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Porous Films

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Porous Materials".

Deadline for manuscript submissions: closed (28 April 2017) | Viewed by 5443

Special Issue Editor


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Guest Editor
Department of Materials Engineering, Technion, Haifa 32000, Israel

Special Issue Information

Dear Colleagues,

Porous thin films can be designed and engineered experimentally. The technological capability of controlling the size, shape, orientation and density of pores is well developed. The chemistry of the pore walls can be altered for various tasks. Extensive experimental studies have been devoted to the characterization of pores surfaces from various viewpoints such as atomic structure, defects and chemical bonds. Nevertheless, basic understanding of the effect of the surface of the pores on the physical, chemical and biological processes occurring inside the pores that yield unique properties, is less known.

This Special Issue aims to provide more knowledge about the unique properties that can only be obtained in porous thin films and expand understanding of the effect of the surface of the pores in obtaining such properties. A large variety of subjects are relevant to this issue, such as utilization of the surface energy of pores, their size and shape to grow crystals with preferred crystallographic orientation under special conditions, to promote special interactions between materials, to create unique composite materials to form new materials with respect to microstructure and chemical compositions, to change phase transition conditions and more. There is no limitation on the type of property that is presented, provided it is unique. In this respect, all properties are relevant, e.g., optical, electrical, magnetic, dielectric, mechanical and biological properties. There are many fabrication processes of porous thin films which are important but they should be correlated with the properties. The Special Issue is open to experimental studies as well as theoretical models. Only new research results will be accepted for publication after the peer review and processing.

Prof. Dr. Shlomo Berger
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Porous thin films
  • Unique properties of porous thin films
  • Effect of the surface energy of pores on chemical and physical processes occurring inside them
  • Correlation between microstructures
  • Composition and properties of porous thin films

Published Papers (1 paper)

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Research

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Article
Preparation and Optimization of Fluorescent Thin Films of Rosamine-SiO2/TiO2 Composites for NO2 Sensing
by María G. Guillén, Francisco Gámez, Belén Suárez, Carla Queirós, Ana M. G. Silva, Ángel Barranco, Juan Ramón Sánchez-Valencia, José María Pedrosa and Tânia Lopes-Costa
Materials 2017, 10(2), 124; https://doi.org/10.3390/ma10020124 - 31 Jan 2017
Cited by 10 | Viewed by 5210
Abstract
The incorporation of a prototypical rosamine fluorescent dye from organic solutions into transparent and microstructured columnar TiO2 and SiO2 (MO2) thin films, prepared by evaporation at glancing angles (GAPVD), was evaluated. The aggregation of the adsorbed molecules, the infiltration efficiency and the adsorption [...] Read more.
The incorporation of a prototypical rosamine fluorescent dye from organic solutions into transparent and microstructured columnar TiO2 and SiO2 (MO2) thin films, prepared by evaporation at glancing angles (GAPVD), was evaluated. The aggregation of the adsorbed molecules, the infiltration efficiency and the adsorption kinetics were studied by means of UV-Vis absorption and fluorescence spectroscopies. Specifically, the infiltration equilibrium as well as the kinetic of adsorption of the emitting dye has been described by a Langmuir type adsorption isotherm and a pseudosecond order kinetic model, respectively. The anchoring mechanism of the rosamine to the MO2 matrix has been revealed by specular reflectance Fourier transform infrared spectroscopy and infiltration from aqueous solutions at different pH values. Finally, the sensing performance towards NO2 gas of optimized films has been assessed by following the changes of its fluorescence intensity revealing that the so-selected device exhibited improved sensing response compared to similar hybrid films reported in the literature. Full article
(This article belongs to the Special Issue Porous Films)
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