- freely available
- re-usable
Symmetry 2012, 4(1), 251-264; doi:10.3390/sym4010251
Published: 21 March 2012
Abstract
: The onset of superconductivity at the transition temperature is marked by the onset of order, which is characterized by an energy gap. Most models of the iron-based superconductors find a sign-changing (s±) order parameter [1,2,3,4,5,6], with the physical implication that pairing is driven by spin fluctuations. Recent work, however, has indicated that LiFeAs has a simple isotropic order parameter [7,8,9] and spin fluctuations are not necessary [7,10], contrary to the models [1,2,3,4,5,6]. The strength of the spin fluctuations has been controversial [11,12], meaning that the mechanism of superconductivity cannot as yet be determined. We report the momentum dependence of the superconducting energy gap, where we find an anisotropy that rules out coupling through spin fluctuations and the sign change. The results instead suggest that orbital fluctuations assisted by phonons [13,14] are the best explanation for superconductivity.LiFeAs is a very remarkable member in the family of iron based superconductors (IBSC). While consisting of key FeAs structural blocks and losing resistance already at 18 K thus bearing all necessary and representative features of these novel materials [15,16,17], LiFeAs superconducts in its stoichiometric composition, is not magnetic [11,12] and its surface electronic structure is the same as in the bulk [18]. Angle-resolved photoemission (ARPES) at ultra-low temperatures (~1 K) [14] offers a unique opportunity to directly determine the full size of the energy gap (Δ) as a function of momentum, virtually in the ground state of a superconductor. Precise and direct determination of the energy gap becomes possible if the maximum energy position of the quasiparticle peak at Fermi momentum (k_{F}) with respect to Fermi level (E_{F}) is determined (inset to Figure 1). LiFeAs is an ideal compound for such ARPES measurements—all Fermi surfaces (locus of k_{F} at E_{F}) are well defined and separated in k-space (Figure 1a), no other gap or depletion of the spectral weight at E_{F} (pseudogap) is present and k_{F} energy distribution curves (EDC) are remarkably sharp.
As has been demonstrated previously [7], the Fermi surface of LiFeAs consists of two hole-like and two electron-like sheets around the center and corners of the Brillouin zone (BZ) respectively (Figure 1a). We start with the determination of the energy gap corresponding to the large hole-like Fermi surface around Γ-point. This Fermi surface (FS) originates purely from in-plane d_{xy} orbitals and therefore is 2D without any noticeable k_{z} dispersion. Single dispersing features shown in Figure 1b,c represent the spectral function in the vicinity of the Fermi level at different momenta (A and B). Already visually, the distributions of intensity are not equivalent. Tracking the EDC’s maxima close to E_{F} (Figure 1d) one clearly notices the difference: the energy gap is not the same in points A and B since the dispersion bends back at different distances from E_{F} and this distance is equal to Δ. This is a direct evidence for the gap anisotropy. We have determined the values of Δ for many k_{F} along the large Fermi surface and the result is shown in Figure 1e,f (see Supporting online material). An oscillating behavior, with the functional form Δ~Δ_{0} + Δ_{1}cos 4ϕ +… is clearly seen. Even the presence of higher harmonics, cos 8ϕ (~12%) and cos 12ϕ (~20%) can be noticed as local extrema at ϕ = πn/4 and asymmetric shape of global maxima and minima (see SOM). The latter are oriented towards the sides and the corners of the BZ respectively.
In Figure 2a we show a typical intensity distribution along one of the radial cuts from the corner of the BZ. This time two dispersing features, which supported electron-like FSs above T_{c}, are seen in spite of a finite three-dimensionality due to peculiar orbital composition (mostly d_{xz,yz} but with finite admixture of d_{xy}) of these FS sheets (see SOM). Panels b) and c) of Figure 2 show momentum dependences of both, the peak and leading edge positions for selected angles which define the direction of the radial cut (see inset to Figure 2). From presented results one can see that the gap on the outer FS contour is smaller than on the inner one and that the gaps change in-phase, i.e., both increase when going from ϕ = 0 to the direction towards the Γ-point. This behavior is confirmed by the more detailed scanning of the angle and plotting the angular dependence for the two gaps (Figure 2d). To investigate the gap function on a larger angular scale, we take advantage of the gap in-phase variations and consider in the following the averaged for both electron-like FSs gap. In such a way we increase the signal-to-noise ratio, otherwise significantly reduced by nearly degeneracy of FSs close to the crossings of two ellipses and by matrix-element effects. Large scans (Figure 2e,f) recorded at different excitation energies (effectively, different k_{z}’s) again demonstrate approximately cos 4ϕ behavior with global maxima of the gaps oriented towards the center of the BZ.
