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Article

Migration Behavior of Lithium during Brine Evaporation and KCl Production Plants in Qarhan Salt Lake

1
Key Laboratory of Bioreactor Engineering and Institute of Applied Chemistry, East China University of Science and Technology, Shanghai 200237, China
2
School of Chemical Engineering, Qinghai University, Xining 810016, China
3
Shanghai Collaborative Innovation Center for Biomanufacturing Technology, Shanghai 200237, China
4
Qinghai Salt Lake Industry Group Co. Ltd., Golmud 816000, China
*
Author to whom correspondence should be addressed.
Minerals 2017, 7(4), 57; https://doi.org/10.3390/min7040057
Submission received: 8 January 2017 / Revised: 28 March 2017 / Accepted: 2 April 2017 / Published: 11 April 2017

Abstract

:
Lithium-brine is an important potential source of lithium. Much research and investigation has been carried out aimed at lithium recovery from brine. Although the distribution and occurrence status of lithium in brine have important implications for lithium recovery, few reports had correlated to this issue. In this article, a study was carried out to explore the lithium migration behavior during brine evaporation and KCl production process at Qarhan Salt Lake. The occurrence status of lithium both in fresh mined brine and residual brine after evaporation were also speculated by means of lithium concentration evaluation and theoretical calculation based on the Pitzer electrolyte solution theory. Results showed that, for Qarhan brine mined from the Bieletan region, most lithium was enriched in the residual brine during the brine evaporation process. The concentration of lithium in the residual brine could be more than 400 mg/L. More than 99.93% lithium ions in residual brine exist in free ions state and lithium does not precipitate from brine with a density of 1.3649 g/mL. The results also revealed that lithium concentration in wastewater discharged from KCl plants can reach a level of 243.8 mg/L. The investigation results provide a theoretical basis for comprehensive development and utilization of lithium resources in Qarhan Salt Lake.

1. Introduction

As an energy metal of the twenty-first century, lithium had attracted more and more attention in the past few decades. Lithium has been widely applied in high energy batteries, controlled thermonuclear reactions, the manufacturing of ceramic and glass, and other fields [1,2,3,4,5,6,7]. Lithium consumption for batteries had increased most significantly due to the development of the electric vehicle industry and the popularity of portable electronic products. Stimulated by the political affairs, economic requirements, and environmental conservation, lithium resources have become the focus of the international mining market and lithium’s position as a strategic resource is becoming more prominent.
Salt lake brine, thermal spring, and oilfield water are important geological sources of lithium. The commercial exploitation of the lithium resource of brine began at the Searles Lake in the US in 1936. Since then, more focus has been placed on recovering lithium from salt lake brine because of its low economical cost and low environmental impact [8,9,10]. As a country possessing huge amount of brine, China accounts for one-third of the world’s liquid lithium reserves. In China, most lithium-rich lakes are located in the Qinghai-Tibet plateau. Among them, Qarhan Salt Lake is the biggest playa lake containing huge lithium reserves of 1.64 Mt. Qarhan has promising research value and development prospects of lithium resource in the near future [4,5,11,12,13]. Despite relevant research on recovering lithium from salt lakes brine having been undertaken since 1970s, currently most of these studies concern lithium distribution during the brine evaporation process focusing on the two types of brine: carbonate-type brine with high lithium concentration, such as Zabuye Salt Lake brine in which concentration of lithium was 1085–1848 mg/L [12] and lithium always precipitate from aqueous in the form of carbonate as brine evaporates [13,14]; and the NaSO4 subtype brine with high lithium concentration such as Zhacang kaca Salt Lake (lithium concentration was 1210–2303 mg/L) [15] and East TaiJanier Salt Lake (543–1496 mg/L) [16]. In this type of brine, lithium will precipitate from solution in the form of sulfate as brine evaporates [15,17]. For the types of brine described above, lithium recovery is relatively easy due to the high concentration and less disturbance of magnesium. However, the studies focusing on the lithium behavior during evaporation process, for MgSO4 subtype brine such as Qarhan Salt Lake brine, are limited and the knowledge on lithium occurrence in this type of brine is rare.
Therefore, the aim of this paper was to investigate and compare the lithium concentration level of Qarhan Salt Lake brine during the process of natural evaporation in order to fully characterize the migration and occurrence status of lithium and hoping to supply some theoretical basis on utilization of lithium resources in the Qarhan Salt Lake. Since the Qarhan Salt Lake not only has huge lithium development potential but also was the biggest KCl base in China, for the purpose of improving the brine utilization rate, lithium can be recovered from brine as a co-product in the fabrication of KCl. The plan is to contribute to the data from the KCl production line at Qarhan Salt Lake in order to fill the gap of information on lithium distribution in the KCl plant. Additionally, to develop lithium resource in a long range, the lithium geographical distribution of whole of the Qarhan Salt Lake was also summarized.

