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Nanomaterials 2016, 6(3), 44; doi:10.3390/nano6030044

High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes

Department of Chemical and Materials Engineering, National University of Kaohsiung, No. 700, Kaohsiung University Road, Kaohsiung 811, Taiwan
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Academic Editors: Ming-Tsang Lee, Te-Hua Fang and Chien-Hung Liu
Received: 29 December 2015 / Revised: 20 February 2016 / Accepted: 23 February 2016 / Published: 9 March 2016
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Abstract

Organic-inorganic hybrid sols (Ti–O–Si precursor) were first synthesized by the sol-gel method at low addition of water, and were then employed to prepare a highly refractive hybrid optical film. This film was obtained by blending the Ti–O–Si precursor with 2-phenylphenoxyethyl acrylate (OPPEA) to perform photo-polymerization by ultraviolet (UV) irradiation. Results show that the film transparency of poly(Ti–O–Si precursor-co-OPPEA) film is higher than that of a pure poly(Ti–O–Si precursor) film, and that this poly(Ti–O–Si precursor-co-OPPEA) hybrid film exhibits a high transparency of ~93.7% coupled with a high refractive index (n) of 1.83 corresponding to a thickness of 2.59 μm. View Full-Text
Keywords: optical thin film; high refractive index; organic/inorganic hybrid; sol gel method optical thin film; high refractive index; organic/inorganic hybrid; sol gel method
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Ma, H.-Y.; Wang, T.-L.; Chang, P.-Y.; Yang, C.-H. High Refractive Organic–Inorganic Hybrid Films Prepared by Low Water Sol-Gel and UV-Irradiation Processes. Nanomaterials 2016, 6, 44.

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