Flux Synthesis, Crystal Structures, and Magnetism of the Series La2n+2MnSen+2O2n+2 (n = 0–2)
AbstractThree members of the homologous series of manganese oxyselenides with the general formula La2n+2MnSen+2O2n+2 (n = 0–2) have been synthesized in a NaI/KI ﬂux and characterized by single-crystalX-raydiffraction,powderX-raydiffractionandmagneticmeasurements. Thestructures consist of chains of edge-sharing MnSe4O2-octahedra along the b-axis which are linked together along the a-axis by edge-sharing OLa4- and/or OLa3Mn-tetrahedra forming inﬁnite ribbons of increasing width. mC-La2MnSe2O2 (Pb2HgCl2O2-type, C2/m, a = 11.6621(5) Å, b = 3.9719(1) Å, c = 7.2049(3) Å, β = 121.655(2)◦) represents a new polymorph of this compound. La4MnSe3O4 (P2/m, a = 9.0055(4) Å, b = 4.0186(1) Å, c = 7.1946(3) Å, β = 109.715(2)◦) and La6MnSe4O6 (C2/m, a = 24.760(2) Å,b = 4.0359(3)Å,c=7.1850(6)Å, β =104.162(3)◦)exhibitnewstructuretypes. Magnetic measurements suggest antiferromagnetic order of the moments below about 15 K with effective magnetic moments of 5.53(1), 5.99(1) and 6.01(1) µB per formula unit for n = 1, 2 and 3, respectively. View Full-Text
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Peschke, S.; Johrendt, D. Flux Synthesis, Crystal Structures, and Magnetism of the Series La2n+2MnSen+2O2n+2 (n = 0–2). Inorganics 2017, 5, 9.
Peschke S, Johrendt D. Flux Synthesis, Crystal Structures, and Magnetism of the Series La2n+2MnSen+2O2n+2 (n = 0–2). Inorganics. 2017; 5(1):9.Chicago/Turabian Style
Peschke, Simon; Johrendt, Dirk. 2017. "Flux Synthesis, Crystal Structures, and Magnetism of the Series La2n+2MnSen+2O2n+2 (n = 0–2)." Inorganics 5, no. 1: 9.
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