2. Materials and Methods

The field samples were taken from the salt ponds and KCl plants of the Qinghai Salt Lake Industry Group Co. at Qarhan. The original brine, both in simulation experiments and field sampling, refers to the brine taken from the entrance of salt pond (Site a) as shown in Figure 1. Field samples from salt ponds were taken according to the sequence of salt crystallization and the brine flow direction. A total of eight solid samples and eight liquid samples were collected from different salt ponds locations, and seven solid samples and 11 liquid samples were collected from KCl plants. For each location, solid samples were collected into wide mouth polyethylene bottles, sealed with sealing tape immediately, and then brought back for lab testing. The liquid samples were collected in polyethylene bottles after rinsing the bottles three times. Liquid samples were centrifuged (3000 rpm) for two minutes to remove sediments and acidized with trace-metal HNO3. The solid samples were suction filtrated to remove brine on their surface, dissolved using ultra-high purity water and acidized with trace-metal HNO3. Samples collected in flotation stage were treated after de-foaming naturally. The cations (Li+, K+, Na+, Mg2+) in all samples were analyzed using inductively coupled plasma atomic emission spectrometer (ICP-AES, ICAP6300, Thermo Fisher, Waltham, MA, USA) and SO42− was determined by gravimetric analysis. Brine density was measured by the method of pycnometer and the solid phase was identified by X-ray diffraction (XRD, Goniometer RINT2000, Rigaku, Akishima, Japan).
Lithium distribution both in solid and liquid phase at different evaporation stages were investigated both in labor and production sites by means of simulation experiments and field sampling. The simulation experiment was carried out in a transparent plastic container, placed outside in natural conditions. Brine was evaporated in the sun at Xining, Qinghai (altitude: 2290 m, atmospheric pressure: 77.273 kPa). Fixed time was assign to observe the brine evaporation degree every day, including temperature, brine temperature, brine depth, density, and crystallization of salt precipitation. In the process, solid and liquid samples were separated by filtration and for chemical analysis. After the solid-liquid separation was carried out, the evaporation and crystallization were continued.

3. Results and Discussion

3.1. Lithium Distribution in Qarhan Salt Lake

A large dry salt plain and 10 varying sized brine lakes constitutes the present terrain of the Qarhan Salt Lake, which is 168 km long from east to west and varies in width from 20~40 km. The Qarhan Salt Lake can be divided into four main regions from east to west: the Huobuxun region, the Qarhan region, the Dabuxun region, and the Bieletan region, as shown in Figure 1. Interstitial brine was mined in the Bieletan region and then transported by collection trenches to salt ponds. Brine was evaporated in these ponds to crystallize carnallite for KCl production. The entrance of the salt pond (Site a) is about 28 km away from the Bieletan region. In order to reduce costs and increase energy saving, brine flow was only driven by its gravitational potential and no extra power was supplied during transportation. After long distance transportation in open-air, brine composition changes and differs from its initial state.
The lithium concentration value in the different regions of whole Qarhan Salt Lake is listed in Table 1. Based on Figure 1, lithium resource distribution in the Qarhan Salt Lake presented a regional feature: lithium gradient concentration of brine increased from east to west, south to north. Bieletan region, the northwest edge of the Qarhan Salt Lake presented the highest lithium concentration level.
The average lithium concentration in the Bieletan region was 594 mg/L and the maximum value even could reach 1.225 g/L, which was almost comparable to the East TaiJanier area. Thus, the Bieletan could also be a region with the highest lithium concentration in the whole Qaidam basin. In the Dabuxun region, the average lithium concentration of interstitial brine was 26.0 mg/L, while it was 88.4 mg/L in the surface brine. This could be because lithium is highly soluble and did not readily produce evaporate minerals when concentrated by evaporation. Lithium would rather stay in residual brines in the surface or shallow subsurface. The lithium concentration of the Huobuxun region was the lowest in the whole Qarhan Salt Lake (only 10.3 mg/L) and its brine magnesium-lithium ratio was more than 2000, too high to recover lithium [10,19]. Since the brine of the Qarhan Salt Lake belongs to the magnesium sulfate subtype, it usually contains high magnesium as shown in Table 1. According to the boundary grade of industrial development, the concentration of lithium in brine should be approximately 25 mg/L. Thus, the brine collected from west of the Qarhan region (such as in the Bieletan and Dabuxun regions) has the potential for lithium exploitation.

