Table of Contents
Magnetochemistry, Volume 4, Issue 2 (June 2018)
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Cover Story (view full-size image) The synthesis and characterization by single-crystal X-ray diffraction of three new dinuclear [...] Read more. The synthesis and characterization by single-crystal X-ray diffraction of three new dinuclear copper(II) complexes—[Cu2(μ–HLn)2(μ-Cl)2Cl2]Cl2, where HLn is as follows: HL1 = N6-propyladeninium, HL2 = N6-butyladeninium, and HL3 = N6-isobutyladeninium—is reported herein. The solid state architectures of all three structures exhibit relevant anion-π+ contacts between the aromatic portion of the positively charged adenine ring and the chloride counterions. In addition, experimental magnetic measurements in the 2–300 K temperature range indicate antiferromagnetic behaviour in all cases, in good agreement with the calculations. View the paper here.