Abstract: The purpose of this review was to investigate the correlation between magnetism and crystallographic structures as it relates to the martensite transformation of Ni2MnGa type alloys, which undergo martensite transformation below the Curie temperature. In particular, this paper focused on the physical properties in magnetic fields. Recent researches show that the martensite starting temperature (martensite transformation temperature) TM and the martensite to austenite transformation temperature (reverse martensite temperature) TR of Fe, Cu, or Co-doped Ni–Mn–Ga ferromagnetic shape memory alloys increase when compared to Ni2MnGa. These alloys show large field dependence of the martensite transformation temperature. The field dependence of the martensite transformation temperature, dTM/dB, is −4.2 K/T in Ni41Co9Mn32Ga18. The results of linear thermal strain and magnetization indicate that a magneto-structural transition occurred at TM and magnetic field influences the magnetism and also the crystal structures. Magnetocrystalline anisotropy was also determined and compared with other components of Ni2MnGa type shape memory alloys. In the last section, magnetic field-induced strain and magnetostriction was determined with some novel alloys.
Tom Marr, Jens Freudenberger, Alexander Kauffmann, Jan Romberg, Ilya Okulov, Romy Petters, Juliane Scharnweber, Andy Eschke, Carl-Georg Oertel, Uta Kühn, Jürgen Eckert, Werner Skrotzki and Ludwig Schultz
Article:
Processing of Intermetallic Titanium Aluminide Wires
Metals 2013,
3(2), 188-201; doi:
10.3390/met3020188 - published online 10 May 2013
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Abstract: This study shows the possibility of processing titanium aluminide wires by cold deformation and annealing. An accumulative swaging and bundling technique is used to co-deform Ti and Al. Subsequently, a two step heat treatment is applied to form the desired intermetallics, which strongly depends on the ratio of Ti and Al in the final composite and therefore on the geometry of the starting composite. In a first step, the whole amount of Al is transformed to TiAl3 by Al diffusion into Ti. This involves the formation of 12% porosity. In a second step, the complete microstructure is transformed into the equilibrium state of -TiAl and TiAl3. Using this approach, it is possible to obtain various kinds of gradient materials, since there is an intrinsic concentration gradient installed due to the swaging and bundling technique, but the processing of pure -TiAl wires is possible as well.
Abstract: Current-activated tip-based sintering (CATS) is a novel process where spark plasma sintering conditions are applied through an electrically conducting tip on a locally controlled area on a green powder compact/bed. The localization of electric current in CATS allows for unique temporal and spatial current and temperature distributions within the tip and powder compact. In this paper, special experimental setups were used to monitor the temperature profiles in the tip and at multiple locations on the surface of nickel powder compacts. A variation in the initial green density was found to have a significant effect on the maximum temperature in the tip as well as the temperature distribution across the powder compact. In general, the lowest green density specimens displayed the best conditions for localized densification. The concept of effective current density is introduced and results are discussed in relation to the densification parameter.
Abstract: Iron-boron based bulk metallic glasses (BMG) development has been initiated using Fe40Ni38Mo4B18 as precursor. Addition of zirconium up to 10 atomic % along with the reduction of Ni proportion improves the glass forming ability (GFA), which is optimum when Ni is suppressed in the alloy. However melting instability occurred during the materials fabrication resulting in the formation of residual crystalline phases closely related to the amorphous phase. Microstructure study shows an evolution from amorphous structure to peculiar acicular structure, particularly for Fe50Ni16Mo6B18Zr10, suggesting the amorphous structure as interconnected atomic sheets like “atomic mille feuilles” whose growth affects the alloys’ GFA.
Abstract: The growing noise exposure of residents, due to a rising number of flights, causes significant impacts on physical health. Therefore it is necessary to reduce the noise emission of aircrafts. During take-off, the noise generated by the jet engines is dominating. One way to lower the noise emission of jet engines is to build an absorption silencer by using porous liners. Because of the high thermic and corrosive attacks as well as high fatigue loads, conventional absorbers cannot be used. A promising material is sintered metal fibre felts. This study investigates the suitability of metal fibre felts for the use as absorption material in silencers. The influences of pore morphology, absorption coefficient, determined with perpendicular sound incidence, as well as geometric parameters of the silencer to the damping are identified. To characterise the material, the parameters fibre diameter, porosity and thickness are determined using three-dimensional computer tomography images. The damping potential of absorption silencers is measured using an impedance tube, which was modified for transmission measurements. The essential parameter to describe the acoustic characteristics of porous materials is the flow resistivity. It depends on the size, shape and number of open pores in the material. Finally a connection between pore morphology, flow resistivity of the metal fibre felts and damping potential of the absorption silencer is given.
Abstract: Shape memory alloy actuators’ strokes can be increased at the expense of recovery force via heat treatment to form compressed springs in their heat-activated, austenitic state. Although there are models to explain their behaviour, few investigations present experimental results for support or validation. The aim of the present paper is to determine via experimentation how certain parameters affect a helical shape memory alloy actuator’s outputs: its transformation times and stroke. These parameters include wire diameter, spring diameter, transition temperature, number of active turns, bias force and direct current magnitude. Six investigations were performed: one for each parameter manipulation. For repeatability and to observe thermo-mechanical training effects, the springs were cyclically activated. The resultant patterns were compared with results predicted from one-dimensional models to elucidate the findings. Generally, it was observed that the transformation times and strokes converged at changing stress levels; the convergence is likely the peak where the summation of elastic stroke and transformation stroke has reached its maximum. During cyclic loading, the actuators’ strokes decreased to a converged value, particularly at larger internal stresses; training should therefore be performed prior to the actuator’s implementation for continual use applications.