation, the average particle size of the Al-Mg powder decreases significantly from 196 µm (2 h) to 64 µm (3 h). Al-Mg powders (after mechanical activation) have a bimodal particle size distribution (2 maxima Dm,1 and Dm,2 are observed in Figure 2; Figure 3). The mass median diameter (d43) for the unimodal distribution function of the commercially available powder and the bimodal distribution function of the mechanically activated powder are approximately the same (the difference is approximately 1 µm). However, the bimodal distribution function (the presence of two fractions) can significantly affect the characteristics of the studied processes.
X-ray fluorescence analysis of the obtained Al-Mg alloy is shown in Table 2. The Al-Mg alloy obtained by casting has an almost equilibrium content of the main components with minimum oxygen content. Quantitative analysis of the oxygen content in the Al-Mg alloy and the mechanically activated Al-Mg powder was performed. It was found that the oxygen content in the Al-Mg alloy before mechanical activation is approximately 0.003 wt %, while the oxygen content in the Al-Mg powder after mechanical activation does not exceed 0.1 wt %. Aluminum powder is known to have a dense oxide film on the surface. The oxide film of the intermetallic Al12Mg17 powder is not as dense as that of aluminum powder. This is due to the protective properties of oxide films. The possibility of the formation of such a film is determined by the condition of continuity formulated by Pilling and Bedworth (Pilling-Bedworth coefficient (PBC)) [33].

=
(1) Al-Mg powders (after mechanical activation) have a bimodal particle size distribution (2 maxima D m,1 and D m,2 are observed in Figure 2; Figure 3). The mass median diameter (d 43 ) for the unimodal distribution function of the commercially available powder and the bimodal distribution function of the mechanically activated powder are approximately the same (the difference is approximately 1 µm). However, the bimodal distribution function (the presence of two fractions) can significantly affect the characteristics of the studied processes.
X-ray fluorescence analysis of the obtained Al-Mg alloy is shown in Table 2. The Al-Mg alloy obtained by casting has an almost equilibrium content of the main components with minimum oxygen content. Quantitative analysis of the oxygen content in the Al-Mg alloy and the mechanically activated Al-Mg powder was performed. It was found that the oxygen content in the Al-Mg alloy before mechanical activation is approximately 0.003 wt %, while the oxygen content in the Al-Mg powder after mechanical activation does not exceed 0.1 wt %. Aluminum powder is known to have a dense oxide film on the surface. The oxide film of the intermetallic Al 12 Mg 17 powder is not as dense as that of aluminum powder. This is due to the protective properties of oxide films. The possibility of the formation of such a film is determined by the condition of continuity formulated by Pilling and Bedworth (Pilling-Bedworth coefficient (PBC)) [33].
According to the condition of continuity, the molecular volume of the oxide formed from the metal and oxygen should be greater than the molecular volume of the metal used to form the oxide molecule. Otherwise, the oxide film is not enough to cover the entire metal with a continuous layer. As a result, the oxide film is loose and porous. If PBC > 1, the film forms under compression conditions; therefore, the film is continuous and may have protective properties. If PBC < 1, the film in the process of its growth sustains tension, which contributes to its destruction and cracking. In this case, the film is not continuous (e.g., the oxide film of magnesium). The effect of magnesium on the oxide film is enhanced, since the magnesium content in the film is always many times higher than the magnesium content in the particle [34]. If the magnesium content is greater than 1% in the alloy, the oxide film consists entirely of magnesium oxide MgO [34]. The PBC coefficient for some metal oxides is shown in Table 3. The SEM images of the Al-Mg powder after 6 h of mechanical activation are shown in Figure 5. Figure 5a,b are identical, but they have different magnifications (Figure 5a magnification is equal × 509, and Figure 5b magnification is equal × 10200). In particular, Figure 5a shows a wide range of powder particle sizes, and Figure 5b shows in more detail the complex shape and structure of the particles. The powder has