This paper presents a simulator model of a diesel engine with a turbocharger for hardware-in-the-loop (HIL) applications, which is used to obtain engine performance data to study the engine performance under faulty conditions, to assist engineers in diagnosis and estimation, and to assist engineers in model-based calibration (MBC). The whole diesel engine system is divided into several functional blocks: air block, injection block, cylinder block, crankshaft block, cooling block, lubrication block, and accessory block. The diesel engine model is based on physical level, semi-physical level and mathematical level concepts, and developed by Matlab/Simulink. All the model parameters are estimated using weighted least-squares optimization and the tuning process details are presented. Since the sub-model coupling may cause errors, the validation process is then given to make the model more accurate. The results show that the tuning process is important for the functional blocks and the validation process is useful for the accuracy of the whole engine model. Subsequently, this program could be used as a plant model for MBC, to develop and test engine control units (ECUs) on HIL equipment for the purpose of improving ECU performance. Full article

We reported the fabrication of an in situ surface-enhanced Raman scattering (SERS) monitoring platform, comprised of a porous eggshell membrane (ESM) bioscaffold loaded with Ag nanoprism via an electrostatic self-assembly approach. The localized surface plasmon resonance (LSPR) property of silver nanoprism leads to the blue color of the treated ESMs. UV-vis diffuse reflectance spectroscopy, scanning electron microscope (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) measurements were employed to observe the microstructure and surface property of Ag nanoprisms on the ESMs. The silver nanoprism-loaded eggshell membrane (AgNP@ESM) exhibited strong catalytic activity for the reduction of 4-nitrophenol by sodium borohydride (NaBH₄) and it can be easily recovered and reused for more than six cycles. Significantly, the composites also display excellent SERS efficiency, allowing the in situ SERS monitoring of molecular transformation in heterogeneous catalysis. The results indicate that the AgNP@ESM biocomposite can achieve both SERS and catalytic functionalities simultaneously in a single entity with high performance, which promotes the potential applications of ESM modified with functional materials. Full article

The toxicity and carcinogenicity of aniline in humans and animals have been well documented. However, the molecular mechanism involved in aniline-induced liver toxicity and carcinogenesis remains unclear. In our research, primary cultured hepatocytes were exposed to aniline (0, 1.25, 2.50, 5.0 and 10.0 μg/mL) for 24 h in the presence or absence of N-acetyl-l-cysteine (NAC). Levels of reactive oxygen species (ROS), malondialdehyde (MDA), and glutathione (GSH), activities of superoxide dismutase (SOD) and catalase (CAT), mitochondrial membrane potential, DNA damage, cell viability, and apoptosis were detected. Levels of ROS and MDA were significantly increased and levels of GSH and CAT, activity of SOD, and mitochondrial membrane potential in hepatocytes were significantly decreased by aniline compared with the negative control group. The tail moment and DNA content of the tail in exposed groups were significantly higher than those in the negative control group. Cell viability was reduced and apoptotic death was induced by aniline in a concentration-dependent manner. The phenomena of ROS generation, oxidative damage, loss of mitochondrial membrane potential, DNA damage and apoptosis could be prevented if ROS inhibitor NAC was added. ROS generation is involved in the loss of mitochondrial membrane potential and DNA injury, which may play a role in aniline-induced apoptosis in hepatocytes. Our study provides insight into the mechanism of aniline-induced toxicity and apoptosis of hepatocytes. Full article

