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Inorganics 2014, 2(3), 424-432; doi:10.3390/inorganics2030424

Gold Thione Complexes

1
Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain
2
Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, S.S. 554 Bivio per Sestu, Monserrato (CA) 09042, Italy
*
Authors to whom correspondence should be addressed.
Received: 2 June 2014 / Revised: 16 July 2014 / Accepted: 18 July 2014 / Published: 4 August 2014
(This article belongs to the Special Issue Frontiers in Gold Chemistry)
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Abstract

The reaction of the ligand Et4todit (4,5,6,7-Tetrathiocino-[1,2-b:3,4-b']-diimidazolyl-1,3,8,10-tetraethyl-2,9-dithione) with gold complexes leads to the dinuclear gold(I) complexes [{Au(C6F5)}2(Et4todit)] and [Au(Et4todit)]2(OTf)2, which do not contain any gold-gold interactions, or to the gold(III) derivative [{Au(C6F5)3}2(Et4todit)]. The crystal structures have been established by X-ray diffraction studies and show that the gold centers coordinate to the sulfur atoms of the imidazoline-2-thione groups. View Full-Text
Keywords: gold(I); gold(III); imidazole derivatives gold(I); gold(III); imidazole derivatives
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MDPI and ACS Style

Caddeo, F.; Fernández-Moreira, V.; Arca, M.; Laguna, A.; Lippolis, V.; Gimeno, M.C. Gold Thione Complexes. Inorganics 2014, 2, 424-432.

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