3.2. Distribution of Lithium during the Evaporation Process at Salt Ponds

Figure 2 shows lithium distribution during brine evaporation process in both the simulation experiment and field sampling from different salt ponds. As brine concentrating lithium in aqueous phase was enrichened, the average concentration of lithium could reach a level of 500 mg/L. In residual brine, this was more than double the concentration in the original brine. The simulation experiments showed that the vast majority of lithium was retained in the aqueous phase and there was a positive correlation between lithium concentrations with brine enrichment degree.
Lithium content in solid phase had no evident change (p > 0.05) during the brine concentration process until bischofite was precipitated. Although brine was more concentrated by natural evaporation, lithium did not saturated or form its own minerals until brine flowed into the residual brine pond. Even the highest mass percent of lithium in solid phase was less than 0.004% and could be ignored. Thus, the solid phase containing lithium mainly was the result of parent brine entrainment. When bischofite began to precipitate, lithium content in the solid phase increased slightly because the lithium isomorphically substitutes magnesium in bischofite. Additionally, the solid identification results shown in Table 2 also confirm that lithium salt was unformed during the whole evaporation process.
The relationship of magnesium-lithium ratio between brine densities during the evaporation process is given in Figure 3. It shows that the Magnesium-lithium ratio does not changed much in early evaporation stage (depicted in magenta and violet colors), but a larger change appears when the brine density value is more than 1.285 g/cm3 (depicted in blue and green colors). The magnesium-lithium ratio decreases sharply in the later stage of evaporation, especially when brine density is more than 1.345 g/cm3. Brine magnesium-lithium ratio decreases almost to half of initial value when the brine density is around 1.372 g/cm3 (depicted in red).
The brine density value could represent the degree of brine concentration because brine density is proportional to the degree of evaporation. The greater the density value, the higher the degree of brine evaporation and lithium enrichment. As shown in Figure 3, the magnesium-lithium ratio remains at about the same level in the early evaporation stage, but a slight decrease appears when the brine density value is more than 1.28 g/cm3, almost the moment when carnallite crystalized. Thus, it can be deduced that the brine magnesium-lithium ratio decrease was caused by carnallite precipitation. This is because carnallite is a double salt that contains 8.64% magnesium and the precipitation led the magnesium ions to migrate to solid from aqueous. The magnesium-lithium ratio decreased sharply in the later stage of evaporation, especially when brine density was more than 1.34. The brine magnesium-lithium ratio value almost decreased half of its original value when the brine density reached 1.37 g/L. However, at this time, the mineralization degree of brine was too high for rapid evaporation. Such a high salinity could significantly decrease the water saturated vapor pressure on the top of the solution and lead to a slow evaporation. Furthermore, at this time the brine surface would be covered by a layer of salt crystal that could block the diffusion of water molecules to the outside. It would be time-consuming to decrease the brine magnesium-lithium ratio through continue evaporation. Continue evaporation brine requires huge place to build a salt pan, thus it is very uneconomical to decrease magnesium-lithium ratio by sustained evaporation for industrial production.

