Special Issue "Characterization and Application of Ionic Liquid-Based Aqueous Biphasic Systems"
Deadline for manuscript submissions: closed (10 September 2013)
Prof. Dr. João Araújo Pereira Coutinho
Departamento de Química, CICECO, Universidade de Aveiro, 3810-193 Aveiro, Portugal
Phone: +234 401 507
Interests: characterization and development of new applications for ionic liquids
Professor Dr. Robin D. Rogers
Center for Green Manufacturing Department of Chemistry/Box 870336 3006D Shelby Hall, 250 Hackberry Lane The University of Alabama Tuscaloosa, AL 35487, USA
Since their first scientific report by Gutowski et al. in 2003, ionic-liquid-based aqueous biphasic systems became one of the most promising areas of application of ionic liquids. Prof. João A.P. Coutinho and Prof. Robin D. Rogers join efforts on this special issue to celebrate the first decade of work on this subject. The last decade witnessed the publication of more than 200 articles in the characterization and application of these systems but, in spite of the reported successes in the extraction and purification of a wide range of compounds, in particular biomolecules, it is sure that this field is still on its infancy. The number of potential systems keeps increasing surpassing by far the conventional polymer-salt or polymer-polymer ABS. Many of their characteristics and properties are still unknown. The driving mechanisms responsible for the phase splitting and partitioning behavior on these systems are only partly understood. No attempts at modeling have yet been reported and only lab scale trials were carried out. Besides ABS extractions from aqueous media using immiscible or partially miscible ionic liquids, thermoreversible systems based on UCST and LCST have been reported extending the range of potential application of liquid-liquid extractions from aqueous media. A deeper understanding of the systems' underlying mechanisms, their application to new fields such as in metal recovery, and a whole range of technical issues related with the back extraction and purification of compounds, as well as the recovery of the ionic liquids employed, must be tackled in what seems to be a most exciting next decade of research on IL-based extractions. This is a moment of celebration for all researchers that have been working on this subject and research contributions on the most various issues related with IL-based extractions from aqueous media are welcome.
Dr. João Araújo Pereira Coutinho
Prof. Dr. Robin D. Rogers
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. Papers will be published continuously (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are refereed through a peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. International Journal of Molecular Sciences is an international peer-reviewed Open Access monthly journal published by MDPI.
- ionic liquids
- aqueous biphasic systems
- aqueous two-phase systems
- aqueous systems
- hydrophobic ionic liquids
- phase diagrams
- liquid-liquid extraction
- thermoreversible systems
Article: Design of Phosphonium-Type Zwitterion as an Additive to Improve Saturated Water Content of Phase-Separated Ionic Liquid from Aqueous Phase toward Reversible Extraction of Proteins
Int. J. Mol. Sci. 2013, 14(9), 18350-18361; doi:10.3390/ijms140918350
Received: 8 August 2013; in revised form: 30 August 2013 / Accepted: 2 September 2013 / Published: 5 September 2013| Download PDF Full-text (1066 KB) | View HTML Full-text | Download XML Full-text
Last update: 11 September 2013