Finally, we determine the superconducting energy gap on the small FS at Γ-point. First of all, we note that the third, closest to Γ, hole-like d_{xz,yz} feature strongly disperses towards the Fermi level but never crosses it, approaching as close as 10 meV at particular k_{z}. A detailed photon energy dependent study (not shown) has confirmed this and showed that the middle hole-like feature supports even smaller FS than it was initially thought [7]. The sizeable, BZ dependent intensity distribution seen in the vicinity of Γ-point is caused by the Van Hove singularity, but the actual FS crossing has been found only for certain k_{z} intervals as is demonstrated by Figure 3. Because of finite k_{z}-dispersion (of the order of 10 meV), the spectra will hardly be sensitive to the onset of superconductivity if the top of this band is situated more than 6 meV away from the Fermi level. It is the case, for instance, when using 20 eV and 50 eV photons (Figure 3a). Nevertheless, higher temperature measurements (Figure 3b) do indicate that the band reaches E_{F} resulting in the so-called “shape resonance” [19]. For those k_{z} the feature undergoes a noticeable transformation when crossing T_{c} (Figure 3b,c). The superconducting energy gap of the size of 6 meV opens and is in agreement with the tunneling spectroscopy and ARPES on Co-doped NaFeAs [20,21,22].
In Figure 4a we summarize our study by presenting the gap function schematically for the whole BZ. The largest gap (~6 meV) corresponds to the small hole-like FS at Γ-point. Along the large 2D hole-like FS the gap varies around ~3.4 meV roughly as 0.5 meV*cos 4ϕ being minimal at the direction towards the electron-like FS. The gap on the outer electron pocket is smaller than on the inner one and both vary around ~3.6 meV as 0.5 meV*cos 4ϕ having maximal values at the direction towards Γ-point. Since ARPES is not sensitive to the sign of the gap, we also sketch (Figure 4b) the other possible gap function which would agree with our observations. We now examine to which extent the obtained gap structure corresponds to the popular s± spin-fluctuation scenario for superconductivity in iron pnictides [1,2,3,4,5,6]. There are two main possibilities for the realization of the s± scenario in terms of gap functions. It can be either nodal and have a functional form with dominant cos k_{x} + cos k_{y} term or nodeless and have a functional form with dominant cos k_{x}*cos k_{y} term, depending on the details of the pair interaction. In real space the former corresponds to the direct Fe-Fe exchange interaction while the latter to the next-nearest-neighbor exchange interaction via As atoms. The Fe-Fe distance in LiFeAs is one of the smallest among all families of pnictides and thus the first possibility is more likely. Moreover, many model calculations of the gap function unanimously predict nodal s± behavior for strongly electron doped materials [1,2,3,4,5,6]. This is natural since upon electron doping the size of hole-like FSs becomes negligible in comparison with the size of electron-like FSs, nesting is destroyed and spin-fluctuation mechanism can only be established when dominant interaction between electron-like pockets would change sign of the order parameter between them (in unfolded BZ). The system should adjust the magnitude of the angle-dependent, ±cos 2ϕ gap component along the two electron FSs to minimize the effect of the inter-electron-pocket repulsion [4]. LiFeAs, though being stoichiometric because of large d_{xy} FS, should adopt this scenario for strongly electron-doped systems because the proportion between the d_{xz, yz} originated FSs is exactly like this. Only one of the hole-like FSs with this orbital composition is present (the other one being completely below the E_{F}) whereas the electron-like pockets are very large with absolutely no sign of (π, π)-nesting [7]. These considerations inevitably imply the presence of nodes and anti-phase behavior of the gaps on electron-like FSs of LiFeAs (Figure 4d), which is clearly not the case according to our experiment. Also, in the simplest case of cos k_{x} + cos k_{y} order parameter one would expect the maximal gaps on the large hole-like FS to be oriented in the direction of electron pockets (Figure 4d). Our results demonstrate just the opposite (Figure 4a and Figure 1e,f).
