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Inorganics 2017, 5(4), 70; https://doi.org/10.3390/inorganics5040070

Redox-Induced Aromatic C–H Bond Functionalization in Metal Complex Catalysis from the Electrochemical Point of View

A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Arbuzov str. 8, 420088 Kazan, Russian Federation
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Received: 18 September 2017 / Revised: 11 October 2017 / Accepted: 12 October 2017 / Published: 16 October 2017
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Abstract

This review generalizes and specifies the oxidizing ability of a number of oxidants used in palladium (Pd)-catalyzed aromatic C–H functionalizations. The redox potentials have been analyzed as the measure of oxidant strength and applied to the reasoning of the efficiency of known reactions where catalytic cycles include cyclometalated palladium complexes (and other organopalladium key intermediates). View Full-Text
Keywords: palladium; oxidant; metal complex catalysis; electrochemistry; redox potential palladium; oxidant; metal complex catalysis; electrochemistry; redox potential
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
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Budnikova, Y.H.; Dudkina, Y.B.; Khrizanforov, M.N. Redox-Induced Aromatic C–H Bond Functionalization in Metal Complex Catalysis from the Electrochemical Point of View. Inorganics 2017, 5, 70.

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