Daily time series of microwave radiometer data obtained in one-orbit direction are full of observation gaps due to satellite configuration and errors from spatial sampling. Such time series carry information about the surface signal including surface emittance and vegetation attenuation, and the atmospheric signal including atmosphere emittance and atmospheric attenuation. To extract the surface signal from this noisy time series, the Time Series Analysis Procedure (TSAP) was developed, based on the properties of the Discrete Fourier Transform (DFT). TSAP includes two stages: (1) identify the spectral features of observation gaps and errors and remove them with a modified boxcar filter; and (2) identify the spectral features of the surface signal and reconstruct it with the Harmonic Analysis of Time Series (HANTS) algorithm. Polarization Difference Brightness Temperature (PDBT) at 37 GHz data were used to illustrate the problems, to explain the implementation of TSAP and to validate this method, due to the PDBT sensitivity to the water content both at the land surface and in the atmosphere. We carried out a case study on a limited heterogeneous crop land and lake area, where the power spectrum of the PDBT time series showed that the harmonic components associated with observation gaps and errors have periods ≤8 days. After applying the modified boxcar filter with a length of 10 days, the RMSD between raw and filtered time series was above 11 K, mainly related to the power reduction in the frequency range associated with observation gaps and errors. Noise reduction is beneficial when applying PDBT observations to monitor wet areas and open water, since the PDBT range between dryland and open water is about 20 K. The spectral features of the atmospheric signal can be revealed by time series analysis of rain-gauge data, since the PDBT at 37 GHz is mainly attenuated by hydrometeors that yield precipitation. Thus, the spectral features of the surface signal were identified in the PDBT time series with the help of the rain-gauge data. HANTS reconstructed the upper envelope of the signal, i.e., correcting for atmospheric influence, while retaining the spectral features of the surface signal. To evaluate the impact of TSAP on retrieval accuracy, the fraction of Water Saturated Surface (WSS) in the region of Poyang Lake was retrieved with 37 GHz observations. The retrievals were evaluated against estimations of the lake area obtained with MODerate-resolution Imaging Spectroradiometer (MODIS) and Advanced Synthetic Aperture Radar (ASAR) data. The Relative RMSE on WSS was 39.5% with unfiltered data and 23% after applying TSAP, i.e., using the estimated surface signal only. Full article

Clouds usually cause invalid observations for sensors aboard satellites, which corrupts the spatio-temporal continuity of land surface parameters retrieved from remote sensing data (e.g., MODerate Resolution Imaging Spectroradiometer (MODIS) data) and prevents the fusing of multi-source remote sensing data in the field of quantitative remote sensing. Based on the requirements of spatio-temporal continuity and the necessity of methods to restore bad pixels, primarily resulting from image processing, this study developed a novel method to derive the spectral reflectance for MODIS band of cloudy pixels in the visual–near infrared (VIS–NIR) spectral channel based on the Bidirectional Reflectance Distribution Function (BRDF) and multi-spatio-temporal observations. The proposed method first constructs the spatial distribution of land surface reflectance based on the corresponding BRDF and the solar-viewing geometry; then, a geographically weighted regression (GWR) is introduced to individually derive the spectral surface reflectance for MODIS band of cloudy pixels. A validation of the proposed method shows that a total root-mean-square error (RMSE) of less than 6% and a total R² of more than 90% are detected, which indicates considerably better precision than those exhibited by other existing methods. Further validation of the retrieved white-sky albedo based on the spectral reflectance for MODIS band of cloudy pixels confirms an RMSE of 3.6% and a bias of 2.2%, demonstrating very high accuracy of the proposed method. Full article

FengYun-3B (FY-3B) soil moisture product, retrieved from passive microwave brightness temperature data based on the Qp model, has rarely been applied at the catchment and region scale. One of the reasons for this is its coarse spatial resolution (25-km). The study in this paper presented a new method to obtain a high spatial resolution soil moisture product by downscaling FY-3B soil moisture product from 25-km to 1-km spatial resolution using the theory of Apparent Thermal Inertia (ATI) under bare surface or sparse vegetation covered land surface. The relationship between soil moisture and ATI was first constructed, and the coefficients were obtained directly from 25-km FY-3B soil moisture product and ATI derived from MODIS data, which is different from previous studies often assuming the same set of coefficients applicable at different spatial resolutions. The method was applied to Naqu area on the Tibetan Plateau to obtain the downscaled 1-km resolution soil moisture product, the latter was validated using ground measurements collected from Soil Moisture/Temperature Monitoring Network on the central Tibetan Plateau (TP-STMNS) in 2012. The downscaled soil moisture showed promising results with a coefficient of determination R² higher than 0.45 and a root mean-square error (RMSE) less than 0.11 m³/m³ when comparing with the ground measurements at 5 sites out of the 9 selected sites. It was found that the accuracy of downscaled soil moisture was largely influenced by the accuracy of the FY-3B soil moisture product. The proposed method could be applied for both bare soil surface and sparsely vegetated surface. Full article

