Journal Description
Polymers
Polymers
is an international, peer-reviewed, open access journal of polymer science published semimonthly online by MDPI. Belgian Polymer Group (BPG), European Colloid & Interface Society (ECIS), National Interuniversity Consortium of Materials Science and Technology (INSTM) and North American Thermal Analysis Society (NATAS) are affiliated with Polymers and their members receive a discount on the article processing charges.
- Open Access— free for readers, with article processing charges (APC) paid by authors or their institutions.
- High Visibility: indexed within Scopus, SCIE (Web of Science), Ei Compendex, PubMed, PMC, FSTA, CAPlus / SciFinder, Inspec, and other databases.
- Journal Rank: JCR - Q1 (Polymer Science) / CiteScore - Q1 (Polymers and Plastics)
- Rapid Publication: manuscripts are peer-reviewed and a first decision is provided to authors approximately 13.7 days after submission; acceptance to publication is undertaken in 2.9 days (median values for papers published in this journal in the second half of 2023).
- Recognition of Reviewers: reviewers who provide timely, thorough peer-review reports receive vouchers entitling them to a discount on the APC of their next publication in MDPI journals, in appreciation of the work.
- Testimonials: See what our authors and editors say about Polymers.
Impact Factor:
5.0 (2022);
5-Year Impact Factor:
5.0 (2022)
Latest Articles
Production and Characterization of Nanocellulose from Maguey (Agave cantala) Fiber
Polymers 2024, 16(10), 1312; https://doi.org/10.3390/polym16101312 (registering DOI) - 07 May 2024
Abstract
Plant fibers have been studied as sources of nanocellulose due to their sustainable features. This study investigated the effects of acid hydrolysis parameters, reaction temperature, and acid concentration on nanocellulose yield from maguey (Agave cantala) fiber. Nanocellulose was produced from the
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Plant fibers have been studied as sources of nanocellulose due to their sustainable features. This study investigated the effects of acid hydrolysis parameters, reaction temperature, and acid concentration on nanocellulose yield from maguey (Agave cantala) fiber. Nanocellulose was produced from the fibers via the removal of non-cellulosic components through alkali treatment and bleaching, followed by strong acid hydrolysis for 45 min using sulfuric acid (H2SO4). The temperature during acid hydrolysis was 30, 40, 50, and 60 °C, and the H2SO4 concentration was 40, 50, and 60 wt. % H2SO4. Results showed that 53.56% of raw maguey fibers were isolated as cellulose, that is, 89.45% was α-cellulose. The highest nanocellulose yield of 81.58 ± 0.36% was achieved from acid hydrolysis at 50 °C using 50 wt. % H2SO4, producing nanocellulose measuring 8–75 nm in diameter and 72–866 nm in length, as confirmed via field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) analysis. Fourier-transform infrared spectroscopy (FTIR) analysis indicated the chemical transformation of fibers throughout the nanocellulose production process. The zeta potential analysis showed that the nanocellulose had excellent colloidal stability with a highly negative surface charge of −37.3 mV. Meanwhile, X-ray diffraction (XRD) analysis validated the crystallinity of nanocellulose with a crystallinity index of 74.80%. Lastly, thermogravimetric analysis (TGA) demonstrated that the inflection point attributed to the cellulose degradation of the produced nanocellulose is 311.41 °C.
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(This article belongs to the Special Issue Advanced Preparation and Application of Cellulose)
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Pressing of Functionalized Polymer Composite Materials to Improve Mössbauer Measurement Signals
by
Justus Pawlak, Jules Brehme, Maximilian Seydi Kilic, Kevin Tran, Justin Koch, Mohammad Beyki, Ralf Sindelar, Robert Patzke and Franz Renz
Polymers 2024, 16(10), 1311; https://doi.org/10.3390/polym16101311 - 07 May 2024
Abstract
Coordination compounds, like iron(II) triazole complexes, exhibit spin crossover (SCO) behavior at around room temperature. Therefore, they are interesting for a variety of possible applications, and it is convenient to integrate them into polymers. Due to a reduction of the iron content and
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Coordination compounds, like iron(II) triazole complexes, exhibit spin crossover (SCO) behavior at around room temperature. Therefore, they are interesting for a variety of possible applications, and it is convenient to integrate them into polymers. Due to a reduction of the iron content and thus also 57Fe content in the sample through integration in polymers, Mössbauer measurements are only possible with greater difficulty or very long measurement times without expensive enrichment of the samples with 57Fe. So, other ways of improving the Mössbauer signal for these composite materials are necessary. Therefore, we pressed these composite materials to improve the Mössbauer spectra. In this study, we synthesized an iron(II) triazole spin crossover complex and an electrospun polymer complex composite nanofiber material including the same complex. For both products, Mössbauer measurements were performed at room temperature before and after using a press to show that the complex composite is not harmed through pressing. We investigate the influence of the pressing impact on the Mössbauer measurements in the context of measurement statistics and the measured signals. We show that pressing is not connected to any changes in the sample regarding the spin and oxidation state. We present that pressing improves the statistics of the Mössbauer measurements significantly. Furthermore, we use SEM measurements and PXRD to investigate whether or not the obtained fiber mats are destroyed in the pressing process.