Let us assume that the unlikely, for effectively electron doped IBSC, scenario of nodeless s± order parameter takes place. Indeed, this would fix the in-phase/anti-phase discrepancy and the orientation of the maxima of the gap on the large hole pocket (Figure 4c). However, the orientation of the extrema of the in-phase oscillating gaps on electron FSs would then be in conflict with the experimentally observed one (Figure 4b). It is known that the orbital character of small portions of electron FSs oriented towards Γ-points is d_{xy} and the interorbital pairing with d_{xz, yz} states on hole FSs is weaker than the intraorbital pairing for the major parts of electron pockets. On the contrary, our data show that the gaps on these portions are maximal (Figure 4a,b and Figure 3e–g).
Another ingredient necessary for realization of spin-fluctuation scenario is apparently missing in LiFeAs. Recent neutron-scattering experiments on similarly prepared single crystals demonstrate that the strength of spin fluctuations in LiFeAs is an order of magnitude weaker than e.g., in Co-doped 122 system with hardly any evidence for the neutron resonance [11]. As a consequence, we were not able to find any evidence of electron-magnon coupling in LiFeAs contrary to the case of optimally doped 122 or exemplary case of cuprates [23]. Moreover, the detected energy spectrum of magnetic fluctuations does not contain any features that can explain the dispersion kinks in electronic spectrum observed earlier [10,11,12]. In Figure 3d we show more evidence for strong electron-boson coupling. All typical energy scales derived in the present and previous [10] studies correspond to phonon modes [24], recently detected experimentally for the center of the BZ by Raman scattering [25] (see also SI). In spite of the noticeable renormalization (kinks) implying considerable electron-phonon coupling, the largest gap in LiFeAs is twice larger than in a weak coupling BCS scheme and its momentum dependence is very peculiar implying that conventional electron-phonon coupling mechanism is not operational in this material.
This brings us to an alternative approach to superconductivity in pnictides based on the orbital fluctuations model [13,14]. A general consensus exists regarding the important role of orbital degrees of freedom played in physics of IBSC. Together with the possibility of Fe3d orbital ordering at structural transition [26], one of the most remarkable and robust experimental evidences for this importance is the universal bandwidth renormalization of the factor of 2–3 found in all families of pnictides and chalcogenides [7,27,28]. This renormalization is captured by e.g., DMFT calculations which take into account the Hund’s rule coupling [29,30,31]. It is therefore not surprising that fluctuations of orbital order can drive the pairing. It was shown that for this interaction to be attractive, a moderate electron-phonon coupling should be present [13,14].
The hallmark of the orbital-fluctuations-mediated-by-phonons scenario is the s++ order parameter, i.e., the superconducting gap of one sign for the whole BZ. According to the authors of [13], this superconducting state is likely to be realized exactly in electron-doped IBSC even without impurities (see Figure 4c in [13]). Taking into account the above remark about the classification of LiFeAs in terms of doping and directly determined gap function for all FSs, this is in perfect agreement with our data. The gap function in band representation calculated in [14] (Figure 7) captures all the peculiarities of experimentally observed one: gaps on electron pockets oscillate in phase, their maxima are oriented towards Γ-point and even the orientation of the extrema on large hole-like d_{xy} FS match the experimental observation.
While the details of the orbital fluctuations mechanism in LiFeAs are still to be understood, for instance, which exactly phonons are crucial for realization of this scenario [13,14] or which role is played by the van Hove singularity, intraband nesting of d_{xy} sheet or higher harmonics, implied by the shape of the gap function, our results clearly suggest that this interaction is a most promising alternative to conventional electron-phonon coupling and to conventional spin fluctuations.
