Continuous Production and Catalysis Optimization of Chemical Industry Processes

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Chemical Processes and Systems".

Deadline for manuscript submissions: 25 October 2024 | Viewed by 1016

Special Issue Editor


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Guest Editor
Department of Chemistry and Organic Technology, Faculty of Chemical Engineering and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, Poland
Interests: catalytic processes; biomass valorization; biorefining; adsorption processes; organic chemical processes; process optimization; material design
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Special Issue Information

Dear Colleagues,

With the growing emphasis on enhancing the sustainability and efficiency of industrial plants, catalytic process integration and optimization are attracting additional interest across the chemical engineering community. Some of the hallmarks of process integration and optimization include a holistic perspective in design and the enhancement of catalytic material and the optimization of existing processes into modern design approaches. These techniques can be applied to individual unit operations, multiple units, a whole industrial facility, or even a cluster of industrial plants.

This Special Issue, entitled “Continuous Production and Catalysis Optimization of Chemical Industry Processes”, aims to cover recent advances in the development and application of catalytic process integration and optimization. Topics include, but are not limited to, methods and/or applications in the following areas:

  • Systematic approaches to industrial catalytic processes;
  • Optimization of catalytic materials;
  • Optimization of unit and total processes;
  • Mitigation of environmental impact;
  • Continuous production studies of emerging processes (e.g., biomass valorization, and biorefining);
  • Integration of renewable energy in catalytic processes;
  • Processes design from laboratory to industrial scale;
  • Implementation of new catalytic and adsorption processes into industrial practice.

Prof. Dr. Izabela Czekaj
Guest Editor

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Keywords

  • catalytic processes optimization
  • biomass valorization
  • organic technology processes
  • continuous chemical processes
  • biorefining
  • process design
  • adsorption processes

Published Papers (2 papers)

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Research

16 pages, 2229 KiB  
Article
Approach to Chemical Process Transition Control via Regulatory Controllers with the Case of a Throughput Fluctuating Ethylene Column
by Dong Huang, Gang Liu, Kezhong Chen, Lizhi Liu and Jinlin Guo
Processes 2024, 12(6), 1105; https://doi.org/10.3390/pr12061105 - 28 May 2024
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Abstract
For chemical processes, dynamic optimization is employed for process transition. On the basis of the multilayer control structure, the employment of dynamic optimization is affected by the regulatory control system. To avoid the adjustment of the regulatory control system, set-point optimization is proposed. [...] Read more.
For chemical processes, dynamic optimization is employed for process transition. On the basis of the multilayer control structure, the employment of dynamic optimization is affected by the regulatory control system. To avoid the adjustment of the regulatory control system, set-point optimization is proposed. For comparison, two types of optimization models, namely direct optimization and set-point optimization, are formulated. The superiority of set-point optimization is rigorously proven. By simulating the commercial process of a throughput-fluctuating ethylene column, the integrated absolute error and maximum deviation of product quality are reduced by more than 150% with set-point optimization. The results indicate that the approach to process transition via regulatory controllers not only avoids the insecurity caused by the switching of set-point controllers but also improves the optimization performance. In conclusion, the proposed optimization structure, namely set-point optimization, is operable and stable for commercial chemical process transitions. Full article
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14 pages, 3300 KiB  
Article
Cs4PMo11VO40-Catalyzed Glycerol Ketalization to Produce Solketal: An Efficient Bioadditives Synthesis Method
by Márcio José da Silva and Cláudio Júnior Andrade Ribeiro
Processes 2024, 12(5), 854; https://doi.org/10.3390/pr12050854 - 24 Apr 2024
Viewed by 560
Abstract
In this work, a series of vanadium-substituted phosphomolybdic acids were synthesized and tested as the catalysts for the synthesis of solketal, a green fuel bioadditive, from the condensation reaction of glycerol with acetone. The objective was to demonstrate that an easily synthesizable solid [...] Read more.
In this work, a series of vanadium-substituted phosphomolybdic acids were synthesized and tested as the catalysts for the synthesis of solketal, a green fuel bioadditive, from the condensation reaction of glycerol with acetone. The objective was to demonstrate that an easily synthesizable solid catalyst can efficiently promote glycerol condensation with acetone at room temperature. The activity of pristine heteropolyacid (i.e., H3PMo12O40) and its vanadium-substituted cesium salts (Cs3+nPMo12-nVnO40; n = 0–3) was evaluated in condensation reactions carried out at room temperature. Among the catalysts tested, Cs4PMo11VO40 was the most active and selective towards a five-member ring solketal isomer (dioxolane). A high yield of solketal (i.e., 95% conversion and 95% selectivity to solketal) was achieved in glycerol condensation with acetone at room temperature within a short reaction time (2 h). The influence of the main reaction parameters, such as the acetone–glycerol molar ratio, catalyst load, and reaction temperatures, was investigated. The greatest activity of the Cs4PMo11VO40 catalyst was correlated to its greatest acidity. Full article
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