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(This article belongs to the Special Issue Functional Polymer Materials and Advanced Processing Technology)
Open AccessReview
Challenges of Green Transition in Polymer Production: Applications in Zero Energy Innovations and Hydrogen Storage
by
Iva Rezić and Ernest Meštrović
Polymers 2024, 16(10), 1310; https://doi.org/10.3390/polym16101310 - 07 May 2024
Abstract
The green transition in the sustainable production and processing of polymers poses multifaceted challenges that demand integral comprehensive solutions. Specific problems of presences of toxic trace elements are often missed and this prevents shifting towards eco-friendly alternatives. Therefore, substantial research and the development
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The green transition in the sustainable production and processing of polymers poses multifaceted challenges that demand integral comprehensive solutions. Specific problems of presences of toxic trace elements are often missed and this prevents shifting towards eco-friendly alternatives. Therefore, substantial research and the development of novel approaches is needed to discover and implement innovative, sustainable production materials and methods. This paper is focused on the most vital problems of the green transition from the aspect of establishing universally accepted criteria for the characterization and classification of eco-friendly polymers, which is essential to ensuring transparency and trust among consumers. Additionally, the recycling infrastructure needs substantial improvement to manage the end-of-life stage of polymer products effectively. Moreover, the lack of standardized regulations and certifications for sustainable polymers adds to the complexity of this problem. In this paper we propose solutions from the aspect of standardization protocols for the characterization of polymers foreseen as materials that should be used in Zero Energy Innovations in Hydrogen Storage. The role model standards originate from eco-labeling procedures for materials that come into direct or prolonged contact with human skin, and that are monitored by different methods and testing procedures. In conclusion, the challenges of transitioning to green practices in polymer production and processing demands a concerted effort from experts in the field which need to emphasize the problems of the analysis of toxic ultra trace and trace impurities in samples that will be used in hydrogen storage, as trace impurities may cause terrific obstacles due to their decreasing the safety of materials. Overcoming these obstacles requires the development and application of current state-of-the-art methodologies for monitoring the quality of polymers during their recycling, processing, and using, as well as the development of other technological innovations, financial initiatives, and a collective commitment to fostering a sustainable and environmentally responsible future for the polymer industry and innovations in the field of zero energy applications.
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(This article belongs to the Section Circular and Green Polymer Science)
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Open AccessArticle
Constructing Self-Healing Polydimethylsiloxane through Molecular Structure Design and Metal Ion Bonding
by
Lvchao Qiu, Yutong Zhou, Zhoufeng Zhao, Qi Wang, Lijun Chu and Shipeng Wen
Polymers 2024, 16(10), 1309; https://doi.org/10.3390/polym16101309 - 07 May 2024
Abstract
Self-healing polydimethylsiloxane (PDMS) has garnered significant attention due to its potential applications across various fields. In this study, a functionalized modification of PDMS containing di-aminos was initially conducted using 2,6-pyridinedicarbonyl chloride to synthesize pyridine-PDMS (Py-PDMS). Subsequently, rare earth metal europium ions (Eu3+
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Self-healing polydimethylsiloxane (PDMS) has garnered significant attention due to its potential applications across various fields. In this study, a functionalized modification of PDMS containing di-aminos was initially conducted using 2,6-pyridinedicarbonyl chloride to synthesize pyridine-PDMS (Py-PDMS). Subsequently, rare earth metal europium ions (Eu3+) were incorporated into Py-PDMS. Due to the coordination interaction between Eu3+ and organic ligands, a coordination cross-linking network was created within the Py-PDMS matrix, resulting in the fabrication of Eu3+-Py-PDMS elastomer. At a molar ratio of Eu3+ to ligands of 1:1, the tensile strength of Eu3+-Py-PDMS reached 1.4 MPa, with a fracture elongation of 824%. Due to the dynamic reversibility of coordination bonds, Eu3+-Py-PDMS with a metal-to-ligand molar ratio of 1:2 exhibited varying self-healing efficiencies at different temperatures. Notably, after 4 h of repair at 60 °C, its self-healing efficiency reached nearly 100%. Furthermore, the gas barrier properties of Eu3+-Py-PDMS with a molar ratio of 1:1 was improved compared with that of Eu3+-Py-PDMS with a molar ratio of 1:1. This study provides an effective strategy for the design and fabrication of PDMS with high mechanical strength, high gas barrier properties, and exceptional self-healing efficiency.
