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Magnetochemistry 2017, 3(1), 15; doi:10.3390/magnetochemistry3010015

Synthesis, Characterization and Copper(2+) Coordination Chemistry of a Polytopic Paramagnetic Ligand

1
Department of Chemistry, Brock University, St. Catharines, ON L2S 3A1, Canada
2
Department of Chemistry, University of Toronto, Toronto, ON M5S 3H6, Canada
*
Author to whom correspondence should be addressed.
Academic Editor: Coen de Graaf
Received: 28 October 2016 / Revised: 26 January 2017 / Accepted: 7 February 2017 / Published: 14 March 2017
(This article belongs to the Special Issue Transition Metal Magnetism)
View Full-Text   |   Download PDF [2123 KB, uploaded 14 March 2017]   |  

Abstract

We describe the synthesis of a new tetratopic phenoxyl radical ligand based on the previously reported ditopic “baqp” radical. The tetratopic ligand is prepared in five steps from 4-tert-butylphenol. Coordination of the ligand with Cu(OAc)2 produced a tetranuclear complex with an S = ½ ground state featuring a coordinated hexa-anion radical with very strong intramolecular antiferromagnetic exchange coupling. View Full-Text
Keywords: redox-active ligands; polytopic ligands; copper; magnetic exchange coupling redox-active ligands; polytopic ligands; copper; magnetic exchange coupling
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Bonanno, N.M.; Lough, A.J.; Poddutoori, P.K.; Lemaire, M.T. Synthesis, Characterization and Copper(2+) Coordination Chemistry of a Polytopic Paramagnetic Ligand. Magnetochemistry 2017, 3, 15.

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