Supporting Online Material
Photoemission experiments have been carried out using the synchrotron radiation from the BESSY (Helmholtz-Zentrum Berlin) storage ring. The end-station “1-cubed ARPES” is equipped with the He3 cryostat which allows collecting the angle-resolved spectra at temperatures below 1 K. The overall energy resolution ranged from ~2.5 meV at hν = 15 eV to ~10 meV at hν = 120 eV. All single crystals have been cleaved in UHV exposing the mirror-like surfaces.
Five large (~3 × 2 × 0.5 mm) single crystals of LiFeAs (T_{c} = 18 K) have been used in the current study, four Li11(SF) and one Li11(Sn). All operations on preparation of the large LiFeAs single crystals have been carried out in a dry box in Ar atmosphere. To grow the single crystal of LiFeAs from the melted tin (sample Li11(Sn)) the reagents in molar ratio Li:Fe:As:Sn = 1.15:1:1:24 were mixed in alumina crucible which was inserted into Nb container sealed under 1.5 atm of argon gas. The Nb container was then sealed in an evacuated quartz ampoule and heated to 1163 K, and after that it was slowly cooled down to 853 K. At this temperature, the liquid tin was removed by decantation and then by centrifugation at high temperature. To grow the LiFeAs single crystals by self-flux method (Li11(SF)) the reagents in molar ratio Li:Fe:As = 3:2:3 were inserted to the same package heated up to 1363 K, kept at this temperature for 5 hours and cooled at a rate of 4.5 K/h down to 873 K and then the furnace was switched on. The plate-like single crystals were separated from the flux mechanically. Phase identification was performed by means of X-Ray powder diffraction analysis of the polycrystalline samples, prepared from the single crystals by grinding them in a dry box. The results of tetragonal P4/nmm unit cell refinement (a = 3.7701(15), c = 6.3512(25) Å, V = 90.27(8) Å^{3} for Li11(SF) and a = 3.7680(24), c = 6.339(4)Å, V = 90.00(13) Å^{3} for Li11(Sn)) are in good agreement with the data available in the literature. The molar ratio of Fe:As close to 1:1, as well as the existence of about 0.5 mol. % of tin in the Li11(Sn) crystals have been identified from the EDX data.
Apart from the mentioned in the main text properties, LiFeAs possesses many other remarkable among IBSC characteristics: the residual resistivity ratio is one of the largest, the material crystallizes in a simple tetragonal lattice so that the unfolding of the BZ is not complicated, Fe-As-Fe angle is the sharpest and there is a glide plane between two Li layers resulting in a non-polar cleave. The absence of nesting and thus the replica because of magnetic folding, moderate three-dimensionality and simple orbital composition offer a unique opportunity to study the gap function in this material. The typical k_{F}-EDC and its derivative are shown in Figure S1 together with energy-momentum intensity plots. Well defined quasiparticles allowed us to determine the energy position of the peaks and leading edge midpoints with the precision of ~0.3 meV. The sensitivity of the latter to the superconductivity is demonstrated in Figure S2.
In Figure S3 we show the results of the fitting experimental data from Figure 1e to the periodic function with higher harmonics with all three amplitudes left as free parameters. The obtained fitting function is Δ = 15.69257–0.00037*(cos 4ϕ + 0.12*cos 8ϕ–0.2*cos 12ϕ) indicating the very significant contribution of the higher harmonics. Usually, the impurity scattering is responsible for a moderate contribution, but typical result would be the flattening of the maxima. In the present case the additional features are rather sharp, though not captured by the free parameters fit, and most likely are due to increased range of the pairing interaction. The observed deviations from cos(4ϕ) on the large d_{xy} FS are indeed anomalous since reasonable gap functions would require that the expansion coefficients of the higher-harmonic basis functions decrease rapidly with increasing angular momentum.