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(This article belongs to the Special Issue Multi-Functional and Intelligent Polymer Composites: Synthesis, Characterization and Applications)
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Open AccessArticle
Polymer Nanocomposite Based on Pyrolyzed Polyacrylonitrile Doped with Carbon Nanotubes: Synthesis, Properties, and Mechanism of Formation
by
Irina Zaporotskova, Olesya Kakorina, Lev Kozhitov, Dmitriy Muratov, Natalia Boroznina, Sergei Boroznin and Alexandra Panchenko
Polymers 2024, 16(10), 1308; https://doi.org/10.3390/polym16101308 - 07 May 2024
Abstract
The paper investigates the possibility of fabricating a carbon nanotubes (CNT)-modified nanocomposite based on pyrolyzed polyacrylonitrile (PPAN). The layered structure of PPAN ensures the attachment of nanotubes (NT) to the polymer matrix, forming enhanced PPAN/CNT nanocomposites. We synthesized a PPAN/CNT polymer nanocomposite and
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The paper investigates the possibility of fabricating a carbon nanotubes (CNT)-modified nanocomposite based on pyrolyzed polyacrylonitrile (PPAN). The layered structure of PPAN ensures the attachment of nanotubes (NT) to the polymer matrix, forming enhanced PPAN/CNT nanocomposites. We synthesized a PPAN/CNT polymer nanocomposite and investigated its mechanical, conductive, and electronic properties. Using the quantum chemical method density functional theory (DFT), we studied an interaction mechanism between PPAN and single-walled carbon nanotubes. We described the structural features and electron energy structure of the obtained systems. We found that the attachment of a CNT to the PPAN matrix increases tensile strength, electrical conductivity, and thermal stability in the complex. The obtained materials were exposed to electromagnetic radiation and the dielectric constant, reflection, transmission, and absorption coefficients were measured. The study demonstrates the possibility of using carbon nanotubes for reinforcing polyacrylonitrile polymer matrix, which can result in the development of an enhanced class of materials possessing the properties of both polymers and CNTs.
Full article
(This article belongs to the Section Polymer Physics and Theory)
Open AccessArticle
Electrospun Polylactide—Poly(ε-Caprolactone) Fibers: Structure Characterization and Segmental Dynamic Response
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Svetlana G. Karpova, Anatoly A. Olkhov, Ivetta A. Varyan, Oksana I. Khan, Andrey A. Botin, Anna V. Naletova, Anatoly A. Popov and Alexey L. Iordanskii
Polymers 2024, 16(10), 1307; https://doi.org/10.3390/polym16101307 - 07 May 2024
Abstract
Electrospun ultrathin fibers based on binary compositions of polylactide (PLA) and poly(ε-caprolactone) (PCL) with the various content from the polymer ratio from 0/100 to 100/0 have been explored. Combining thermal (DSC) and spectropy (ESR) techniques, the effect of biopolymer content on the characteristics
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Electrospun ultrathin fibers based on binary compositions of polylactide (PLA) and poly(ε-caprolactone) (PCL) with the various content from the polymer ratio from 0/100 to 100/0 have been explored. Combining thermal (DSC) and spectropy (ESR) techniques, the effect of biopolymer content on the characteristics of the crystal structure of PLA and PCL and the rotative diffusion of the stable TEMPO radical in the intercrystallite areas of PLA/PCL compositions was shown. It was revealed that after PLA and PCL blending, significant changes in the degree of crystallinity of PLA, PCL segment mobility, sorption of the Tempo probe, as well as its activation energy of rotation in the intercrystalline areas of PLA/PCL fibers, were evaluated. The characteristic region of biopolymers’ composition from 50/50 to 30/70% PLA/PCL blend ratio was found, where the inversion transition of PLA from dispersive medium to dispersive phase where an inversion transition is assumed when the continuous medium of the PLA transforms into a discrete phase. The performed studies made it possible, firstly, to carry out a detailed study of the effect of the system component ratio on the structural and dynamic characteristics of the PLA/PCL film material at the molecular level.
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(This article belongs to the Collection Polymers for Controlled Drug Release)
Open AccessArticle
Improvement of Geotechnical Properties of Clayey Soil Using Biopolymer and Ferrochromium Slag Additives
by
Mustafa Yasin Çetin, Baki Bağrıaçık, Hatice Merve Annagür and Szymon Topoliński
Polymers 2024, 16(10), 1306; https://doi.org/10.3390/polym16101306 - 07 May 2024
Abstract
The geotechnical properties of clay soil and its mixtures with different proportions (0.75%, 0.85%, 1%, and 1.15%) of Agar Gum biopolymer and Ferrochromium Slag (0.25%, 0.50%, 0.75%, and 1%), having various curing times and freeze-thaw cycles, were studied through a series of soil
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The geotechnical properties of clay soil and its mixtures with different proportions (0.75%, 0.85%, 1%, and 1.15%) of Agar Gum biopolymer and Ferrochromium Slag (0.25%, 0.50%, 0.75%, and 1%), having various curing times and freeze-thaw cycles, were studied through a series of soil mechanical tests to investigate possibilities to improve its undesired/problematic plasticity, compaction, and shear strength characteristics. The results revealed that treatment with an optimal ratio of 1% Agar Gum and 1% Ferrochromium Slag alone, as well as together with, improved the geotechnical properties of the clay soil considerably. Both the unconfined and shear strength properties, along with the cohesion and internal friction angle, increased as much as 47 to 173%, depending on the curing time. The higher the curing time, the higher the shear strength, cohesion, and internal friction angle are up to 21 days. Deteriorating the soil structure and/or fabric, freeze-thaw cycles, however, seem to have an adverse effect on the strength. The higher the freeze-thaw cycle, the lower the shear strength, cohesion, and internal friction angle. Also, some improvements in the plasticity and compaction properties were determined, and environmental concerns regarding Ferrochromium Slag usage have been addressed.
