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Inorganics 2018, 6(1), 18; https://doi.org/10.3390/inorganics6010018

Exploring Mechanisms in Ni Terpyridine Catalyzed C–C Cross-Coupling Reactions—A Review

1
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of Russian Academy of Sciences, 8, Arbuzov Str., 420088 Kazan, Russia
2
A. M. Butlerov Chemistry Institute, Kazan Federal University, Kremlevskaya str. 18, 420008 Kazan, Russia
3
Department of Chemistry, Lehigh University, 6 E. Packer Ave., Bethlehem, PA 18015, USA
4
Department für Chemie, Institut für Anorganische Chemie, Universität zu Köln, Greinstraße 6, D-50939 Köln, Germany
*
Authors to whom correspondence should be addressed.
Received: 9 November 2017 / Revised: 30 December 2017 / Accepted: 18 January 2018 / Published: 23 January 2018
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Abstract

In recent years, nickel has entered the stage for catalyzed C–C cross-coupling reactions, replacing expensive palladium, and in some cases enabling the use of new substrate classes. Polypyridine ligands have played an important role in this development, and the prototypical tridentate 2,2′:6′,2′′-terpyridine (tpy) stands as an excellent example of these ligands. This review summarizes research that has been devoted to exploring the mechanistic details in catalyzed C–C cross-coupling reactions using tpy-based nickel systems. View Full-Text
Keywords: nickel; 2,2′:6′,2′′-terpyridine; catalysis; mechanism; electrosynthesis; cross-coupling nickel; 2,2′:6′,2′′-terpyridine; catalysis; mechanism; electrosynthesis; cross-coupling
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
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Budnikova, Y.H.; Vicic, D.A.; Klein, A. Exploring Mechanisms in Ni Terpyridine Catalyzed C–C Cross-Coupling Reactions—A Review. Inorganics 2018, 6, 18.

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