One could, in principle, consider intraorbital d_{xy} interaction as dominant since the maxima of the electron FS sheets’ gaps are oriented towards center of the BZ, but then the orientation of the gap maxima on the large hole FS sheet would not match, instead pointing towards possible importance of the intraband scattering (with the coupling constant increased because of the nested character of the large hole pocket).
Two remarks should be made as regards the electron FS in the corner of the BZ. Because of the mutual crossing seen in Figure 2a to occur below the Fermi level, the orbital composition implied by our experiment differs from the one accepted in the literature. The small portions of the d_{xy}-character oriented towards the center correspond now to the inner electron FS, not to the outer. We note, however, that the separation of the electron-like FS to the inner and outer pockets itself is rather symbolic. The degeneracy along the sides of the BZ leading to the crossing of the ellipses from unfolded BZ is indeed lifted by the spin-orbit interaction, as well as the degeneracy of the middle and inner hole bands in the Γ-point, but the experimental splitting is at least an order of magnitude smaller than predicted in the calculations.
Table 1. Phonon modes calculated ([24]), measured at the center of BZ ([25]) and ARPES kink energies from [10] and present study (in meV). |
meV | As ↔ E_{g} | As ↕ A_{1 g} | Fe ↕ B_{1 g} | Fe ↔ E_{g} | Li ↔ E_{g} | Li ↕ A_{1 g} |
---|---|---|---|---|---|---|
Theory [24] | 15.1 | 23.5 | 28.1 | 30 | 36.8 | 44.5 |
Raman [25] | - | 23 | 28–29 | 36 | 37–38 | 41–42 |
ARPES kinks ([10], Figure 3d) | 15, 16 | 21 | 30 | 38 | 38 | 44 |
Acknowledgements
We acknowledge useful discussions with Andrey Chubukov, Ilya Eremin, Igor Mazin, Antonio Bianconi, Carsten Honerkamp, Christian Hess, Hidenori Takagi, Dima Efremov and Sergey Skornyakov. This work was supported by the DFG priority program SPP1458, Grants No. KN393/4, BO1912/2-1. I.M. acknowledges support from the RFBR-DFG (Project No. 10-03-91334).
References
- Hirschfeld, P.J.; Korshunov, M.M.; Mazin, I.I. Gap symmetry and structure of Fe-based superconductors. Rep. Prog. Phys. 2011, 74, 124508:1–44. [Google Scholar]
- Chubukov, A.V. Pairing mechanism in Fe-based superconductors. 2011. Available online: http://arxiv.org/pdf/1110.0052v1.pdf (accessed on 20 March 2012). Unpublished. [Google Scholar]
- Eremin, I.; Chubukov, A.V. Magnetic degeneracy and hidden metallicity of the spin-density-wave state in ferropnictides. Phys. Rev. B 2010, 81, 024511:1–14. [Google Scholar]
- Graser, S.; Maier, T.A.; Hirschfeld, P.J.; Scalapino, D.J. Near-degeneracy of several pairing channels in multiorbital models for the Fe pnictides. New J. Phys. 2009, 11, 02501. [Google Scholar]
- Thomale, R.; Platt, C.; Hu, J.; Honerkamp, C.; Andrei Bernevig, B. Doping-dependent pairing symmetry in the iron-pnictides. Phys. Rev. B 80, 180505:1–4.