Although there have been numerous studies examining the toxicity and carcinogenicity of nickel compounds in humans and animals, its molecular mechanisms of action are not fully elucidated. In our research, NIH/3T3 cells were exposed to nickel-refining fumes at the concentrations of 0, 6.25, 12.50, 25, 50 and 100 μg/mL for 24 h. Cell viability, cell apoptosis, reactive oxygen species (ROS) level, lactate dehydrogenase (LDH) assay, the level of glutathione (GSH), activities of superoxide dismutase (SOD), catalase (CAT), and malondialdehyde (MDA) level were detected. The exposure of NIH/3T3 cells to nickel-refining fumes significantly reduced cell viability and induced cell apoptotic death in a dose-dependent manner. Nickel-refining fumes significantly increased ROS levels and induced DNA damage. Nickel-refining fumes may induce the changes in the state of ROS, which may eventually initiate oxidative stress, DNA damage and apoptosis of NIH/3T3 cells. Full article

Considering large and complex areas like the Tibetan Plateau, an analysis of the spatial distribution of the solar radiative budget over time not only requires the use of satellite remote sensing data, but also of an algorithm that accounts for strong variations of topography. Therefore, this research aims at developing a method to produce time series of solar radiative fluxes at high temporal and spatial resolution based on observed surface and atmosphere properties and topography. The objective is to account for the heterogeneity of the land surface using multiple land surface and atmospheric MODIS data products combined with a digital elevation model to produce estimations daily at the kilometric level. The developed approach led to the production of a three-year time series (2008–2010) of daily solar radiation budget at one kilometer spatial resolution across the Tibetan Plateau. The validation showed that the main improvement from the proposed method is a higher spatial and temporal resolution as compared to existing products. However, even if the solar radiation estimates are satisfying on clear sky conditions, the algorithm is less reliable under cloudy sky condition and the albedo product used here has a too coarse temporal resolution and is not accurate enough over rugged terrain. Full article

The time lag between anomalies in precipitation and vegetation activity plays a critical role in early drought detection as agricultural droughts are caused by precipitation shortages. The aim of this study is to explore a new approach to estimate the time lag between a forcing (precipitation) and a response (NDVI) signal in the frequency domain by applying cross-spectral analysis. We prepared anomaly time series of image data on TRMM3B42 precipitation (accumulated over antecedent durations of 10, 60, and 150 days) and NDVI, reconstructed and interpolated MOD13A2 and MYD13A2 to daily interval using a Fourier series method to model time series affected by gaps and outliers (iHANTS) for a dry and a wet year in a drought-prone area in the northeast region of China. Then, the cross-spectral analysis was applied pixel-wise and only the phase lag of the annual component of the forcing and response signal was extracted. The 10-day antecedent precipitation was retained as the best representation of forcing. The estimated phase lag was interpreted using maps of land cover and of available soil water-holding capacity and applied to investigate the difference in phenology responses between a wet and dry year. In both the wet and dry year, we measured consistent phase lags across land cover types. In the wet year with above-average precipitation, the phase lag was rather similar for all land cover types, i.e., 7.6 days for closed to open grassland and 14.5 days for open needle-leaved deciduous or evergreen forest. In the dry year, the phase lag increased by 7.0 days on average, but with specific response signals for the different land cover types. Interpreting the phase lag against the soil water-holding capacity, we observed a slightly higher phase lag in the dry year for soils with a higher water-holding capacity. The accuracy of the estimated phase lag was assessed through Monte Carlo simulations and presented reliable estimates for the annual component. Full article

Most land surface models require information on aerodynamic roughness length and its temporal and spatial variability. This research presents a practical approach for determining the aerodynamic roughness length at fine temporal and spatial resolution over the landscape by combining remote sensing and ground measurements. The basic framework of Raupach, with the bulk surface parameters redefined by Jasinski et al., has been applied to optical remote sensing data collected by the HJ-1A/1B satellites. In addition, a method for estimating vegetation height was introduced to derive the aerodynamic roughness length, which is preferred by users over the height-normalized form. Finally, mapping different vegetation classes was validated taking advantage of the data-dense field experiments conducted in the Heihe Watershed Allied Telemetry Experimental Research (HiWATER) project. Overall, the roughness model performed well against the measurements collected at most HiWATER flux tower sites. However, deviations still occurred at some sites, which have been further analyzed. Full article

