Twinned Crystals

A special issue of Symmetry (ISSN 2073-8994). This special issue belongs to the section "Chemistry: Symmetry/Asymmetry".

Deadline for manuscript submissions: closed (20 September 2018) | Viewed by 2781

Special Issue Editors


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Guest Editor
Department for Nanostructured materials, Jozef Stefan Institute, SI-1000 Ljubljana, Slovenia
Interests: atomistic studies and structural modeling of twinned crystals; chemically induced twinning; self-assembly; nucleation and growth of twinned crystals

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Guest Editor
Department for Nanostructured materials, Jozef Stefan Institute, SI-1000 Ljubljana, Slovenia
Interests: atomistic studies and structural modeling of twinned crystals; chemically induced twinning; self-assembly; nucleation and growth of twinned crystals

Special Issue Information

Dear Colleagues,

Twinning and related crystallographic transformations have always been an exciting subject for mineralogists and materials scientists. Range of conditions trigger twinning of crystals—from mechanical deformation, phase transformation, chemical stabilization to topotaxial replacement and self-assembly. While the formation mechanisms of deformation and transformation twins are well understood, there are many open questions related to the formation of growth twins, often attributed to accidental attachment during crystal growth. Recent advances in electron microscopy methods and theoretical modeling that allow studying the local structure and chemistry of twin boundaries at the atomic scale have provided a unique opportunity to resolve questions related to twin boundary structure, their thermodynamic stability, mechanisms that trigger their formation, and often, an orchestrated assembly of twin-based modulated structures.

The Special Issue invites contributions addressing fundamentals of twinning, their crystallography, twin operators, experimental atomic-scale and first principles theoretical studies of twin boundary structure and chemistry, including investigations dealing with the formation and growth of twins in diverse materials. Original studies, as well as comprehensive review papers, from earliest investigations to the latest insights into the specific topics of this Special Issue, are welcome.

Prof. Dr. Aleksander Recnik
Assist. Prof. Dr. Nina Daneu
Guest Editors

Manuscript Submission Information

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Keywords

  • crystallography of twinned crystals
  • mechanical twinning
  • twinning and polytypism
  • tropochemical twinning
  • twining through self-assembly
  • growth of twinned crystals
  • ab-initio calculations
  • stability of twinned crystals.

Published Papers (1 paper)

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Research

6 pages, 5587 KiB  
Article
Peculiarities of the Twinning in Silicon during Ball Milling in the Presence of Two Different Materials
by Boris A. Kulnitskiy, Igor A. Perezhogin, Mikhail Yu. Popov, Danila A. Ovsyannikov and Vladimir D. Blank
Symmetry 2018, 10(6), 200; https://doi.org/10.3390/sym10060200 - 02 Jun 2018
Cited by 4 | Viewed by 2329
Abstract
The structure of silicon, along with mixtures of silicon and boron carbide (B4C) powders and silicon and diamond powders with different proportions after mechanoactivation, has been studied by transmission electron microscopy (TEM) methods. It was shown that silicon and boron carbide [...] Read more.
The structure of silicon, along with mixtures of silicon and boron carbide (B4C) powders and silicon and diamond powders with different proportions after mechanoactivation, has been studied by transmission electron microscopy (TEM) methods. It was shown that silicon and boron carbide experience twinning according to the known twinning mechanisms. In addition to the initial phase with a diamond lattice, the particles of two other phases were detected for silicon, including: the Kasper phase (SiIII) and lonsdaleite (SiIV). We established that the phase transformations in silicon can happen due to different mechanisms. Full article
(This article belongs to the Special Issue Twinned Crystals)
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