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(This article belongs to the Collection Progress in Recycling of (Bio)Polymers and Composites)
Open AccessArticle
Piezoelectric Yield of Single Electrospun Poly(acrylonitrile) Ultrafine Fibers Studied by Piezoresponse Force Microscopy and Numerical Simulations
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Margherita Montorsi, Lorenzo Zavagna, Lorenzo Scarpelli, Bahareh Azimi, Simone Capaccioli, Serena Danti and Massimiliano Labardi
Polymers 2024, 16(10), 1305; https://doi.org/10.3390/polym16101305 - 07 May 2024
Abstract
Quantitative converse piezoelectric coefficient (d33) mapping of polymer ultrafine fibers of poly(acrylonitrile) (PAN), as well as of poly(vinylidene fluoride) (PVDF) as a reference material, obtained by rotating electrospinning, was carried out by piezoresponse force microscopy in the constant-excitation frequency-modulation mode
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Quantitative converse piezoelectric coefficient (d33) mapping of polymer ultrafine fibers of poly(acrylonitrile) (PAN), as well as of poly(vinylidene fluoride) (PVDF) as a reference material, obtained by rotating electrospinning, was carried out by piezoresponse force microscopy in the constant-excitation frequency-modulation mode (CE-FM-PFM). PFM mapping of single fibers reveals their piezoelectric activity and provides information on its distribution along the fiber length. Uniform behavior is typically observed on a length scale of a few micrometers. In some cases, variations with sinusoidal dependence along the fiber are reported, compatibly with a possible twisting around the fiber axis. The observed features of the piezoelectric yield have motivated numerical simulations of the surface displacement in a piezoelectric ultrafine fiber concerned by the electric field generated by biasing of the PFM probe. Uniform alignment of the piezoelectric axis along the fiber would comply with the uniform but strongly variable values observed, and sinusoidal variations were occasionally found on the fibers laying on the conductive substrate. Furthermore, in the latter case, numerical simulations show that the piezoelectric tensor’s shear terms should be carefully considered in estimations since they may provide a remarkably different contribution to the overall deformation profile.
Full article
(This article belongs to the Special Issue Electrospun Polymer Nanofibers: Preparation, Design, and Characterization)
Open AccessReview
Biopolymer Materials in Triboelectric Nanogenerators: A Review
by
Qiliang Zhu, Enqi Sun, Zequan Zhao, Tong Wu, Shuchang Meng, Zimeng Ma, Shoaib Muhammad, Hafeez Ur Rehman, Xia Cao and Ning Wang
Polymers 2024, 16(10), 1304; https://doi.org/10.3390/polym16101304 - 07 May 2024
Abstract
In advancing the transition of the energy sector toward heightened sustainability and environmental friendliness, biopolymers have emerged as key elements in the construction of triboelectric nanogenerators (TENGs) due to their renewable sources and excellent biodegradability. The development of these TENG devices is of
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In advancing the transition of the energy sector toward heightened sustainability and environmental friendliness, biopolymers have emerged as key elements in the construction of triboelectric nanogenerators (TENGs) due to their renewable sources and excellent biodegradability. The development of these TENG devices is of significant importance to the next generation of renewable and sustainable energy technologies based on carbon-neutral materials. This paper introduces the working principles, material sources, and wide-ranging applications of biopolymer-based triboelectric nanogenerators (BP-TENGs). It focuses on the various categories of biopolymers, ranging from natural sources to microbial and chemical synthesis, showcasing their significant potential in enhancing TENG performance and expanding their application scope, while emphasizing their notable advantages in biocompatibility and environmental sustainability. To gain deeper insights into future trends, we discuss the practical applications of BP-TENG in different fields, categorizing them into energy harvesting, healthcare, and environmental monitoring. Finally, the paper reveals the shortcomings, challenges, and possible solutions of BP-TENG, aiming to promote the advancement and application of biopolymer-based TENG technology. We hope this review will inspire the further development of BP-TENG towards more efficient energy conversion and broader applications.