As a typical inland river basin, Heihe River basin has been experiencing severe water resource competition between different land cover types, especially in the middle stream and downstream areas. Terrestrial actual evapotranspiration (ETa), including evaporation from soil and water surfaces, evaporation of rainfall interception, transpiration of vegetation canopy and sublimation of snow and glaciers, is an important component of the water cycle in the Heihe River basin. We developed a hybrid remotely sensed ETa estimation model named ETMonitor to estimate the daily actual evapotranspiration of the Heihe River basin for the years 2009–2011 at a spatial resolution of 1 km. The model was forced by a variety of biophysical parameters derived from microwave and optical remote sensing observations. The estimated ETa was evaluated using eddy covariance (EC) flux observations at local scale and compared with the annual precipitation and the MODIS ETa product (MOD16) at regional scale. The spatial distribution and the seasonal variation of the estimated ETa were analyzed. The results indicate that the estimated ETa shows reasonable spatial and temporal patterns with respect to the diverse cold and arid landscapes in the upstream, middle stream and downstream regions, and is useful for various applications to improve the rational allocation of water resources in the Heihe River basin. Full article

Accurate evapotranspiration (ET) estimation is very crucial for water resource management, particularly for the arid and semi-arid region. The remote sensing-based Priestley-Taylor method (RS-PT method) can estimate ET at regional scale, using the feature space of remotely sensed land surface temperature (LST) and vegetation index (VI). This study evaluates the RS-PT feature space method over an arid and semi-arid region in northwest China using satellite data from the moderate-resolution space-borne sensor Advanced Along-Track Scanning Radiometer (AATSR), the observations from the high-resolution airborne sensor Wide-angle Infrared Dual-mode line/area Array Scanner (WiDAS) and ground measurements of heat fluxes collected in summer 2008. The results show that the mean difference for latent heat flux (LE) estimates resulting from different domain sizes is 69.5 W/m². When using high-resolution images from airborne measurements, the dry boundary is strongly affected by the pixels of impervious surfaces, which lead to a mean difference of 15.36 W/m² for LE estimates. In addition, the physically based Surface Energy Balance Index (SEBI) model is used to analyze the accuracy of dry/wet boundaries in the RS-PT method. Compared with the SEBI-estimated relative evaporative fraction (Λ_r), the RS-PT method underestimated Λ_r by ~0.11. For the RS-PT method, the uncertainty in the determination of the dry/wet boundaries has a significant impact on the accuracy of the ET estimate, not only depending on the size of the area to build the feature space, but also on the land covers. Full article

The reliable estimation of spatially distributed Land Surface Temperature (LST) is useful for monitoring regional land surface heat fluxes. A single-channel method is developed to derive the LST over the Heihe River Basin in China using data from the infrared sensor (IRS) onboard the Chinese “Environmental and Disaster Monitoring and Forecasting with a Small Satellite Constellation” (HJ-1B for short for one of the satellites), with ancillary water vapor information from Moderate Resolution Imaging Spectroradiometer (MODIS) products (MOD05) and in situ automatic sun tracking photometer CE318 data for the first time. In situ LST data for the period from mid-June to mid-September 2012 were acquired from automatic meteorological stations (AMS) that are part of Heihe Watershed Allied Telemetry Experimental Research (HiWATER) project. MOD05-based LST and CE318-based LST are compared with in situ measurements at 16 AMS sites with land cover types of vegetable, maize and orchards. The results show that the use of the MOD05 product could achieve a comparable accuracy in LST retrieval with that achieved using the CE318 data. The largest difference between the MOD05-based LST and CE318-based LST is 0.84 K throughout the study period over the Heihe River Basin. The standard deviation (STD), root mean square error (RMSE), and correlation coefficient (R) of HJ-1B/IRS vs. the in situ measurements are 2.45 K, 2.78 K, and 0.67, respectively, whereas those for the MODIS 1 km LST product vs. the in situ measurements are 4.07 K, 2.98 K, and 0.79, respectively. The spatial pattern of the HJ-1B/LST over the study area in the Heihe River Basin generally agreed well with the MODIS 1 km LST product and contained more detailed spatial textures. Full article