separate particles of irregular shape, which is typical for materials after mechanical activation. According to the condition of continuity, the molecular volume of the oxide formed from the metal and oxygen should be greater than the molecular volume of the metal used to form the oxide molecule. Otherwise, the oxide film is not enough to cover the entire metal with a continuous layer. As a result, the oxide film is loose and porous. If PBC > 1, the film forms under compression conditions; therefore, the film is continuous and may have protective properties. If PBC < 1, the film in the process of its growth sustains tension, which contributes to its destruction and cracking. In this case, the film is not continuous (e.g., the oxide film of magnesium). The effect of magnesium on the oxide film is enhanced, since the magnesium content in the film is always many times higher than the magnesium content in the particle [34]. If the magnesium content is greater than 1% in the alloy, the oxide film consists entirely of magnesium oxide MgO [34]. The PBC coefficient for some metal oxides is shown in Table 3. The SEM images of the Al-Mg powder after 6 h of mechanical activation are shown in Figure 5. Figure 5a,b are identical, but they have different magnifications (Figure 5a magnification is equal × 509, and Figure 5b magnification is equal × 10200). In particular, Figure 5a shows a wide range of powder particle sizes, and Figure 5b shows in more detail the complex shape and structure of the particles. The powder has separate particles of irregular shape, which is typical for materials after mechanical activation. The XRD pattern of the mechanically activated Al-Mg powder is shown in Figure 6. It was found that peaks in the XRD pattern corresponds to the Al 12 Mg 17 phase. According to the Al-Mg state diagram, the Al 12 Mg 17 phase is formed at the same percentage (Al 50%/Mg 50%) of each component in the alloy, which is confirmed by the results of chemical analysis (Table 2). It should also be noted that  The XRD pattern of the mechanically activated Al-Mg powder is shown in Figure 6. It was found that peaks in the XRD pattern corresponds to the Al12Mg17 phase. According to the Al-Mg state diagram, the Al12Mg17 phase is formed at the same percentage (Al 50%/Mg 50%) of each component in the alloy, which is confirmed by the results of chemical analysis (Table 2). It should also be noted that the XRD patterns of the mechanically activated Al-Mg powder and commercially available Al-Mg powder are completely identical.

Calorimetric Studies
The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of the Al-Mg powder after 2, 4, and 6 h of mechanical activation are shown in Figure 7. As can be seen from TG/DSC curves, the Al-Mg powder after 2 h of mechanical activation does not show endothermic melting. The Al-Mg powders after 4 h and 6 h of mechanical activation show endothermic melting, which corresponds to the melting point of 450 °C and is consistent with the Al-Mg state diagram [35].

Calorimetric Studies
The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of the Al-Mg powder after 2, 4, and 6 h of mechanical activation are shown in Figure 7. As can be seen from TG/DSC curves, the Al-Mg powder after 2 h of mechanical activation does not show endothermic melting. The Al-Mg powders after 4 h and 6 h of mechanical activation show endothermic melting, which corresponds to the melting point of 450 • C and is consistent with the Al-Mg state diagram [35].
The oxidation degree of the powder obtained after 2 h of mechanical activation is 70.65% at two exothermic peaks at temperatures around 600 • C and 820 • C. The oxidation degree of the powder obtained after 4 h of mechanical activation is 77.31% at four exothermic peaks at temperatures around 520 • C and 710 • C. The oxidation degree of the powder obtained after 6 h of mechanical activation is 74.4% at exothermic peaks at temperatures around 520 • C and 690 • C. The oxidation degree of the powders obtained after 4 and 6 h of mechanical activation is close to the theoretical value for the case of complete oxidation (77.4%), which indicates the formation of Al 2 O 3 and MgO [16]. According to the results of thermal analysis, with an increase in the time of mechanical activation, the exothermic peak shifts to the zone of lower temperatures, and mechanical activation for more than 4 h does not significantly affect the position of peaks on the TG/DSC curves of the studied materials.
