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Processes 2016, 4(1), 1;

Modeling of the Copolymerization Kinetics of n-Butyl Acrylate and d-Limonene Using PREDICI ®

Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation, University of Ottawa, 161 Louis Pasteur Pvt., Ottawa, ON K1N 6N5, Canada
Facultad de Química, Departamento de Ingeniería Química, Universidad Nacional Autónoma de México, México D.F. 04510, Mexico
Author to whom correspondence should be addressed.
Academic Editor: Masoud Soroush
Received: 29 November 2015 / Accepted: 16 December 2015 / Published: 24 December 2015
(This article belongs to the Special Issue Polymer Modeling, Control and Monitoring)
View Full-Text   |   Download PDF [2177 KB, uploaded 24 December 2015]   |  


Kinetic modeling of the bulk copolymerization of d-limonene (Lim) and n-butyl acrylate (BA) at 80 °C was performed using PREDICI®. Model predictions of conversion, copolymer composition and average molecular weights are compared to experimental data at five different feed compositions (BA mol fraction = 0.5 to 0.9). The model illustrates the significant effects of degradative chain transfer due to the allylic structure of Lim as well as the intramolecular chain transfer mechanism due to BA. View Full-Text
Keywords: modeling; polymerization kinetics; n-butyl acrylate; d-limonene modeling; polymerization kinetics; n-butyl acrylate; d-limonene

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Ren, S.; Vivaldo-Lima, E.; Dubé, M.A. Modeling of the Copolymerization Kinetics of n-Butyl Acrylate and d-Limonene Using PREDICI ®. Processes 2016, 4, 1.

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