Supported Bimetallic AuPd Nanoparticles as a Catalyst for the Selective Hydrogenation of Nitroarenes
AbstractThe solvent-free selective hydrogenation of nitrobenzene was carried out using a supported AuPd nanoparticles catalyst, prepared by the modified impregnation method (MIm), as efficient catalyst >99% yield of aniline (AN) was obtained after 15 h at 90 °C, 3 bar H2 that can be used without any further purification or separation, therefore reducing cost and energy input. Supported AuPd nanoparticles catalyst, prepared by MIm, was found to be active and stable even after four recycle experiments, whereas the same catalyst prepared by SIm was deactivated during the recycle experiments. The most effective catalyst was tested for the chemoselective hydrogenation of 4-chloronitrobenzene (CNB) to 4-chloroaniline (CAN). The activation energy of CNB to CAN was found to be 25 kJ mol−1, while that of CNB to AN was found to be 31 kJ mol−1. Based on this, the yield of CAN was maximized (92%) by the lowering the reaction temperature to 25 °C. View Full-Text
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Qu, R.; Macino, M.; Iqbal, S.; Gao, X.; He, Q.; Hutchings, G.J.; Sankar, M. Supported Bimetallic AuPd Nanoparticles as a Catalyst for the Selective Hydrogenation of Nitroarenes. Nanomaterials 2018, 8, 690.
Qu R, Macino M, Iqbal S, Gao X, He Q, Hutchings GJ, Sankar M. Supported Bimetallic AuPd Nanoparticles as a Catalyst for the Selective Hydrogenation of Nitroarenes. Nanomaterials. 2018; 8(9):690.Chicago/Turabian Style
Qu, Ruiyang; Macino, Margherita; Iqbal, Sarwat; Gao, Xiang; He, Qian; Hutchings, Graham J.; Sankar, Meenakshisundaram. 2018. "Supported Bimetallic AuPd Nanoparticles as a Catalyst for the Selective Hydrogenation of Nitroarenes." Nanomaterials 8, no. 9: 690.
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