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Polymers 2017, 9(7), 267; https://doi.org/10.3390/polym9070267

A New Polymer-Based Fluorescent Chemosensor Incorporating Propane-1,3-Dione and 2,5-Diethynylbenzene Moieties for Detection of Copper(II) and Iron(III)

1
Key Laboratory for Organic Electronics & Information Displays (KLOEID) and Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210046, China
2
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
3
College of Geography and Biological Information, Nanjing University of Posts and Telecommunications, Nanjing 210046, China
*
Authors to whom correspondence should be addressed.
Academic Editor: Ying-Ling Liu
Received: 18 May 2017 / Revised: 27 June 2017 / Accepted: 3 July 2017 / Published: 6 July 2017
(This article belongs to the Special Issue Polymeric Membranes)
Full-Text   |   PDF [5093 KB, uploaded 6 July 2017]   |  

Abstract

A novel conjugated polymer (PDBDBM) was developed by the polymerization of 1,4-dioctyloxy-2,5-diethynylbenzene with 1,3-bis(4-bromophenyl)propane-1,3-dione based on Pd-catalyzed Sonogashira-coupling reaction. The obtained polymer PDBDBM exhibited bright green photoluminescence under UV irradiation. According to the metal ion titration experiments, PDBDBM showed high sensitivity and selectivity for detection of Cu2+ and Fe3+ over other metal ions. The fluorescent detection limits of PDBDBM were calculated to be 5 nM for Cu2+ and 0.4 μM for Fe3+ and the Stern–Volmer quenching constant for Cu2+ and Fe3+ were found to be 1.28 × 108 M−1 and 2.40 × 104 M−1, respectively. These results indicated that the polymer can be used as a potential probe for Cu2+ and Fe3+ detection. View Full-Text
Keywords: conjugated polymers; sensor; ion detection; copper(II); iron(III) conjugated polymers; sensor; ion detection; copper(II); iron(III)
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Yang, D.; Dai, C.; Hu, Y.; Liu, S.; Weng, L.; Luo, Z.; Cheng, Y.; Wang, L. A New Polymer-Based Fluorescent Chemosensor Incorporating Propane-1,3-Dione and 2,5-Diethynylbenzene Moieties for Detection of Copper(II) and Iron(III). Polymers 2017, 9, 267.

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