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Polymers 2017, 9(7), 262; https://doi.org/10.3390/polym9070262

Homo- and Copolymerizations of Ethylene and Norbornene Using Bis(β-ketoamino) Titanium Catalysts Containing Pyrazolone Rings

1
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610550, China
2
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China
3
School of Materials Science and Engineering, PCFM Lab, GD HPPC Lab, Sun Yat-sen University, Guangzhou 510275, China
*
Author to whom correspondence should be addressed.
Academic Editor: Changle Chen
Received: 14 June 2017 / Revised: 27 June 2017 / Accepted: 28 June 2017 / Published: 30 June 2017
(This article belongs to the Special Issue Olefin Polymerization and Polyolefin)
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Abstract

A series of bis(β-ketoamino) titanium complexes containing pyrazolone rings (13) have been synthesized, characterized, and used as precursors for homo- and copolymerization of ethylene and norbornene. The titanium complexes activated with methylaluminoxane (MAO) exhibited good activities for homopolymerization of ethylene (E) to produce linear polyethylenes (PEs). Ethylene–norbornene copolymers (E–N) were also prepared by these catalysts with moderate activities, and influences of ligand substituents and norbornene addition on copolymer microstructure were studied in detail. Microstructure analysis of the E–N copolymers by 13C NMR and differential scanning calorimetry (DSC) techniques showed that alternating (ENEN) and isolated (ENEE) norbornene predominately appeared in the copolymer chain, and the NN dyad and NNN triad sequences were also present in the copolymers obtained by the less bulky catalyst 1. View Full-Text
Keywords: bis(β-ketoamino) titanium catalyst; ethylene; norbornene; polymerization bis(β-ketoamino) titanium catalyst; ethylene; norbornene; polymerization
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Pei, L.; He, S.; Gao, J.; Liao, H.; Gao, H. Homo- and Copolymerizations of Ethylene and Norbornene Using Bis(β-ketoamino) Titanium Catalysts Containing Pyrazolone Rings. Polymers 2017, 9, 262.

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