Full article
(This article belongs to the Special Issue Environment-Friendly Polymers: Synthesis, Processing and Applications (2nd Edition))
Open AccessArticle
Empowering Rehabilitation: Design and Structural Analysis of a Low-Cost 3D-Printed Smart Orthosis
by
Florin Popișter, Mihai Dragomir, Paul Ciudin and Horea Ștefan Goia
Polymers 2024, 16(10), 1303; https://doi.org/10.3390/polym16101303 - 07 May 2024
Abstract
Three-dimensional (3D) printing of polymer materials encompasses a wide range of applications and innovations. Polymer-based 3D printing, also known as additive manufacturing, has gained significant attention due to its versatility, cost-effectiveness, and potential to revolutionize various industries. The current paper focuses on obtaining
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Three-dimensional (3D) printing of polymer materials encompasses a wide range of applications and innovations. Polymer-based 3D printing, also known as additive manufacturing, has gained significant attention due to its versatility, cost-effectiveness, and potential to revolutionize various industries. The current paper focuses on obtaining a durable low-cost rehabilitation knee orthosis. Researchers propose that the entire structure should be obtained using modern equipment within the additive manufacturing domain—3D printing. The researchers focus on determining, through a 3D analysis of the entire 3D model assembly, which parts present a high degree of stress when a kinematic simulation is developed. The entire 3D model of the orthosis starts based on the result obtained from a 3D scanning of the knee joint of a patient, providing a precise fixation, and allowing for direct personalization. Based on the results and identification of the critical parts, there will be used different materials and a combination of 3D printing strategies to validate the physical model of the entire orthosis. For the manufacturing process, the researchers use two types of low-cost fused filament fabrication (FFF), which are easy to find on the worldwide market. The motivation for manufacturing the entire assembly using 3D printing techniques is the short time in which complex shapes can be obtained, which is relevant for the present study. The main purpose of the present research is to advance orthotic technology by developing an innovative knee brace made of 3D-printed polymers that are designed to be lightweight, easy-to-use, and provide comfort and functionality to patients during the rehabilitation process.
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(This article belongs to the Special Issue Mechanical and Physical Properties of 3D Printed Polymer Materials)
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Open AccessArticle
Effect of Feed Mass, Reactor Temperature, and Time on the Yield of Waste Polypropylene Pyrolysis Oil Produced via a Fixed-Bed Reactor
by
Saša Papuga, Jelena Savković, Milica Djurdjevic and Stefano Vecchio Ciprioti
Polymers 2024, 16(10), 1302; https://doi.org/10.3390/polym16101302 - 07 May 2024
Abstract
This paper presents the results of investigations into the pyrolysis of waste polypropylene in a laboratory fixed-bed batch reactor. The experiments were designed and verified in such a way as to allow the application of the response surface methodology (RSM) in the development
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This paper presents the results of investigations into the pyrolysis of waste polypropylene in a laboratory fixed-bed batch reactor. The experiments were designed and verified in such a way as to allow the application of the response surface methodology (RSM) in the development of an empirical mathematical model that quantifies the impacts mentioned above. The influence of the mass of the raw material (50, 100, and 150 g) together with the reactor temperature (450, 475, and 500 °C) and the reaction time (45, 50 and 75 min) was examined. It has been shown that the mass of the raw material, i.e., the filling volume of the reactor, has a significant influence on the pyrolysis oil yield. This influence exceeds the influence of reactor temperature and reaction time. This was explained by observing the temperature change inside the reactor at three different spots at the bottom, middle, and top of the reactor. The recorded temperature diagrams show that, with greater masses of feedstock, local overheating occurs in the middle part of the reactor, which leads to the overcracking of volatile products and, from there, to an increased formation of non-condensable gases, i.e., a reduced yield of pyrolytic oil.
Full article
(This article belongs to the Special Issue Recent Developments in Thermal and Catalytic Recycling of Plastic Waste)
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Open AccessCorrection
Correction: Namathoti, S.; Vakkalagadda, M.R.K. Development of Multiwalled Carbon Nanotubes/Halloysite Nanotubes Reinforced Thermal Responsive Shape Memory Polymer Nanocomposites for Enhanced Mechanical and Shape Recovery Characteristics in 4D Printing Applications. Polymers 2023, 15, 1371
by
Sivanagaraju Namathoti and Manikanta Ravindra Kumar Vakkalagadda
Polymers 2024, 16(10), 1301; https://doi.org/10.3390/polym16101301 - 07 May 2024
Abstract
The authors wish to make the following corrections to this paper: [...]
