Magnetic Nanomaterials and Their Applications

This Special Issue of Nanomaterials is dedicated to the development of new magnetic nanomaterials and their applications in biomedicine, catalysis, spintronics and other areas. The publications in this Issue demonstrate that the interest in magnetic nanomaterials is continuously growing and their realm is expanding rapidly. Some highlights of the publications in this issue are discussed below. [...].

maximum phase angle. Moreover in this work it was demonstrated that the indirect spin exchange coupling of top CoFeB and bottom CoFeB layers in CoFeB/MgO/CoFeB oscillates [3]. Similarly, in the other paper, the CoFeB/AlO x /Co multilayer film was used to investigate the strength of indirect spin exchange-coupling between CoFeB and Co strength and the χ ac in a low-frequency alternating magnetic field, for various thicknesses of the barrier layer AlO x [4]. It was found that the maximum χ ac value is obtained at the optimal frequency of 500 Hz. As the frequency increased further to 1000 Hz, the susceptibility rapidly declined to almost zero. It was established that the magnetic characteristics are related to the crystallinity of the Co and the thickness of the AlO x barrier layer. The multilayered magnetic tunnel junctions, with a high susceptibility in a low-frequency alternate-current magnetic field, are expected to find applications in low-frequency storage drives and magnetic recording media.
Rao et al. [5] prepared MgO films on Si substrates by direct current sputtering and investigated the effects of thermal annealing on the structural and magnetic properties of the films. It was found that there is a close correlation between room temperature ferromagnetism, crystallinity, and the magnesium vacancy concentrations in MgO thin films. The initial as-grown MgO films were amorphous due to the large lattice mismatch between MgO and Si substrate and demonstrated up to 9.62 emu/cm room temperature saturation magnetization values. However, after annealing, the films became nanocrystalline and the saturation magnetization values significantly decreased. The origin of the room temperature ferromagnetism has been explained by the presence of the magnesium cation vacancies. Thus, this research has shown an interesting approach to produce room temperature ferromagnetic MgO films and also helped to interpret the origin of ferromagnetism in MgO layes.
Finally, two papers on the use of magnetic nanomaterials in catalysis have been published by our group. Greene et al. [6] reported the synthesis, characterization and photocatalytic studies of cobalt ferrite-silica-titania core-shell nanostructures. In this work, the CoFe 2 O 4 @SiO 2 @TiO 2 core-shell magnetic nanostructures have been prepared by the coating of cobalt ferrite nanoparticles with a double SiO 2 /TiO 2 layer using metallorganic precursors. Then the core-shell nanoparticles were sintered at 600 °C to produce the photocatalytically active anatase phase at the surface of nanoparticles. It was found that these nanocomposites demonstrated a very efficient photocatalytic oxidation of methylene blue under UV light. The retention of magnetism in these core-shell nanostructures was of particular importance allowing the full magnetic recovery and re-use of the catalyst.
Govan et al. [7] reviewed the main recent advances in the development of magnetically recoverable nanocatalytic systems by the immobilisation of homogeneous catalysts onto magnetic nanoparticles. Particular attention was paid to magnetic core-shell nanostructures as substrates for catalyst immobilisation. The authors have also discussed binding of magnetic nanoparticles to inorganic catalytic mesoporous structures, catalytic metal organic frameworks (MOF), immobilization of catalytically active small organic molecules and polymers on magnetic carriers. In addition, some recent results on enzymatic catalysis using enzymes bound to magnetic nano-carriers have also been considered. The review has pointed out that very important progress was achieved in the development of various functional coatings on magnetic nanostructures including polymeric, dendritic, mesoporous zeolite-like and MOF coatings. The use of these functional coatings opens up new horizons in the development of new multifunctional catalysts with high reactivity and selectivity.
Overall, the papers published in this Special Issue represent important developments in the area of magnetic nanomaterials. We recommend you read through this Special Issue and look forward to seeing further progress in research on magnetic nanomaterials and their relevant applications.

Conflicts of Interest
The author declares no conflict of interest.