- Kuroki, K.; Onari, S.; Arita, R.; Usui, H.; Tanaka, Y.; Kontani, H.; Aoki, H. Unconventional pairing originating from the disconnected fermi surfaces of superconducting LaFeAsO_{1-x}F_{x}. Phys. Rev. Lett. 2008, 101, 087004. [Google Scholar]
- Borisenko, S.V.; Zabolotnyy, V.B.; Evtushinsky, D.V.; Kim, T.K.; Morozov, I.V.; Yaresko, A.N.; Kordyuk, A.A.; Behr, G.; Vasiliev, A.; Follath, R.; Büchner, B. Superconductivity without nesting in LiFeAs. Phys. Rev. Lett. 2010, 105, 067002. [Google Scholar]
- Inosov, D.S.; White, J.S.; Evtushinsky, D.V.; Morozov, I.V.; Cameron, A.; Stockert, U.; Zabolotnyy, V.B.; Kim, T.K.; Kordyuk, A.A.; Borisenko, S.V.; et al. Weak superconducting pairing and a single isotropic energy gap in stoichiometric LiFeAs. Phys. Rev. Lett. 2010, 104, 187001:1–4. [Google Scholar]
- Stockert, U.; Abdel-Hafiez, M.; Evtushinsky, D.V.; Zabolotnyy, V.B.; Wolter, A.U.B.; Wurmehl, S.; Morozov, I.; Klingeler, R.; Borisenko, S.V.; Büchner, B.; Braden, M. Specific heat and angle-resolved photoemission spectroscopy study of the superconducting gaps in LiFeAs. Phys. Rev. B 2011, 83, 224512:1–6. [Google Scholar]
- Kordyuk, A.A.; Zabolotnyy, V.B.; Evtushinsky, D.V.; Kim, T.K.; Morozov, I.V.; Kulić, M.L.; Follath, R.; Behr, G.; Büchner, B.; Borisenko, S.V. Angle-resolved photoemission spectroscopy of superconducting LiFeAs: Evidence for strong electron-phonon coupling. Phys. Rev. B 2011, 83, 134513:1–6. [Google Scholar]
- Qureshi, N.; Steffens, P.; Drees, Y.; Komarek, A.C.; Lamago, D.; Sidis, Y.; Harnagea, L.; Grafe, H.-J.; Wurmehl, S.; Büchner, B.; Braden, M. Incommensurate magnetic excitations in superconducting LiFeAs. 2011. Available online: http://arxiv.org/pdf/1108.6187v1.pdf (accessed on 20 March 2012). Unpublished. [Google Scholar]
- Taylor, A.E.; Pitcher, M.J.; Ewings, R.A.; Perring, T.G.; Clarke, S.J.; Boothroyd, A.T. Spin fluctuations in LiFeAs observed by neutron scattering. Phys. Rev. B 2011, 83, 220514:1–4. [Google Scholar]
- Kontani, H.; Onari, S. Orbital-fluctuation-mediated superconductivity in iron pnictides: Analysis of the five-orbital hubbard-holstein model. Phys. Rev. Lett. 2010, 104, 157001:1–4. [Google Scholar]
- Yanagi, Y.; Yamakawa, Y.; Ono, Y. Two types of s-wave pairing due to magnetic and orbital fluctuations in the two-dimensional 16-band d-p model for iron-based superconductors. Phys. Rev. B 2010, 81, 054518:1–10. [Google Scholar]
- Wang, X.C.; Liu, Q.Q.; Lv, Y.X.; Gao, W.B.; Yang, L.X.; Yu, R.C.; Li, F.Y.; Jin, C.Q. The superconductivity at 18 K in LiFeAs system. Solid State Commun. 2008, 148, 538–540. [Google Scholar]
- Tapp, J.H.; Tang, Z.J.; Lv, B. Sasmal, K.; Lorenz, B.; Chu, P.C.W.; Guloy, A.M. LiFeAs: An intrinsic FeAs-based superconductor with T_{c} = 18 K. Phys. Rev. B 2008, 78, 060505:1–4. [Google Scholar]
- Morozov, I.; Boltalin, A.; Volkova, O.; Vasiliev, A.; Kataeva, O.; Stocker, U.; Abdel-Hafiez, M.; Bombor, D.; Bachmann, A.; Harnagea, L.; et al. Single crystal growth and characterization of superconducting LiFeAs. Cryst. Growth Des. 2010, 10, 4429–4432. [Google Scholar]
- Lankau, A.; Koepernik, K.; Borisenko, S.; Zabolotnyy, V.; Büchner, B.; van den Brink, J.; Eschrig, H. Absence of surface states for LiFeAs investigated using density functional calculations. Phys. Rev. B 2010, 82, 184518:1–5. [Google Scholar]
- Innocenti, D.; Caprara, S.; Poccia, N.; Ricci, A.; Valletta, A.; Bianconi, A. Shape resonance for the gaps near a Lifshitz transition: the effect of electron hopping between layers. Supercond. Sci. Technol. 2011, 24, 015012. [Google Scholar] [CrossRef]
- Hänke, T.; Sykora, S.; Schlegel, R.; Baumann, D.; Harnagea, L.; Wurmehl, S.; Daghofer, M.; Büchner, B.; van den Brink, J.; Hess, C. Probing unconventional superconductivity in LiFeAs by quasiparticle interference. 2012. Available online: http://arxiv.org/pdf/1106.4217v3.pdf (accessed on 20 March 2012). Unpublished. [Google Scholar]
- Takagi, H. Workshop on iron pnictides in Bad Honnef, Germany, 12–13 April, 2011. Unpublished.