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Open AccessArticle
Mitigation of Soil Erosion and Enhancement of Slope Stability through the Utilization of Lignin Biopolymer
by
Pouyan Bagheri, Ivan Gratchev, Masih Zolghadr, Suwon Son and Jin Man Kim
Polymers 2024, 16(9), 1300; https://doi.org/10.3390/polym16091300 - 06 May 2024
Abstract
Human activities have had a profound impact on the environment, particularly in relation to surface erosion and landslides. These processes, which are natural phenomena, have been exacerbated by human actions, leading to detrimental consequences for ecosystems, communities, and the overall health of the
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Human activities have had a profound impact on the environment, particularly in relation to surface erosion and landslides. These processes, which are natural phenomena, have been exacerbated by human actions, leading to detrimental consequences for ecosystems, communities, and the overall health of the planet. The use of lignin (LIG) as a biopolymer soil additive material is regarded as an eco-friendly solution against soil erosion and slope failure which holds immense promise. However, significant research gaps currently hinder a comprehensive understanding of its mechanisms and effectiveness. Experimental studies offer a robust platform to address these gaps by providing controlled conditions for assessing soil stability, exploring mechanisms, and evaluating adaptability. Bridging these research gaps will contribute to the development of innovative and sustainable strategies for mitigating soil erosion and preventing slope failure, thereby promoting environmental resilience and resource conservation. This study aimed to investigate the effect of the LIG biopolymer on mitigation of soil erosion, slope failure and the enhancement of soil strength by conducting laboratory tests (UU triaxial, unconfined compressive strength (UCS), and soaking) as well as flume experiments under uniform rainfall events. The alterations in the engineering characteristics and erosion resistance of silty soil mixed with a LIG additive at concentrations of 1% and 3.0% by weight have been examined. The results show that the LIG-treated samples demonstrated an enhanced resistance to surface erosion and an enhanced prevention of slope failure, as well as improved shear stress, cohesion, stiffness, and resistance to water infiltration.
Full article
(This article belongs to the Special Issue Biodegradable Polymer Composites: Fabrication and Applications II)
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Open AccessArticle
Modelling Fatigue Crack Growth in High-Density Polyethylene and Acrylonitrile Butadiene Styrene Polymers
by
Rhys Jones, Anthony J. Kinloch and Andrew S. M. Ang
Polymers 2024, 16(9), 1299; https://doi.org/10.3390/polym16091299 - 06 May 2024
Abstract
Prior studies into fatigue crack growth (FCG) in fibre-reinforced polymer composites have shown that the two methodologies of Simple-Scaling and the Hartman–Schijve crack growth equation, which is based on relating the FCG rate to the Schwalbe crack driving force, Δκ, were
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Prior studies into fatigue crack growth (FCG) in fibre-reinforced polymer composites have shown that the two methodologies of Simple-Scaling and the Hartman–Schijve crack growth equation, which is based on relating the FCG rate to the Schwalbe crack driving force, Δκ, were able to account for differences observed in the measured delamination growth curves. The present paper reveals that these two approaches are also able to account for differences seen in plots of the rate of crack growth, da/dt, versus the range of the imposed stress intensity factor, ΔK, associated with fatigue tests on different grades of high-density polyethylene (HDPE) polymers, before and after electron-beam irradiation, and for tests conducted at different R ratios. Also, these studies are successfully extended to consider FCG in an acrylonitrile butadiene styrene (ABS) polymer that is processed using both conventional injection moulding and additive-manufactured (AM) 3D printing.
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(This article belongs to the Section Polymer Physics and Theory)
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Open AccessArticle
Flame-Retarded and Heat-Resistant PP Compounds for Halogen-Free Low-Smoke Cable Protection Pipes (HFLS Conduits)
by
Athanasios D. Porfyris, Afxentis Vafeiadis, Christina I. Gkountela, Christos Politidis, Georgios Messaritakis, Epameinondas Orfanoudakis, Silvia Pavlidou, Dimitrios M. Korres, Apostolos Kyritsis and Stamatina N. Vouyiouka
Polymers 2024, 16(9), 1298; https://doi.org/10.3390/polym16091298 - 06 May 2024
Abstract
Conduits are plastic tubes extensively used to safeguard electrical cables, traditionally made from PVC. Recent safety guidelines seek alternatives due to PVC’s emission of thick smoke and toxic gases upon fire incidents. Polypropylene (PP) is emerging as a viable alternative but requires modification
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Conduits are plastic tubes extensively used to safeguard electrical cables, traditionally made from PVC. Recent safety guidelines seek alternatives due to PVC’s emission of thick smoke and toxic gases upon fire incidents. Polypropylene (PP) is emerging as a viable alternative but requires modification with suitable halogen-free additives to attain flame retardancy (FR) while maintaining high mechanical strength and weathering resistance, especially for outdoor applications. The objective of this study was to develop two FR systems for PP: one comprising a cyclic phosphonate ester and a monomeric N-alkoxy hindered amine adjuvant achieving V0, and another with hypophosphite and bromine moieties, along with a NOR-HAS adjuvant achieving V2. FR performance along with mechanical properties, physicochemical characterization, and dielectric behavior were evaluated prior to and after 2000 h of UV weathering or heat ageing. The developed FR systems set the basis for the production of industrial-scale masterbatches, from which further optimization to minimize FR content was performed via melt mixing with PP towards industrialization of a low-cost FR formulation. Accordingly, two types of corrugated conduits (ø20 mm) were manufactured. Their performance in terms of flame propagation, impact resistance, smoke density, and accelerated UV weathering stability classified them as Halogen Free Low Smoke (HFLS) conduits; meanwhile, they meet EU conduit standards without significantly impacting conduit properties or industrial processing efficiency.