3.3. Lithium Occurrence Status during Brine Evaporation

A chemical model for sea water was presented by Garrels to assess the percentages of the major dissolved species [20], however, due to the super high ionic strength of brine, it is inapplicable to use this model into salt lake brine system without parameter correction. In the 1980s, Harive and Wear recompiled the Pitzer electrolyte thermodynamic calculation formula [21,22] as follows:
ϕ 1 = ( i m i ) 1 { 2 [ A ϕ I 3 2 ( 1 + 1.2 I 1 2 ) + i c = 1 N c i A = 1 N A m c m A ( B c A ϕ + Z C c A ) ] + i c = 1 N c 1 j A = i c + 1 N c m c m c ( Φ c c ϕ + i A = 1 N c m A ψ c c A ) + i c = 1 N A 1 j N = i A + 1 N A m A m A ( Φ A A ϕ + j c = 1 N c m c ψ A c c + i N = 1 N N j A = 1 N A m N m A λ N A + i N = 1 N N j c = 1 N c m N m c λ N c ) }
ln γ M = Z M 2     + i A = 1 N A m A ( 2 B M A + Z C M A )     + i c = 1 N A m c ( 2 Φ M c + i A = 1 N A m A ψ M c A ) + i A = 1 N A 1 j A + 1 N A m A m A ψ A A M     + | Z M | i c = 1 N c i A = 1 N A m c m A C c A + i N = 1 N N m N ( 2 λ N M )
ln γ X = Z X 2 F     + i c = 1 N A m c ( 2 B c X + Z C c X )     + i A = 1 N A m A ( 2 Φ X A + i c = 1 N A m c ψ X c A ) + i c = 1 N c 1 j c = i c + 1 N A m c m c ψ c c M     + | Z X | i c = 1 N c i A = 1 N A m c m A C c A + i N = 1 N N m N ( 2 λ N X )
ln γ N = i c = 1 N c m c ( 2 λ A c ) + i A = 1 N A m A ( 2 λ N A )
In the above formulas: I for ion strength, Aφ for Debye-Hükel coefficient. M, c, and c’ for cations, X, A, and A’ for anions, mc for molality of cation, Zc for charge number of cation, and Nc for the species number of cations. The anions A and neutral molecule N can be defined in same manner. The functions of F, C, Z, Aφ, ψ, Φ, Bφ, and B was defined as follows:
F = A ϕ [ I 1 2 ( 1 + 1.2 I 1 2 ) + 2 l n ( 1 + 1.2 I 1 2 ) 1.2 + i c = 1 N c i A = 1 N A m c m A B c A + i c = 1 N c i c = i c + 1 N c m c m c Φ c c + i A = 1 N A i A = i A + 1 N A m A m A Φ A A ]
C M X = C M X ϕ ( 2 | Z M Z X | 1 2 )
Z = i | Z i | M i
B c A ϕ = β c A ( 0 ) + β c A ( 1 ) e x p ( α 1 I 1 2 ) + β c A ( 2 ) e x p ( α 2 I 1 2 )
B c A = β c A ( 0 ) + β c A ( 1 ) g ( α 1 I 1 2 ) + β c A ( 2 ) g ( α 2 I 1 2 )
B c A = [ β c A ( 1 )   g ( α 1 I 1 2 ) + β c A ( 2 )   g ( α 2 I 1 2 ) ] / I
g ( x ) = 2 [ 1 ( 1 + x ) exp ( x ) ] / x 2
  g ( x ) = 2 [ 1 ( 1 + x + x 2 2 ) exp ( x ) ] / x 2
α1 = 2.0 kg1/2 mol−1/2 and α2 = 0 for the electrolyte solution which contains at least one monovalent ion; α1 = 1.4 kg1/2 mol−1/2 and α2 = 12 kg1/2 mol−1/2 for the electrolyte solution in which anions and cations were both divalent.
Φ i j Φ = θ i j + E θ i j + I E θ i j
Φ i j = ϕ i j + E θ i j
Φ i j = E θ i j
If the suitable Pitzer parameters were available, then the osmotic coefficient and the ionic activity coefficient for each species in the system of high concentration mixed electrolyte solution could be calculated by the H-W equation. Song and Yan [23] presented the mixing Pitzer parameters for lithium brine system in 2003. Thus, the procedures was to find the proper thermodynamic parameters of the Pitzer model for the Li+, Na+, K+, Mg2+/Cl, SO42− brine system and use them to calculate individual ion activity coefficients values. Then, according to the coefficient values of each ion and dissociation constants, the percentages of all species can be obtained simultaneously. In this work, the individual ion activity coefficients were calculated by H-W equation and the parameters used in the equation are listed in Table 3 and Table 4.
The chemical composition and calculation activity coefficient of individual ion in the Qarhan Salt Lake brine before and after evaporation are shown in Table 5. Superscript “O” and “R” represent the original brine and the residual brine after evaporation.
The chloride ion was generally believed not to form ion pairs with alkali metal and alkaline earth metal ions. It is still assumed that chloride ions do not form ion pairs when applying the chemical model to dealing with the Qarhan lithium-brine system. According to the Qarhan Salt Lake brine, sulfate can be considered in the calculation process. Thus, for lithium, two equations can be obtained as follows:
m L i T o t a l l + = m L i F r e e + + m ( L i S O 4 2 )
γ L i + m L i + × γ S O 4 2 m S O 4 2 γ L i S O 4 m L i S O 4 = K d i s s
The dissociation constant and activity coefficient of ion-pairs are listed in Table 6. The rest of the ions were processed in the same way as lithium, then a series of equations can be obtained. The proportion of the free ion and the ion pair for major dissolved species can be calculated by solving these equations (for a detailed process, see Reference [19]).
A summary value, the proportion of the free ion and the ion pair for major dissolved species in the Qarhan Salt Lake, is shown in Table 7. The calculation results show that the vast majority of lithium occurrence are free ions in brine during the whole evaporation process. There was a slight decrease in the percentage value of lithium ion-pair as the brine evaporated. The percent value of Li-SO4 in residue brine was just 0.02% lower than the original brine. Only magnesium ions are significant combined into ion pairs, and the other alkali metal ions are not conspicuous. Comparing the percentage value of lithium ion-pair in the Qarhan Salt Lake with East TaiJanier [21], it was found that lithium in the brine of the Qarhan Salt Lake was more likely to occur as free ions. This could be due to the higher concentration of magnesium in brine and the stronger combination trend between magnesium and sulfate.

