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Polymers 2016, 8(3), 62; doi:10.3390/polym8030062

Polydopamine Particle as a Particulate Emulsifier

1
Department of Applied Chemistry, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan
2
Division of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
*
Author to whom correspondence should be addressed.
Academic Editor: To Ngai
Received: 23 January 2016 / Revised: 9 February 2016 / Accepted: 18 February 2016 / Published: 26 February 2016
(This article belongs to the Special Issue Selected Papers from ASEPFPM2015)
View Full-Text   |   Download PDF [13824 KB, uploaded 26 February 2016]   |  

Abstract

“Pickering-type” emulsions were prepared using polydopamine (PDA) particles as a particulate emulsifier and n-dodecane, methyl myristate, toluene or dichloromethane as an oil phase. All the emulsions prepared were oil-in-water type and an increase of PDA particle concentration decreased oil droplet diameter. The PDA particles adsorbed to oil–water interface can be crosslinked using poly(ethylene imine) as a crosslinker, and the PDA particle-based colloidosomes were successfully fabricated. Scanning electron microscopy studies of the colloidosomes after removal of inner oil phase revealed a capsule morphology, which is strong evidence for the attachment of PDA particles at the oil–water interface thereby stabilizing the emulsion. The colloidosomes after removal of inner oil phase could retain their capsule morphology, even after sonication. On the other hand, the residues obtained after oil phase removal from the PDA particle-stabilized emulsion prepared in the absence of any crosslinker were broken into small fragments of PDA particle flocs after sonication. View Full-Text
Keywords: Pickering emulsion; polydopamine; oil–water interface; crosslinking; colloidosome Pickering emulsion; polydopamine; oil–water interface; crosslinking; colloidosome
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Nishizawa, N.; Kawamura, A.; Kohri, M.; Nakamura, Y.; Fujii, S. Polydopamine Particle as a Particulate Emulsifier. Polymers 2016, 8, 62.

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