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(This article belongs to the Special Issue State-of-the-Art Polymer Science and Technology in Greece II)
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Open AccessArticle
A New Sustainable PPT Coating Based on Recycled PET to Improve the Durability of Hydraulic Concrete
by
Adrián Bórquez-Mendivil, Carlos Paulino Barrios-Durstewitz, Rosa Elba Núñez-Jáquez, Abel Hurtado-Macías, Jesús Eduardo Leal-Pérez, Joaquín Flores-Valenzuela, Blanca Alicia García-Grajeda, Francisca Guadalupe Cabrera-Covarrubias, José Miguel Mendivil-Escalante and Jorge Luis Almaral-Sánchez
Polymers 2024, 16(9), 1297; https://doi.org/10.3390/polym16091297 - 06 May 2024
Abstract
A new, sustainable polypropylene terephthalate (PPT) coating was synthesized from recycled polyethylene terephthalate (PET) and applied onto a hydraulic concrete substrate to improve its durability. For the first step, PET bottle wastes were ground and depolymerized by glycolysis using propylene glycol (PG) in
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A new, sustainable polypropylene terephthalate (PPT) coating was synthesized from recycled polyethylene terephthalate (PET) and applied onto a hydraulic concrete substrate to improve its durability. For the first step, PET bottle wastes were ground and depolymerized by glycolysis using propylene glycol (PG) in a vessel-type reactor (20–180 °C) to synthesize bis(2-hydroxypropyl)-terephthalate (BHPT), which was applied as a coating to one to three layers of hydraulic concrete substrate using the brushing technique and polymerized (150 °C for 15 h) to obtain PPT. PET, BHPT, and PPT were characterized by FT-IR, PET, and PPT using TGA, and the PPT coatings by SEM (thickness), ASTM-D3359-17 (adhesion), and water contact angle (wettability). The durability of hydraulic concrete coated with PPT was studied using resist chloride ion penetration (ASTM-C1202-17), carbonation depth at 28 days (RILEM-CPC-18), and the absorption water ratio (ASTM-C1585-20). The results demonstrated that the BHPT and PPT were synthetized (FT-IR), and PPT had a similar thermal behavior to PET (TGA); the PPT coatings had good adhesion to the substrate, with thicknesses of micrometric units. PPT coatings presented hydrophilic hydrophilic behavior like PET coatings, and the durability of hydraulic concrete coated with PPT (2–3 layers) improved (migration of chloride ions decreased, carbonation depth was negligible, and the absorption water ratio decreased).
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(This article belongs to the Section Polymer Composites and Nanocomposites)
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Nonlinear Conductivity and Thermal Stability of Anti-Corona Epoxy Resin Nanocomposites
by
Yanli Liu, Junguo Gao, Ning Guo, Jiaming Sun, Haitao Hu and Xiaohong Chi
Polymers 2024, 16(9), 1296; https://doi.org/10.3390/polym16091296 - 05 May 2024
Abstract
The long-term operation of motors induces substantial alterations in the surface conductivity and nonlinear coefficient of anti-corona paint, diminishing its efficacy and jeopardizing the longevity of large motors. Hence, the development of high-performance anti-corona paint holds paramount importance in ensuring motor safety. In
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The long-term operation of motors induces substantial alterations in the surface conductivity and nonlinear coefficient of anti-corona paint, diminishing its efficacy and jeopardizing the longevity of large motors. Hence, the development of high-performance anti-corona paint holds paramount importance in ensuring motor safety. In this study, we integrate two nano-fillers, namely silicon carbide (SiC) and organic montmorillonite (O-MMT), into a composite matrix comprising micron silicon carbide and epoxy resin (SiC/EP). Subsequently, three distinct types of anti-corona paint are formulated: SiC/EP, Nano-SiC/EP, and O-MMT/SiC/EP. Remarkably, O-MMT/SiC/EP exhibits a glass transition temperature about 25 °C higher than that of SiC/EP, underscoring its superior thermal properties. Moreover, the introduction of nano-fillers markedly augments the surface conductivity of the anti-corona paint. Aging tests, conducted across varying temperatures, unveil a notable reduction in the fluctuation range of surface conductivity post-aging. Initially, the nonlinear coefficients exhibit a declining trend, succeeded by an ascending trajectory. The O-MMT/SiC/EP composite displays a maximum nonlinearity coefficient of 1.465 and a minimum of 1.382. Furthermore, the incorporation of nanofillers amplifies the dielectric thermal stability of epoxy resin composites, with O-MMT/SiC/EP showcasing the pinnacle of thermal endurance. Overall, our findings elucidate the efficacy of nano-fillers in enhancing the performance and longevity of anti-corona paint, particularly highlighting the exceptional attributes of the O-MMT/SiC/EP composite in bolstering motor safety through improved thermal stability and electrical properties.