3.4. Distribution of Lithium at the KCl Production Plants

Since another aim of this study was to contribute lithium distribution information in the whole KCl production line for recovering lithium from brine as a co-product of KCl, lithium distribution in KCl plants should also be taken into account. Figure 4 is the flow chart of KCl production in plant. The feed material of KCl production at plants was carnallite, which could be obtained after brine evaporation. When crude carnallite is taken out of the carnallite ponds, it is usually in a state of liquid-solid mixture and is always mixed with about 20% sodium chloride (NaCl), which needs to be removed before producing KCl. Furthermore, the crude carnallite mined from carnallite pond often mixes with a lot of brine. A huge thickener was used to remove redundant brine to meet flotation specifications. Hence, in production operations, NaCl was reverse flotation from carnallite, first using alkyl-morpholine as a collector, then the treated carnallite with a low NaCl content (less than 5%) was decomposed and recrystallized in a crystallizer to produce KCl. The KCl from the crystallizer was centrifuged and dried for packing after filtered.
Figure 5 illustrated the lithium distribution in KCl plant. According to the situation in plants, the maximum lithium content values for samples were 400 mg/L in aqueous phase and 0.005% in solid phase.
As shown in Figure 5, in the aqueous phase of thickener A, although average lithium concentration in aqueous almost has same level with the brine of the carnallite pond, there were still some differences in lithium concentration between the overflow and underflow. The lithium concentration in the underflow being higher than the overflow might be caused by higher solid content in the underflow. The survey showed that solid lithium content of the scavenging flotation foam phase would have an obvious decrease compared with the roughing flotation foam phase. However, the reasons for this phenomenon are not very clear and there is little research reported on it. After the first de-brine, the sharp decrease in the content of lithium in both the aqueous and solid phases could be due to drip washing: to meet purity specifications of final KCl, the easy soluble ions absorbed on the surface of carnallite, such as lithium and magnesium, are always removed by drip washing in the de-brine process. Based on the information in Figure 5, it is speculated that in plants, most lithium was dissolved and discharged with wastewater. Then the lithium concentration in the wastewater pond from KCl plants was detected and it was found that the lithium concentration could reach a level of 243.8 mg/L. This confirms the speculation and means besides the residual brine in evaporation process, the wastewater in the KCl plants also should be fully used to recovered lithium as a co-production of KCl.

4. Conclusions

In summary, the investigation came to the following conclusions: (1) the brine collected from west of the Qarhan region such as in the Bieletan and Dabuxun regions, is a prospective source for lithium exploitation. (2) Based on the results from simulation experiments and field sampling (both the salt pond in open air and the KCl plant), it is reasonable to believe that most of the lithium was enriched in the residue brine after carnallite precipitation. The residue brine and wastewater from the KCl plants should be used for lithium recovery. (3) More than 99.6% of the lithium ions in the liquid phase of the Qarhan Salt Lake occurred in the form of free ions, and the lithium ions did not precipitate because the brine was concentrated to a density of 1.3649 g/cm3.