- Liu, Z.-H.; Nakayama, K.; Chen, G .-F.; Dong, S.; He, J.-B.; Wang, D.-M.; Xia, T.-L.; Umezawa, K.; Kawahara, T.; Souma, S.; et al. Unconventional superconducting gap in NaFe$_{0.95}$Co$_{0.05}$As observed by ARPES. Phys. Rev. B 2011, 84, 064519:1–5. [Google Scholar]
- Dahm, T.; Hinkov, V.; Borisenko, S.V.; Kordyuk, A.A.; Zabolotnyy, V.B.; Fink, J.; Büchner, B.; Scalapino, D.J.; Hanke, W.; Keimer, B.; et al. Strength of the spin-fluctuation-mediated pairing interaction in a high-temperature superconductor. Nat. Phys. 2009, 5, 217. [Google Scholar]
- Jishi, R.A.; Alyahyaei, H.M. Electronic and lattice dynamical properties of the iron-based superconductors LiFeAs and NaFeAs. Adv. Condens. Matter Phys. 2010, 2010, 804343. [Google Scholar]
- Um, Y.J.; Park, J.T.; Min, B.H.; Song, Y.J.; Kwon, Y.S.; Keimer, B.; Le Tacon, M. Raman scattering study of the lattice dynamics of superconducting LiFeAs. 2011. Available online: http://arxiv.org/pdf/1109.5797.pdf (accessed on 20 March 2012). Unpublished. [Google Scholar]
- Kruger, F.; Kumar, S.; Zaanen, J.; Brink, J. van den. Spin-orbital frustrations and anomalous metallic state in iron-pnictide superconductors. Phys. Rev. B 2009, 79, 054504:1–15. [Google Scholar]
- Zabolotnyy, V.B.; Inosov, D.S.; Evtushinsky, D.V.; Koitzsch, A.; Kordyuk, A.A.; Sun, G.L.; Park, J.T.; Haug, D.; Hinkov, V.; Boris, A.V.; et al. (π, π)-Electronic order in iron arsenide superconductors. Nature 2009, 457, 569–572. [Google Scholar]
- Chen, F.; Zhou, B.; Zhang, Y.; Wei, J.; Ou, H.-W.; Zhao, J.-F.; He, C.; Ge, Q.-Q.; Arita, M.; Shimada, K.; et al. Electronic structure of Fe_{1.04}(Te_{0.66}Se_{0.34}). Phys. Rev. B 2010, 81, 014526. [Google Scholar]
- Yin, Z.P.; Haule, K.; Kotliar, G. Magnetism and charge dynamics in iron pnictides. Nat. Phys. 2011, 7, 294–297. [Google Scholar] [CrossRef]
- Skornyakov, S.L.; Skorikov, N.A.; Lukoyanov, A.V.; Shorikov, A.O.; Anisimov, V.I. LDA+DMFT spectral functions and effective electron mass enhancement in superconductor LaFePO. Phys. Rev. B 2010, 81, 174522:1–6. [Google Scholar]
- Ferber, J.; Foyevtsova, K.; Valenti, R.; Jeschke, H.O. Effects of correlation in LiFeAs. 2011. Available online: http://itp.uni-frankfurt.de/~jeschke/papers/arxiv1111.1620v1.pdf (accessed on 20 March 2012). Unpublished. [Google Scholar]
© 2012 by the authors; licensee MDPI, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).