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(This article belongs to the Special Issue New Insight into Polymer Dynamics)
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Modified Composite Biodegradable Mulch for Crop Growth and Sustainable Agriculture
by
Bo Guo, Liyan Zhu, Xiaochan He, Xiaojun Zhou, Boru Dong and Jialei Liu
Polymers 2024, 16(9), 1295; https://doi.org/10.3390/polym16091295 - 05 May 2024
Abstract
Using biodegradable films as a substitute for conventional polyolefin films has emerged as a crucial technology to combat agricultural white pollution. To address the shortcomings in the tensile strength, water vapor barrier properties, and degradation period of PBAT-based biodegradable films, this investigation aimed
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Using biodegradable films as a substitute for conventional polyolefin films has emerged as a crucial technology to combat agricultural white pollution. To address the shortcomings in the tensile strength, water vapor barrier properties, and degradation period of PBAT-based biodegradable films, this investigation aimed to create a composite film that could improve the diverse properties of PBAT films. To achieve this, a PBAT/PLA-PPC-PTLA ternary blend system was introduced in the study. The system effectively fused PBAT with PLA and PPC, as evidenced by electron microscopy tests showing no apparent defects on the surface and cross-section of the blended film. The developed ternary blend system resulted in a 58.62% improvement in tensile strength, a 70.33% enhancement in water vapor barrier properties, and a 30-day extension of the functional period compared to pure PBAT biodegradable films. Field experiments on corn crops demonstrated that the modified biodegradable film is more suitable for agricultural production, as it improved thermal insulation and moisture retention, leading to a 5.45% increase in corn yield, approaching the yield of traditional polyolefin films.
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(This article belongs to the Special Issue High Performance Polymer Membranes II)
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Biosynthesis of Polyhydroxyalkanoates in Cupriavidus necator B-10646 on Saturated Fatty Acids
by
Natalia O. Zhila, Kristina Yu. Sapozhnikova, Evgeniy G. Kiselev, Ekaterina I. Shishatskaya and Tatiana G. Volova
Polymers 2024, 16(9), 1294; https://doi.org/10.3390/polym16091294 - 05 May 2024
Abstract
It has been established that the wild-type Cupriavidus necator B-10646 strain uses saturated fatty acids (SFAs) for growth and polyhydroxyalkanoate (PHA) synthesis. It uses lauric (12:0), myristic (14:0), palmitic (16:0) and stearic (18:0) acids as carbon sources; moreover, the elongation of the C-chain
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It has been established that the wild-type Cupriavidus necator B-10646 strain uses saturated fatty acids (SFAs) for growth and polyhydroxyalkanoate (PHA) synthesis. It uses lauric (12:0), myristic (14:0), palmitic (16:0) and stearic (18:0) acids as carbon sources; moreover, the elongation of the C-chain negatively affects the biomass and PHA yields. When bacteria grow on C12 and C14 fatty acids, the total biomass and PHA yields are comparable up to 7.5 g/L and 75%, respectively, which twice exceed the values that occur on longer C16 and C18 acids. Regardless of the type of SFAs, bacteria synthesize poly(3-hydroxybutyrate), which have a reduced crystallinity (Cx from 40 to 57%) and a molecular weight typical for poly(3-hydroxybutyrate) (P(3HB)) (Mw from 289 to 465 kDa), and obtained polymer samples demonstrate melting and degradation temperatures with a gap of about 100 °C. The ability of bacteria to assimilate SFAs opens up the possibility of attracting the synthesis of PHAs on complex fat-containing substrates, including waste.
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(This article belongs to the Special Issue Bio-Based Polymers' Application and Technology for Better Quality of Life)
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A Review of Natural Fiber-Reinforced Composites for Lower-Limb Prosthetic Designs
by
Angel D. Castro-Franco, Miriam Siqueiros-Hernández, Virginia García-Angel, Ismael Mendoza-Muñoz, Lidia E. Vargas-Osuna and Hernán D. Magaña-Almaguer
Polymers 2024, 16(9), 1293; https://doi.org/10.3390/polym16091293 - 05 May 2024
Abstract
This paper presents a comprehensive review of natural fiber-reinforced composites (NFRCs) for lower-limb prosthetic designs. It covers the characteristics, types, and properties of natural fiber-reinforced composites as well as their advantages and drawbacks in prosthetic designs. This review also discusses successful prosthetic designs
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This paper presents a comprehensive review of natural fiber-reinforced composites (NFRCs) for lower-limb prosthetic designs. It covers the characteristics, types, and properties of natural fiber-reinforced composites as well as their advantages and drawbacks in prosthetic designs. This review also discusses successful prosthetic designs that incorporate NFRCs and the factors that make them effective. Additionally, this study explores the use of computational biomechanical models to evaluate the effectiveness of prosthetic devices and the key factors that are considered. Overall, this document provides a valuable resource for anyone interested in using NFRCs for lower-limb prosthetic designs.
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(This article belongs to the Special Issue A Commemorative Issue in Honor of Professor Jose M. Kenny: Advances in Polymer Composites and Nanocomposites)
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