Special Issue "Dynamic Stereochemistry"
A special issue of Molecules (ISSN 1420-3049).
Deadline for manuscript submissions: closed (15 October 2013)
Prof. Dr. Stig Allenmark
Department of Chemistry and Molecular Biology, Goteborg University, SE-41296 Goteborg, Sweden
Phone: +46 317723841
Fax: +46 317723840
Interests: enantioselectivity in chromatography and in catalytic reactions; chiroptical methods for solving stereochemical problems
The Nobel Prize in Chemistry 1969 was awarded jointly to Derek H. R. Barton and Odd Hassel "for their contributions to the development of the concept of conformation and its application in chemistry". Their work, which started already in the 1930’s, can be said to mark the transition from constitutional to conformational aspects of organic molecules and thereby paved the way to studies of dynamic stereochemistry. The later development of this field has been enormous and of immense importance for our understanding of a variety of phenomena, like rotation and inversion barriers or mechanisms of enantiomer interconversions in stereochemically labile compounds as well as other stereoselective interconversions of compounds exhibiting different types of chirality.
This Special Issue on Dynamic Stereochemistry is intended to attract researchers in this field who want to contribute their latest results to the forum of Molecules. It is my hope that a good deal of interesting papers will be submitted that will reflect the potential and rapid development in this important area of organic chemistry.
Dr. Stig Allenmark
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. Papers will be published continuously (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are refereed through a peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed Open Access monthly journal published by MDPI.
- conformational analysis
- intramolecular dynamics
- barriers to rotation
- inversion barriers
- hypervalent compounds
- molecular propellers
- dynamic kinetic resolution
- dynamic chromatography
- potential energy surfaces (PES)
- computational methods
Article: Chiroptical Properties and the Racemization of Pyrene and Tetrathiafulvalene-Substituted Allene: Substitution and Solvent Effects on Racemization in Tetrathiafulvalenylallene
Molecules 2014, 19(3), 2829-2841; doi:10.3390/molecules19032829
Received: 21 January 2014; in revised form: 21 February 2014 / Accepted: 23 February 2014 / Published: 4 March 2014| Download PDF Full-text (818 KB) | View HTML Full-text | Download XML Full-text | Supplementary Files
Article: Influence of Temperature on the Enantioselectivity of Koga Tetraamines on Amylose Chiral Stationary Phases
Molecules 2014, 19(1), 9-21; doi:10.3390/molecules19010009
Received: 25 October 2013; in revised form: 4 December 2013 / Accepted: 10 December 2013 / Published: 19 December 2013| Download PDF Full-text (1261 KB) | View HTML Full-text | Download XML Full-text
Molecules 2013, 18(12), 15541-15572; doi:10.3390/molecules181215541
Received: 7 November 2013; in revised form: 9 December 2013 / Accepted: 11 December 2013 / Published: 13 December 2013| Download PDF Full-text (423 KB)
Article: Examination of the Potential for Adaptive Chirality of the Nitrogen Chiral Center in Aza-Aspartame
Molecules 2013, 18(12), 14739-14746; doi:10.3390/molecules181214739
Received: 3 October 2013; in revised form: 7 November 2013 / Accepted: 12 November 2013 / Published: 28 November 2013| Download PDF Full-text (465 KB)
Article: Perfluoroalkanesulfonamide Organocatalysts for Asymmetric Conjugate Additions of Branched Aldehydes to Vinyl Sulfones
Molecules 2013, 18(12), 14529-14542; doi:10.3390/molecules181214529
Received: 30 October 2013; in revised form: 20 November 2013 / Accepted: 21 November 2013 / Published: 25 November 2013| Download PDF Full-text (393 KB)
Article: Deracemization of Axially Chiral Nicotinamides by Dynamic Salt Formation with Enantiopure Dibenzoyltartaric Acid (DBTA)
Molecules 2013, 18(11), 14430-14447; doi:10.3390/molecules181114430
Received: 15 October 2013; in revised form: 13 November 2013 / Accepted: 19 November 2013 / Published: 21 November 2013| Download PDF Full-text (1560 KB)
Article: Conformational Analysis of Geometric Isomers of Pitavastatin Together with Their Lactonized Analogues
Molecules 2013, 18(11), 13283-13296; doi:10.3390/molecules181113283
Received: 24 September 2013; in revised form: 17 October 2013 / Accepted: 19 October 2013 / Published: 28 October 2013| Download PDF Full-text (899 KB) | Supplementary Files
Article: Characterization of Amide Bond Conformers for a Novel Heterocyclic Template of N-acylhydrazone Derivatives
Molecules 2013, 18(10), 11683-11704; doi:10.3390/molecules181011683
Received: 4 August 2013; in revised form: 10 September 2013 / Accepted: 13 September 2013 / Published: 25 September 2013| Download PDF Full-text (970 KB)
Last update: 2 May 2013