Acknowledgments

This research was supported in by the National Natural Science Foundation of China (U1507122, 21266027) and the Natural Science Foundation of Qinghai Province, 2016-ZJ-734. The authors also thank Sheng-Tai Zhang (Qinghai Salt Lake Industry Group Co.) for help with specimen collection.

Author Contributions

Bozhong Mu and Weijun Song designed the experiments. Weijun Song carried out the samples analysis. Yuanqin Ma and Weijun Song collected the samples and did the preliminary analysis. Hongze Gang and Shizhong Yang provided suggestions for the experiments and results analysis. Weijun Song prepared the manuscript with contributions from all co-authors.

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. (A) Qarhan Salt Lake ichnography; (B) Detail of salt pond in the Salt Lake Group. The sampling site in evaporation precess was presented by yellow dots. (a: source brine; b: NaCl pond 1; c: NaCl pond 2; d: brine adjusting pond; e: carnallite pond 1; f: carnallite pond 2; g: carnallite pond 3; h: residue brine pond).
Figure 1. (A) Qarhan Salt Lake ichnography; (B) Detail of salt pond in the Salt Lake Group. The sampling site in evaporation precess was presented by yellow dots. (a: source brine; b: NaCl pond 1; c: NaCl pond 2; d: brine adjusting pond; e: carnallite pond 1; f: carnallite pond 2; g: carnallite pond 3; h: residue brine pond).
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Figure 2. Lithium distribution during the brine evaporation process.
Figure 2. Lithium distribution during the brine evaporation process.
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Figure 3. The variation tendency of magnesium-lithium ratio during evaporation process. Time course of brine evaporation is represented by different colors. The size of the area has a positive correlation with density and [Mg2+]/[Li+].
Figure 3. The variation tendency of magnesium-lithium ratio during evaporation process. Time course of brine evaporation is represented by different colors. The size of the area has a positive correlation with density and [Mg2+]/[Li+].
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Figure 4. Flow chart of KCl production in plant.
Figure 4. Flow chart of KCl production in plant.
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Figure 5. The distribution of lithium at KCl production plant.
Figure 5. The distribution of lithium at KCl production plant.
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Table 1. Lithium concentration and the magnesium-lithium ratio of the Qarhan Salt Lake.
Table 1. Lithium concentration and the magnesium-lithium ratio of the Qarhan Salt Lake.
Lake NameWater TypepHSalinity (g/L)Mg2+ (g/L)Li+ (mg/L)[Mg2+]/[Li+]
HuobuxunInterstitial brine6.70311.221.1910.32057.76
Huobuxun (N)Surface brine-306.87.7488.487.55
Huobuxun (S)Surface brine6.70346.119.7119.61004.08
TuanjieSurface brine5.40425.398.6959.01672.71
XiezuoSurface brine5.50358.564.6928.6226.18
QarhanInterstitial brine7.00321.128.6715.61837.63
DabuxunSurface brine5.32307.2–470.2118.6988.41342.65
DabuxunInterstitial brine6.70331.846.5426.01789.96
BieletanInterstitial brine6.50358.064.15124.0517.34
BieletanSubsurface brine-289.0–470.19.76–109.790.0–1225.0100–200
Xiao BieleSurface brine6.2386.981.5766.31230.34
Da BieleSurface brine7.0362.930.9937.0837.57
SenieSurface brine7.1332.318.12191.094.87
Data source: Reference [18].
Table 2. Identification results of solid phase during the brine evaporation process.
Table 2. Identification results of solid phase during the brine evaporation process.
Density (g/cm3)Halite (%)Bischofite (%)Carnallite (%)
1.26029550
1.27689460
1.294444749
1.321824571
1.337324868
1.355970030
1.357928513
1.363401000
1.364801000