The summarized results of the obtained experimental data of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) are presented in Table 4, as well as the results of mass changes depending on the mechanical activation duration are shown in Figure 8.  The oxidation degree of the powder obtained after 2 h of mechanical activation is 70.65% at two exothermic peaks at temperatures around 600 °C and 820 °C. The oxidation degree of the powder obtained after 4 h of mechanical activation is 77.31% at four exothermic peaks at temperatures around

Combustion Heat and Burning Rate
The combustion heat was determined for the samples whose compositions are shown in Table  1. As can be seen from Figure 9, the addition of the mechanically activated Al-Mg powder to the composition of HEMs leads to an increase in the combustion heat by approximately 23% compared with the composition without the mechanically activated Al-Mg powder. It was found that the addition of the mechanically activated Al-Mg powder to the composition BC (basic composition), regardless of the duration of mechanical activation and dispersion of the powder, does not affect the combustion heat. Comparison of the studied Al-Mg powder after 6 h of mechanical activation and commercially available Al-Mg powder showed that the difference in the combustion heat is 3% (7.4 ± 0.2 MJ/kg for the mechanically activated Al-Mg powder and 7.1 ± 0.2 MJ/kg for the commercially available powder). From experimental data, it was found that the combustion heat of the compositions of HEMs does not depend on the method of obtaining powders and is the same for all compositions containing the Al-Mg powders. As can be seen from Table 2 and Figure 9, during mechanical activation, there are no changes in the chemical composition of the material, which would contribute to an increase in the combustion heat.

Combustion Heat and Burning Rate
The combustion heat was determined for the samples whose compositions are shown in Table 1. As can be seen from Figure 9, the addition of the mechanically activated Al-Mg powder to the composition of HEMs leads to an increase in the combustion heat by approximately 23% compared with the composition without the mechanically activated Al-Mg powder. It was found that the addition of the mechanically activated Al-Mg powder to the composition BC (basic composition), regardless of the duration of mechanical activation and dispersion of the powder, does not affect the combustion heat. Comparison of the studied Al-Mg powder after 6 h of mechanical activation and commercially available Al-Mg powder showed that the difference in the combustion heat is 3% (7.4 ± 0.2 MJ/kg for the mechanically activated Al-Mg powder and 7.1 ± 0.2 MJ/kg for the commercially available powder). From experimental data, it was found that the combustion heat of the compositions of HEMs does not depend on the method of obtaining powders and is the same for all compositions containing the Al-Mg powders. As can be seen from Table 2 and Figure 9, during mechanical activation, there are no changes in the chemical composition of the material, which would contribute to an increase in the combustion heat. The results of the burning rate of the prepared compositions of HEMs (Table 1) in the air at normal pressure ( Figure 10) were obtained. The sample containing only amorphous boron powder (composition BC) has the lowest burning rate, while when the Al-Mg powder was added to the composition, the burning rate of the composition increases by approximately 47%. At the same time, the Al-Mg powder obtained after 6 h of mechanical activation gives the largest increase in the burning rate. Comparison of the studied Al-Mg powder obtained after 6 h of mechanical activation and the commercially available Al-Mg powder showed that the difference in the burning rate is 8% (2.5 ± 0.1 mm/s for the Al-Mg powder obtained after 6 h of mechanical activation and 2.3 ± 0.1 mm/s for the The results of the burning rate of the prepared compositions of HEMs (Table 1) in the air at normal pressure ( Figure 10) were obtained. The sample containing only amorphous boron powder (composition BC) has the lowest burning rate, while when the Al-Mg powder was added to the composition, the burning rate of the composition increases by approximately 47%. At the same time, the Al-Mg powder obtained after 6 h of mechanical activation gives the largest increase in the burning rate. Comparison of the studied Al-Mg powder obtained after 6 h of mechanical activation and the commercially available Al-Mg powder showed that the difference in the burning rate is 8% (2.5 ± 0.1 mm/s for the Al-Mg powder obtained after 6 h of mechanical activation and 2.3 ± 0.1 mm/s for the commercially available powder). The results of the burning rate of the prepared compositions of HEMs (Table 1) in the air at normal pressure ( Figure 10) were obtained. The sample containing only amorphous boron powder (composition BC) has the lowest burning rate, while when the Al-Mg powder was added to the composition, the burning rate of the composition increases by approximately 47%. At the same time, the Al-Mg powder obtained after 6 h of mechanical activation gives the largest increase in the burning rate. Comparison of the studied Al-Mg powder obtained after 6 h of mechanical activation and the commercially available Al-Mg powder showed that the difference in the burning rate is 8% (2.5 ± 0.1 mm/s for the Al-Mg powder obtained after 6 h of mechanical activation and 2.3 ± 0.1 mm/s for the commercially available powder). The difference in the combustion modes is probably explained the difference in the structure of the Al-Mg powder particles and the formation of bimodal particle size distribution. The difference in the structure as well as formation of bimodal distribution are explained by the difference in the method for obtaining the Al-Mg powders. The commercially available Al-Mg powder was obtained by spraying inert gas in a sealed chamber. The studied Al-Mg powder was obtained by mechanical activation in the planetary mill, and the phase composition of the studied Al-Mg powder is dominated by the Al12Mg17 phase. The mechanically activated Al12Mg17 powder has increased reactivity and is easier to react due to structural yielding and the formation linear crystal defects: dislocations and point defects (ionic and atomic vacancies, interstitial ions) [36].