Several methods currently exist to efficiently correct topographic effects on the radiance measured by satellites. Most of those methods use topographic information and satellite data at the same spatial resolution. In this study, the 30 m spatial resolution data of the Digital Elevation Model (DEM) from ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) are used to account for those topographic effects when retrieving land surface reflectance from satellite data at lower spatial resolution (e.g., 1 km). The methodology integrates the effects of sub-pixel topography on the estimation of the total irradiance received at the surface considering direct, diffuse and terrain irradiance. The corrected total irradiance is then used to compute the topographically corrected surface reflectance. The proposed method has been developed to be applied on various kilometric pixel size satellite data. In this study, it was tested and validated with synthetic Landsat data aggregated at 1 km. The results obtained after a sub-pixel topographic correction are compared with the ones obtained after a pixel level topographic correction and show that in rough terrain, the sub-pixel topography correction method provides better results even if it tends to slightly overestimate the retrieved land surface reflectance in some cases. Full article

Land surface albedo is an essential parameter for monitoring global/regional climate and land surface energy balance. Although many studies have been conducted on global or regional land surface albedo using various remote sensing data over the past few decades, land surface albedo product with a high spatio–temporal resolution is currently very scarce. This paper proposes a method for deriving land surface albedo with a high spatio–temporal resolution (space: 30 m and time: 2–4 days). The proposed method works by combining the land surface reflectance data at 30 m spatial resolution obtained from the charge-coupled devices in the Huanjing-1A and -1B (HJ-1A/B) satellites with the Moderate Resolution Imaging Spectroradiometer (MODIS) land surface bidirectional reflectance distribution function (BRDF) parameters product (MCD43A1), which is at a spatial resolution of 500 m. First, the land surface BRDF parameters for HJ-1A/B land surface reflectance with a spatial–temporal resolutions of 30 m and 2–4 day are calculated on the basis of the prior knowledge from the MODIS BRDF product; then, the calculated high resolution BRDF parameters are integrated over the illuminating/viewing hemisphere to produce the white- and black-sky albedos at 30 m resolution. These results form the basis for the final land surface albedo derivation by accounting for the proportion of direct and diffuse solar radiation arriving at the ground. The albedo retrieved by this novel method is compared with MODIS land surface albedo products, as well as with ground measurements. The results show that the derived land surface albedo during the growing season of 2012 generally achieved a mean absolute accuracy of ±0.044, and a root mean square error of 0.039, confirming the effectiveness of the newly proposed method. Full article

Rainfall interception loss of forest is an important component of water balance in a forested ecosystem. The Gash analytical model has been widely used to estimate the forest interception loss at field scale. In this study, we proposed a simple model to estimate rainfall interception loss of heterogeneous forest at regional scale with several reasonable assumptions using remote sensing observations. The model is a modified Gash analytical model using easily measured parameters of forest structure from satellite data and extends the original Gash model from point-scale to the regional scale. Preliminary results, using remote sensing data from Moderate Resolution Imaging Spectroradiometer (MODIS) products, field measured rainfall data, and meteorological data of the Automatic Weather Station (AWS) over a picea crassifolia forest in the upper reaches of the Heihe River Basin in northwestern China, showed reasonable accuracy in estimating rainfall interception loss at both the Dayekou experimental site (R² = 0.91, RMSE = 0.34 mm∙d ⁻¹) and the Pailugou experimental site (R² = 0.82, RMSE = 0.6 mm∙d ⁻¹), compared with ground measurements based on per unit area of forest. The interception loss map of the study area was shown to be strongly heterogeneous. The modified model has robust physics and is insensitive to the input parameters, according to the sensitivity analysis using numerical simulations. The modified model appears to be stable and easy to be applied for operational estimation of interception loss over large areas. Full article