1.365401000
1.366801000
1.38911990
1.369201000
Table 3. Pitzer parameters of the single electrolyte used in the chemical model of the Qarhan brine system.
Table 3. Pitzer parameters of the single electrolyte used in the chemical model of the Qarhan brine system.
CationAnionβ(0)β(1)β(2)CφReference
Na+Cl0.07650.2664-0.00127[21]
Na+SO42−0.019581.113-0.00497[21]
K+Cl-0.048350.2122-−0.00084[21]
K+SO42−0.049950.7793--[21]
Mg2+Cl0.352351.6815-0.00519[21]
Mg2+SO42−0.22103.343−37.230.025[21]
Li+Cl0.20818−0.07264-−0.004241[23]
Li+SO42−0.143961.17736-−0.05710[23]
Table 4. Mix Pitzer parameters used in the chemical model of the Qarhan brine system.
Table 4. Mix Pitzer parameters used in the chemical model of the Qarhan brine system.
ParameterValueReferenceParameterValueReference
θ Na , Li 0.02016[23] Φ Na , Li , SO 4 −0.00600[23]
θ Na , Mg 0.07000[21] Φ Na , K , SO 4 -[21]
θ Na , K −0.01200[21] Φ Na , K , Cl −0.007416[21]
θ K , Li −0.05075[21] Φ Na , Mg , Cl −0.007774[21]
θ K , Mg 0.00000[21] Φ Na , Mg , SO 4 −0.01000[21]
θ Mg , Li 0.010196[21] Φ K , Li , SO 4 −0.00180[21]
θ Cl , SO 4 0.02000[21] Φ K , Li , Cl −0.01200[21]
Φ Cl , SO 4 , Li −0.01236[23] Φ K , Mg , SO 4 −0.01500[23]
Φ Cl , SO 4 , Na 0.001400[21] Φ K , Mg , Cl −0.00797[21]
Φ Cl , SO 4 , Mg −0.04800[21] Φ Mg , Li , Cl −0.005909[23]
Φ Cl , SO 4 , K −0.02200[21] Φ Mg , Li , SO 4 −0.0005947[23]
Φ Na , Li , Cl 0.005700[23]---
Table 5. Chemical composition and activity coefficient of the Qarhan Salt Lake, 25 °C.
Table 5. Chemical composition and activity coefficient of the Qarhan Salt Lake, 25 °C.
IonsLi+Na+K+Mg2+ClSO42−
Molality (mol/Kg)O0.02471.12420.44463.90298.59140.4040
Activity coefficient3.46391.09910.27414.02697.36920.0146
Molality (mol/Kg)R0.06070.09020.02016.537610.41581.4151
Activity coefficient2.94571.65030.173514.427333.08420.0132
Table 6. The dissociation constant of major dissolved species and activity coefficient of ion-pairs.
Table 6. The dissociation constant of major dissolved species and activity coefficient of ion-pairs.
SpeciesNa2SO4K2SO4MgSO4Li2SO4Reference
Dissociation constant0.1905460.1096480.0043650.640000[20,24]
Ion–pairsNa–SO4K–SO4Mg–SO4Li–SO4Reference
Activity coefficient0.630000.630001.130000.63000[22,25]
Table 7. Occurrence state of major dissolved species before and after brine evaporation at 25 °C.
Table 7. Occurrence state of major dissolved species before and after brine evaporation at 25 °C.
IonOriginal BrineResidue Brine
Occurrence StatusPercentOccurrence StatusPercent
K+Free ion99.946%Free ion99.976%
K-SO40.054%K-SO40.024%
Li+Free ion99.911%Free ion99.931%
Li-SO40.089%Li-SO40.069%
Mg2+Free ion89.931%Free ion78.463%
Mg-SO410.069%Mg-SO421.573%
Na+Free ion99.874%Free ion99.818%
Na-SO40.126%Na-SO40.182%
SO42−K-SO40.060%K-SO4-
Li-SO40.005%Li-SO4-
Mg-SO497.277%Mg-SO499.500%
Na-SO40.350%Na-SO40.001%
Free ion2.327%Free ion0.4999%

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Song, W.; Gang, H.; Ma, Y.; Yang, S.; Mu, B. Migration Behavior of Lithium during Brine Evaporation and KCl Production Plants in Qarhan Salt Lake. Minerals 2017, 7, 57. https://doi.org/10.3390/min7040057

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Song W, Gang H, Ma Y, Yang S, Mu B. Migration Behavior of Lithium during Brine Evaporation and KCl Production Plants in Qarhan Salt Lake. Minerals. 2017; 7(4):57. https://doi.org/10.3390/min7040057

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Song, Weijun, Hongze Gang, Yuanqing Ma, Shizhong Yang, and Bozhong Mu. 2017. "Migration Behavior of Lithium during Brine Evaporation and KCl Production Plants in Qarhan Salt Lake" Minerals 7, no. 4: 57. https://doi.org/10.3390/min7040057

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