The summary results of the obtained experimental data are presented in Table 5, where Qcombustion heat; U-burning rate; ΔQ and ΔU-difference in the combustion heat and burning rate of the compositions with Al-Mg alloy from the base composition. The difference in the combustion modes is probably explained the difference in the structure of the Al-Mg powder particles and the formation of bimodal particle size distribution. The difference in the structure as well as formation of bimodal distribution are explained by the difference in the method for obtaining the Al-Mg powders. The commercially available Al-Mg powder was obtained by spraying inert gas in a sealed chamber. The studied Al-Mg powder was obtained by mechanical activation in the planetary mill, and the phase composition of the studied Al-Mg powder is dominated by the Al 12 Mg 17 phase. The mechanically activated Al 12 Mg 17 powder has increased reactivity and is easier to react due to structural yielding and the formation linear crystal defects: dislocations and point defects (ionic and atomic vacancies, interstitial ions) [36].
The summary results of the obtained experimental data are presented in Table 5, where Q-combustion heat; U-burning rate; ∆Q and ∆U-difference in the combustion heat and burning rate of the compositions with Al-Mg alloy from the base composition.

Conclusions
The Al-Mg powder, in view of its high exothermicity, was used as the catalytic additive that is capable of increasing the energy parameters of boron in the high-energy compositions and also significantly increasing their burning rate.
The addition of the mechanically activated Al 12 Mg 17 powder to the composition (SKDM-80 + ammonium perchlorate + amorphous boron) leads to an increase in the burning rate and the combustion heat by approximately 47% and 24%, respectively. The greatest increase in the burning rate is achieved when using Al 12 Mg 17 powder obtained after 6 h of mechanical activation in the planetary mill.
Comparison of the burning rate and the combustion heat of the Al-Mg powders obtained by various methods showed that the addition of the studied Al 12 Mg 17 powder obtained after 6 h of mechanical activation provides an increase in the burning rate by 8% (2.5 ± 0.1 mm/s for the mechanically activated Al 12 Mg 17 powder and 2.3 ± 0.1 mm/s for the commercially available powder) and the combustion heat by 3% (7.4 ± 0.2 MJ/kg for the mechanically activated Al 12 Mg 17 powder and 7.1 ± 0.2 MJ/kg for the commercially available powder).
It was found that the addition of the Al-Mg powder in the compositions of HEMs, regardless of the method of obtaining and dispersion of the powders, does not affect a significant change in heat release.
The phase composition of the commercially available Al-Mg powder and intermetallic powder obtained by the alloying and subsequent mechanical activation in the planetary mill are represented by the fragile intermetallic Al 12 Mg 17 phase, which according to the state diagram of the Al-Mg system corresponds to the eutectic region.
It was found that the increase in the duration of mechanical activation of the Al-Mg powder from 2 to 3 h leads to a significant decrease in particle size from 196 to 64 µm, and the morphology of the Al-Mg powder consists of individual particles of irregular shape, which is typical for powders after mechanical milling. It should be noted that Al-Mg powders (after mechanical activation) have a bimodal particle size distribution. The mass median diameter (d 43 ) for the unimodal distribution function of the commercially available powder and the bimodal distribution function of the mechanically activated powder are approximately the same (the difference is 1 µm).
It was found that with an increase in the duration of mechanical activation in the planetary mill, the exothermic peak of the Al 12 Mg 17 powder on the DSC curve shifts to the zone of lower temperatures, and mechanical activation for more than 4 h does not significantly affect the position of peaks on the TG/DSC curves of the studied materials.